In this work,the 0.1-0.5 mol·L-1 N,N-dimethylhydroxylamine(DMHA) were irradiated to 5-25 kGy,and gaseous products of mainly hydrogen,methane,ethane and n-butane were measured by gas chromatography.The results sho...In this work,the 0.1-0.5 mol·L-1 N,N-dimethylhydroxylamine(DMHA) were irradiated to 5-25 kGy,and gaseous products of mainly hydrogen,methane,ethane and n-butane were measured by gas chromatography.The results show that the volume fraction of hydrogen and methane increases with the concentration of DMHA and dose,and the latter does not change markedly at high doses.展开更多
Ni/ZrO2 catalysts were prepared by the incipient-wetness impregnation method and were investigated in activity and selectivity for the selective catalytic methanation of CO in hydrogen-rich gases with more than 20 vol...Ni/ZrO2 catalysts were prepared by the incipient-wetness impregnation method and were investigated in activity and selectivity for the selective catalytic methanation of CO in hydrogen-rich gases with more than 20 vol% CO2. The result showed that Ni loadings significantly influenced the performance of Ni/ZrO2 catalyst. The 1.6 wt% Ni loading catalyst exhibited the highest catalytic activity among all the catalysts in the selective methanation of CO in hydrogen-rich gas. The outlet concentration of CO was less than 20 ppm with the hydrogen consumption below 7%, at a gas-hourly-space velocity as high as 10000 h-1 and a temperature range of 260 °C to 280 °C. The X-ray diffraction （XRD） and temperature programmed reduction （TPR） measurements showed that NiO was dispersed thoroughly on the surface of ZrO2 support if Ni loading was under 1.6 wt%. When Ni loading was increased to 3 wt% or above, the free bulk NiO species began to assemble, which was not favorable to increase the selectivity of the catalyst.展开更多
Waste heat recovery(WHR)is one of the most useful ways to improve the efficiency of internal combustion engines,and an electricity-cooling cogeneration system(ECCS)based on Rankin-absorption refrigeration combined cyc...Waste heat recovery(WHR)is one of the most useful ways to improve the efficiency of internal combustion engines,and an electricity-cooling cogeneration system(ECCS)based on Rankin-absorption refrigeration combined cycle for the WHR of gaseous fuel engines is proposed in the paper.This system can avoid wasting the heat in condenser so that the efficiency of the whole WHR system improves,but the condensing temperature of Rankin cycle(RC)must increase in order to use absorption refrigeration system,which leads to the decrease of RC output power.Therefore,the relationship between the profit of absorption refrigeration system and the loss of RC in this combined system is the mainly studied content in the paper.Because the energy quality of cooling and electricity are different,cooling power in absorption refrigeration is converted to corresponding electrical power consumed by electric cooling system,which is defined as equivalent electrical power.With this method,the effects of some important operation parameters on the performance of the ECCS are researched,and the equivalent efficiency,exergy efficiency and primary energy rate are compared in the paper.展开更多
基金Supported by Natural Science Foundation of China(Contract No.20771074)Shanghai Leading Academic Disciplines(Contract No.S30109)
文摘In this work,the 0.1-0.5 mol·L-1 N,N-dimethylhydroxylamine(DMHA) were irradiated to 5-25 kGy,and gaseous products of mainly hydrogen,methane,ethane and n-butane were measured by gas chromatography.The results show that the volume fraction of hydrogen and methane increases with the concentration of DMHA and dose,and the latter does not change markedly at high doses.
基金the National Natural Science Foundation of China (20576023)the Guangdong Province Natural Science Foundation (06025660)
文摘Ni/ZrO2 catalysts were prepared by the incipient-wetness impregnation method and were investigated in activity and selectivity for the selective catalytic methanation of CO in hydrogen-rich gases with more than 20 vol% CO2. The result showed that Ni loadings significantly influenced the performance of Ni/ZrO2 catalyst. The 1.6 wt% Ni loading catalyst exhibited the highest catalytic activity among all the catalysts in the selective methanation of CO in hydrogen-rich gas. The outlet concentration of CO was less than 20 ppm with the hydrogen consumption below 7%, at a gas-hourly-space velocity as high as 10000 h-1 and a temperature range of 260 °C to 280 °C. The X-ray diffraction （XRD） and temperature programmed reduction （TPR） measurements showed that NiO was dispersed thoroughly on the surface of ZrO2 support if Ni loading was under 1.6 wt%. When Ni loading was increased to 3 wt% or above, the free bulk NiO species began to assemble, which was not favorable to increase the selectivity of the catalyst.
基金supported by the National Basic Research Program of China("973"Project)(Gran No.2011CB707201)
文摘Waste heat recovery(WHR)is one of the most useful ways to improve the efficiency of internal combustion engines,and an electricity-cooling cogeneration system(ECCS)based on Rankin-absorption refrigeration combined cycle for the WHR of gaseous fuel engines is proposed in the paper.This system can avoid wasting the heat in condenser so that the efficiency of the whole WHR system improves,but the condensing temperature of Rankin cycle(RC)must increase in order to use absorption refrigeration system,which leads to the decrease of RC output power.Therefore,the relationship between the profit of absorption refrigeration system and the loss of RC in this combined system is the mainly studied content in the paper.Because the energy quality of cooling and electricity are different,cooling power in absorption refrigeration is converted to corresponding electrical power consumed by electric cooling system,which is defined as equivalent electrical power.With this method,the effects of some important operation parameters on the performance of the ECCS are researched,and the equivalent efficiency,exergy efficiency and primary energy rate are compared in the paper.
