The solution purification process is an essential step in zinc hydrometallurgy. The performance of solution purification directly affects the normal functioning and economical benefits of zinc hydrometallurgy. This pa...The solution purification process is an essential step in zinc hydrometallurgy. The performance of solution purification directly affects the normal functioning and economical benefits of zinc hydrometallurgy. This paper summarizes the authors' recent work on the modeling, optimization, and control of solution purification process. The online measurable property of the oxidation reduction potential(ORP) and the multiple reactors, multiple running statuses characteristic of the solution purification process are extensively utilized in this research. The absence of reliable online equipment for detecting the impurity ion concentration is circumvented by introducing the oxidationreduction potential into the kinetic model. A steady-state multiple reactors gradient optimization, unsteady-state operationalpattern adjustment strategy, and a process evaluation strategy based on the oxidation-reduction potential are proposed. The effectiveness of the proposed research is demonstrated by its industrial experiment.展开更多
The extraction of low concentration cadmium from a system containing high concentration zinc was studied and got CdS product directly. A new liquid membrane system taking DIPSA, TIBPS as carriers, (NH 4) 2S as preci...The extraction of low concentration cadmium from a system containing high concentration zinc was studied and got CdS product directly. A new liquid membrane system taking DIPSA, TIBPS as carriers, (NH 4) 2S as precipitating agent was reported. Precipitating Cd 2+ in the internal aq. phase that is used to treat sulfuric acid leaching solution of zinc oxide in zinc hydrometallurgy has gotten satisfied results of extracting cadmium from high concentration zinc. After one stage of batch process under the optimum liquid membrane conditions, 98.6% transferring rate and 98.1% extracting rate of cadmium was obtained with only less than 1.0% transferring rate of zinc, and the feed solution can be purified very well.展开更多
The investigation of recovery Ga 3+ by emulsion liquid membrane (ELM) using Tri alkyl oxide phosphine (TRPO) as the mobile carrier was reported. The optimum emulsion liquid membrane conditions were determinated....The investigation of recovery Ga 3+ by emulsion liquid membrane (ELM) using Tri alkyl oxide phosphine (TRPO) as the mobile carrier was reported. The optimum emulsion liquid membrane conditions were determinated. They were: the feed pH 1.0, organic phase consisting of 5% TRPO, 4% LMS 2 and 2% liquid paraffin in kerosene solution, 10% K 4[Fe(CN) 6] aq. solution as the stripping agent, R oi =2∶1, R ew =1∶5. At the optimum ELM operating condition, the recovery rate of gallium was 96.5%, and the oil phase can be reused for 5 times.展开更多
In order to improve the refining effect of zinc ore and promote the development of this industry,taking the hydrometallurgical zinc smelting process as an example,this paper first establishes a model for the recycling...In order to improve the refining effect of zinc ore and promote the development of this industry,taking the hydrometallurgical zinc smelting process as an example,this paper first establishes a model for the recycling of waste residues in the hydrometallurgical process,proposes optimization measures based on proven comprehensive recycling technology for purifying residues to obtain higher valuable metal recovery rate,and provides reference for those in relevant fields.展开更多
基金supported by the National Natural Science Foundation of China(61603418,61673400,61273185)the Foundation for Innovative Research Groups of the National Natural Science Foundation of China(61621062)the Innovation-driven Plan in Central South University(2015cx007)
文摘The solution purification process is an essential step in zinc hydrometallurgy. The performance of solution purification directly affects the normal functioning and economical benefits of zinc hydrometallurgy. This paper summarizes the authors' recent work on the modeling, optimization, and control of solution purification process. The online measurable property of the oxidation reduction potential(ORP) and the multiple reactors, multiple running statuses characteristic of the solution purification process are extensively utilized in this research. The absence of reliable online equipment for detecting the impurity ion concentration is circumvented by introducing the oxidationreduction potential into the kinetic model. A steady-state multiple reactors gradient optimization, unsteady-state operationalpattern adjustment strategy, and a process evaluation strategy based on the oxidation-reduction potential are proposed. The effectiveness of the proposed research is demonstrated by its industrial experiment.
文摘The extraction of low concentration cadmium from a system containing high concentration zinc was studied and got CdS product directly. A new liquid membrane system taking DIPSA, TIBPS as carriers, (NH 4) 2S as precipitating agent was reported. Precipitating Cd 2+ in the internal aq. phase that is used to treat sulfuric acid leaching solution of zinc oxide in zinc hydrometallurgy has gotten satisfied results of extracting cadmium from high concentration zinc. After one stage of batch process under the optimum liquid membrane conditions, 98.6% transferring rate and 98.1% extracting rate of cadmium was obtained with only less than 1.0% transferring rate of zinc, and the feed solution can be purified very well.
文摘The investigation of recovery Ga 3+ by emulsion liquid membrane (ELM) using Tri alkyl oxide phosphine (TRPO) as the mobile carrier was reported. The optimum emulsion liquid membrane conditions were determinated. They were: the feed pH 1.0, organic phase consisting of 5% TRPO, 4% LMS 2 and 2% liquid paraffin in kerosene solution, 10% K 4[Fe(CN) 6] aq. solution as the stripping agent, R oi =2∶1, R ew =1∶5. At the optimum ELM operating condition, the recovery rate of gallium was 96.5%, and the oil phase can be reused for 5 times.
文摘In order to improve the refining effect of zinc ore and promote the development of this industry,taking the hydrometallurgical zinc smelting process as an example,this paper first establishes a model for the recycling of waste residues in the hydrometallurgical process,proposes optimization measures based on proven comprehensive recycling technology for purifying residues to obtain higher valuable metal recovery rate,and provides reference for those in relevant fields.
