A series of aluminium-containing α-type hydrated zirconium hydrogen phosphates,Zr_(1-x)Alx (H_(1+x/2)PO_4 )_2 with x=0-0.06,were hydrothermally synthesized and characterizedby means of X-ray diffraction,differential ...A series of aluminium-containing α-type hydrated zirconium hydrogen phosphates,Zr_(1-x)Alx (H_(1+x/2)PO_4 )_2 with x=0-0.06,were hydrothermally synthesized and characterizedby means of X-ray diffraction,differential thermal analysis and thermogravimetric analysis.The proton conductivity,1.2×10￣(-4) S·cm￣(-1)at 180℃ was found in Zr_(0.98)Al_(0.02)(H_(1.01)PO_4)_2·H_2O.Humidity-sensing measurements were carried out at 120℃ and 140℃ respectively.Even a limited substitution of Al for Zr can enhance both proton conductivity and humidity sensitivity.展开更多
A γ - type of layered zirconium hydrogen phosphate, Zr(HPO 4) 2·2H 2O( γ ZrP), was synthesized under hydrothermal conditions and characterized by powder X ray diffraction and thermogravimetric analysis....A γ - type of layered zirconium hydrogen phosphate, Zr(HPO 4) 2·2H 2O( γ ZrP), was synthesized under hydrothermal conditions and characterized by powder X ray diffraction and thermogravimetric analysis. The temperature dependence of the proton conductivity in γ ZrP was investigated in a temperature range of 23￣413 ℃ by ac impedance spectroscopy. The variation of the conductivity with water loss and phase transitions was observed. The best proton conductivity in γ ZrP is 6×10 -4 S·cm -1 at 60 ℃. The proton conductivities in the dehydrated sample are ￣10 -5 at 150 ℃ and ￣10 -4 S·cm -1 at 350 ℃, respectively. The conductivities as a function of humidity in the temperature range of 120￣200 ℃ were measured.展开更多
Capacitive humidity sensors were made of nanometer barium titanate.The pellets were prepared under different pressures between 3920N to 7850N force.The capacitance changes in three orders of magnitude in the relative ...Capacitive humidity sensors were made of nanometer barium titanate.The pellets were prepared under different pressures between 3920N to 7850N force.The capacitance changes in three orders of magnitude in the relative humidity range of 10%～98%,indicating high humidity sensitivity of the sensors.At a certain measuring frequency,the capacitance of the sensors increases as increasing of the preparation pressure,while the sensitivity of the sensors basically remains the same.The frequencies corresponding to the peaks of the dielectric loss of the sensors move to the higher frequency direction as increasing of the relative humidity.At a certain humidity,the frequencies corresponding to the peaks of the dielectric loss move to the higher frequency direction as increasing of the preparation pressure.展开更多
Resistive-type film humidity sensors were prepared with a silicone-containing polyelectrolyte （Si-PE） and their humidity sensitive properties have been investigated. The sensors so obtained show high sensitivity to ...Resistive-type film humidity sensors were prepared with a silicone-containing polyelectrolyte （Si-PE） and their humidity sensitive properties have been investigated. The sensors so obtained show high sensitivity to humidity variation over a wide range of RH （20-96%）. In addition, they exhibit high reversibility, quick response and well long-term stability.展开更多
1 Results Humidity sensors have been widely used in meteorology, process controlling, agriculture and manufacturing. In recent year, more attention has been paid to resistive-type polymeric humidity sensors. Polyelect...1 Results Humidity sensors have been widely used in meteorology, process controlling, agriculture and manufacturing. In recent year, more attention has been paid to resistive-type polymeric humidity sensors. Polyelectrolytes are the most usually used materials for their advantages of high sensitivity, fast response, easy preparation, low cost, etc[1,2]. In this paper quaternized and salt-doped copolymer of 2-(dimethylamino) ethylmethacrylate (DMAEMA) with poly(ethylene glycol) methyl ether methacrylate ...展开更多
文摘A series of aluminium-containing α-type hydrated zirconium hydrogen phosphates,Zr_(1-x)Alx (H_(1+x/2)PO_4 )_2 with x=0-0.06,were hydrothermally synthesized and characterizedby means of X-ray diffraction,differential thermal analysis and thermogravimetric analysis.The proton conductivity,1.2×10￣(-4) S·cm￣(-1)at 180℃ was found in Zr_(0.98)Al_(0.02)(H_(1.01)PO_4)_2·H_2O.Humidity-sensing measurements were carried out at 120℃ and 140℃ respectively.Even a limited substitution of Al for Zr can enhance both proton conductivity and humidity sensitivity.
文摘A γ - type of layered zirconium hydrogen phosphate, Zr(HPO 4) 2·2H 2O( γ ZrP), was synthesized under hydrothermal conditions and characterized by powder X ray diffraction and thermogravimetric analysis. The temperature dependence of the proton conductivity in γ ZrP was investigated in a temperature range of 23￣413 ℃ by ac impedance spectroscopy. The variation of the conductivity with water loss and phase transitions was observed. The best proton conductivity in γ ZrP is 6×10 -4 S·cm -1 at 60 ℃. The proton conductivities in the dehydrated sample are ￣10 -5 at 150 ℃ and ￣10 -4 S·cm -1 at 350 ℃, respectively. The conductivities as a function of humidity in the temperature range of 120￣200 ℃ were measured.
基金The project is supported by the National Natural Science Foundation of China （60074031, 60474052）.
文摘Capacitive humidity sensors were made of nanometer barium titanate.The pellets were prepared under different pressures between 3920N to 7850N force.The capacitance changes in three orders of magnitude in the relative humidity range of 10%～98%,indicating high humidity sensitivity of the sensors.At a certain measuring frequency,the capacitance of the sensors increases as increasing of the preparation pressure,while the sensitivity of the sensors basically remains the same.The frequencies corresponding to the peaks of the dielectric loss of the sensors move to the higher frequency direction as increasing of the relative humidity.At a certain humidity,the frequencies corresponding to the peaks of the dielectric loss move to the higher frequency direction as increasing of the preparation pressure.
文摘Resistive-type film humidity sensors were prepared with a silicone-containing polyelectrolyte （Si-PE） and their humidity sensitive properties have been investigated. The sensors so obtained show high sensitivity to humidity variation over a wide range of RH （20-96%）. In addition, they exhibit high reversibility, quick response and well long-term stability.
文摘1 Results Humidity sensors have been widely used in meteorology, process controlling, agriculture and manufacturing. In recent year, more attention has been paid to resistive-type polymeric humidity sensors. Polyelectrolytes are the most usually used materials for their advantages of high sensitivity, fast response, easy preparation, low cost, etc[1,2]. In this paper quaternized and salt-doped copolymer of 2-(dimethylamino) ethylmethacrylate (DMAEMA) with poly(ethylene glycol) methyl ether methacrylate ...
