In this work,several experiments were conducted at isobaric and isothermal condition in a CSTR reactor to study the kinetics of methane hydrate formation and dissociation.Experiments were performed at five temperature...In this work,several experiments were conducted at isobaric and isothermal condition in a CSTR reactor to study the kinetics of methane hydrate formation and dissociation.Experiments were performed at five temperatures and three pressure levels(corresponding to equilibrium pressure).Methane hydrate formation and dissociation rates were modeled using mass transfer limited kinetic models and mass transfer coefficients for both formation and dissociation were calculated.Comparison of results,shows that mass transfer coefficients for methane hydrate dissociation are one order greater than formation conditions.Mass transfer coefficients were correlated by polynomials as relations of pressure and temperature.The results and the method can be applied for prediction of methane production from naturally occurring methane hydrate deposits.展开更多
为探究枸杞真空冷冻干燥过程中的热质迁移,克服应力应变现象不能直观获取的问题,该研究通过对鲜枸杞切片试验图像二值化处理,建立了鲜枸杞真空冷冻干燥的热-质-结构耦合的物理模型,对真空冷冻干燥过程中枸杞温度变化、水分变化以及其内...为探究枸杞真空冷冻干燥过程中的热质迁移,克服应力应变现象不能直观获取的问题,该研究通过对鲜枸杞切片试验图像二值化处理,建立了鲜枸杞真空冷冻干燥的热-质-结构耦合的物理模型,对真空冷冻干燥过程中枸杞温度变化、水分变化以及其内部的应力应变进行了热-质-力耦合分析,并对分析结果进行试验验证。模拟分析结果表明,预冻结过程中,细胞始终在膨胀,当细胞完全冻结时细胞所受应力达到最大,而干燥阶段热质传递对应力影响较小。提高真空冷冻干燥过程中的升温速率,在一定程度上能够缩短冻干所需时间,并且真空冷冻干燥过程中的枸杞样本的含水率下降速率随干燥时间的增大而减小,该变化趋势与Wang and Singh模型更加贴合(R2为0.983)。试验验证结果表明,该研究建立的模型能够较好反映并预测真空冷冻干燥过程枸杞样本的温度及应力应变的变化趋势(R2为0.857)。研究结果可为真空冷冻干燥系统优化和工艺参数的科学制定提供参考。展开更多
文摘In this work,several experiments were conducted at isobaric and isothermal condition in a CSTR reactor to study the kinetics of methane hydrate formation and dissociation.Experiments were performed at five temperatures and three pressure levels(corresponding to equilibrium pressure).Methane hydrate formation and dissociation rates were modeled using mass transfer limited kinetic models and mass transfer coefficients for both formation and dissociation were calculated.Comparison of results,shows that mass transfer coefficients for methane hydrate dissociation are one order greater than formation conditions.Mass transfer coefficients were correlated by polynomials as relations of pressure and temperature.The results and the method can be applied for prediction of methane production from naturally occurring methane hydrate deposits.
文摘为探究枸杞真空冷冻干燥过程中的热质迁移,克服应力应变现象不能直观获取的问题,该研究通过对鲜枸杞切片试验图像二值化处理,建立了鲜枸杞真空冷冻干燥的热-质-结构耦合的物理模型,对真空冷冻干燥过程中枸杞温度变化、水分变化以及其内部的应力应变进行了热-质-力耦合分析,并对分析结果进行试验验证。模拟分析结果表明,预冻结过程中,细胞始终在膨胀,当细胞完全冻结时细胞所受应力达到最大,而干燥阶段热质传递对应力影响较小。提高真空冷冻干燥过程中的升温速率,在一定程度上能够缩短冻干所需时间,并且真空冷冻干燥过程中的枸杞样本的含水率下降速率随干燥时间的增大而减小,该变化趋势与Wang and Singh模型更加贴合(R2为0.983)。试验验证结果表明,该研究建立的模型能够较好反映并预测真空冷冻干燥过程枸杞样本的温度及应力应变的变化趋势(R2为0.857)。研究结果可为真空冷冻干燥系统优化和工艺参数的科学制定提供参考。
