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Studies on Hydroiodination and Deconjugation of 5-Aryloxy-(thiophenyl)-3-pentyn-2-one 被引量:1
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作者 刘利军 罗芬台 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2002年第9期895-898,共4页
b Institute of Chemistry, Academia Sinica, Taipei, Taiwan 11529, China One pot hydroiodination and deconjugation of 5 aryloxy(or thiophenyl) 3 pentyn 2 one with a reagent system of sodium iodide/trimethylsily... b Institute of Chemistry, Academia Sinica, Taipei, Taiwan 11529, China One pot hydroiodination and deconjugation of 5 aryloxy(or thiophenyl) 3 pentyn 2 one with a reagent system of sodium iodide/trimethylsilyl chloride/water in acetonitrile at 25 ℃ have been described. The plausible mechanism was discussed. The reaction provided a simple and useful method for the preparation of ( Z ) β substituted β,γ enones and ( Z ) β substituted α,β unsaturated ketones. 展开更多
关键词 substituted β γ enone hydroiodination deconjugation
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