In this study,the scale and internal oxidation of hot-rolled ultra-high strength steel sheets were characterized.It was found that both the formation of the scale and the internal oxidation of Si and Mn depended on th...In this study,the scale and internal oxidation of hot-rolled ultra-high strength steel sheets were characterized.It was found that both the formation of the scale and the internal oxidation of Si and Mn depended on the coiling temperature and position of the steel sample on the strip coil.At a relatively high coiling temperature,a large amount of internal oxidation was observed on the samples cut from the middle of the coil.The depth of the internal oxidation zone exceeded 10 μm and a thin iron layer covering the scale was observed in some cases.Pickling and cold-rolling experiments were conducted on selected samples.Scale pickling was found to be greatly delayed by the formation of an iron layer,which frequently resulted in under-pickled defects.In addition,pickling of the entire internal oxidation zone was difficult,except at the grain boundaries,where the degree of internal Si and Mn oxidation was enriched.The surface of the cold-rolled steel sheet was ruined by the remaining oxidation zone in the subsurface of the pickled steel.The internal oxidation of hot-rolled ultra-high strength steel must be precisely controlled to improve the subsequent surface quality of cold-rolled steel.展开更多
Since the 2050 mm hot strip mill was put into operation in 1989, Baosteel has made great achievements in increasing productivity, developing new process technologies and steel products and improving product quality. I...Since the 2050 mm hot strip mill was put into operation in 1989, Baosteel has made great achievements in increasing productivity, developing new process technologies and steel products and improving product quality. In the past 18 years from 1989 to 2007 ,Baosteel has constructed five hot strip mills with a total annual capacity of 19.8 Mt. Indices for technology standards, product categories and steel grades, product quality, both technically and economically, take the lead domestically or reached the world class level. As there are many hot strip mills that expected to be put into operation by the end of 2010 ,the overall annual capacity will exceed 30 Mt ,and the product will cover grain oriented (GO) Si steels and alloyed steels.展开更多
The analysis of bending in finishing rolling was performed. An asymmetrical rolling force model was established, and the upper and lower neutral points were determined. Thc bending which resulted from the asymmetrical...The analysis of bending in finishing rolling was performed. An asymmetrical rolling force model was established, and the upper and lower neutral points were determined. Thc bending which resulted from the asymmetrical rolling force at the roll gap was studied and related flexibility equations were proposed according to elastic mechanics. Moreover, material mechanics was used to analyze the effects of temperature difference and self-weight on the bending out of the roll gap, and the flexibility equations were constructed. The main factors on bending were summed up, and the bending rule in the rolling could be obtained. In addition practical calculation was made with the production data of ribbon steel from Laiwu Iron & Steel Group Co. Ltd.展开更多
为提高热轧态0Cr21A16合金板材的组织均匀性和塑性,以改善其高温性能及冷加工特性,分析研究了不同温度的热处理试验及组织性能。采用光学显微镜、X射线衍射仪、Gleeble高温热拉伸实验、扫描电镜和纳米压痕仪等研究了热处理前后0Cr21Al6...为提高热轧态0Cr21A16合金板材的组织均匀性和塑性,以改善其高温性能及冷加工特性,分析研究了不同温度的热处理试验及组织性能。采用光学显微镜、X射线衍射仪、Gleeble高温热拉伸实验、扫描电镜和纳米压痕仪等研究了热处理前后0Cr21Al6合金板材的显微组织和力学性能。结果表明,通过热处理的方式改善0Cr21Al6合金板材的组织均匀性,在960℃保温6 min 40 s后快速冷却,晶粒平均尺寸为42μm,整体的晶粒尺寸相对于940、980、1000、1020℃热处理后较为均匀、细小,硬度和塑性达到最佳匹配,断裂韧度KIC在960℃处理下达到最佳,拥有最佳的综合性能,可有效避免生产过程中材料的脆性断裂问题。另外Gleeble实验显示1000℃以上的热处理温度不再适合于热加工。展开更多
Descaling of hot-rolled stainless steel is generally implemented through pickling process in HNO_3-HF mixed acids,which induces severe environmental concerns of nitrogen oxide(NOx)gases and nitrites.According to the...Descaling of hot-rolled stainless steel is generally implemented through pickling process in HNO_3-HF mixed acids,which induces severe environmental concerns of nitrogen oxide(NOx)gases and nitrites.According to the electrochemical measurement,the mass loss test and the appearance analysis,a new pickling process which employed HCl-based solution was proposed and evaluated to provide theoretical basis for the development of environment-friendly and highly effective pickling process.Under the experimental condition,the HCl-based solution can compete with ordinary HNO_3-HF mixed acids in terms of pickling efficiency,surface integrity and the removal of Crdepleted layer.The descaling process of 430hot-rolled stainless steel in the HCl-based solution consisted of three steps.The descaling solution penetrated the oxide scales into the underlying metal,dissolving the Cr-depleted layer and part of substrates.The oxide scales peeled off from the stainless steel and a polished and smooth surface was exposed.The descaled stainless steel was dissolved uniformly in the HCl-based solution;therefore,the pickling duration was vital for desired surface integrity.Under the static condition,the appropriate descaling time of 430 hotrolled stainless steel in HCl-based solution was 400 s.展开更多
文摘In this study,the scale and internal oxidation of hot-rolled ultra-high strength steel sheets were characterized.It was found that both the formation of the scale and the internal oxidation of Si and Mn depended on the coiling temperature and position of the steel sample on the strip coil.At a relatively high coiling temperature,a large amount of internal oxidation was observed on the samples cut from the middle of the coil.The depth of the internal oxidation zone exceeded 10 μm and a thin iron layer covering the scale was observed in some cases.Pickling and cold-rolling experiments were conducted on selected samples.Scale pickling was found to be greatly delayed by the formation of an iron layer,which frequently resulted in under-pickled defects.In addition,pickling of the entire internal oxidation zone was difficult,except at the grain boundaries,where the degree of internal Si and Mn oxidation was enriched.The surface of the cold-rolled steel sheet was ruined by the remaining oxidation zone in the subsurface of the pickled steel.The internal oxidation of hot-rolled ultra-high strength steel must be precisely controlled to improve the subsequent surface quality of cold-rolled steel.
文摘Since the 2050 mm hot strip mill was put into operation in 1989, Baosteel has made great achievements in increasing productivity, developing new process technologies and steel products and improving product quality. In the past 18 years from 1989 to 2007 ,Baosteel has constructed five hot strip mills with a total annual capacity of 19.8 Mt. Indices for technology standards, product categories and steel grades, product quality, both technically and economically, take the lead domestically or reached the world class level. As there are many hot strip mills that expected to be put into operation by the end of 2010 ,the overall annual capacity will exceed 30 Mt ,and the product will cover grain oriented (GO) Si steels and alloyed steels.
文摘The analysis of bending in finishing rolling was performed. An asymmetrical rolling force model was established, and the upper and lower neutral points were determined. Thc bending which resulted from the asymmetrical rolling force at the roll gap was studied and related flexibility equations were proposed according to elastic mechanics. Moreover, material mechanics was used to analyze the effects of temperature difference and self-weight on the bending out of the roll gap, and the flexibility equations were constructed. The main factors on bending were summed up, and the bending rule in the rolling could be obtained. In addition practical calculation was made with the production data of ribbon steel from Laiwu Iron & Steel Group Co. Ltd.
文摘为提高热轧态0Cr21A16合金板材的组织均匀性和塑性,以改善其高温性能及冷加工特性,分析研究了不同温度的热处理试验及组织性能。采用光学显微镜、X射线衍射仪、Gleeble高温热拉伸实验、扫描电镜和纳米压痕仪等研究了热处理前后0Cr21Al6合金板材的显微组织和力学性能。结果表明,通过热处理的方式改善0Cr21Al6合金板材的组织均匀性,在960℃保温6 min 40 s后快速冷却,晶粒平均尺寸为42μm,整体的晶粒尺寸相对于940、980、1000、1020℃热处理后较为均匀、细小,硬度和塑性达到最佳匹配,断裂韧度KIC在960℃处理下达到最佳,拥有最佳的综合性能,可有效避免生产过程中材料的脆性断裂问题。另外Gleeble实验显示1000℃以上的热处理温度不再适合于热加工。
基金Item Sponsored by National Natural Science Foundation of China(51304042,51374059)New Century Excellent Talents in University of China(NCET-11-0077)
文摘Descaling of hot-rolled stainless steel is generally implemented through pickling process in HNO_3-HF mixed acids,which induces severe environmental concerns of nitrogen oxide(NOx)gases and nitrites.According to the electrochemical measurement,the mass loss test and the appearance analysis,a new pickling process which employed HCl-based solution was proposed and evaluated to provide theoretical basis for the development of environment-friendly and highly effective pickling process.Under the experimental condition,the HCl-based solution can compete with ordinary HNO_3-HF mixed acids in terms of pickling efficiency,surface integrity and the removal of Crdepleted layer.The descaling process of 430hot-rolled stainless steel in the HCl-based solution consisted of three steps.The descaling solution penetrated the oxide scales into the underlying metal,dissolving the Cr-depleted layer and part of substrates.The oxide scales peeled off from the stainless steel and a polished and smooth surface was exposed.The descaled stainless steel was dissolved uniformly in the HCl-based solution;therefore,the pickling duration was vital for desired surface integrity.Under the static condition,the appropriate descaling time of 430 hotrolled stainless steel in HCl-based solution was 400 s.