Recent progress of hybrid cathode interface layer for organic solar cells

Organic solar cells(OSCs)have gained conspicuous progress during the past few decades due to the development of materials and upgrading of the device structure.The power conversion efficiency(PCE)of the single-junction device had surpassed 19%.The cathode interface layer(CIL),by optimizing the connection between the active layer and the cathode electrode,has become a momentous part to strengthen the performances of the OSCs.Simultaneously,CIL is also indispensable to illustrating the working mechanism of OSCs and enhancing the stability of the OSCs.In this essay,hybrid CILs in OSCs have been summarized.Firstly,the advancement and operating mechanism of OSCs,and the effects and relevant design rules of CIL are briefly concluded;secondly,the significant influence of CIL on enhancing the stability and PCE of OSCs is presented;thirdly,the characteristics of organic hybrid CIL and organic-inorganic hybrid CIL are introduced.Finally,the conclusion and outlook of CIL are summarized.

Resilient performance of self-centering hybrid rocking walls with curved interface under pseudo-static loading

Frame and rocking wall(FRW)structures have excellent resilient performance during earthquakes.However,the concrete at interfacial corners of rocking walls(RWs)is easily crushed due to local extreme compression during the rocking process.An innovative RW with a curved interface is proposed to prevent interfacial corners from producing local damage,enhancing its earthquake resilient performance(ERP).The precast wall panel with a curved interface is assembled into an integral self-centering hybrid rocking wall(SCRW)by two post-tensioned unbonded prestressed tendons.Moreover,two ordinary energy dissipation steel rebars and two shear reinforcements are arranged to increase the energy dissipation capacity and lateral resistance.Two SCRW specimens and one monolithic reinforced concrete(RC)shear wall(SW)were tested under pseudo-static loading to compare the ERPs of the proposed SCRW and the SW,focusing on studying the effect of the curved interface on the SCRW.The key resilient performance of rocking effects,failure modes,and hysteretic properties of the SCRW were explored.The results show that nonlinear deformations of the SCRW are concentrated along the interface between the SCRW and the foundation,avoiding damage within the SCRW.The restoring force provided by the prestressed tendons can effectively realize self-centering capacity with small residual deformation,and the resilient performance of the SCRW is better than that of monolithic SW.In addition,the curved interface of the SCRW makes the rocking center change and move inward,partially relieving the stress concentration and crush of concrete.The rocking range of the rocking center is about 41.4%of the width of the SCRW.

A Stable FE-FD Method for Anisotropic Parabolic PDEs with Moving Interfaces

In this paper,a new finite element and finite difference(FE-FD)method has been developed for anisotropic parabolic interface problems with a known moving interface using Cartesian meshes.In the spatial discretization,the standard P,FE discretization is applied so that the part of the coefficient matrix is symmetric positive definite,while near the interface,the maximum principle preserving immersed interface discretization is applied.In the time discretization,a modified Crank-Nicolson discretization is employed so that the hybrid FE-FD is stable and second order accurate.Correction terms are needed when the interface crosses grid lines.The moving interface is represented by the zero level set of a Lipschitz continuous function.Numerical experiments presented in this paper confirm second orderconvergence.

Gradient-augmented hybrid interface capturing method for incompressible two-phase flow

Motivated by inconveniences of present hybrid methods,a gradient-augmented hybrid interface capturing method（GAHM） is presented for incompressible two-phase flow.A front tracking method（FTM） is used as the skeleton of the GAHM for low mass loss and resources.Smooth eulerian level set values are calculated from the FTM interface,and are used for a local interface reconstruction.The reconstruction avoids marker particle redistribution and enables an automatic treatment of interfacial topology change.The cubic Hermit interpolation is employed in all steps of the GAHM to capture subgrid structures within a single spacial cell.The performance of the GAHM is carefully evaluated in a benchmark test.Results show significant improvements of mass loss,clear subgrid structures,highly accurate derivatives（normals and curvatures） and low cost.The GAHM is further coupled with an incompressible multiphase flow solver,Super CE/SE,for more complex and practical applications.The updated solver is evaluated through comparison with an early droplet research.

Bias-induced reconstruction of hybrid interface states in magnetic molecular junctions

Based on first-principles calculations,the bias-induced evolutions of hybrid interface states inπ-conjugated tricene and in insulating octane magnetic molecular junctions are investigated.Obvious bias-induced splitting and energy shift of the spin-resolved hybrid interface states are observed in the two junctions.The recombination of the shifted hybrid interface states from different interfaces makes the spin polarization around the Fermi energy strongly bias-dependent.The transport calculations demonstrate that in theπ-conjugated tricene junction,the bias-dependent hybrid interface states work efficiently for large current,current spin polarization,and distinct tunneling magnetoresistance.But in the insulating octane junction,the spin-dependent transport via the hybrid interface states is inhibited,which is only slightly disturbed by the bias.This work reveals the phenomenon of bias-induced reconstruction of hybrid interface states in molecular spinterface devices,and the underlying role of conjugated molecular orbitals in the transport ability of hybrid interface states.

Scalable Quantum Information Transfer between Individual Nitrogen-Vacancy Centers by a Hybrid Quantum Interface

We develop a design of a hybrid quantum interface for quantum information transfer （QIT）, adopting a nanome- chanical resonator as the intermedium, which is magnetically coupled with individual nitrogen-vacancy centers as the solid qubits, while eapacitively coupled with a coplanar waveguide resonator as the quantum data bus. We describe the Hamiltonian of the model, and analytically demonstrate the QIT for both the resonant interaction and large detuning cases. The hybrid quantum interface allows for QIT between arbitrarily selected individual nitrogen-vacancy centers, and has advantages of the sealability and controllability. Our methods open an alter- native perspective for implementing QIT, which is important during quantum storing or processing procedures in quantum computing.

Quantum state transfer via a hybrid solid–optomechanical interface

We propose a scheme to implement quantum state transfer between two distant quantum nodes via a hybrid solid–optomechanical interface. The quantum state is encoded on the native superconducting qubit, and transferred to the microwave photon, then the optical photon successively, which afterwards is transmitted to the remote node by cavity leaking,and finally the quantum state is transferred to the remote superconducting qubit. The high efficiency of the state transfer is achieved by controllable Gaussian pulses sequence and numerically demonstrated with theoretically feasible parameters.Our scheme has the potential to implement unified quantum computing–communication–computing, and high fidelity of the microwave–optics–microwave transfer process of the quantum state.

Analysis of Drivers＇Burden and Man－Machine Interfaces in High－Speed Locomotive Driving Cab

With the introduction of high-speed trains into chinese railway system, closeattention should be paid to the aspects of safety in hish-speed railways. Thereare many interfaces which are very important and directly related to drivmgsafety. This paper focuses on features of design and analyses the principles ofsafety.

Fast charge transport motivated by tunable Mo2C/Mo2N high-quality heterointerface for superior pseudocapacitive storage

The development of potential transition-metal carbide/nitride heterojunctions is hindered by overall understanding and precise modulation for heterointerface effects.Herein,we demonstrate that Mo_(2)C/Mo_(2)N heterojunction with the precisely regulated high-quality interface can achieve marvelous rate performance and energy output via enlarging the interface-effect range and maximizing "accelerated charge" amount The heterointerface mechanism improving properties is synergistically revealed from kinetics and thermodynamics perspectives.Kinetics analysis confirms that the self-built electric field affords a robust force to drive rapid interface electrons/ions migration.The small adsorption energy,high density of states and quite low diffusion barrier thermodynamically enhance the electrochemical reaction dynamics on heterointerface.Consequently,the almost optimal performance of ultrahigh capacitance retention(85.6% even at 10 A g^(-1)) and pronounced energy output(96.4 Wh kg^(-1))in hybridsupercapacitors than other Mo_(2)C/Mo_(2)N-based materials is presented.This work gives new insight into the energy storage mechanism of heterojunction and guides the design of advanced electrodes.

Regulatable Orthotropic 3D Hybrid Continuous Carbon Networks for Efficient Bi-Directional Thermal Conduction

Vertically oriented carbon structures constructed from low-dimen-sional carbon materials are ideal frameworks for high-performance thermal inter-face materials(TIMs).However,improving the interfacial heat-transfer efficiency of vertically oriented carbon structures is a challenging task.Herein,an orthotropic three-dimensional(3D)hybrid carbon network(VSCG)is fabricated by depositing vertically aligned carbon nanotubes(VACNTs)on the surface of a horizontally oriented graphene film(HOGF).The interfacial interaction between the VACNTs and HOGF is then optimized through an annealing strategy.After regulating the orientation structure of the VACNTs and filling the VSCG with polydimethylsi-loxane(PDMS),VSCG/PDMS composites with excellent 3D thermal conductive properties are obtained.The highest in-plane and through-plane thermal conduc-tivities of the composites are 113.61 and 24.37 W m^(-1)K^(-1),respectively.The high contact area of HOGF and good compressibility of VACNTs imbue the VSCG/PDMS composite with low thermal resistance.In addition,the interfacial heat-transfer efficiency of VSCG/PDMS composite in the TIM performance was improved by 71.3%compared to that of a state-of-the-art thermal pad.This new structural design can potentially realize high-performance TIMs that meet the need for high thermal conductivity and low contact thermal resistance in interfacial heat-transfer processes.

Skin-inspired interface modification strategy toward a structurefunction integrated hybrid smart fabric system with self-powered sensing property for versatile applications

Fabric-based composites with superior mechanical properties and excellent perceptive function are highly desirable.However,it remains a huge challenge to attain structure-function integration,especially for hybrid fabric composites.Herein,a skin-inspired interface modification strategy is proposed toward this target by constructing a hybrid smart fabric system consisting of two types of smart fabrics:carbon nanotube(CNT)/MXene-modified aramid fabrics and zinc oxide nanorod(ZnO NR)-modified carbon fabrics.Based on that,flexible piezoelectric pressure sensors with skin-like hierarchical perception interfaces are fabricated,which demonstrate superb sensitivity of 2.39 V·kPa^(-1)and are capable of various wearable monitoring tasks.Besides,the interface-modified hybrid fabric reinforced plastics can also be fabricated,which are proven to possess 13.6%higher tensile strength,10.1%elastic modulus.More impressively,their average energy absorption can be improved by 111.9%,accompanied with inherent damage alert capability.This offers a paradigm to fabricate structure-function integrated hybrid smart fabric composites for the smart clothing and intelligent aerial vehicles.

Hybrid Modified Rubber Powder and Its Application in Cement Mortar

This research focused on using the waste rubber powder as a kind of regenerate resources to improve the mechanical properties of cement mortar.The two kinds of hybrid modified rubber powder TRP and ATRP were prepared by sol-gel method and then used in cement mortar.The structures and properties of them were studied.It is shown that the nano Si-O-Si network is generated in TRP and ATRP networks and the hydrophilic group is grafted on the surface of ATRP.The mechanical properties of rubber-treated mortar（RTM） were tested and the microstructures of them were also studied.Compared to the mortars with unmodified rubber powders（RP）,NaOH treated rubber powder（SRP） and coupling agent treated rubber powder（CRP）,the RTM with ATRP has the highest compressive strength and flexural strength.The stress-strain curves shown that the peak of stress of RTM with ATRP is increased and indicated the higher compression deformation and toughness.It is found that the interfacial adhesion between the ATRP and cement mortar is increased distinctly by SEM,which results in enhanced ductility and mechanical properties of RTM with ATRP.

Dual-layer vermiculite nanosheet based hybrid film to suppress dendrite growth in lithium metal batteries

Lithium metal anode has become a favorable candidate for next-generation rechargeable batteries.However, the unstable interface between lithium metal and electrolyte leads to the growth of dendrites,resulting in the low Coulombic efficiency and even the safety concerns. Herein, a rigid-flexible dual-layer vermiculite nanosheet(VN) based organic-inorganic hybrid film on lithium metal anode is proposed to suppress dendrite growth and relieve volume fluctuations. The inner mechanically robust VN layer(3 μm thick) enhances the mechanical properties of the protective layer, while the outer polymer(4 μm thick) can enhance the flexibility of the hybrid layer. The Li | Li symmetric cell with protected lithium shows an extended life of over 670 h. The full cell with Li anode protected by dual-layer interface exhibits a better capacity retention of 80% after 174 cycles in comparison to bare Li anode with 94 cycles.This study provides a novel approach and a significant step towards prolonging lifespan of lithium metal batteries.

Structural considerations in friction welding of hybrid Al_2O_3-reinforced aluminum composites

Comparative studies on the relationship between the welding parameters and joining efficiency in the friction welding of hybrid Al203-reinforced aluminum composites were conducted. Metal matrix composites （MMCs） with 37% （volume fraction） aluminum particle were joined by friction welding. The results show that the effects of the rotation speed on the reduction rate of particle size are greater than those of the upset pressure, and the area of the MMC weld zone decreases as the joining efficiency increases, while it is considered that the joining efficiency does not increase as the reduction rate of particle size decreases. During the macro-examination of the bonding interlace, a gray discolored region was observed on the bonding interface, and the center of the region was dark gray. After the micro-examination of the bonding interface, base metal made some second particulate formed by condensed alumina particulate but discoloration part distributed minute alumina particulate without second particulate. Consequently, it was also observed that rotational speed of 3 000 r/min and upset pressure of 63.6 MPa showed a very good.joint.

Modulating the zinc ion flux and electric field intensity by multifunctional metal-organic complex interface layer for highly stable Zn anode

The uncontrollable growth of Zn dendrites accompanied by side reactions severely impedes the industrialized process of zinc ion electrochemical energy storage devices.Herein,we propose a practical metalorganic complex interface layer to manipulate the zinc ion flux and electric field intensity,enabling highly homogeneous zinc electrodeposition.The zinc-terephthalic acid complex(ZnPTA)with lower adsorption energy for zinc ion(-1.3 eV)builds a zincophilic interface favoring the ordered nucleation and growth of Zn.Moreover,the ZnPTA layer can serve as physical barrier to protect the newly deposited Zn from corrosion in the aqueous electrolyte.The modified Zn anode with the ZnPTA layer(ZnPTA@Zn)demonstrates excellent cycling stability more than 3000 h at 1 mA/cm^(2).Besides,the zinc-ion battery and zinc-ion hybrid capacitor using the ZnPTA@Zn electrode deliver outstanding cycle performance(up to 5500 cycles with high residual capacity ratio of 77.9%).This work provides a promising metal-organic complex interface design on enhancing the performance of Zn metal anode.

Setup and application of a structural seismic hybrid simulation system on local area network

To implement structural hybrid simulation independent of the control system of any testing equipment in civil engineering, an external command control approach is put forward. Several setup technologies and the corresponding API approaches are investigated to simultaneously combine numerical simulation with physical testing. Hybrid program technology is put forward and described in detail, using Visual C++ program to effectively and accurately control testing equipment and MATLAB program to implement numerical simulation with easy extension. The control program of testing equipment and numerical simulation program are integrated by calling MATLAB engine in Visual C++. A hybrid simulation about a full-scale six-story masonry structure is carried out. The testing results manifest that the external command control approach has the versatility because of simple hardware connection and control program independent on control software of testing equipment; powerful program function of Visual C++ and flexible program of MATLAB are integrated by hybrid program technology; hybrid simulation system provides a realistic and cost-effective testing platform that enables earthquake engineer researchers to accurately and efficiently capture the seismic performance of large or complex structures without having to carry out physical testing of the entire structure.

Effect of Probabilistic Pattern on System Voltage Stability in Decentralized Hybrid Power System

This paper presents an proportional integral (PI) based voltage-reactive power control for wind diesel based decentralized hybrid power system with wide range of disturbances to demonstrate the compensation effect on system with intelligent tuning methods such as genetic algorithm (GA), artificial neural network (ANN) and adaptive neuro fuzzy inference system (ANFIS). The effect of probabilistic load and/or input power pattern is introduced which is incorporated in MATLAB simulink model developed for the study of decentralized hybrid power system. Results show how tuning method becomes important with high percentage of probabilistic pattern in system. Testing of all tuning methods shows that GA, ANN and ANFIS can preserve optimal performances over wide range of disturbances with superiority to GA in terms of settling time using Integral of Square of Errors (ISE) criterion as fitness function.

基于滑模变结构的混合微电网接口变换器双向下垂控制

由于混合微电网中的交直流子网具有不同的动态特性,当系统发生负荷突变时,会在双向接口变换器(bidirectional interface converter, BIC)两侧子网间产生功率波动,使交流母线频率和直流母线电压动态响应变差,为此提出了基于分数阶滑模控制器(fractional order sliding mode controller, FOSMC)的双向下垂控制策略。将具有鲁棒性强、响应速度快和抗干扰能力强的滑模变结构控制引入到BIC的控制中,得到改进型的分数阶滑模控制器,以改善系统的暂态响应过程。通过Matlab/Simulink平台搭建了仿真模型,在多种工况下验证了该控制策略的有效性。与传统双向下垂控制相比,该控制算法可以在保证系统原有稳态特性的同时,加快整个系统的响应速度,抑制暂态过程中BIC传输功率的瞬间波动,减小功率波动对交直流子网母线的反作用,提高整个系统的动态性能和抗扰动性能。

VAE乳胶粉/碳纤维复合改性混凝土的力学性能

为探究醋酸乙烯酯-乙烯共聚物(VAE)乳胶粉和碳纤维对混凝土力学性能的混杂改性效果及机理,制备了1种VAE乳胶粉改性混凝土(VAEMC)、3种碳纤维改性混凝土(CFMC)和3种VAE乳胶粉/碳纤维复合改性混凝土(VAE/CFMC),测试了改性混凝土的电阻率和力学性能,并进行了扫描电镜试验和压汞试验.结果表明:VAE乳胶粉可以促进碳纤维的分散,VAE/CFMC的电阻率小于CFMC;与CFMC相比,VAE/CFMC的力学性能更佳;VAE乳胶粉与碳纤维具有“正混杂效应”,复掺VAE乳胶粉与碳纤维时,混凝土的力学性能呈现出“1+1>2”的复合增强效果;VAE乳胶粉可以优化CFMC的孔隙结构,细化其孔径,增强碳纤维/混凝土基体界面的物理结合,使碳纤维的破坏形式由拉滑破坏转变为拉断破坏.

铝/铜蓝-红激光复合焊接头组织及性能

为实现动力电池的高效可靠焊接,文中采用蓝-红复合激光进行了1050 Al/T2 Cu搭接焊,分析了激光功率对接头显微组织、相分布、力学性能及导电性能的影响规律.结果表明,铝/铜搭接接头焊缝表面平整,截面呈现T形,PB(蓝光功率)保持300 W,PR(红光功率)在700~1400 W区间内增加,铜侧熔深由60μm增大到1000μm,在PR=800 W时实现良好的冶金结合.焊缝组织由Al固溶体、Al-Cu共晶相和Al_(2)Cu金属间化合物组成,随激光功率增大,焊缝局部出现Al_(4)Cu_(9)相,边缘出现AlCu,Al_(4)Cu_(9)和AlCu_(3)相.在PR=800 W下抗剪强度达到最高108.6 MPa,接触电阻达到最小94μΩ,裂纹由两极交界处Al_(2)Cu区域萌生,沿焊缝边缘由外层Al_(2)Cu区扩展到底部Al固溶体和Al-Cu共晶区交界处,断裂形式为解理断裂.