Hydrogen combustion in a nuclear power plant may threaten the integrity of some important systems and components.In this paper,the effect of hydrogen combustion in the primary pump compartment is analyzed by different...Hydrogen combustion in a nuclear power plant may threaten the integrity of some important systems and components.In this paper,the effect of hydrogen combustion in the primary pump compartment is analyzed by different initial hydrogen concentration and igniter locations using Computational Fluid Dynamics method.The results show that the combustion is confined to a limited area without pump damage at about 6.6%hydrogen volume fraction.Once igniting the hydrogen,the combustion affects the whole compartment at the 12%hydrogen volume fraction.The stress caused by the great temperature gradient or high temperature may damage the primary pump. Igniters at the lower location accelerate the combustion process and cause a threat to the pump integrity.展开更多
The conversion of CO_(2) electrocatalytic hydrogenation into energy-rich fuel is considered to be the most effective way to carbon recycle.Nitrogen-doping carbonized ZIF-8 is proposed as carrier of the earth-rich Sn c...The conversion of CO_(2) electrocatalytic hydrogenation into energy-rich fuel is considered to be the most effective way to carbon recycle.Nitrogen-doping carbonized ZIF-8 is proposed as carrier of the earth-rich Sn catalyst to overcome the limit of electron transfer and CO_(2) adsorption capacity of Sn.Hierarchically porous structure of Sn doped carbonized ZIF-8 is controlled by hydrothermal and carbonization conditions,which induces much higher specific surface area than that of the commercial Sn nanoparticle(1003.174 vs.7.410 m^(2)·g^(-1)).The shift of nitrogen peaks in X-ray Photoelectron Spectroscopy spectra indicates interaction between ZIF-8 and Sn,which induces the shift of electron cloud from Sn to the chemical nitrogen to enhance conductivity and regulate electron transfer from catalyst to CO_(2).Lower mass transfer resistance and Warburg resistance are investigated through EIS,which significantly improves the catalytic activity for CO_(2) reduction reaction(CO_(2)RR).Onset potential of the reaction is reduced from-0.74 V to less than-0.54 V vs.RHE.The total Faraday efficiency of HCOOH and CO reaches 68.9%at-1.14 V vs.RHE,which is much higher than that of the commercial Sn(45.0%)and some other Sn-based catalyst reported in the literature.展开更多
A new hydrogen storage alloy pair, La0.6Ml0.4Ni4.7 Cr0.3-La0.2Mm0.8Ni4.35Fe0.65, was developed to serve as a bus hydride air conditioner, which utilizes the waste heat of exhaust gases of a bus as the high temperature...A new hydrogen storage alloy pair, La0.6Ml0.4Ni4.7 Cr0.3-La0.2Mm0.8Ni4.35Fe0.65, was developed to serve as a bus hydride air conditioner, which utilizes the waste heat of exhaust gases of a bus as the high temperature source. Under the operating temperature of 150-250 °C/35-40°C/15-20°C, the maximum working hydrogen capacity and the theoretical value of COPc are 4.5 and 0.74 H/mol M respectively, which can meet the practical requirements.展开更多
基金Supported by National Basic Research Program of China(No.2009CB724301)National Natural Science Foundation of China(No.11075104)
文摘Hydrogen combustion in a nuclear power plant may threaten the integrity of some important systems and components.In this paper,the effect of hydrogen combustion in the primary pump compartment is analyzed by different initial hydrogen concentration and igniter locations using Computational Fluid Dynamics method.The results show that the combustion is confined to a limited area without pump damage at about 6.6%hydrogen volume fraction.Once igniting the hydrogen,the combustion affects the whole compartment at the 12%hydrogen volume fraction.The stress caused by the great temperature gradient or high temperature may damage the primary pump. Igniters at the lower location accelerate the combustion process and cause a threat to the pump integrity.
基金the National Natural Science Foundation of China(Joint Fund U1663223 and 21776034)Science Fund for Creative Research Groups of the National Natural Science Foundation of China(22021005)+3 种基金the National Key Research and Development Program of China(2016YFB0101203)Educational Department of Liaoning Province of China(LT2015007)Fundamental Research Funds for the Central Universities(DUT16TD19)the Changjiang Scholar Program(T2012049).
文摘The conversion of CO_(2) electrocatalytic hydrogenation into energy-rich fuel is considered to be the most effective way to carbon recycle.Nitrogen-doping carbonized ZIF-8 is proposed as carrier of the earth-rich Sn catalyst to overcome the limit of electron transfer and CO_(2) adsorption capacity of Sn.Hierarchically porous structure of Sn doped carbonized ZIF-8 is controlled by hydrothermal and carbonization conditions,which induces much higher specific surface area than that of the commercial Sn nanoparticle(1003.174 vs.7.410 m^(2)·g^(-1)).The shift of nitrogen peaks in X-ray Photoelectron Spectroscopy spectra indicates interaction between ZIF-8 and Sn,which induces the shift of electron cloud from Sn to the chemical nitrogen to enhance conductivity and regulate electron transfer from catalyst to CO_(2).Lower mass transfer resistance and Warburg resistance are investigated through EIS,which significantly improves the catalytic activity for CO_(2) reduction reaction(CO_(2)RR).Onset potential of the reaction is reduced from-0.74 V to less than-0.54 V vs.RHE.The total Faraday efficiency of HCOOH and CO reaches 68.9%at-1.14 V vs.RHE,which is much higher than that of the commercial Sn(45.0%)and some other Sn-based catalyst reported in the literature.
文摘A new hydrogen storage alloy pair, La0.6Ml0.4Ni4.7 Cr0.3-La0.2Mm0.8Ni4.35Fe0.65, was developed to serve as a bus hydride air conditioner, which utilizes the waste heat of exhaust gases of a bus as the high temperature source. Under the operating temperature of 150-250 °C/35-40°C/15-20°C, the maximum working hydrogen capacity and the theoretical value of COPc are 4.5 and 0.74 H/mol M respectively, which can meet the practical requirements.
