Effects of temperature, particle size, and air humidity on sensibility of typical high-energetic explosives

The production and utilization of high-energetic explosives often pose a range of safety hazards,with sensitivity being a key factor in evaluating these risks.To investigate how temperature,particle size,and air humidity affect the responsiveness of commonly used high-energetic explosives,a series of BAM(Bundesanstalt für Materialforschung und-prüfung)impact and friction sensitivity tests were carried out to determine the critical impact energy and critical load pressure of four representative high-energetic explosives(RDX,HMX,PETN and CL-20)under different temperatures,particle sizes,and air humidity conditions.The experimental findings facilitated an examination of temperature and particle size affecting the sensitivity of high-energetic explosives,along with an assessment of the influence of air humidity on sensitivity testing.The results clearly indicate that high-energetic explosives display a substantial decline in critical reaction energy when subjected to micrometre-sized particles and an air humidity level of 45%at a temperature of 90℃.Furthermore,it was noted that the critical reaction energy of high-energetic explosives diminishes with an increase in temperature within 25℃−90℃.In the same vein,as the particle sizes of high-energetic explosives increase,so does the critical reaction energy for micrometre-sized particles.High air humidity significantly affects the sensitivity testing of high-energetic explosives,emphasizing the importance of refraining from conducting sensitivity tests in such conditions.

Hyperbranched phthalocyanine enabling black-phase formamidinium perovskite solar cells processing and operating in humidity open air

The extreme instability of pureα-phase FAPbI_(3) under high humidity conditions restricts the highthroughput fabrication in unmodified air environments,resulting in poor performance ofα-phase FAPbI_(3) perovskite devices obtained by scalable fabrication methods.Here we synthesized hyperbranched copper phthalocyanine(HCuPc)as a supramolecular additive with twisted phthalocyanine units to realize the molecular-level encapsulation at the grain boundaries through supramolecular interaction,which greatly broadened the processing window of FAPbI_(3) under high humidity.At the same time,unlike traditional encapsulation layer that carrier can only be collected by tunneling effect,the twisted phthalocyanine ring of HCu Pc in perovskite films is more conducive to hole extraction.Finally,a record efficiency was achieved in pure FAPbI_(3) based inverted structured solar cell by blade-coating to the best of our knowledge,even under unmodified humid air conditions(relative humidity of 65%–85%).The best operational stability of 3D pure FAPbI_(3) devices can also be achieved at the same time and unencapsulated HCuPc-FAPbI_(3) device can even operate with negligible degradation for 100 h in the open air(RH 30%–40%).

Development and experimental validation of a one-dimensional dynamic hygrothermal modeling based on air humidity ratio

A modified one-dimensional transient hygrothermal model for multilayer wall was proposed using air humidity ratio and temperature as the driving potentials.The solution for the governing equations was obtained numerically by implementing the finite-difference scheme.To evaluate the accuracy of the model,a test system was built up to measure relative humidity and temperature within a porous wall and compare with the prediction of the model.The prediction results have good agreement with the experimental results.For the interface close to indoor side,the maximum deviation of temperature between calculated and test data is 1.87 K,and the average deviation is 0.95 K;the maximum deviation of relative humidity is 11.4%,and the average deviation is 5.7%.For the interface close to outdoor side,the maximum deviation of temperature between prediction and measurement is 1.78 K,and the average deviation is 1.1 K;the maximum deviation of relative humidity is 9.9%,and the average deviation is 4.2%.

Simulation and analysis of humid air turbine cycle based on aeroderivative three-shaft gas turbine

Due to the fact that the turbine outlet temperature of aeroderivative three-shaft gas turbine is low,the conventional combined cycle is not suitable for three-shaft gas turbines.However,the humid air turbine(HAT)cycle provides a new choice for aeroderivative gas turbine because the humidification process does not require high temperature.Existing HAT cycle plants are all based on single-shaft gas turbines due to their simple structures,therefore converting aeroderivative three-shaft gas turbine into HAT cycle still lacks sufficient research.This paper proposes a HAT cycle model on a basis of an aeroderivative three-shaft gas turbine.Detailed HAT cycle modelling of saturator,gas turbine and heat exchanger are carried out based on the modular modeling method.The models are verified by simulations on the aeroderivative three-shaft gas turbine.Simulation results show that the studied gas turbine with original size and characteristics could not reach the original turbine inlet temperature because of the introduction of water.However,the efficiency still increases by 0.16%when the HAT cycle runs at the designed power of the simple cycle.Furthermore,simulations considering turbine modifications show that the efficiency could be significantly improved.The results obtained in the paper can provide reference for design and analysis of HAT cycle based on multi-shaft gas turbine especially the aeroderivative gas turbine.

Study on Calculations of Humidification Tower with Humid Air Turbine Cycle at High Temperature and Pressure

Humidification is an important step in humid air turbine system. The calculation on humidification is carried out at 423.15—573.15K, 5—15MPa. The results suggest that to produce high-enthalpy moist air, high water temperature and large water flow are needed. The water temperature is the most sensitive parameter to the humidification tower. And it is better for the humidification tower to work at temperature higher than 523 K when the system pressure is higher than 5 MPa. The comparison between the model used in this paper and ideal model shows that the ideal model can be used in simulation to simply the calculation when the temperature is lower than 473 K and pressure is lower than 5 MPa.

Response of Tomato Sugar and Acid Metabolism and Fruit Quality under Different High Temperature and Relative Humidity Conditions

The combined stress of high temperature and high relative air humidity is one of the most serious agrometeorological disasters that restricts the production capacity of protected agriculture.However,there is little information about the precise interaction between them on tomato fruit quality.The objectives of this study were to explore the effects of the combined stress of high temperature and relative humidity on the sugar and acid metabolism and fruit quality of tomato fruits,and to determine the best relative air humidity for fruit quality under high temperature environments.Four temperature treatments(32℃,35℃,38℃,41℃),three relative air humidity(50%,70%,90%)and four duration(3,6,9,12 d)orthogonal experiments were conducted,with 28℃,50%as control.The results showed that under high temperature and relative air humidity,the activity of sucrose metabolizing enzymes in young tomato fruits changed,which reduced fruits soluble sugar content;in addition,enzyme activities involved phosphopyruvate carboxylase(PEPC),mitochondria aconitase(MDH)and citrate synthetase(CS)increased which increased the content of organic acids(especially malic acid).Eventually,vitamin C,total sugar and sugar-acid ratio decreased significantly,while the titratable acid increased,resulting in a decrease in fruit flavor quality and nutritional quality in ripe fruit.Specifically,a temperature of 32℃and a relative air humidity of 70%were the best cultivation conditions for tomato reproductive growth period under high temperature.Our results indicating that fruit quality reduced under high temperature at the flowering stage,while increasing the relative air humidity to 70%could alleviate this negative effect.Our results are benefit to better understand the interaction between microclimate parameters under specific climatic conditions in the greenhouse environment and their impact on tomato flavor quality.

Electro-Hydrodynamics and Kinetic Modeling of Dry and Humid Air Flows Activated by Corona Discharges

The present work is devoted to the 2D simulation of a point-to-plane Atmospheric Corona Discharge Reactor （ACDR） powered by a DC high voltage supply. The corona reactor is periodically crossed by thin mono filamentary streamers with a natural repetition frequency of some tens of kHz. The study compares the results obtained in dry air and in air mixed with a small amount of water vapour （humid air）. The simulation involves the electro-dynamics~ chemical kinetics and neutral gas hydrodynamics phenomena that influence the kinetics of the chemical species transformation. Each discharge lasts about one hundred of a nanosecond while the post- discharge occurring between two successive discharges lasts one hundred of a microsecond. The ACDR is crossed by a lateral dry or humid air flow initially polluted with 400 ppm of NO. After 5 ms, the time corresponding to the occurrence of 50 successive discharge/post-discharge phases, a higher NO removal rate and a lower ozone production rate are found in humid air. This change is due to the presence of the HO2 species formed from the H primary radical in the discharge zone.

Kinetic study of key species and reactions of atmospheric pressure pulsed corona discharge in humid air

In this study, we examined the key particles and chemical reactions that substantially influence plasma characteristics. In summarizing the chemical reaction model for the discharge process of N_(2)–O_(2)–H_(2)O(g)mixed gases, 65 particle types and 673 chemical reactions were investigated. On this basis, a global model of atmospheric pressure humid air discharge plasma was developed, with a focus on the variation of charged particles densities and chemical reaction rates with time under the excitation of a 0–200 Td pulsed electric field. Particles with a density greater than 1% of the electron density were classified as key particles. For such particles, the top ranking generation or consumption reactions(i.e. where the sum of their rates was greater than 95% of the total rate of the generation or consumption reactions) were classified as key chemical reactions. On the basis of the key particles and reactions identified, a simplified global model was derived. A comparison of the global model with the simplified global model in terms of the model parameters, particle densities, reaction rates(with time), and calculation efficiencies demonstrated that both models can adequately identify the key particles and chemical reactions reflecting the chemical process of atmospheric pressure discharge plasma in humid air. Thus, by analyzing the key particles and chemical reaction pathways, the charge and substance transfer mechanism of atmospheric pressure pulse discharge plasma in humid air was revealed, and the mechanism underlying water vapor molecules’ influence on atmospheric pressure air discharge was elucidated.

PRELIMINARY STUDY OF INDOOR FEATURES OF TEMPERATURE AND HUMIDITY FOR ROOMS FACING NORTH-SOUTH IN WINTER IN A LOW-LATITUDE PLATEAU CITY

Analyzing observations of wintertime air temperature in both indoor and outdoor surroundings in Kunming, a city lying in low latitudes, characteristics of temperature and humidity have been studied for the interior of rooms facing north-south under different weather conditions. Significant warming effect has been identified in terms of lowest and daily-mean indoor temperature in the area of Kunming. The heating amplitude ranges from 7.7C to 10.0C and from 4.6C to 5.8C for the interior part of rooms facing the south and from 4.6C to 7.0C and from 1.3C to 4.4C for the interior part of rooms facing the north, respectively for the two elements. The highest air temperature is higher indoor than outdoor for rooms facing the south, but otherwise is usually true for rooms facing the north. Additional findings point out that buildings not only help maintain relatively warm indoor temperature but delay its variation. The diurnal cycle of temperature indoor is smaller and ranges by 40% ~ 48% for south-facing rooms, and by 20% ~ 30% for north-facing rooms, than outdoor, and the highest temperature is about 2 hours late inside the room than outside. It shows how inertly indoor temperature varies. The work also finds that relative humidity is less indoor in southward rooms than in northward ones and difference is the largest on fine days but the smallest when it is overcast. For the diurnal variation, the indoor relative humidity is large at nighttime with small amplitude but small during daytime with large amplitude. The above-presented results can be served as scientific foundation for more research on climate in low-latitude cities and rational design of urban architectures.

The Processes-Based Attributes of Four Major Surface Melting Events over the Antarctic Ross Ice Shelf

The Ross-Amundsen sector is experiencing an accelerating warming trend and a more intensive advective influx of marine air streams.As a result,massive surface melting events of the ice shelf are occurring more frequently,which puts the West Antarctica Ice Sheet at greater risk of degradation.This study shows the connection between surface melting and the prominent intrusion of warm and humid air flows from lower latitudes.By applying the Climate Feedback-Response Analysis Method(CFRAM),the temporal surge of the downward longwave(LW)fluxes over the surface of the Ross Ice Shelf(RIS)and adjacent regions are identified for four historically massive RIS surface melting events.The melting events are decomposed to identify which physical mechanisms are the main contributors.We found that intrusions of warm and humid airflow from lower latitudes are conducive to warm air temperature and water vapor anomalies,as well as cloud development.These changes exert a combined impact on the abnormal enhancement of the downward LW surface radiative fluxes,significantly contributing to surface warming and the resultant massive melting of ice.

Design Research of a Novel Aftercool-Humidifier Concept for Humid Air Turbine Cycle

Humid air turbine cycle(HAT)has potential of electrical efficiencies comparable to combined cycle,with lower investment cost and NO_(x) emission.The typical heat exchanger network of HAT consists of intercooler(if there is),aftercooler,recuperator,economizer and humidifier,which brings higher efficiency but makes the system more complex.To simplify HAT layout,a novel humidifier concept is proposed by integrating the aftercooler into traditional counter-current humidifier.Based on this concept,a one-dimensional model including pressure drop and exergy calculation is established to distinguish the thermodynamic and hydrodynamic characteristics,and then the structural parameters,such as the number of rows and columns,tube diameter,pitch and type for a micro HAT are identified.The results show that the aftercool-humidifier plays the same role as original aftercooler and humidifier,and can match the in-tube air,out-tube air and water stream well with lower volume.In the case of micro HAT cycle,the volume of heat and mass transfer area can be reduced by 47%compared with traditional design.The major thermal resistance occurred in the convection heat transfer process inside the tube;however,using enhanced tube cannot effectively improve the compactness of device.

Influence of Humidity and Air Pressure on the Ion Mobility Based on Drift Tube Method

The measurement of ion mobility is important for calculating the corona loss of the transmission lines,and for establishing corona loss and ion current models that take humidity and air pressure into consideration.This paper describes a needle-ring corona discharge experiment setup based on a prior study,which simulates different humidity and air pressure conditions;it is observed that the execution of the ion gate is improved in this experiment from off-on-off to off-on to achieve higher ion current amplitude.Additionally,positive and negative ion mobility under different humidity and air pressure is obtained,with the positive ion mobility measurements in the range of 1.1126 to 1.9167 cm2/V·s,and the negative ion mobility measurements in the range of 1.3574 to 2.5643 cm2/V·s.The experimental results indicate that ion mobility decreases nonlinearly with increase in humidity,but trends towards saturation in the 30%–70%relative humidity range.Finally,a parameter correction method for calibrating the relationship among the ion mobility,humidity,and air pressure is proposed.

Enabling Argyrodite Sulfides as Superb Solid-State Electrolyte with Remarkable Interfacial Stability Against Electrodes

While argyrodite sulfides are getting more and more attention as highly promising solid-state electrolytes(SSEs)for solid batteries,they also suffer from the typical sulfide setbacks such as poor electrochemical compatibility with Li anode and high-voltage cathodes and serious sensitivity to humid air,which hinders their practical applications.Herein,we have devised an effective strategy to overcome these challenging shortcomings through modification of chalcogen chemistry under the guidance of theoretical modeling.The resultant Li_(6.25)PS_(4)O_(1.25)Cl_(0.75)delivered excellent electrochemical compatibility with both pure Li anode and high-voltage LiCoO_(2)cathode,without compromising the superb ionic conductivity of the pristine sulfide.Furthermore,the current SSE also exhibited highly improved stability to oxygen and humidity,with further advantage being more insulating to electrons.The remarkably enhanced compatibility with electrodes is attributed to in situ formation of helpful electrolyte–electrode interphases.The formation of in situ anode–electrolyte interphase(AEI)enabled stable Li plating/stripping in the Li|Li_(6.25)PS_(4)O_(1.25)Cl_(0.75)|Li symmetric cells at a high current density up to 1 mA cm^(-2)over 200 h and 2 mA cm^(-2)for another 100 h.The in situ amorphous nano-film cathode–electrolyte interphase(CEI)facilitated protection of the SSE from decomposition at elevated voltage.Consequently,the synergistic effect of AEI and CEI helped the LiCoO_(2)|Li_(6.25)PS_(4)O_(1.25)Cl_(0.75)|Li full-battery cell to achieve markedly better cycling stability than that using the pristine Li_(6)PS_(5)Cl as SSE,at a high area loading of the active cathode material(4 mg cm^(-2))in type-2032 coin cells.This work is to add a desirable SSE in the argyrodite sulfide family,so that high-performance solid battery cells could be fabricated without the usual need of strict control of the ambient atmosphere.

INFLUENCE OF AIR HUMIDITY ON THE SUPPRESSION OF FUGITIVE DUST BY USING A WATER-SPRAYING SYSTEM

One of the main origins of fugitive dust emission arises from bulk handling in quarries or mines, in particular, from bulk materials falling from a hopper or a conveyor belt. Water-spraying systems, using two-phase nozzles, are one of the methods to suppress such dust emission. In this work we tried to develop a mathematical model to correlate air humidity, water flux through the nozzle and the dust （in particular PM10） emission, in order to improve the application and efficiency of these systems. Sand from the Yellow River in China was dropped from a conveyor belt into a dust chamber at 1 kg·min^-1, wherefrom the emitted dust was sucked off and quantified via a cascade impactor. A two-phase nozzle was installed in the dust chamber with a water flux through the nozzle of 1.2 to 3 L·h^-1, whereas the relative air humidity changed between 55 and 73%. Dust emission was found to be linearly dependent on relative air humidity. Furthermore model equations were developed to describe the dependence of PM10 emission on water flux and relative air humidity.

Modeling of Soybean Plant Sap Flow

Soybean (Glycine max. (L.) Merr.) sap flow during the growth stages in relation to soil moisture, nutrition, and weather conditions determine the plant development. Modeling this process helps to better understand the plant water-nutrition uptake and improve the decisions of efficient irrigation management and other inputs for effective soybean production. Field studies of soybean sap flow took place in 2017-2021 at Marianna, Arkansas using heat balance stem flow gauges to measure the sap flow during the reproductive growth stages R3-R7. Plant water uptake was measured using the lysimeter-container method. The uniform sap flow-based hydraulic system in the soil-root-stem-leaf pathway created negative water tensions with osmotic processes and water surface tensions in stomata cells as water evaporation layers increase are the mechanism of the plant water uptake. Any changes the factors like soil water tension, solar radiation, or air relative humidity immediately, within a few seconds, affect the system’s balance and cause simultaneously appropriate reactions in different parts of the system. The plant water use model was created from plant emergence, vegetative to final reproductive growth stages depending on soil-weather conditions, plant morphology, and biomass. The main factors of the model include solar radiation, air temperature, and air relative humidity. The effective sap flow uptake occurs around 0.8 KPa VPD. Further research is needed to optimize the model’s factors to increase the plant growth dynamics and yield productivity.

Study on the Dry Island Effect in Xiamen City

Using relative humidity data from two meteorological stations in Xiamen and absolute humidity calculated from temperature and water vapor,the annual,seasonal and monthly change characteristic of relative humidity and absolute humidity were comprehensive analyzed.Then the dry island effect of Xiamen city was studied.The result demonstrated that because of unique geographical features,the air humidity showed different change rules between urban and suburb.There was no obvious dry island effect in urban and suburb at last century.The change trend of average air humidity was unapparent before 90th of last century.From early 90th of last century,the air humidity in suburb began to decrease obviously.There was dry mutation for these two stations in 1993 and 2004 respectively.From the beginning of early of this century,both areas became dry obviously.The seasonal average relative humidity of Tongan station decreased each season,but what in Xiamen station changed unapparent.The seasonal average absolute humidity of Tongan station decreased apparently in spring and summer,but what did not change obviously in autumn and winter.The seasonal average absolute humidity of Xiamen station decreased apparently in summer,but what did not change apparently in other seasons.As respect from climate change of air humidity of each time,it decreased obviously at all four times at Tongan station.Relative humidity diminished most apparently at 8 and 20 o'clock.Absolute humidity diminished most apparently at 14 o'clock.For Xiamen station,relative humidity diminished most apparently at 14 o'clock.Absolute humidity diminished most apparently at 2 and 20 o'clock.

Control Means and Data Analysis of Environmental Factors of Facility Watermelon in Beijing Area

In this study, the environmental indicators （including temperature, light, air relative humidity and CO2 concentration） of facility watermelon in Beijing area were monitored with US350 environmental sensor during the whole growth period. The results showed that in the solar greenhouses in Beijing area, the average air temperature was in the range of 10.67-29.95 ℃ during the whole growth period of watermelon, the average soil temperature ranged from 16.92 to 35.10 ℃, the average light intensity changed from 268.37 to 13 842.60 Ix, the average air relative humidity ranged from 52.40% to 94.26%, and the average CO2 concentration was in the range of 455-631 ml/m3; and in the spring greenhouses in Beijing area, the variation range of average air temperature was 14.05-29.84 ℃ during the whole growth period of watermelon, the average soil temperature ranged from 17.47 to 28.12 ℃, the average light intensity was in the range of 55.80-12 858.64 Ix, the average soil moisture content ranged from 18.19%-34.56%, the variation range of average air relative humidity was 20.72%-96.26%, and the average CO2 concentra- tion was in the range of 351-544 ml/m3,

Investigation into the roles of interfacial H_(2)O structure in catalytic oxidation of HCHO and CO over CuMnO_(2) catalysts

The rapid deactivation of cost-effective MnO_(2)-based catalysts in humid air limits their application in practice,and the identification of the role of water in an oxidation process is significant for developing water-resistant MnO_(2)-based catalysts.Here,CuMnO_(2)showed a20.3%HCHO conversion in 10 hr at room temperature in humid air with relative humidity of 40%,but deactivated in 3 hr in dry air.The excellent activity and stability of HCHO oxidation in humid air were attributed to the positive effect of H_(2)O on HCHO oxidation to the H_(2)O-HOCH_(2)OH supermolecule assemblies via hydrogen bonds formed on CuMnO_(2).H_(2)O-HOCH_(2)OH supermolecule assemblies tend to be oxidized to carbonate,which is further oxidized to CO_(2).Furthermore,CuMnO_(2)exhibited a much poorer activity of CO oxidation in humid air,but the CO conversion was still 100%in 10 hr in dry air.H_(2)O showed a competitive adsorption effect to CO on CuMnO_(2).CuMnO_(2)could be applied in HCHO elimination in humid air and CO elimination in dry air.

Experimental Study on Turbulent Structure of Humid Air Flame in a Bluff-body Burner

The main objective of the present experimental study is to analyze the turbulent structure in humid airnon-premixed flame, and determine the effect of humidity on the flow field and the flame stability limit in turbulentnon-premixed flame. Particle Image Velocimetry (PIV) is used to capture the instantaneous appearance ofvortex structures and obtain the quantitative velocity field. The distributions of Reynolds shear stress, mean androot-mean squared fluctuating (rms) velocities are examined to get insight into the effect of fuel-to-air velocity ratioon velocity flow field. The results show that with steam addition, the air-driven vortex in the bluff-body wakeis thinner; the biggest peaks of rms velocity and Reynolds shear stress are lower; the distance between the peaksof rms velocity on the sides of centerline reduces. Besides these, the flame stability is affected. Both central fuelpenetration limit and partially quenching limit reduce with steam addition.

Impact of meteorological condition changes on air quality and particulate chemical composition during the COVID-19 lockdown

Stringent quarantine measures during the Coronavirus Disease 2019(COVID-19)lockdown period(January 23,2020 to March 15,2020)have resulted in a distinct decrease in anthropogenic source emissions in North China Plain compared to the paralleled period of 2019.Particularly,22.7%decrease in NO_(2)and 3.0%increase of O_(3)was observed in Tianjin,nonlinear relationship between O_(3)generation and NO_(2)implied that synergetic control of NOx and VOCs is needed.Deteriorating meteorological condition during the COVID-19 lockdown obscured the actual PM2.5 reduction.Fireworks transport in 2020 Spring Festival(SF)triggered regional haze pollution.PM2.5 during the COVID-19 lockdown only reduced by 5.6%in Tianjin.Here we used the dispersion coefficient to normalize the measured PM2.5(DN-PM2.5),aiming to eliminate the adverse meteorological impact and roughly estimate the actual PM2.5 reduction,which reduced by 17.7%during the COVID-19 lockdown.In terms of PM2.5 chemical composition,significant NO_(3)−increase was observed during the COVID-19 lockdown.However,as a tracer of atmospheric oxidation capacity,odd oxygen(Ox=NO_(2)+O_(3))was observed to reduce during the COVID-19 lockdown,whereas relative humidity(RH),specific humidity and aerosol liquid water content(ALWC)were observed with noticeable enhancement.Nitrogen oxidation rate(NOR)was observed to increase at higher specific humidity and ALWC,especially in the haze episode occurred during 2020SF,high air humidity and obvious nitrate generation was observed.Anomalously enhanced air humidity may response for the nitrate increase during the COVID-19 lockdown period.