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Effects of applied potential on the stress corrosion cracking behavior of 7003 aluminum alloy in acid and alkaline chloride solutions 被引量:6
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作者 Xiao-yan Zhang Ren-guo Song +2 位作者 Bin Sun Hai Lu Chao Wang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2016年第7期819-826,共8页
Potentiodynamic polarization tests and slow strain rate test(SSRT) in combination with fracture morphology observations were conducted to investigate the stress corrosion cracking(SCC) behavior of 7003 aluminum al... Potentiodynamic polarization tests and slow strain rate test(SSRT) in combination with fracture morphology observations were conducted to investigate the stress corrosion cracking(SCC) behavior of 7003 aluminum alloy(AA7003) in acid and alkaline chloride solutions under various applied potentials(Ea). The results show that AA7003 is to a certain extent susceptible to SCC via anodic dissolution(AD) at open-circuit potential(OCP) and is highly susceptible to hydrogen embrittlement(HE) at high negative Ea in the solutions with p H levels of 4 and 11. The susceptibility increases with negative shift in the potential when Ea is less than-1000 m V vs. SCE. However, the susceptibility distinctly decreases because of the inhibition of AD when Ea is equal to-1000 m V vs. SCE. In addition, the SCC susceptibility of AA7003 in the acid chloride solution is higher than that in the alkaline solution at each potential. Moreover, the effect of hydrogen on SCC increases with increasing hydrogen ion concentration. 展开更多
关键词 aluminum alloys stress corrosion cracking susceptibility hydrogen embrittlement potential acid solutions alkaline solutions
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The effects of sulfide stress cracking on the mechanical properties and intergranular cracking of P110 casing steel in sour environments 被引量:6
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作者 Hou Duo Zeng Dezhi +2 位作者 Shi Taihe Zhang Zhi Deng Wenliang 《Petroleum Science》 SCIE CAS CSCD 2013年第3期385-394,共10页
Variation and degradation of P-110 casing steel mechanical properties, due to sulfide stress cracking (SSC) in sour environments, was investigated using tensile and impact tests. These tests were carried out on spec... Variation and degradation of P-110 casing steel mechanical properties, due to sulfide stress cracking (SSC) in sour environments, was investigated using tensile and impact tests. These tests were carried out on specimens, which were pretreated under the following conditions for 168 hours: temperature, 60 ℃; pressure, 10 MPa; H2S partial pressure, 1 MPa and CO2 partial pressure, 1 MPa; preload stress, 80% of the yield strength (os); medium, simulated formation water. The reduction in tensile and impact strengths for P-110 casing specimens in corrosive environments were 28% and 54%, respectively. The surface morphology analysis indicated that surface damage and uniform plastic deformation occurred as a result of strain aging. Impact toughness of the casing decreased significantly and intergranular cracking occurred when specimens were maintained at a high stress level of 85% %. 展开更多
关键词 Acidic solutions high-temperature corrosion hydrogen embrittlement intergranular corrosion sulfide stress cracking
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氢对X80钢在库尔勒土壤模拟溶液中应力腐蚀开裂行为的影响 被引量:7
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作者 谢飞 王丹 +3 位作者 吴明 宋嘉良 张康南 杨旭 《中南大学学报(自然科学版)》 EI CAS CSCD 北大核心 2016年第2期690-696,共7页
采用电化学充氢技术、动电位扫描技术、交流阻抗技术(EIS)和慢应变速率拉伸试验(SSRT)研究库尔勒土壤模拟溶液中氢对X80管线钢应力腐蚀开裂(SCC)行为的影响,并利用扫描电镜(SEM)观察试样断口形貌。研究结果表明:充氢电流密度和充氢时间... 采用电化学充氢技术、动电位扫描技术、交流阻抗技术(EIS)和慢应变速率拉伸试验(SSRT)研究库尔勒土壤模拟溶液中氢对X80管线钢应力腐蚀开裂(SCC)行为的影响,并利用扫描电镜(SEM)观察试样断口形貌。研究结果表明:充氢电流密度和充氢时间的增加均能加速金属腐蚀反应;随着充氢量的增大,试样自腐蚀电位呈下降趋势,腐蚀速率逐渐增大,氢促进了X80钢在库尔勒模拟溶液中腐蚀的发展;电化学充氢后,X80钢的应力腐蚀开裂行为主要由氢致开裂(HIC)作用决定,阳极溶解过程只起到辅助裂纹形核的作用,因为氢能引起材料局部塑性变形,促进裂纹尖端形核和扩展。 展开更多
关键词 X80钢 电化学 土壤模拟溶液 应力腐蚀开裂
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氢对铜电化学行为和NaNO_2溶液应力腐蚀的影响
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作者 乔利杰 汪松 +3 位作者 刘纶 黄震中 褚武扬 肖纪美 《北京科技大学学报》 EI CAS CSCD 北大核心 1995年第6期572-575,579,共5页
纯铜充氢后并不改变组织结构和晶粒大。而且抗拉强度、延伸率和面缩率也不变化,这表明铜没有氢脆。在NaNO_2溶液中,氢使纯铜的腐蚀电位、反应电阻降低,使应力腐蚀开裂敏感性升高,断口形貌不发生变化。
关键词 亚硝酸溶液 应力腐蚀 电化学
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氢对铜的电化学行为和应力腐蚀的影响
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作者 刘纶 乔利杰 +2 位作者 褚武扬 汪松 肖纪美 《金属热处理学报》 CSCD 1994年第4期50-54,共5页
纯铜充氢后并不改变组织结构和晶粒大小而且抗拉强度、伸长率和面缩率也不变化,这表明铜没有氢脆,在NaNO_2溶液中,氢使纯铜电位降低,使应力腐蚀开裂敏感性升高,但断口形貌不发生变化。
关键词 纯铜 应力腐蚀 亚硝酸钠溶液
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近中性土壤溶液中X65管线钢应力腐蚀开裂研究
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作者 涂圣文 帅健 刘德绪 《焊管》 2015年第1期5-10,共6页
将中国西部某管线现场取得的土壤样品配制成土壤溶液,对X65管线钢在该土壤溶液中进行氢渗透、慢拉伸和应力波动试验。通过观察试验数据和试件主断面及表面扫描电镜图,评价X65管线钢在该土壤溶液中发生SCC的敏感性及其他力学因素对SCC的... 将中国西部某管线现场取得的土壤样品配制成土壤溶液,对X65管线钢在该土壤溶液中进行氢渗透、慢拉伸和应力波动试验。通过观察试验数据和试件主断面及表面扫描电镜图,评价X65管线钢在该土壤溶液中发生SCC的敏感性及其他力学因素对SCC的影响。结果表明:X65管线钢在试验土壤溶液中对SCC是敏感的,氢原子的渗入使得敏感性提高,且提升的幅度较大,CO2气体能够促进氢在管线钢中的渗透;应力波动对应力腐蚀开裂初始阶段裂纹的萌生有重要的影响,二次应力波动试验表明,交变载荷的作用能够导致裂纹的进一步扩展。 展开更多
关键词 X65管线钢 近中性土壤溶液 应力腐蚀开裂 氢渗透 慢拉伸 应力波动
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大容积气瓶用高强韧材料4130DX的开发
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作者 王洪海 陈冬 许胜 《中国特种设备安全》 2023年第12期90-94,共5页
通过优化4130X的成分,适当提高Cr和Mo的含量,降低Si和Mn的含量,添加0.04%~0.10%的V,控制V/N之比大于4:1,开发了气瓶用无缝钢管材料4130DX,研究了V的碳氮化物的析出强化和细晶强化对材料强度、塑性和韧性的影响,通过对比试验验证了新开发... 通过优化4130X的成分,适当提高Cr和Mo的含量,降低Si和Mn的含量,添加0.04%~0.10%的V,控制V/N之比大于4:1,开发了气瓶用无缝钢管材料4130DX,研究了V的碳氮化物的析出强化和细晶强化对材料强度、塑性和韧性的影响,通过对比试验验证了新开发的4130DX材料在较高的强度下仍具有较高的塑性和韧性、良好的抗疲劳性能和抗硫化氢应力腐蚀(SSC)性能,可用于制造高强度气瓶。 展开更多
关键词 高强韧材料 微合金化 固溶强化 细晶强化 硫化氢应力腐蚀
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SCC investigation of low alloy ultra-high strength steel 30CrMnSiNi2A in 3.5wt% NaCl solution by slow strain rate technique 被引量:3
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作者 Liu Jianhua Guo Qiang +1 位作者 Yu Mei Li Songmei 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2014年第5期1327-1333,共7页
To evaluate stress corrosion cracking(SCC) mechanism of low alloy ultra-high strength steel 30CrMnSiNi2 A in environment containing NaCl, SCC behavior of the steel in 3.5wt% NaCl solution is investigated by slow str... To evaluate stress corrosion cracking(SCC) mechanism of low alloy ultra-high strength steel 30CrMnSiNi2 A in environment containing NaCl, SCC behavior of the steel in 3.5wt% NaCl solution is investigated by slow strain rate technique(SSRT) with various strain rates and applied potentials, surface analysis technique, and electrochemical measurements. SCC susceptibility of the steel increases rapidly with strain rate decreasing from 1 · 10 5s 1to 5 · 10 7s 1, and becomes stable when strain rate is lower than 5 · 10 7s 1. SCC propagation of the steel in the solution at open circuit potential(OCP) needs sufficient hydrogen which is supplied at a certain strain rate.Fracture surface at OCP has similar characteristics with that at cathodic polarization 1000 mVSCE, which presents characteristic fractography of hydrogen induced cracking(HIC).All of these indicate that SCC behavior of the steel in the solution at OCP is mainly controlled by HIC rather than anodic dissolution(AD). 展开更多
关键词 hydrogen NaCl solution stress corrosion cracking Slow strain rate technique Ultra-high strength steel
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电化学充氢对X80管线钢在鹰潭土壤模拟溶液中应力腐蚀行为的影响 被引量:10
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作者 梅华生 王长朋 +2 位作者 张帷 周漪 杨王玲 《中国腐蚀与防护学报》 CSCD 北大核心 2013年第5期388-394,共7页
采用电化学技术、慢应变速率拉伸实验和扫描电镜(SEM)对电化学充氢后的X80管线钢在鹰潭土壤模拟溶液中的应力腐蚀行为进行了研究。结果表明:X80管线钢静态充氢后在鹰潭土壤模拟溶液中具有较高的应力腐蚀(SCC)敏感性,其断口模式为穿晶断... 采用电化学技术、慢应变速率拉伸实验和扫描电镜(SEM)对电化学充氢后的X80管线钢在鹰潭土壤模拟溶液中的应力腐蚀行为进行了研究。结果表明:X80管线钢静态充氢后在鹰潭土壤模拟溶液中具有较高的应力腐蚀(SCC)敏感性,其断口模式为穿晶断裂;随着电化学充氢时间的延长,氢致塑性损失不断增加,拉伸断口由韧窝状韧性断口向脆性解理断口发展,SCC敏感性增大;电化学充氢促进了点蚀坑的萌生,点蚀坑和第二相夹杂是SCC裂纹萌生的重要原因。 展开更多
关键词 X80管线钢 应力腐蚀 电化学充氢 土壤模拟溶液
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