It was proposed how the concentration distribution was calculated in the treble lager wall of hgdrogenation reactor according to the principle of hydrogen diffusion at the steady state in this paper. Based on the stea...It was proposed how the concentration distribution was calculated in the treble lager wall of hgdrogenation reactor according to the principle of hydrogen diffusion at the steady state in this paper. Based on the steady hydrogen permeation current density i∞ measund with the hydrogen probe at a given temperature, the hydmpen concentrationson the key interfaces and hydrogen distribution at any given mdial profile in the single, double or treble layer wall of hydrogenation reactor could be found by applying the presented equations throoph suitable parmeters ioput. The theoretical bases were provided for developing the nondestructive probing technique of the concentration of atomic hydmpen in the wallS of hydrogenation reactors.展开更多
A two-dimensional non-isothermal mathematical model has been developed for the ethane dehydrogenation reaction in a fixed-bed catalytic membrane reactor. Since ethane dehydrogenation is an equilibrium reaction,removal...A two-dimensional non-isothermal mathematical model has been developed for the ethane dehydrogenation reaction in a fixed-bed catalytic membrane reactor. Since ethane dehydrogenation is an equilibrium reaction,removal of produced hydrogen by the membrane shifts the thermodynamic equilibrium to ethylene production.For further displacement of the dehydrogenation reaction, oxidative dehydrogenation method has been used.Since ethane dehydrogenation is an endothermic reaction, the energy produced by the oxidative dehydrogenation method is consumed by the dehydrogenation reaction. The results show that the oxidative dehydrogenation method generated a substantial improvement in the reactor performance in terms of high conversions and signi ficant energy saving. It was also established that the sweep gas velocity in the shell side of the reactor is one of the most important factors in the effectiveness of the reactor.展开更多
A newly developed automatic spiral cladding machine for internal surface of hydrogenated reactor elbow is introduced.Workpiece being welded is rotated at various speeds and fed in along axial direction.TIG welding pro...A newly developed automatic spiral cladding machine for internal surface of hydrogenated reactor elbow is introduced.Workpiece being welded is rotated at various speeds and fed in along axial direction.TIG welding process with filler metal is applied with this machine.Welding is performed in flat position. The machine is intellectually controlled by a microprocessor. Torch waving width and welding speed is varied according to a formula,that the product of waving width and welding speed is constant. So the thickness of cladding layers at different points is uniform. The requirements of hydrogenation to cladding are conformed with this machine.展开更多
Acetone hydrogenation in a fixed bed reactor packed with spherical catalyst particles was simulated to study the effects of inlet gas velocity and particle diameter on hydrogenation reaction. Computational results sho...Acetone hydrogenation in a fixed bed reactor packed with spherical catalyst particles was simulated to study the effects of inlet gas velocity and particle diameter on hydrogenation reaction. Computational results show that the catalyst particles in the reactor are almost isothermal, and the high isopropanol concentration appears at the lee of the particles. With the increase of inlet velocity, the outlet isopropanol mole fraction decreases, and the total pressure drop increases drastically. Small diameter catalyst particles are favorable for acetone hydrogenation, but result in large pressure drop.展开更多
文摘It was proposed how the concentration distribution was calculated in the treble lager wall of hgdrogenation reactor according to the principle of hydrogen diffusion at the steady state in this paper. Based on the steady hydrogen permeation current density i∞ measund with the hydrogen probe at a given temperature, the hydmpen concentrationson the key interfaces and hydrogen distribution at any given mdial profile in the single, double or treble layer wall of hydrogenation reactor could be found by applying the presented equations throoph suitable parmeters ioput. The theoretical bases were provided for developing the nondestructive probing technique of the concentration of atomic hydmpen in the wallS of hydrogenation reactors.
文摘A two-dimensional non-isothermal mathematical model has been developed for the ethane dehydrogenation reaction in a fixed-bed catalytic membrane reactor. Since ethane dehydrogenation is an equilibrium reaction,removal of produced hydrogen by the membrane shifts the thermodynamic equilibrium to ethylene production.For further displacement of the dehydrogenation reaction, oxidative dehydrogenation method has been used.Since ethane dehydrogenation is an endothermic reaction, the energy produced by the oxidative dehydrogenation method is consumed by the dehydrogenation reaction. The results show that the oxidative dehydrogenation method generated a substantial improvement in the reactor performance in terms of high conversions and signi ficant energy saving. It was also established that the sweep gas velocity in the shell side of the reactor is one of the most important factors in the effectiveness of the reactor.
文摘A newly developed automatic spiral cladding machine for internal surface of hydrogenated reactor elbow is introduced.Workpiece being welded is rotated at various speeds and fed in along axial direction.TIG welding process with filler metal is applied with this machine.Welding is performed in flat position. The machine is intellectually controlled by a microprocessor. Torch waving width and welding speed is varied according to a formula,that the product of waving width and welding speed is constant. So the thickness of cladding layers at different points is uniform. The requirements of hydrogenation to cladding are conformed with this machine.
基金supported by the National Natural Science Foundation of China(No.51276181)the National Basic Research Program of China(No.2011CB710705)the National Natural ScienceFoundation of China(No.51106158)
文摘Acetone hydrogenation in a fixed bed reactor packed with spherical catalyst particles was simulated to study the effects of inlet gas velocity and particle diameter on hydrogenation reaction. Computational results show that the catalyst particles in the reactor are almost isothermal, and the high isopropanol concentration appears at the lee of the particles. With the increase of inlet velocity, the outlet isopropanol mole fraction decreases, and the total pressure drop increases drastically. Small diameter catalyst particles are favorable for acetone hydrogenation, but result in large pressure drop.
