Isotope hydrograph separation in alpine catchments:a review

Isotope hydrograph separation （IHS） is a basic tool in applied hydrology. Its application has expanded to surface water and groundwater interaction, and eco-hydrological processes from runoff generation processes. This paper reviews the progress made in IHS for alpine catchments, with emphasis on its significance in reflecting the impact of global change on water resources. Also, the principle of IHS and its uncertainties are explained in detail. The mechanism of variation of stable isotopes in snow-melt water is discussed, and then methods are presented to improve the separation during snow-melt such as volume weighted average method （VWA）, current melt-water method （CMW） and runoff-corrected event water approach （RunCE）, with their advantages and disadvantages explained. New approaches may extend the applications of IllS, for example, large basin studies combined with GIS, and develop new theories of runoff generation combined with other pararneters such as deuterium excess and DOC.

Progress on the Use of Stable Isotope Techniques in Catchment Hydrograph Separation: A Review

Hydrograph separation is a fundamental catchment descriptor,revealing information about sources of water in runoff generation processes. The water isotopes are ideal tracers in studying hydrological processes since the isotope fractionation produces a natural labeling effect within the hydrologic cycle. The water isotope technique has become one of effective means for investigating complex hydrologic system on a catchment scale. This paper reviews the progress on the use of stable water isotope techniques in catchment hydrograph separation in last decades. Also,the isotope mixing model for hydrograph separation and its uncertainties are explained in detail. In future research,there are three hot issues in the use of isotopic hydrograph separation（ IHS） ： integrating new approaches into IHS,calibration and verification of IHS model and IHS application in large river basins.

Characteristics of Stable Isotopes in an Inland Lake and Their Implications for Water Management in Northwestern China

Bosten Lake is the largest inland freshwater lake in China, functioning as a critical control and allocation facility for agricultural, industrial, ecological and social development in southern Xinjiang in northwestern China. The distribution of stable isotopes, spatial and temporal variations of δ18O, and hydrograph separation of Bosten Lake and its principal recharge rivers—the Kaidu River and the Huangshuigou River—were analyzed using isotope composition. Hydrograph separation indicated that Bosten lake water comprised four components as follows: river runoff, groundwater, agricultural and industrial drainage, and local precipitation. Their contributions were 31%, 35%, 25%, and 9%, respectively. Irrigation drainage and industrial wastewater, enriched high TDS, were the main factors affecting the water quality of Bosten Lake. The δ18O of lake water, which was significantly reduced compared with river water, remained below the local meteoric water line (LMWL), indicating strong evaporation in the lake, especially during summer. The spatial and temporal distribution of δ18O exhibited slow water circulation in the lake. Both the Kaidu River and the Huangshuigou River depend on alpine precipitation and glacier snow, especially the Kaidu River, where ice-snow-melt water accounts for 43% of the river runoff. These rivers are sensitive to climate change. The Bosten Lake inflows would be reduced by the decrease in river runoff and groundwater under future climate change. To improve water quality and reduce evaporative loss, the amount of wastewater should be strictly restricted by local government, and water diversions from Bosten Lake should be concentrated between May and September.

Contribution of the cryosphere to runoff in“Chinese water tower”based on environmental isotopes

Cryospheric meltwater is an important runoff component and it profoundly influences changes in water resources in the Tibetan Plateau.Significant changes in runoff components occur in the three-river headwater region(TRHR),which is an important part of“Chinese Water Tower”due to climate warming.However,these effects remain unclear owing to the sparse and uneven distribution of monitoring sites and limited field investigations.Quantifying the contribution of cryospheric meltwater to outlet runoff is a key scientific question that needs to be addressed.In this study,we analyzed 907 precipitation,river water,ground ice,supra-permafrost water,and glacier snow meltwater samples collected from October 2019 to September 2020 in the TRHR.The following results were obtained:(1)There was significant spatio-temporal variation in stable isotopes in different waters;(2)The seasonal trends of stable isotopes for different waters,the relationship between each water body and the local meteoric water line(LWML)confirmed that river water was mainly recharged by precipitation,supra-permafrost water,and glacier snow meltwater;(3)Precipitation,supra-permafrost water,and glacier snow meltwater accounted for 52%,39%,and 9%of river water,respectively,during the ablation period according to the end-member mixing analysis(EMMA);(4)In terms of future runoff components,there will be many challenges due to increasing precipitation and evaporation,decreasing snow cover,glacier retreat,and permafrost degradation.Therefore,it is crucial to establish the“star-machine-ground”observation networks,forecast extreme precipitation and hydrological events,build the“TRHE on the Cloud”platform,and implement systematic hydraulic engineering projects to support the management and utilization of water resources in the TRHR.The findings of environmental isotope analysis provide insights into water resources as well as scientific basis for rational use of water resources in the TRHR.