The presented article shows an estimation method of optimum autofrettage pressure taking into consideration subsequent cyclic loading. An autofrettage process is used in pressure vessel applications for strength impro...The presented article shows an estimation method of optimum autofrettage pressure taking into consideration subsequent cyclic loading. An autofrettage process is used in pressure vessel applications for strength improvement. The process relies on applying massive pressure that causes internal portions of the part to yield plastically, resulting in internal compressive residual stresses when pressure is released. Later applied working pressure (much lower than autofrettage pressure) creates stress reduced by the residual compressive stress improving the structural performance of the pressure vessels. The optimum autofrettage pressure is a load that maximizes the fatigue life of the structure at the working load. The estimation method of that pressure of a hydrogen valve is the subject of the presented work. Finite element and fatigue analyses were employed to investigate the presented problem. An automated model was developed to analyze the design for various autofrettage pressures. As the results of the procedure, the optimum autofrettage pressure is determined. The research has shown that the developed method can profitably investigate the complex parts giving the autofrettage load that maximizes the fatigue life. The findings suggest that the technique can be applied to a large group of products subjected to the autofrettage process.展开更多
This study evaluated the Cretaceous(Campanian–Maastrichtian) kaolinitic sediments of the Ajali/Mamu and Enugu/Nkporo Formations from the Lower Benue Trough of Nigeria. A combined method of inductively coupled plasma...This study evaluated the Cretaceous(Campanian–Maastrichtian) kaolinitic sediments of the Ajali/Mamu and Enugu/Nkporo Formations from the Lower Benue Trough of Nigeria. A combined method of inductively coupled plasma–mass spectrometry and isotope ratio mass spectrometry was used to investigate trace and rareearth element geochemistry and hydrogen and oxygen isotopic compositions. These data were then used to infer the sediments' provenance and paleoclimatic conditions during their deposition. The sediments contained low concentrations of most trace elements, with the exceptions of Zr(651–1352 ppm), Ba(56–157 ppm), V(38–90 ppm),and Sr(15.1–59.6 ppm). Average values of Co and Ni were1.5 and 0.7 ppm, respectively. Trace and rare earth element values were lower than corresponding values for upper continental crust and Post-Archean Australian Shale, with the exception of Zr. The samples showed only slight light rare-earth enrichment and nearly flat heavy rare-earth depletion patterns, with negative Eu and Tm anomalies,typical of felsic sources. Geochemical parameters such as La/Sc, Th/Sc, and Th/Co ratios support that the kaolinitic sediments were derived from a felsic rock source, likely deposited in an oxic environment.^(18 )O values ranged from+ 15.4 to + 21.2% for the investigated samples, consistent with a residual material derived from chemicalweathering of felsic rock and redeposited in a sedimentary basin(typical values of + 19 to + 21.2%). While in the basin, the sediments experienced extended interactions with meteoric water enriched in d D and d16 O. However,the variation in d D and d16 O values for the investigated samples is attributed to the high temperature of formation(54–91 °C). The d D and d^(18 )O values suggest that the sediments, although obtained from different localities within the Lower Benue Trough, formed under similar hot,tropical climatic conditions.展开更多
The hydrogen distribution of 16MnR steel weldment in hydrogen contained environment was calculated using the finite element method （ FEM）. The effect of welding residual stress on hydrogen diffusion has been discuss...The hydrogen distribution of 16MnR steel weldment in hydrogen contained environment was calculated using the finite element method （ FEM）. The effect of welding residual stress on hydrogen diffusion has been discussed using a 3-D sequential coupling finite element analysis procedure complied by Abaqus code. The hydrogen diffusion coefficient in weld metal, the heat affected zone （HAZ）, and the base metal of the 16MnR steel weldment were measured using the electrochemical permeation technique. The hydrogen diffusion without the effect of stress was also calculated and compared. Owing to the existence of welding residual stress, the hydrogen concentration was obviously increased and the hydrogen wouM diffuse and accumulate in the higher stress region.展开更多
In this paper,the influence of microelements yttrium(Y)and tellurium(Te)on the diffusible hydrogen in weld bead has been investigated in a systemic way by means of alloying addition in the molten pool(AAMP).The result...In this paper,the influence of microelements yttrium(Y)and tellurium(Te)on the diffusible hydrogen in weld bead has been investigated in a systemic way by means of alloying addition in the molten pool(AAMP).The results indicate that AAMP can notably reduce the diffusible hydrogen,economize the precious microelements microelements and improve the technological properties.Thus the microelements will play an important role in further developing the welding materials.This paper lays emphasis on the discussion of the mechanism of reducing hydrogen by microelements Y and Te.It is considered from the results that both Y and Te belong to surface active elements and can reduce the diffusible hydrogen in weld bead because they can change the surface properlies of molten pool metal and reduce the absorption of hydrogen atom in arc space of liquid metal surface.This research has a great significance in the development and utilization of microelements in welding.展开更多
The hydrogen content in molten Al Cu alloy increases remarkably when the temperature of the melt rises to about 780 ℃. The effects of alloying element are theoretically analyzed in terms of Wagner interaction paramet...The hydrogen content in molten Al Cu alloy increases remarkably when the temperature of the melt rises to about 780 ℃. The effects of alloying element are theoretically analyzed in terms of Wagner interaction parameter. Furthermore, analyses indicate that the alloy element Cu plays an important role in the hydrogen content in superheated Al Cu alloy melt below about 780 ℃. The conclusion is drawn that the degree of gassing in molten Al Cu alloy is bound up with the properties of oxide film of Al alloy melts. The results make it clear that the hydrogen content in the molten aluminum reduces with increasing element Cu dissolved in aluminum melts at the same temperature. [展开更多
A series of selective dissolution experiments were conducted on the hydrogenic ferromanganese crusts collected near Line Island to study the geochemistry of Mn, Fe, Cu, Co, Ni and Ti. Despite of the fact that the very...A series of selective dissolution experiments were conducted on the hydrogenic ferromanganese crusts collected near Line Island to study the geochemistry of Mn, Fe, Cu, Co, Ni and Ti. Despite of the fact that the very close intergrowth between amorphous ferric oxyhydroxides and δ-MnO2 exists in the hydrogenic ferromanganese crusts, there is no isomorphous substitution between iron and manganese. This is because the two elements in oxides have different crystal chemistry and geochemistry, such assertion being in agreement with the results of selective dissolution experiments. Transitional metal elements such as Cu, Co, Ni and Ti are enriched in different phases, i.e. Ni and Co are incorporated into δ-MnO2 while Cu and Ti are incorporated into ferric oxyhydroxides. The distributions of the elements in amorphous ferric oxyhydroxides and δ-MnO2 are controlled by the existing states of the elements in the seawater and the crystal chemistry and geochemistry of these elements/ions in oxides.展开更多
In this paper, the general calculation formulas of radial matrix elements for relativistic n-dimensional hydrogen atom of spin S=0 are obtained, and the recurrence relation of different power order radial matrix eleme...In this paper, the general calculation formulas of radial matrix elements for relativistic n-dimensional hydrogen atom of spin S=0 are obtained, and the recurrence relation of different power order radial matrix elements are also derived.展开更多
文摘The presented article shows an estimation method of optimum autofrettage pressure taking into consideration subsequent cyclic loading. An autofrettage process is used in pressure vessel applications for strength improvement. The process relies on applying massive pressure that causes internal portions of the part to yield plastically, resulting in internal compressive residual stresses when pressure is released. Later applied working pressure (much lower than autofrettage pressure) creates stress reduced by the residual compressive stress improving the structural performance of the pressure vessels. The optimum autofrettage pressure is a load that maximizes the fatigue life of the structure at the working load. The estimation method of that pressure of a hydrogen valve is the subject of the presented work. Finite element and fatigue analyses were employed to investigate the presented problem. An automated model was developed to analyze the design for various autofrettage pressures. As the results of the procedure, the optimum autofrettage pressure is determined. The research has shown that the developed method can profitably investigate the complex parts giving the autofrettage load that maximizes the fatigue life. The findings suggest that the technique can be applied to a large group of products subjected to the autofrettage process.
文摘This study evaluated the Cretaceous(Campanian–Maastrichtian) kaolinitic sediments of the Ajali/Mamu and Enugu/Nkporo Formations from the Lower Benue Trough of Nigeria. A combined method of inductively coupled plasma–mass spectrometry and isotope ratio mass spectrometry was used to investigate trace and rareearth element geochemistry and hydrogen and oxygen isotopic compositions. These data were then used to infer the sediments' provenance and paleoclimatic conditions during their deposition. The sediments contained low concentrations of most trace elements, with the exceptions of Zr(651–1352 ppm), Ba(56–157 ppm), V(38–90 ppm),and Sr(15.1–59.6 ppm). Average values of Co and Ni were1.5 and 0.7 ppm, respectively. Trace and rare earth element values were lower than corresponding values for upper continental crust and Post-Archean Australian Shale, with the exception of Zr. The samples showed only slight light rare-earth enrichment and nearly flat heavy rare-earth depletion patterns, with negative Eu and Tm anomalies,typical of felsic sources. Geochemical parameters such as La/Sc, Th/Sc, and Th/Co ratios support that the kaolinitic sediments were derived from a felsic rock source, likely deposited in an oxic environment.^(18 )O values ranged from+ 15.4 to + 21.2% for the investigated samples, consistent with a residual material derived from chemicalweathering of felsic rock and redeposited in a sedimentary basin(typical values of + 19 to + 21.2%). While in the basin, the sediments experienced extended interactions with meteoric water enriched in d D and d16 O. However,the variation in d D and d16 O values for the investigated samples is attributed to the high temperature of formation(54–91 °C). The d D and d^(18 )O values suggest that the sediments, although obtained from different localities within the Lower Benue Trough, formed under similar hot,tropical climatic conditions.
文摘The hydrogen distribution of 16MnR steel weldment in hydrogen contained environment was calculated using the finite element method （ FEM）. The effect of welding residual stress on hydrogen diffusion has been discussed using a 3-D sequential coupling finite element analysis procedure complied by Abaqus code. The hydrogen diffusion coefficient in weld metal, the heat affected zone （HAZ）, and the base metal of the 16MnR steel weldment were measured using the electrochemical permeation technique. The hydrogen diffusion without the effect of stress was also calculated and compared. Owing to the existence of welding residual stress, the hydrogen concentration was obviously increased and the hydrogen wouM diffuse and accumulate in the higher stress region.
文摘In this paper,the influence of microelements yttrium(Y)and tellurium(Te)on the diffusible hydrogen in weld bead has been investigated in a systemic way by means of alloying addition in the molten pool(AAMP).The results indicate that AAMP can notably reduce the diffusible hydrogen,economize the precious microelements microelements and improve the technological properties.Thus the microelements will play an important role in further developing the welding materials.This paper lays emphasis on the discussion of the mechanism of reducing hydrogen by microelements Y and Te.It is considered from the results that both Y and Te belong to surface active elements and can reduce the diffusible hydrogen in weld bead because they can change the surface properlies of molten pool metal and reduce the absorption of hydrogen atom in arc space of liquid metal surface.This research has a great significance in the development and utilization of microelements in welding.
文摘The hydrogen content in molten Al Cu alloy increases remarkably when the temperature of the melt rises to about 780 ℃. The effects of alloying element are theoretically analyzed in terms of Wagner interaction parameter. Furthermore, analyses indicate that the alloy element Cu plays an important role in the hydrogen content in superheated Al Cu alloy melt below about 780 ℃. The conclusion is drawn that the degree of gassing in molten Al Cu alloy is bound up with the properties of oxide film of Al alloy melts. The results make it clear that the hydrogen content in the molten aluminum reduces with increasing element Cu dissolved in aluminum melts at the same temperature. [
基金supported by China Ocean Mineral Resources Research and Development Association (COMRA) (DY105-05-01-05)China Ministry of Education (205089)China National Natural Science Foundation (40076015).
文摘A series of selective dissolution experiments were conducted on the hydrogenic ferromanganese crusts collected near Line Island to study the geochemistry of Mn, Fe, Cu, Co, Ni and Ti. Despite of the fact that the very close intergrowth between amorphous ferric oxyhydroxides and δ-MnO2 exists in the hydrogenic ferromanganese crusts, there is no isomorphous substitution between iron and manganese. This is because the two elements in oxides have different crystal chemistry and geochemistry, such assertion being in agreement with the results of selective dissolution experiments. Transitional metal elements such as Cu, Co, Ni and Ti are enriched in different phases, i.e. Ni and Co are incorporated into δ-MnO2 while Cu and Ti are incorporated into ferric oxyhydroxides. The distributions of the elements in amorphous ferric oxyhydroxides and δ-MnO2 are controlled by the existing states of the elements in the seawater and the crystal chemistry and geochemistry of these elements/ions in oxides.
文摘In this paper, the general calculation formulas of radial matrix elements for relativistic n-dimensional hydrogen atom of spin S=0 are obtained, and the recurrence relation of different power order radial matrix elements are also derived.
