The time of the energy emission between two neighbouring electron levels in the hydrogen atom has been calculated first on the basis of the quantum aspects of the Joule-Lenz law, next this time is approached with the ...The time of the energy emission between two neighbouring electron levels in the hydrogen atom has been calculated first on the basis of the quantum aspects of the Joule-Lenz law, next this time is approached with the aid of the electrodynamical parameters characteristic for the electron motion in the atom. Both methods indicate a similar result, namely that the time of emission is close to the time period of the electromagnetic wave produced in course of the emission. As a by-product of calculations, the formula representing the radius of the electron microparticle is obtained from a simple combination of the expressions for the Bohr magnetic moment and a quantum of the magnetic flux.展开更多
Optical emission spectroscopy(OES), as a simple in situ method without disturbing the plasma, has been performed for the plasma diagnosis of a 2.45 GHz permanent magnet electron cyclotron resonance(PMECR) ion sour...Optical emission spectroscopy(OES), as a simple in situ method without disturbing the plasma, has been performed for the plasma diagnosis of a 2.45 GHz permanent magnet electron cyclotron resonance(PMECR) ion source at Peking University(PKU). A spectrum measurement platform has been set up with the quartz-chamber electron cyclotron resonance(ECR) ion source [Patent Number: ZL 201110026605.4] and experiments were carried out recently. The electron temperature and electron density inside the ECR plasma chamber have been measured with the method of line intensity ratio of noble gas. Hydrogen plasma processes inside the discharge chamber are discussed based on the diagnostic results. What is more, the superiority of the method of line intensity ratio of noble gas is indicated with a comparison to line intensity ratio of hydrogen. Details will be presented in this paper.展开更多
Hydrogen sulfide(H_(2)S)emitted from construction and demolition waste landfills has received increasing attention.Besides its unpleasant odor,longterm exposure to a very low concentration of H_(2)S can cause a public...Hydrogen sulfide(H_(2)S)emitted from construction and demolition waste landfills has received increasing attention.Besides its unpleasant odor,longterm exposure to a very low concentration of H_(2)S can cause a public health issue.In the case of construction and demolition(C&D)waste landfills,where gas collection systems are not normally required,the generated H_(2)S is typically not controlled and the number of treatment processes to control H_(2)S emissions in situ is limited.An attractive alternative may be to use chemically or biologically active landfill covers.A few studies using various types of cover materials to attenuate H_(2)S emissions demonstrated that H_(2)S emissions can be effectively reduced.In this study,therefore,the costs and benefits of H_(2)S-control cover systems including compost,soil amended with lime,fine concrete,and autotrophic denitrification were evaluated.Based on a case-study landfill area of 0.04 km^(2),the estimated H_(2)S emissions of 80900 kg over the 15-year period and costs of active cover system components(ammonium nitrate fertilizer for autotrophic denitrification cover,lime,fine concrete,and compost),ammonium nitrate fertilizer is the most cost effective,followed by hydrated lime,fine concrete,and yard waste compost.Fine concrete and yard waste compost covers are expensive measures to control H_(2)S emissions because of the large amount of materials needed to create a cover.Controlling H_(2)S emissions using fine concrete and compost is less expensive at landfills that provide on-site concrete recovery and composting facilities;however,ammonium nitrate fertilizer or hydrated lime would still be more cost effective applications.展开更多
Based on ab initio molecular dynamics simulations and density functional theory, we performed a systematic theoretical study to elucidate the correlation between the H-bonded environment and X- ray emission spectra of...Based on ab initio molecular dynamics simulations and density functional theory, we performed a systematic theoretical study to elucidate the correlation between the H-bonded environment and X- ray emission spectra of liquid water. The spectra generated from excited water molecules embedded in an intact H-bonded environment yield broader spectral peaks and a larger spectral range than the spectra generated from water molecules in a broken H-bonded environment. Such differences are caused by the local electronic structures on the excited water molecules within the core-hole lifetime that evolve differently through the rearrangement of neighboring water molecules in different H-bonded environments.展开更多
文摘The time of the energy emission between two neighbouring electron levels in the hydrogen atom has been calculated first on the basis of the quantum aspects of the Joule-Lenz law, next this time is approached with the aid of the electrodynamical parameters characteristic for the electron motion in the atom. Both methods indicate a similar result, namely that the time of emission is close to the time period of the electromagnetic wave produced in course of the emission. As a by-product of calculations, the formula representing the radius of the electron microparticle is obtained from a simple combination of the expressions for the Bohr magnetic moment and a quantum of the magnetic flux.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11175009 and 11575013)
文摘Optical emission spectroscopy(OES), as a simple in situ method without disturbing the plasma, has been performed for the plasma diagnosis of a 2.45 GHz permanent magnet electron cyclotron resonance(PMECR) ion source at Peking University(PKU). A spectrum measurement platform has been set up with the quartz-chamber electron cyclotron resonance(ECR) ion source [Patent Number: ZL 201110026605.4] and experiments were carried out recently. The electron temperature and electron density inside the ECR plasma chamber have been measured with the method of line intensity ratio of noble gas. Hydrogen plasma processes inside the discharge chamber are discussed based on the diagnostic results. What is more, the superiority of the method of line intensity ratio of noble gas is indicated with a comparison to line intensity ratio of hydrogen. Details will be presented in this paper.
基金This research was supported by the Environmental Research and Education Foundation(EREF),USA.
文摘Hydrogen sulfide(H_(2)S)emitted from construction and demolition waste landfills has received increasing attention.Besides its unpleasant odor,longterm exposure to a very low concentration of H_(2)S can cause a public health issue.In the case of construction and demolition(C&D)waste landfills,where gas collection systems are not normally required,the generated H_(2)S is typically not controlled and the number of treatment processes to control H_(2)S emissions in situ is limited.An attractive alternative may be to use chemically or biologically active landfill covers.A few studies using various types of cover materials to attenuate H_(2)S emissions demonstrated that H_(2)S emissions can be effectively reduced.In this study,therefore,the costs and benefits of H_(2)S-control cover systems including compost,soil amended with lime,fine concrete,and autotrophic denitrification were evaluated.Based on a case-study landfill area of 0.04 km^(2),the estimated H_(2)S emissions of 80900 kg over the 15-year period and costs of active cover system components(ammonium nitrate fertilizer for autotrophic denitrification cover,lime,fine concrete,and compost),ammonium nitrate fertilizer is the most cost effective,followed by hydrated lime,fine concrete,and yard waste compost.Fine concrete and yard waste compost covers are expensive measures to control H_(2)S emissions because of the large amount of materials needed to create a cover.Controlling H_(2)S emissions using fine concrete and compost is less expensive at landfills that provide on-site concrete recovery and composting facilities;however,ammonium nitrate fertilizer or hydrated lime would still be more cost effective applications.
文摘Based on ab initio molecular dynamics simulations and density functional theory, we performed a systematic theoretical study to elucidate the correlation between the H-bonded environment and X- ray emission spectra of liquid water. The spectra generated from excited water molecules embedded in an intact H-bonded environment yield broader spectral peaks and a larger spectral range than the spectra generated from water molecules in a broken H-bonded environment. Such differences are caused by the local electronic structures on the excited water molecules within the core-hole lifetime that evolve differently through the rearrangement of neighboring water molecules in different H-bonded environments.