Water Role and Its Influence on Hydrogen Isotopic Composition of Natural Gas during Gas Generation

In order to discuss the role and influence of water during the generation of natural gas,the participation mechanism of water during the evolution of organic matter and its influences were summarized.In addition,we carried out an anhydrous cracking experiment of oil extracted from the Feixianguan Formation source rock in a closed system,which led to the establishment of the kinetic models for describing carbon and hydrogen isotopic fractionation during gas generation from organic matter.The models were calibrated and then applied to the northeastern Sichuan Basin.By combining a series of gas generation experiments from octadecane pyrolysis without water or with distilled water in varying mass proportions,several results were proved:(1) the hydrogen isotopic composition of natural gas becomes lighter with the participation of formation water;(2) we can quantitatively study the hydrogen isotopic fractionation with the kinetic model for describing carbon isotopic fractionation; (3) more abundant and reliable geological information can be obtained through the combined application of carbon and hydrogen isotopic indices.

Dynamic heating and thermal destruction conditions of quartz particles in polydisperse plasma flow of RF-ICP torch system

Numerical simulation of turbulent mixing process of polydisperse quartz particle(particle size distribution in the range of 0.1-0.4 mm)flow with Ar and Ar-H2 plasma generated by radio frequency inductively coupled plasma(RF-ICP)torch has been made.An approximate two-stage approach has been proposed to calculate the spatial-temporal distributions of temperature and resulting thermal stress in quartz particles during dynamic heating in polydisperse plasma flow.The influence of working gas compositions,particle size distributions,injection angle and flow rate of carrier gas on the thermal destruction conditions of quartz particles has been determined under different particle feed rates.It is found that all the solid quartz particles(0.1-0.4 mm)could be thermal destructed without overheating in RF-ICP torch system,when the hydrogen volume fraction in working gases is more than 1.5%-2%and particle feed rate is in a certain range.The values of the maximum and minimum feed rates have been determined under different hydrogen volume fractions.An optimal particle injection angle and flow rate of carrier gas is found around 50°-60°and 160-220 slpm,under which the value of maximum equivalent thermal stress in quartz particles is highest.

HYDROGEN ISOTOPE FRACTIONATION BETWEEN ILVAITE AND WATER

A lot of experimental studies have been made on hydrogen isotope fractionation for hydrous minerals, such as mica, amphibole, epidote-group minerals, serpentine, aluminous-chlorite etc., since the 1970s. This plays an important role in the development of hydrogen isotope geochemistry. We have first made the experimental study on

Altitudinal effect of soil n-alkane δD values on the eastern Tibetan Plateau and their increasing isotopic fractionation with altitude

Stable isotope paleoaltimetry has provided unprecedented insights into the topographic histories of many of the world's highest mountain ranges. However, on the Tibetan Plateau(TP), stable isotopes from paleosols generally yield much higher paleoaltitudes than those based on fossils. It is therefore essential when attempting to interpret accurately this region's paleoaltitudes that the empirical calibrations of local stable isotopes and the relations between them are established. Additionally,it is vital that careful estimations be made when estimate how different isotopes sourced from different areas may have been influenced by different controls. We present here 29 hydrogen isotopic values for leaf wax-derived n-alkanes(i.e., δD_(wax) values,and abundance-weighted average δD values of C_(29) and C_(31)) in surface soils, as well as the δD values of soil water(δD_(sw)) samples(totaling 22) from Mount Longmen(LM), on the eastern TP(altitude ~0.8–4.0 km above sea level(asl), a region climatically affected by the East Asian Monsoon(EAM). We compared our results with published data from Mount Gongga(GG). In addition,47 river water samples, 55 spring water samples, and the daily and monthly summer precipitation records(from May to October,2015) from two precipitation observation stations were collected along the GG transect for δD analysis. LM soil δD_(wax) values showed regional differences and responded strongly to altitude, varying from.160‰ to.219‰, with an altitudinal lapse rate(ALR) of.18‰ km^(-1)(R^2=0.83; p<0.0001; n=29). These δD_(wax) values appeared more enriched than those from the GG transect by ~40‰. We found that both the climate and moisture sources led to the differences observed in soil δD_(wax) values between the LM and GG transects. We found that, as a general rule, ε_(wax/rw), ε_(wax/p) and εwax/sw values(i.e., the isotopic fractionation of δD_(wax) corresponding to δD_(rw), δD_p and δD_(sw)) increased with increasing altitude along both the LM and GG transects(up to 34‰ and 50‰, respectively). Basing its research on a comparative study of δD_(wax), δD_p, δD_(rw)(δD_(springw)) and δD_(sw), this paper discusses the effects of moisture recycling, glacier-fed meltwater, relative humidity(RH), evapotranspiration(ET), vegetation cover, latitude,topography and/or other factors on ε_(wax/p) values. Clearly, if ε_(wax-p) values at higher altitudes are calculated using smaller ε_(wax-p) values from lower altitudes, the calculated paleowaterδD_p values are going to be more depleted than the actual δD values, and any paleoaltitude would therefore be overestimated.