Hydrogermylation of alkenes and alkynes provides a straightforward synthetic route to organogermanium compounds that have been found applications in organic synthesis,medicinal chemistry,and material science.This pape...Hydrogermylation of alkenes and alkynes provides a straightforward synthetic route to organogermanium compounds that have been found applications in organic synthesis,medicinal chemistry,and material science.This paper reviews the advances in transition-metal-catalyzed hydrogermylation of unsaturated carbon-carbon bonds,including alkenes,alkynes,dienes,and allenes,with the objective of providing readers with the status of the field.Progress,problems,and perspectives in this field are discussed.展开更多
基金supported by the National Key Research and Development Program of the Ministry of Science and Technology of China(2021YFA1500203)Natural Science Foundation of China(22201290,22061160464,and 21821002)Shanghai Sailing Program(22YF1458200).
文摘Hydrogermylation of alkenes and alkynes provides a straightforward synthetic route to organogermanium compounds that have been found applications in organic synthesis,medicinal chemistry,and material science.This paper reviews the advances in transition-metal-catalyzed hydrogermylation of unsaturated carbon-carbon bonds,including alkenes,alkynes,dienes,and allenes,with the objective of providing readers with the status of the field.Progress,problems,and perspectives in this field are discussed.
