Ag nanoparticles were sputter-deposited on ammonium persulfate((NH_4)_2S_2O_8) powder to obtain(NH_4)_2S_2O_8-Ag powder, which was used to synthesize the HCl-doped polyaniline-Ag(HCl-PANI-Ag) composite via a polymeriz...Ag nanoparticles were sputter-deposited on ammonium persulfate((NH_4)_2S_2O_8) powder to obtain(NH_4)_2S_2O_8-Ag powder, which was used to synthesize the HCl-doped polyaniline-Ag(HCl-PANI-Ag) composite via a polymerization procedure. The Ag nanoparticles were dispersed in the HCl-PANI matrix, and their sizes mainly ranged from 3 to 6 nm. The Ag nanoparticles did not affect the structure of emeraldine salt in the composite, and they increased the ordered crystalline regions in the HCl-PANI matrix. The HCl-PANI-Ag composite had a conductivity of(6.8 ± 0.1) S/cm, which is about four times larger than that of the HCl-PANI. The charge transport mechanism in the composite is explained by the three-dimensional Mott variable-range hopping(3D-Mott-VRH).展开更多
基金financially supported by the Fundamental Research Funds for the Central Universities of China (No. 8220)
文摘Ag nanoparticles were sputter-deposited on ammonium persulfate((NH_4)_2S_2O_8) powder to obtain(NH_4)_2S_2O_8-Ag powder, which was used to synthesize the HCl-doped polyaniline-Ag(HCl-PANI-Ag) composite via a polymerization procedure. The Ag nanoparticles were dispersed in the HCl-PANI matrix, and their sizes mainly ranged from 3 to 6 nm. The Ag nanoparticles did not affect the structure of emeraldine salt in the composite, and they increased the ordered crystalline regions in the HCl-PANI matrix. The HCl-PANI-Ag composite had a conductivity of(6.8 ± 0.1) S/cm, which is about four times larger than that of the HCl-PANI. The charge transport mechanism in the composite is explained by the three-dimensional Mott variable-range hopping(3D-Mott-VRH).
