The surfaces of X80 pipeline steel welded joints were processed with a CO2 laser, and the effects of laser heat treatment (LHT) on H2S stress corrosion in the National Association of Corrosion Engineers (NACE) sol...The surfaces of X80 pipeline steel welded joints were processed with a CO2 laser, and the effects of laser heat treatment (LHT) on H2S stress corrosion in the National Association of Corrosion Engineers (NACE) solution were analyzed by a slow strain rate test. The fracture morphologies and chemical components of corrosive products before and after LHT were analyzed by scanning electron microscopy and energy-dispersive spectroscopy, respectively, and the mechanism of LHT on stress corrosion cracking was discussed. Results showed that the fracture for welded joints was brittle in its original state, while it was transformed to a ductile fracture after LHT. The tendencies of hydrogen-induced corrosion were reduced, and the stress corrosion sensitivity index decreased from 35.2% to 25.3%, indicating that the stress corrosion resistance of X80 pipeline steel welded joints has been improved by LHT.展开更多
Based on welding thermal simulation on Nb-microaUoyed XSO pipeline stee! using Gleeble-3500 thermal simulation equipment, microstlttcture and impact toughness in coarse grain heat-affected zone (CGHAZ) under differe...Based on welding thermal simulation on Nb-microaUoyed XSO pipeline stee! using Gleeble-3500 thermal simulation equipment, microstlttcture and impact toughness in coarse grain heat-affected zone (CGHAZ) under different welding parameters were investigated in this paper. The results show that high heat inputs with low preheats or low heat inputs with high preheats should be applied to achieve high impact toughness. Coarse original austenite grains may lower impact toughness. CGHAZ microstructure is mostly composed of upper bainite, granular bainite and lath bainite. The phase composition of microstructure and the quantity, size, shape of M/A constituents both have effects on impact toughness.展开更多
In this paper,the transportation economy of two heated crude oil pipelines laid in one ditch is analyzed by taking into account the influence of operating temperature,interval between two pipelines,and distance betwee...In this paper,the transportation economy of two heated crude oil pipelines laid in one ditch is analyzed by taking into account the influence of operating temperature,interval between two pipelines,and distance between two heating stations on the heating energy consumption.To analyze the transportation economy,the two heated crude oil pipelines laid in one ditch are simulated under four operating conditions based on an unstructured finite volume method.Compared with laying two crude oil pipelines separately in two ditches,the results attest notably higher soil temperature,meaning reduced heat dissipation of each pipeline by laying two pipelines in one ditch.It is inferred that for the same desired oil temperature at the inlet of the next heating station,laying two pipelines in one ditch requires lower oil temperature at the outlet of heating station,indicating decreased energy cost at the heating station and improved transportation economy.Then economy analysis of four configurations of laying two pipelines in one ditch is performed.By comparing the results of four conditions,the interval between two pipelines of 1.2 m is found to save the energy most efficiently,which is as large as 26.6%compared with that of laying two pipelines in two separate ditches.In addition,narrowing the pipeline interval and extending the distance between heating stations is beneficial to save heating energy.This study is expected to provide valuable guidance for operation optimization of heated crude oil pipelines.展开更多
A mathematical model for one-dimensional heat transfer in pipelines undergoing freezing induced by liquid nitrogen is elaborated.The basic premise of this technology is that the content within a pipeline is frozen to ...A mathematical model for one-dimensional heat transfer in pipelines undergoing freezing induced by liquid nitrogen is elaborated.The basic premise of this technology is that the content within a pipeline is frozen to form a plug or two plugs at a position upstream and downstream from a location where work a modification or a repair must be executed.Based on the variable separation method,the present model aims to solve the related coupled heat conduction and moving-boundary phase change problem.An experiment with a 219 mm long pipe,where water was taken as the plugging agent,is presented to demonstrate the relevance and reliability of the proposed model(results show that the error is within 18%).Thereafter,the model is applied to predict the cooling and freezing process of pipelines with different inner diameters at different liquid nitrogen refrigeration temperatures when water is used as the plugging agent.展开更多
The relationship between the microstructure and toughness of welding heat-affected zone in XSO grade pipeline steels is studied. It is found that the intercritical reheated coarse-grained heat-affected zone (ICCGHAZ...The relationship between the microstructure and toughness of welding heat-affected zone in XSO grade pipeline steels is studied. It is found that the intercritical reheated coarse-grained heat-affected zone (ICCGHAZ) of experimental steels has the lowest toughness values when the secondary peak temperature is at intercritical ( α + γ ) region during multi-pass welding. The local embrittlement is mainly attributed to the morphology, amount and size of M-A constituent. It is also found that the microstructural inhabitanee at ICCGHAZ has a deleterious effect on the toughness. On the basis of above experimental results, it is suggested that the local embrittlement should be prevented by using pre-heating thermal cycle which could eliminate the microstructural inhabitance and using post-heating thermal cycle which could improve the morphology, amount and size of MA constituent.展开更多
The influence of the secondary thermal cycle on the microstructure of coarse grain heat-affected zone in an XIO0 pipeline steel was investigated by means of a thermal simulation technique and microscopic analysis meth...The influence of the secondary thermal cycle on the microstructure of coarse grain heat-affected zone in an XIO0 pipeline steel was investigated by means of a thermal simulation technique and microscopic analysis method. The property of coarse grain heat-affected zone was characterized by Charpy V-Notch impact properties testing. The results indicated that the experimental steel exhibited local brittleness of intercritically reheated coarse-grained heat-affected zone when the peak tempera- ture of secondary thermal cycle was in the range of two phases region ( ~ and 3/). There were two main reasons for the local brittleness. The first was that the microstructures of intercritically reheated coarse-grained heat-affected zone were not fined although partial grain recrystallization occurred. The second was that M-A islands, which had the higher content, larger size and higher hardness, existed in intercritically reheated coarse-grained heat-affected zone.展开更多
The effects of alloying elements in welding wires and submerged arc welding process on the microstructures and low-temperature impact toughness of weld metals have been investigated. The results indicate that the opti...The effects of alloying elements in welding wires and submerged arc welding process on the microstructures and low-temperature impact toughness of weld metals have been investigated. The results indicate that the optimal contents of alloying elements in welding wires can improve the low-temperature impact toughness of weld metals because the proeutectoid ferrite and bainite formations can be suppressed, and the fraction of acicular ferrite increases. However, the contents of alloying elements need to vary along with the welding heat input. With the increase in welding heat input, the contents of alloying elements in welding wires need to be increased accordingly. The microstructures mainly consisting of acicular ferrite can be obtained in weld metals after four-wire submerged arc welding using the wires with a low carbon content and appropriate contents of Mn, Mo, Ti-B, Cu, Ni, and RE, resulting in the high low-temperature impact toughness of weld metals.展开更多
Buried pipelines are widely used for transporting oil in remote cold regions. However, the warm oil can induce considerable thermal influence on the surrounding frozen soils and result in severe maintenance problems. ...Buried pipelines are widely used for transporting oil in remote cold regions. However, the warm oil can induce considerable thermal influence on the surrounding frozen soils and result in severe maintenance problems. This paper presents a case study of the thermal influence of ponding and buried warm-oil pipelines on permafrost along the China-Russia Crude Oil Pipeline(CRCOP) in Northeast China. Since its operation in 2011, the operation of the warm-oil pipelines has led to rapid warming and thawing of the surrounding permafrost and development of sizable ponding along the pipeline route,which, in return, exacerbates the permafrost degradation. A field study was conducted along a 400-km long segment of the CRCOP in permafrost regions of Northeast China to collect the location and size information of ponding. A two-dimensional heat transfer model coupled with phase change was established to analyze the thermal influence of ponding and the operation of warm-oil pipelines on the surrounding permafrost. In-situ measured ground temperatures from a monitoring site were obtained to validate the numerical model. The simulation results show that ponding accelerates the development of the thaw bulb around the pipeline. The maximum thaw depth below the pipeline increases from 4 m for the case without ponding to 9 m for the case with ponding after 50 years of operation, and ponding directly above the pipe induces the maximum thaw depth. Engineering measures should be adopted to control the size or even eliminate surface water-rich ponding for the long-term performance of buried warm-oil pipelines.展开更多
The chamber device was designed and set up to simulate the in-service welding. The results show : the t8/5 , t8/3 and inner wall peak temperature Tp decrease with the cooling rate increases. The welding energy is car...The chamber device was designed and set up to simulate the in-service welding. The results show : the t8/5 , t8/3 and inner wall peak temperature Tp decrease with the cooling rate increases. The welding energy is carried off by flowing medium, the cooling rate increases, and many unbalanced microstructures such as granular bainite, martensite and M-A generate ; it worsens the properties of HAZ. Under air-cooling, the cooling rate is slow, the austenite grain grows obviously, the lath ferrite crosses the whole austenite, and it causes the hardness value is also big. The change of HAZ width is not obvious with the increase of cooling rate; and burn-through is not susceptible to the cooling rate. The quench microstructures increase and the hydrogen does not outflow from the HAZ easily when increase the cooling rate, so the susceptibility of hydrogen cracking increases.展开更多
Transportation of petroleum products through pipeline presents considerable risks including wax formation and deposition as a result of heat loss of fluids, which is harmful to the flow due to the reduced inner diamet...Transportation of petroleum products through pipeline presents considerable risks including wax formation and deposition as a result of heat loss of fluids, which is harmful to the flow due to the reduced inner diameter or totally blocked pipelines in extreme cases. The production interruption due to blocked pipelines can cause colossal financial loss. Therefore, in order to diminish those adverse effects, it is critical that pipeline design for flow assurance should be considered. Flow assurance is a relatively new field in oil and gas industry, it means that the flow of hydrocarbon stream from one point to another must be ensured successfully and economically. Although flow assurance is extremely diverse, encompassing many discrete and specialized subjects and bridging across the full gamut of engineering disciplines, our work concentrated principally on the study of wax deposit in the pipelines. The main purpose of this paper is to focus on the aspect of material in pipeline design and the selection of thermal insulation coatings. Furthermore, operating parameters such as pressure, temperature and flowrate will be examined to achieve optimum results. For the case study in this paper, the pipeline connecting Ca NguVang Oilfield’s Wellhead Platform (WHP) to the Central Processing Platform of Bach Ho Oilfield (CPP-3) in Vietnam will be studied. Hence, this work covers several aspects, namely the theoretical study, the modeling using Excel as well as using specialized software OLGA, and finally the application for a real case in the petroleum industry in Vietnam.展开更多
This paper reports the outcome of a study investigating four electrical heat-tracing strategies that can be employed to avoid wax deposition in subsea flowlines transporting untreated crude oil from subsea wells to a ...This paper reports the outcome of a study investigating four electrical heat-tracing strategies that can be employed to avoid wax deposition in subsea flowlines transporting untreated crude oil from subsea wells to a host installation. The strategies, described in the paper, are distinct by the configuration of deploying the heat tracing along the pipe and by the activation schedule (continuous or alternating heating cycles). The study demonstrates quantitatively that the electrical power required for maintaining wax-free flow depends strongly on the employed strategy. The complex thermo-hydraulic flow was modeled using a commercial Dynamic Multiphase Flow Simulator with wax deposition option and thermal insulation as an input parameter. In conclusion, the paper ranks the strategies according to their computed energy efficiency, thus providing quantitative benchmarks for preliminary wax control assessment.展开更多
In this study, the microstructure evolution and corrosion resistance in O. 5 M Na2CO3 - 1 M NaHCO3 solution of X80 high-deformability ( X8OHD ) pipeline steel coarse-grained heat-affected zone (CGHAZ) with several...In this study, the microstructure evolution and corrosion resistance in O. 5 M Na2CO3 - 1 M NaHCO3 solution of X80 high-deformability ( X8OHD ) pipeline steel coarse-grained heat-affected zone (CGHAZ) with several heat input levels were investigated. It is shown that the microstructure of CGHAZ changes from bainite ferrite to granular bainite as the heat input increasing. In addition, the corrosion resistance and the stability of passive film of base material are better than those of CGHAZ with several heat input levels. Too small or too big heat input is inadvisable and better corrosion resistance of CGHAZ is attained when heat input is 30 kJ/cm.展开更多
At present, the main attention of researchers is paid to the deterioration of heat transfer when heating the outer surface of the pipe with the liquid or steam, flowing inside it, in the presence of films or deposits ...At present, the main attention of researchers is paid to the deterioration of heat transfer when heating the outer surface of the pipe with the liquid or steam, flowing inside it, in the presence of films or deposits on its inner surface. However, when pipe is heating by heat carrier medium, flowing inside it, film on the inner pipe surface serve a dual protective function, protecting the pipe from corrosion and reducing its thermal stress. The article represents the results of the computational analysis of protective films influence on the thermal stressed state of headers and steam pipelines of combined-cycle power plants (CCPP) heat-recovery steam generators at different transient operating conditions particularly at startups from different initial temperature states and thermal shock. It is shown that protective films have a significant influence on the stresses magnitude and damage accumulation mainly for great temperature disturbances (for thermal shock). Calculations were carried out at various thicknesses of films and assuming that their thermal conductivity less than thermal conductivity of the steam pipelines metal.展开更多
基金financially supported by the Chief Expert (Engineer) Project of Jiangsu Provincial Association for Science (No. 2012-09)
文摘The surfaces of X80 pipeline steel welded joints were processed with a CO2 laser, and the effects of laser heat treatment (LHT) on H2S stress corrosion in the National Association of Corrosion Engineers (NACE) solution were analyzed by a slow strain rate test. The fracture morphologies and chemical components of corrosive products before and after LHT were analyzed by scanning electron microscopy and energy-dispersive spectroscopy, respectively, and the mechanism of LHT on stress corrosion cracking was discussed. Results showed that the fracture for welded joints was brittle in its original state, while it was transformed to a ductile fracture after LHT. The tendencies of hydrogen-induced corrosion were reduced, and the stress corrosion sensitivity index decreased from 35.2% to 25.3%, indicating that the stress corrosion resistance of X80 pipeline steel welded joints has been improved by LHT.
文摘Based on welding thermal simulation on Nb-microaUoyed XSO pipeline stee! using Gleeble-3500 thermal simulation equipment, microstlttcture and impact toughness in coarse grain heat-affected zone (CGHAZ) under different welding parameters were investigated in this paper. The results show that high heat inputs with low preheats or low heat inputs with high preheats should be applied to achieve high impact toughness. Coarse original austenite grains may lower impact toughness. CGHAZ microstructure is mostly composed of upper bainite, granular bainite and lath bainite. The phase composition of microstructure and the quantity, size, shape of M/A constituents both have effects on impact toughness.
文摘In this paper,the transportation economy of two heated crude oil pipelines laid in one ditch is analyzed by taking into account the influence of operating temperature,interval between two pipelines,and distance between two heating stations on the heating energy consumption.To analyze the transportation economy,the two heated crude oil pipelines laid in one ditch are simulated under four operating conditions based on an unstructured finite volume method.Compared with laying two crude oil pipelines separately in two ditches,the results attest notably higher soil temperature,meaning reduced heat dissipation of each pipeline by laying two pipelines in one ditch.It is inferred that for the same desired oil temperature at the inlet of the next heating station,laying two pipelines in one ditch requires lower oil temperature at the outlet of heating station,indicating decreased energy cost at the heating station and improved transportation economy.Then economy analysis of four configurations of laying two pipelines in one ditch is performed.By comparing the results of four conditions,the interval between two pipelines of 1.2 m is found to save the energy most efficiently,which is as large as 26.6%compared with that of laying two pipelines in two separate ditches.In addition,narrowing the pipeline interval and extending the distance between heating stations is beneficial to save heating energy.This study is expected to provide valuable guidance for operation optimization of heated crude oil pipelines.
文摘A mathematical model for one-dimensional heat transfer in pipelines undergoing freezing induced by liquid nitrogen is elaborated.The basic premise of this technology is that the content within a pipeline is frozen to form a plug or two plugs at a position upstream and downstream from a location where work a modification or a repair must be executed.Based on the variable separation method,the present model aims to solve the related coupled heat conduction and moving-boundary phase change problem.An experiment with a 219 mm long pipe,where water was taken as the plugging agent,is presented to demonstrate the relevance and reliability of the proposed model(results show that the error is within 18%).Thereafter,the model is applied to predict the cooling and freezing process of pipelines with different inner diameters at different liquid nitrogen refrigeration temperatures when water is used as the plugging agent.
基金This work was supported by the National Natural Science Foundation of China(No. 50874090).
文摘The relationship between the microstructure and toughness of welding heat-affected zone in XSO grade pipeline steels is studied. It is found that the intercritical reheated coarse-grained heat-affected zone (ICCGHAZ) of experimental steels has the lowest toughness values when the secondary peak temperature is at intercritical ( α + γ ) region during multi-pass welding. The local embrittlement is mainly attributed to the morphology, amount and size of M-A constituent. It is also found that the microstructural inhabitanee at ICCGHAZ has a deleterious effect on the toughness. On the basis of above experimental results, it is suggested that the local embrittlement should be prevented by using pre-heating thermal cycle which could eliminate the microstructural inhabitance and using post-heating thermal cycle which could improve the morphology, amount and size of MA constituent.
基金This work was supported by the National Natural Science Foundation of China( No. 50874090).
文摘The influence of the secondary thermal cycle on the microstructure of coarse grain heat-affected zone in an XIO0 pipeline steel was investigated by means of a thermal simulation technique and microscopic analysis method. The property of coarse grain heat-affected zone was characterized by Charpy V-Notch impact properties testing. The results indicated that the experimental steel exhibited local brittleness of intercritically reheated coarse-grained heat-affected zone when the peak tempera- ture of secondary thermal cycle was in the range of two phases region ( ~ and 3/). There were two main reasons for the local brittleness. The first was that the microstructures of intercritically reheated coarse-grained heat-affected zone were not fined although partial grain recrystallization occurred. The second was that M-A islands, which had the higher content, larger size and higher hardness, existed in intercritically reheated coarse-grained heat-affected zone.
基金supported by the Research and Development Project of Science and Technology of Hebei Province, China (No.03212211D and No.002121186D)
文摘The effects of alloying elements in welding wires and submerged arc welding process on the microstructures and low-temperature impact toughness of weld metals have been investigated. The results indicate that the optimal contents of alloying elements in welding wires can improve the low-temperature impact toughness of weld metals because the proeutectoid ferrite and bainite formations can be suppressed, and the fraction of acicular ferrite increases. However, the contents of alloying elements need to vary along with the welding heat input. With the increase in welding heat input, the contents of alloying elements in welding wires need to be increased accordingly. The microstructures mainly consisting of acicular ferrite can be obtained in weld metals after four-wire submerged arc welding using the wires with a low carbon content and appropriate contents of Mn, Mo, Ti-B, Cu, Ni, and RE, resulting in the high low-temperature impact toughness of weld metals.
基金supported by the Strategic Priority Research Program of Chinese Academy of Sciences(Grant No.XDA2003020102)the China Postdoctoral Science Foundation(No.2019M653797)+1 种基金the National Natural Science Foundation of China(No.41630636 and No.41772325)the Major Program of the Bureau of International Cooperation,the Chinese Academy of Sciences(131B62KYSB20170012).
文摘Buried pipelines are widely used for transporting oil in remote cold regions. However, the warm oil can induce considerable thermal influence on the surrounding frozen soils and result in severe maintenance problems. This paper presents a case study of the thermal influence of ponding and buried warm-oil pipelines on permafrost along the China-Russia Crude Oil Pipeline(CRCOP) in Northeast China. Since its operation in 2011, the operation of the warm-oil pipelines has led to rapid warming and thawing of the surrounding permafrost and development of sizable ponding along the pipeline route,which, in return, exacerbates the permafrost degradation. A field study was conducted along a 400-km long segment of the CRCOP in permafrost regions of Northeast China to collect the location and size information of ponding. A two-dimensional heat transfer model coupled with phase change was established to analyze the thermal influence of ponding and the operation of warm-oil pipelines on the surrounding permafrost. In-situ measured ground temperatures from a monitoring site were obtained to validate the numerical model. The simulation results show that ponding accelerates the development of the thaw bulb around the pipeline. The maximum thaw depth below the pipeline increases from 4 m for the case without ponding to 9 m for the case with ponding after 50 years of operation, and ponding directly above the pipe induces the maximum thaw depth. Engineering measures should be adopted to control the size or even eliminate surface water-rich ponding for the long-term performance of buried warm-oil pipelines.
文摘The chamber device was designed and set up to simulate the in-service welding. The results show : the t8/5 , t8/3 and inner wall peak temperature Tp decrease with the cooling rate increases. The welding energy is carried off by flowing medium, the cooling rate increases, and many unbalanced microstructures such as granular bainite, martensite and M-A generate ; it worsens the properties of HAZ. Under air-cooling, the cooling rate is slow, the austenite grain grows obviously, the lath ferrite crosses the whole austenite, and it causes the hardness value is also big. The change of HAZ width is not obvious with the increase of cooling rate; and burn-through is not susceptible to the cooling rate. The quench microstructures increase and the hydrogen does not outflow from the HAZ easily when increase the cooling rate, so the susceptibility of hydrogen cracking increases.
文摘Transportation of petroleum products through pipeline presents considerable risks including wax formation and deposition as a result of heat loss of fluids, which is harmful to the flow due to the reduced inner diameter or totally blocked pipelines in extreme cases. The production interruption due to blocked pipelines can cause colossal financial loss. Therefore, in order to diminish those adverse effects, it is critical that pipeline design for flow assurance should be considered. Flow assurance is a relatively new field in oil and gas industry, it means that the flow of hydrocarbon stream from one point to another must be ensured successfully and economically. Although flow assurance is extremely diverse, encompassing many discrete and specialized subjects and bridging across the full gamut of engineering disciplines, our work concentrated principally on the study of wax deposit in the pipelines. The main purpose of this paper is to focus on the aspect of material in pipeline design and the selection of thermal insulation coatings. Furthermore, operating parameters such as pressure, temperature and flowrate will be examined to achieve optimum results. For the case study in this paper, the pipeline connecting Ca NguVang Oilfield’s Wellhead Platform (WHP) to the Central Processing Platform of Bach Ho Oilfield (CPP-3) in Vietnam will be studied. Hence, this work covers several aspects, namely the theoretical study, the modeling using Excel as well as using specialized software OLGA, and finally the application for a real case in the petroleum industry in Vietnam.
文摘This paper reports the outcome of a study investigating four electrical heat-tracing strategies that can be employed to avoid wax deposition in subsea flowlines transporting untreated crude oil from subsea wells to a host installation. The strategies, described in the paper, are distinct by the configuration of deploying the heat tracing along the pipe and by the activation schedule (continuous or alternating heating cycles). The study demonstrates quantitatively that the electrical power required for maintaining wax-free flow depends strongly on the employed strategy. The complex thermo-hydraulic flow was modeled using a commercial Dynamic Multiphase Flow Simulator with wax deposition option and thermal insulation as an input parameter. In conclusion, the paper ranks the strategies according to their computed energy efficiency, thus providing quantitative benchmarks for preliminary wax control assessment.
基金This work was supported by The National Natural Science Foundation of China (No. 51271099).
文摘In this study, the microstructure evolution and corrosion resistance in O. 5 M Na2CO3 - 1 M NaHCO3 solution of X80 high-deformability ( X8OHD ) pipeline steel coarse-grained heat-affected zone (CGHAZ) with several heat input levels were investigated. It is shown that the microstructure of CGHAZ changes from bainite ferrite to granular bainite as the heat input increasing. In addition, the corrosion resistance and the stability of passive film of base material are better than those of CGHAZ with several heat input levels. Too small or too big heat input is inadvisable and better corrosion resistance of CGHAZ is attained when heat input is 30 kJ/cm.
文摘At present, the main attention of researchers is paid to the deterioration of heat transfer when heating the outer surface of the pipe with the liquid or steam, flowing inside it, in the presence of films or deposits on its inner surface. However, when pipe is heating by heat carrier medium, flowing inside it, film on the inner pipe surface serve a dual protective function, protecting the pipe from corrosion and reducing its thermal stress. The article represents the results of the computational analysis of protective films influence on the thermal stressed state of headers and steam pipelines of combined-cycle power plants (CCPP) heat-recovery steam generators at different transient operating conditions particularly at startups from different initial temperature states and thermal shock. It is shown that protective films have a significant influence on the stresses magnitude and damage accumulation mainly for great temperature disturbances (for thermal shock). Calculations were carried out at various thicknesses of films and assuming that their thermal conductivity less than thermal conductivity of the steam pipelines metal.