Hydrochemical characteristics and evolution of groundwater in the dried-up river oasis of the Tarim Basin,Central Asia

Intense human activities in arid areas have great impacts on groundwater hydrochemical cycling by causing groundwater salinization.The spatiotemporal distributions of groundwater hydrochemistry are crucial for studying groundwater salt migration,and also vital to understand hydrological and hydrogeochemical processes of groundwater in arid inland oasis areas.However,due to constraints posed by the paucity of observation data and intense human activities,these processes are not well known in the dried-up river oases of arid areas.Here,we examined spatiotemporal variations and evolution of groundwater hydrochemistry using data from 199 water samples collected in the Wei-Ku Oasis,a typical arid inland oasis in Tarim Basin of Central Asia.As findings,groundwater hydrochemistry showed a spatiotemporal dynamic,while its spatial distribution was complex.TDS and δ18O of river water in the upstream increased from west to east,whereas ion concentrations of shallow groundwater increased from northwest to southeast.Higher TDS was detected in spring for shallow groundwater and in summer for middle groundwater.Pronounced spatiotemporal heterogeneity demonstrated the impacts of geogenic,climatic,and anthropogenic conditions.For that,hydrochemical evolution of phreatic groundwater was primarily controlled by rock dominance and evaporation-crystallization process.Agricultural irrigation and drainage,land cover change,and groundwater extraction reshaped the spatiotemporal patterns of groundwater hydrochemistry.Groundwater overexploitation altered the leaking direction between the aquifers,causing the interaction between saltwater and freshwater and the deterioration of groundwater environment.These findings could provide an insight into groundwater salt migration under human activities,and hence be significant in groundwater quality management in arid inland oasis areas.

Hydrochemical Dynamic Characteristics and Evolution of Underground Brine in the Mahai Salt Lake of the Qaidam Basin Qinghai-Tibet Plateau

The mineral rock salts present in the Mahai Salt Lake of the Qaidam basin exhibit high solubilities in water. In addition, the multicomponent underground brine exhibits a high salinity and is easily precipitated. In the natural state, brine transport in the brine layer is extremely slow, and the brine is in a relatively stable chemical equilibrium state with the rock salt media. However, during mining, both the seepage and the chemical fields fluctuate significantly, thereby disrupting the equilibrium and leading to variations in the chemical composition and dynamic characteristics of the brine. Therefore, we selected underground brine from the Mahai Salt Lake, collecting a total of 183 brine samples over three stages of mining（i.e., the early stage of underground brine extraction, the initial stage of mining, and the later stage of mining）. Using a range of analytical techniques, the chemical dynamics of the underground brine water and its evolution were systematically studied. We found that evaporation and enrichment were the main mechanisms of underground brine evolution in the Mahai Salt Lake, with cation exchange and mineral dissolution/precipitation being key factors in determining the dynamic characteristics and evolution of the brine.