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Hydrodynamic Effects on Surface Morphology Evolution of Titanium Alloy under Intense Pulsed Ion Beam Irradiation
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作者 董艇舰 荣翠华 +13 位作者 梁家昌 刘波 赵小勇 陈董燕 张彬 王浩 李海波 张世贵 蒋玉平 罗兵 周小文 王涛 喻晓 乐小云 《Chinese Physics Letters》 SCIE CAS CSCD 2017年第5期84-87,共4页
The hydrodynamic effects of molten surface of titanium alloy on the morphology evolution by intense pulsed ion beam (IPIB) irradiation are studied. It is experimentally revealed that under irradiation of IPIB pulses... The hydrodynamic effects of molten surface of titanium alloy on the morphology evolution by intense pulsed ion beam (IPIB) irradiation are studied. It is experimentally revealed that under irradiation of IPIB pulses, the surface morphology of titanium alloy in a spatial scale of μm exhibits an obvious smoothening trend. The mechanism of this phenomenon is explained by the mass transfer caused by the surface tension of molten metal. Hydrodynamic simulation with a combination of the finite element method and the level set method reveals that the change in curvature on the molten surface leads to uneven distribution of surface tension. Mass transfer is caused by the relief of surface tension, and meanwhile a flattening trend in the surface morphology evolution is achieved. 展开更多
关键词 hydrodynamic effects on Surface Morphology Evolution of Titanium Alloy under Intense Pulsed Ion Beam Irradiation
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Assessment of the Tidal Current Energy Resources and the Hydrodynamic Impacts of Energy Extraction at the PuHu Channel in Zhoushan Archipelago,China 被引量:1
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作者 WU He YU Huaming +3 位作者 FANG Yizhou ZHOU Qingwei ZHUO Fengxuan KELLY Ryan M. 《Journal of Ocean University of China》 SCIE CAS CSCD 2021年第3期478-488,共11页
An unstructured model FVCOM(The Unstructured Grid Finite Volume Community Ocean Model)with sink momentum term was applied to simulate the tidal current field in Zhoushan Archipelago,China,with focus on the region name... An unstructured model FVCOM(The Unstructured Grid Finite Volume Community Ocean Model)with sink momentum term was applied to simulate the tidal current field in Zhoushan Archipelago,China,with focus on the region named PuHu Channel between Putuo Island and Hulu Island.The model was calibrated with several measurements in the channel,and the model perform-ance was validated.An examination of the spatial and temporal distributions of tidal energy resources based on the numerical simula-tion revealed that the greatest power density of tidal energy during spring tide is 3.6kWm^(−2)at the northern area of the channel.Two parameters were introduced to characterize the generation duration of the tidal array that causes the temporal variation of tidal current energy.The annual average available energy in the channel was found to be approximately 2.6MW.The annual generating hours at rated power was found to be 1800 h when the installed capacity of tidal array is approximately 12MW.A site for the tidal array with 25 turbines was selected,and the layout of the array was configured based on the EMEC specifications.Hydrodynamic influence due to the deployment of the tidal array was simulated by the modified FVCOM model.The simulation showed that the tidal level did not significantly change because of the operation of the tidal array.The velocity reduction covered a 2km^(2)area of the downstream the tidal array,with a maximum velocity reduction of 8cms−1 at mid-flood tide,whereas the streamwise velocity on both sides of the farm increased slightly. 展开更多
关键词 tidal current energy resources assessment numerical simulation hydrodynamic effects
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A Hydrodynamic Model for Dimpled Mechanical Gas Seal Considering Interaction Effect 被引量:1
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作者 时礼平 黄巍 王晓雷 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2015年第4期438-445,共8页
The mechanical gas seal of aero engine has to face the problems of high wear rate and short lifetime.Surface texture has shown beneficial effects over the tribological characteristics.Here,a hydrodynamic model for dim... The mechanical gas seal of aero engine has to face the problems of high wear rate and short lifetime.Surface texture has shown beneficial effects over the tribological characteristics.Here,a hydrodynamic model for dimpled annular area of mechanical gas seal considering the″interaction effect″between adjacent dimples is developed based on the Reynolds equation.Different multi-row columns are chosen and the dimensionless pressure in radial and circumferential directions is calculated.The results indicate that the″interaction effect″is more obvious in the circumferential direction than in the radial direction,even when the area and depth of the dimples are same.Moreover,for the 5×5column,the dimensionless average pressure considering the″interaction effect″increases by45.41% compared with the 1×5column.Further analysis demonstrates that the model with the 5×5column can be more reasonable with the consideration of reducing the calculation error caused by boundary conditions to investigate the hydrodynamic effect for dimpled mechanical gas seal. 展开更多
关键词 surface texture mechanical gas seal hydrodynamic effect interaction effect aero engine
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Hydrodynamic Analysis of Elastic Floating Collars in Random Waves 被引量:5
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作者 白晓东 赵云鹏 +1 位作者 董国海 李玉成 《China Ocean Engineering》 SCIE EI CSCD 2015年第3期341-356,共16页
As the main load-bearing component of fish cages, the floating collar supports the whole cage and undergoes large deformations. In this paper, a mathematical method is developed to study the motions and elastic deform... As the main load-bearing component of fish cages, the floating collar supports the whole cage and undergoes large deformations. In this paper, a mathematical method is developed to study the motions and elastic deformations of elastic floating collars in random waves. The irregular wave is simulated by the random phase method and the statistical approach and Fourier transfer are applied to analyze the elastic response in both time and frequency domains. The governing equations of motions are established by Newton's second law, and the governing equations of deformations are obtained based on curved beam theory and modal superposition method. In order to validate the numerical model of the floating collar attacked by random waves, a series of physical model tests are conducted. Good relationship between numerical simulation and experimental observations is obtained. The numerical results indicate that the transfer function of out-of-plane and in-plane deformations increase with the increasing of wave frequency. In the frequency range between 0.6 Hz and 1.1 Hz, a linear relationship exists between the wave elevations and the deformations. The average phase difference between the wave elevation and out-of-plane deformation is 60° with waves leading and the phase between the wave elevation and in-plane deformation is 10° with waves lagging. In addition, the effect of fish net on the elastic response is analyzed. The results suggest that the deformation of the floating collar with fish net is a little larger than that without net. 展开更多
关键词 floating collars random waves hydrodynamic characteristics in-plane and out-of-plane deformation net effect
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Natural convection flow of a couple stress fluid between two vertical parallel plates with Hall and ion-slip effects 被引量:1
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作者 D.Srinivasacharya K.Kaladhar 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2012年第1期41-50,共10页
The Hall and ion-slip effects on fully developed electrically conducting couple stress fluid flow between vertical parallel plates in the presence of a temperature dependent heat source are investigated. The governing... The Hall and ion-slip effects on fully developed electrically conducting couple stress fluid flow between vertical parallel plates in the presence of a temperature dependent heat source are investigated. The governing non-linear partial differential equations are transformed into a system of ordinary differential equations using similarity transformations. The resulting equations are then solved using the homotopy analysis method (HAM). The effects of the magnetic parameter, Hall parameter, ion-slip parameter and couple stress fluid parameter on velocity and temperature are discussed and shown graphically 展开更多
关键词 Free convection Couple stress fluid Magneto- hydrodynamics Hall and ion-slip effects - HAM
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Numerical analysis of submarine landslides using a smoothed particle hydrodynamics depth integral model 被引量:2
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作者 WANG Zhongtao LI Xinzhong +1 位作者 LIU Peng TAO Yanqi 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2016年第5期134-140,共7页
Submarine landslides can cause severe damage to marine engineering structures. Their sliding velocity and runout distance are two major parameters for quantifying and analyzing the risk of submarine landslides.Current... Submarine landslides can cause severe damage to marine engineering structures. Their sliding velocity and runout distance are two major parameters for quantifying and analyzing the risk of submarine landslides.Currently, commercial calculation programs such as BING have limitations in simulating underwater soil movements. All of these processes can be consistently simulated through a smoothed particle hydrodynamics(SPH) depth integrated model. The basis of the model is a control equation that was developed to take into account the effects of soil consolidation and erosion. In this work, the frictional rheological mode has been used to perform a simulation study of submarine landslides. Time-history curves of the sliding body's velocity, height,and length under various conditions of water depth, slope gradient, contact friction coefficient, and erosion rate are compared; the maximum sliding distance and velocity are calculated; and patterns of variation are discussed.The findings of this study can provide a reference for disaster warnings and pipeline route selection. 展开更多
关键词 sliding velocity runout distance smoothed particle hydrodynamics depth integral method frictional rheological model erosion effect
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Friction Characteristics of Mechanical Seals with Laser-textured Seal Faces 被引量:9
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作者 YU Xin-qi 1,2, HE Song 1, CAI Ren-ling 1 (1. Research Institute of Pressure Vessel and Process Equi pment, East China University of Science and Technology, Shanghai 200237, China 2. College of Mechanical Science and Engineering, Hebei University of Science an d Technology, Shijiazhuang 050018, China) 《厦门大学学报(自然科学版)》 CAS CSCD 北大核心 2002年第S1期157-,共1页
Heat generated by friction between faces of mechanica l seals is a major factor that causes deterioration of the seals and shortens th eir service life. Excessive temperature rise can greatly alter the seal geometry a... Heat generated by friction between faces of mechanica l seals is a major factor that causes deterioration of the seals and shortens th eir service life. Excessive temperature rise can greatly alter the seal geometry and vaporize the sealing fluid, resulting in friction of boundary lubrication. These effects on face seals usually lead to excessive leakage and ultimately ren der the seal inoperable. In order to maintain the reliability of seals, high fri ction and unwanted wear must be avoided. Using the laser-texturing process to produce regular micro-surface structures is a fast and convenient technique compared to some more conventional etching or erosion technique currently used by the seal industry for various grooved face seals. Indeed, by using a pulse laser, better control is obtained on the geometr y, size and pore ratio of seal rings made of metallic or ceramic materials. In t his study, seal rings are made of silicon carbide and carbon. Mating faces of th e rings are polished and only silicon carbide rings are laser-textured. The las er texturing can be controlled to produce spherical pores at selected diameters, depths and pore ratio. The textured rings are then super-polished to remove th e bulges formed on the pores rims. After this process the average pore diameter, pore depth and pore ratio reach the predetermined parameter. Some untextured ri ngs are also treated to the same surface roughness and served as a reference for comparison of the textured rings. A special test rig is used to simulate a mech anical seal system and to measure the effect of the laser texturing on friction and seal performance. Tests are performed at various rotational speeds and vario us axial loads. Compared with the conventional mechanical seals, temperature rise, friction torq ue and friction coefficient of mechanical seals with laser-textured seal faces are much lower. These preliminary results show the potential of improving fricti on performance and increasing seal life with laser-textured seal faces. 展开更多
关键词 LASER mechanical seals friction characteristics hydrodynamic effects
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SPATIAL DISTRIBUTION OF NUTRIENTS OF SHALLOW LAKE IN THE ZHALONG WETLAND 被引量:4
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作者 WANG Lei ZHANG Guang-Xin 《湿地科学》 CSCD 2006年第3期193-197,共5页
The Zhalong wetland,a Ramsar listed wetland in China,which is located in the lower reaches of theWuyu’er River,perennially takes in lots of nutrient input of N and P from around the catchment.Nutrient substanceswere ... The Zhalong wetland,a Ramsar listed wetland in China,which is located in the lower reaches of theWuyu’er River,perennially takes in lots of nutrient input of N and P from around the catchment.Nutrient substanceswere especially accumulated in the shallowlakes owning to the low-lying topography.The Xianhe Lake,where is loca-ted in buffer zone of the Zhalong wetland reserve,was chosen as our target area.The spatial variation of nutrient sub-stances in the shallow lakes was discussed and its influence factors were pointed out.The results showed that nitrogenand phosphorus in the wetland water existed mainly in the form of organic ones.The concentration of total nitrogen(TN)ranged from 0.65 mg/L to 10.64 mg/L and total phosphorus(TP) ranged from 0.013 mg/L to 0.052 mg/L.Ratio ofN/P was between 25.6 and 206.5.The water quality of the Xianhe Lake has been contaminated and is in heavy eutroph-ication.Total P has been acting as the major limiting factor.The distribution pattern of nitrogen and phosphorus in wet-land water showed characteristics of internal release except for the stream mouth area.There,the vertical distributions ofnitrogen and phosphorus nutrients were from both exterior source and internal release,and was mainly influenced by ex-terior source during flood period.Strong hydrodynamic disturb contributed to nitrogen and phosphorus nutrients suspen-ding and releasing in the sediments.The nutrients distribution in the water varied independent on regional changes ofdifferent frequency of hydrodynamic disturb.Mineralization and denitrification might be promoted in high frequency hy-drodynamic disturb area.In growing period,the absorption ofPhragmitesto nutrients was an important mechanism of nu-trients descending and spatial variation in the shallow lake. 展开更多
关键词 the Zhalong wetland NITROGEN PHOSPHORUS hydrodynamic effect plant absorption
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A composite micromotor driven by self-thermophoresis and Brownian rectification
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作者 Xin Lou Nan Yu +3 位作者 Ke Chen Xin Zhou Rudolf Podgornik Mingcheng Yang 《Chinese Physics B》 SCIE EI CAS CSCD 2021年第11期107-111,共5页
Brownian motors and self-phoretic microswimmers are two typical micromotors,for which thermal fluctuations play different roles.Brownian motors utilize thermal noise to acquire unidirectional motion,while thermal fluc... Brownian motors and self-phoretic microswimmers are two typical micromotors,for which thermal fluctuations play different roles.Brownian motors utilize thermal noise to acquire unidirectional motion,while thermal fluctuations randomize the self-propulsion of self-phoretic microswimmers.Here we perform mesoscale simulations to study a composite micromotor composed of a self-thermophoretic Janus particle under a time-modulated external ratchet potential.The composite motor exhibits a unidirectional transport,whose direction can be reversed by tuning the modulation frequency of the external potential.The maximum transport capability is close to the superposition of the drift speed of the pure Brownian motor and the self-propelling speed of the pure self-thermophoretic particle.Moreover,the hydrodynamic effect influences the orientation of the Janus particle in the ratched potential,hence also the performance of the composite motor.Our work thus provides an enlightening attempt to actively exploit inevitable thermal fluctuations in the implementation of the self-phoretic microswimmers. 展开更多
关键词 Brownian motors self-phoretic microswimmers thermal noise hydrodynamic effect
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Diffusion of a chemically active colloidal particle in composite channels
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作者 Xin Lou Rui Liu +3 位作者 Ke Chen Xin Zhou Rudolf Podgornik Mingcheng Yang 《Chinese Physics B》 SCIE EI CAS CSCD 2022年第4期436-440,共5页
Diffusion of colloidal particles in microchannels has been extensively investigated,where the channel wall is either a no-slip or a slip-passive boundary.However,in the context of active fluids,driving boundary walls ... Diffusion of colloidal particles in microchannels has been extensively investigated,where the channel wall is either a no-slip or a slip-passive boundary.However,in the context of active fluids,driving boundary walls are ubiquitous and are expected to have a substantial effect on the particle dynamics.By mesoscale simulations,we study the diffusion of a chemically active colloidal particle in composite channels,which are constructed by alternately arranging the no-slip and diffusio-osmotic boundary walls.In this case,the chemical reaction catalyzed by the active colloidal particle creates a local chemical gradient along the channel wall,which drives a diffusio-osmotic flow parallel to the wall.We show that the diffusio-osmotic flow can significantly change the spatial distribution and diffusion dynamics of the colloidal particle in the composite channels.By modulating the surface properties of the channel wall,we can achieve different patterns of colloidal position distribution.The findings thus propose a novel possibility to manipulate colloidal diffusion in microfluidics,and highlight the importance of driving boundary walls in dynamics of colloidal particles in microchannels. 展开更多
关键词 DIFFUSION composite channels diffusio-osmotic flow hydrodynamic effect
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Increasing operational stability of journal bearing in hydraulic suspension micro-pump by herringbone grooved structure
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作者 HONG Tao XING GuanYing +2 位作者 ZUO HuaiYu XUE Song LUO XiaoBing 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2024年第3期853-862,共10页
The operational stability of radial journal bearings is the bottleneck that limits the reliability of hydraulic suspension micropump. Due to self-excited vibrations, the whirl amplitude of the plain journal bearing(PJ... The operational stability of radial journal bearings is the bottleneck that limits the reliability of hydraulic suspension micropump. Due to self-excited vibrations, the whirl amplitude of the plain journal bearing(PJB) is large at high rotational speeds,which will accelerate wear failure. It has been proven that employing herringbone grooved journal bearing(HGJB) is an effective method to reduce the whirl amplitude and improve operational stability. However, enhancing the stability of journal bearings in micro-pumps by herringbone grooved structures has rarely been studied, and its effect needs to be verified. We validated the mechanism of the stability improvement with the CFD method and compared the dynamic characteristics of HGJB and PJB by rotor dynamics evaluation and experiment. The experimental results show that under the same conditions the whirl amplitude of the HGJB decreases by 29.61% in the x direction and by 24.09% in the y direction compared with that of the PJB. This study reveals the effect of the herringbone grooved structure on the operational stability of bearings and may provide guidance for the reliability improvement of hydraulic suspension micro-pump. 展开更多
关键词 journal bearing herringbone groove hydrodynamic effect micro-pump
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Experimental study on hydrodynamic effect of orientation micro-pored surfaces 被引量:20
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作者 BAI ShaoXian1,2, PENG XuDong1,2, LI JiYun1,2 & MENG XiangKai1,2 1College of Mechanical Engineering, Zhejiang University of Technology, Hangzhou 310032, China 2Key Laboratory of Special Purpose Equipment and Advanced Processing Technology, Ministry of Education, Zhejiang University of Technology, Hangzhou 310032, China 《Science China(Technological Sciences)》 SCIE EI CAS 2011年第3期659-662,共4页
The orientation of the dimple increases the flow distance in the dimple and produces fluid cumulative effect in the dimple length direction, which leads to obvious hydrodynamic effect as a result. In order to investig... The orientation of the dimple increases the flow distance in the dimple and produces fluid cumulative effect in the dimple length direction, which leads to obvious hydrodynamic effect as a result. In order to investigate the hydrodynamic effect of orientation dimples, a series of experiments was carried out on a ring-on-ring test. Multi-pored faces were tested with different dimple inclination angles and slender ratios. Film thickness and frictional torque were measured under different conditions of load and rotation speed. Experimental results showed that the orientation dimple could produce obvious dynamic effect by change of the flow direction and the increasing dimple orientation leads to increase of the load capability. The hydrodynamic effect strongly depends on dimple orientation parameters such as inclination angle and slender ratio. A larger load capability can be available by increasing dimple orientation and rotation speed. Experimental results agreed well with the theory that orientation micro-pores can significantly improve hydrodynamic performance of surfaces. 展开更多
关键词 orientation micro-pore multi-pored face hydrodynamic effect
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The effective hydrodynamic radius in the Stokes-Einstein relation is not a constant 被引量:1
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作者 Gan Ren 《Communications in Theoretical Physics》 SCIE CAS CSCD 2022年第9期177-182,共6页
Variants based on the assumption of effective hydrodynamic radius being a constant are usually adopted to test the Stokes-Einstein(SE)relation.The rationality of the assumption is examined by performing molecular dyna... Variants based on the assumption of effective hydrodynamic radius being a constant are usually adopted to test the Stokes-Einstein(SE)relation.The rationality of the assumption is examined by performing molecular dynamics simulations with the truncated Lennard-Jones-like(TLJ)model,Kob-Andersen model and ortho-terphenyl(OTP)model.The results indicate the assumption is generally not established except for special case.The effective hydrodynamic radius is observed to increase with decreasing temperature for TLJ model but is decreased for Kob-Andersen and OTP model;and which is almost a constant for TLJ particle with enough rigidity.The variant of SE relation D~Th is invalid for the three models except for the TLJ particle with enough rigidity.We propose similar inconsistency may be also existed in other liquids and the assumption should be critically evaluated when adopted to test the SE relation. 展开更多
关键词 Stokes-Einstein relation effective hydrodynamic radius Stokes’formula
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HYDRODYNAMIC RESISTANCE EFFECT OF FLUID LAYER BETWEEN TWO IMMERSED APPROACHING PARTICLES
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作者 Yanpeng Li Bofeng Bai 《China Particuology》 SCIE EI CAS CSCD 2006年第5期220-228,共9页
A three-dimensional direct simulation of an immersed solid particle approaching another particle, or a flat wall, is conducted to investigate the mechanics of hydrodynamic impact of immersed particles. The simulation ... A three-dimensional direct simulation of an immersed solid particle approaching another particle, or a flat wall, is conducted to investigate the mechanics of hydrodynamic impact of immersed particles. The simulation method is based on a modified immersed boundary method using a fixed grid system. When the particle separation distance becomes smaller than grid spacing, to account for the hydrodynamic resistance effect of liquid layer between particles near contact, a microlayer model is developed to allow determination of the pressure profile within the micro-layer without neglecting the inertial force of the layer flow. The pressure force is then taken into account in equation of particle motion. Comparisons of the simulation results with the experimental results reported in the literature are shown to substantiate the model presented in this study. The simulations reveal the complex three-dimensional flow field of the liquid and the motion of the approaching particle. The fluid pressure in the gap caused by the unsteady motion of the particle is significantly increased when the separation distance of particles is less than about one-tenth diameters of particle. Therefore the velocity of approaching particle starts to decrease due to the hydrodynamic resistance force at this position. 展开更多
关键词 direct simulation microlayer model immersed boundary method hydrodynamic resistance effect
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Modeling the electrostatic effect on the hydrodynamic behavior in FCC risers: From understanding to application
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作者 Guoqiang Chen Qinglin Su Zhenghong LUO 《Particuology》 SCIE EI CAS CSCD 2016年第2期122-132,共11页
A CFD simulation was proposed to investigate the electrostatic effect on the hydrodynamic behavior of turbulent gas-solid flow in FCC risers. The simulation was first verified using the open experimental data with exp... A CFD simulation was proposed to investigate the electrostatic effect on the hydrodynamic behavior of turbulent gas-solid flow in FCC risers. The simulation was first verified using the open experimental data with expected electrostatic effects observed in FCC risers. The influences of several operating parameters on the degree of electrification in FCC risers were analyzed, such as surface charge densities, pressure, gas velocity. It was noted that the gas velocity played a highly significant role compared with solid flux, while the effect of pressure was relatively weak. Further analysis showed that a much stronger electrostatic effect was found in small-scale FCC risers than their large-scale counterparts, and in addition, the major regions affected by the electrostatic charge depend on the scale of the riser. Finally, an external electric field was applied to optimize the flow field distribution in the FCC riser. The results of the electrostatic effects on the hydrodynamic behaviors in FCC risers are of great use in providing a reference for the optimization of FCC risers and their scaling. 展开更多
关键词 Multiphase flow Mathematical modeling hydrodynamics FCC riser Electrostatic effect
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Tribological mechanisms of slurry abrasive wear 被引量:3
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作者 Yulong LI Paul SCHREIBER +1 位作者 Johannes SCHNEIDER Christian GREINER 《Friction》 SCIE EI CAS CSCD 2023年第6期1079-1093,共15页
Abrasive wear mechanisms—including two-body and three-body abrasion—dominate the performance and lifespan of tribological systems in many engineering fields,even of those operating in lubricated conditions.Bearing s... Abrasive wear mechanisms—including two-body and three-body abrasion—dominate the performance and lifespan of tribological systems in many engineering fields,even of those operating in lubricated conditions.Bearing steel(100Cr6)pins and discs in a flat-on-flat contact were utilized in experiments together with 5 and 13 μm Al_(2)O_(3)-based slurries as interfacial media to shed light on the acting mechanisms.The results indicate that a speed-induced hydrodynamic effect occurred and significantly altered the systems'frictional behavior in tests that were performed using the 5 μm slurry.Further experiments revealed that a speed-dependent hydrodynamic effect can lead to a 14% increase in film thickness and a decrease in friction of around 2/3,accompanied by a transition from two-body abrasion to three-body abrasion and a change in wear mechanism from microcutting and microploughing to fatigue wear.Surprisingly,no correlation could be found between the total amount of wear and the operating state of the system during the experiment;however,the wear distribution over pin and disc was observed to change significantly.This paper studies the influence of the hydrodynamic effect on the tribological mechanism of lubricated abrasive wear and also highlights the importance to not only consider a tribological systems'global amount of wear. 展开更多
关键词 abrasive wear two-body abrasion three-body abrasion hydrodynamic effect STEEL
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Intrinsic viscosity of polymer solutions: fresh ideas to an old problem 被引量:2
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作者 Deyue Yan 《Science China Chemistry》 SCIE EI CAS CSCD 2015年第5期835-838,共4页
Intrinsic viscosity is one of the most fundamental properties of dilute polymer solutions; its study forms an integral part of the cornerstone of the modern macromolecular theory. However, a general theory applicable ... Intrinsic viscosity is one of the most fundamental properties of dilute polymer solutions; its study forms an integral part of the cornerstone of the modern macromolecular theory. However, a general theory applicable to any chain architectures and solvent conditions has remained elusive, due to the formidable challenges in the theoretical treatment of the long-range, many-body and accumulative hydrodynamic effects. Recently, Lijia An and coworkers at the Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, has developed a new approach that largely overcomes these challenges. Their new theory provides a simple and unified theoretical framework for describing the intrinsic viscosity of polymers with arbitrary architectures under any solvent conditions and forms the theoretical basis for inferring the polymer chain structure from intrinsic viscosity measurements. Comparisons with existing experimental data yield extensive, quantitative agreement. 展开更多
关键词 polymer solution intrinsic viscosity polymer chain structure hyperbranched polymers hydrodynamic effects
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