Surface Patterning of Metal Zinc Electrode with an In‑Region Zincophilic Interface for High‑Rate and Long‑Cycle‑Life Zinc Metal Anode

The undesirable dendrite growth induced by non-planar zinc(Zn)deposition and low Coulombic efficiency resulting from severe side reactions have been long-standing challenges for metallic Zn anodes and substantially impede the practical application of rechargeable aqueous Zn metal batteries(ZMBs).Herein,we present a strategy for achieving a high-rate and long-cycle-life Zn metal anode by patterning Zn foil surfaces and endowing a Zn-Indium(Zn-In)interface in the microchannels.The accumulation of electrons in the microchannel and the zincophilicity of the Zn-In interface promote preferential heteroepitaxial Zn deposition in the microchannel region and enhance the tolerance of the electrode at high current densities.Meanwhile,electron aggregation accelerates the dissolution of non-(002)plane Zn atoms on the array surface,thereby directing the subsequent homoepitaxial Zn deposition on the array surface.Consequently,the planar dendrite-free Zn deposition and long-term cycling stability are achieved(5,050 h at 10.0 mA cm^(−2) and 27,000 cycles at 20.0 mA cm^(−2)).Furthermore,a Zn/I_(2) full cell assembled by pairing with such an anode can maintain good stability for 3,500 cycles at 5.0 C,demonstrating the application potential of the as-prepared ZnIn anode for high-performance aqueous ZMBs.

Square grid pattern with direction-selective surface discharges in dielectric barrier discharge

A new phenomenon that a filament discharged only once instead of twice in a cycle of the applied voltage is observed in a square grid pattern in a dielectric barrier discharge(DBD)with a larger gas gap,which is named intermittent discharge.Its spatiotemporal dynamics and the formation mechanism are studied by the multiple photomultiplier tubes and an intensified charge-coupled device.Corresponding to the positions of spots in the picture with an exposure time of 40 ms,there are some bright spots(discharge spots)and black spots(non-discharged spots)in the instantaneous image with an exposure time of 10μs(a half cycle of the applied voltage).There are at least two bright spots around one black spot and vice versa.The surface discharges(SDS)can be observed between any two adjacent spots.The intensity of the SDSbetween the bright spot and the black spot is 2.5 times greater than that between two adjacent bright spots,which indicates that the SDSare directional-selective.The intermittent discharge with positive(negative)current polarity changes to that with negative(positive)current polarity,after it sustains up to 14 voltage cycles at the longest.The spatial distribution of the electric field component is calculated through COMSOL software to solve the Poisson equation numerically.It is found that the inhomogeneous distribution of surface electric field is caused by the inhomogeneous distribution of wall charges,which leads to direction-selective SDS.The intermittent discharge is formed by the competition between the direction-selective SDSand volume discharges(VDS)in DBD.This is the reason why the intermittent discharge is generated.

Color as Material: Ceramic Surfaces in the Work of Gio Ponti in Milan (1927-1970)

The study is based on the analysis of the design and operational path conducted by the architect Gio Ponti on ceramic materials between the late 1920s and the early 1970s,with particular attention to applications in the Milanese context.Milan represents the main laboratory for experimenting with the figurative,plastic and chromatic potential of modern ceramic surfaces.The analysis of archival documentation preserved at the CSAC Archive in Parma,the Gio Ponti Archives in Milan and the Archivio Progetti at the Iuav University of Venice allows for a deeper understanding of the design path at different scales,from the design of specific lines of ceramics for industry,to their application in buildings.The second part of the analysis is aimed at tracing the conservation problems of ceramic surfaces,with the aim of highlighting both the cultural and technical aspects that are affecting the conservation of this heritage.Connected to the latter aspect is a focus on the principal deterioration phenomena of modern ceramic surfaces related to different types of substrates,providing in-depth knowledge that opens up new strategies for their conservation.

Introduction of Multiscaled Longitudinal Vortices by Fractal-Patterned Surface Roughness

To determine the type of surface roughness pattern that is suitable for adaptive suppression of the drag of an obstacle, we observed flow structures introduced by such obstacles. Several roughness patterns were tested: geometric patterns, fractal patterns, reptile-skin patterns, and patterns of circular cylinders arranged in a lattice and in a zigzag manner. A suitable pattern for adaptive control of flow is one that generates longitudinal vortices with nonconstant distances. The preferred instability mode of a laminar boundary layer is expected to be selected automatically from fluctuations involving many frequencies and caused by fractal patterns. Snake- and reptile-skin patterns may have a similar ability as fractal patterns because they consist of multiscale patterns. The longitudinal vortices generated from peculiar positions and concave corners in patterns were observed. The distance between these vortices is not constant because the onset of vortices is at concave corners in fractal patterns. These vortices have differing strengths and easily cause nonlinear interactions, so they can disturb a laminar boundary layer with several higher-harmonic frequencies. The velocity profiles of the laminar boundary-layer flow over the fractal patterns were measured by using hydrogen bubbles. The results show the down-wash flow between the longitudinal vortices, which means that the vortices may effectively suppress the boundary layer separation in an adverse pressure gradient.

The patterns of surface capillary-gravity short-crested waves with uniform current fields in coastal waters

A fully three-dimensional surface gravitycapillary short-crested wave system is studied as two progressive wave-trains of equal amplitude and frequency, which are collinear with uniform currents and doubly-periodic in the horizontal plane, are propagating at an angle to each other. The first- and second-order asymptotic analytical solutions of the short-crested wave system are obtained via a perturbation expansion in a small parameter associated with the wave steepness, therefore depicting a series of typical three-dimensional wave patterns involving currents, shallow and deep water, and surface capillary waves, and comparing them with each other.

Trend surface analysis of forest landscape pattern in Guandishan forest region of Shanxi,China

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Propagation of Surface Wave Along a Thin Plasma Column and Its Radiation Pattern

Propagation of the surface waves along a two-dimensional plasma column and the far-field radiation patterns are studied in thin column approximation. Wave phase and attenuation coefficients are calculated for various plasma parameters. The radiation patterns are shown. Results show that the radiation patterns are controllable by flexibly changing the plasma length and other parameters in comparison to the metal monopole antenna. It is meaningful and instructional for the optimization of the plasma antenna design.

Pattern recognition of surface electromyography signal based on wavelet coefficient entropy

This paper introduced a novel, simple and ef-fective method to extract the general feature of two surface EMG (electromyography) signal patterns: forearm supination (FS) surface EMG signal and forearm pronation (FP) surface EMG signal. After surface EMG (SEMG) signal was decomposed to the fourth resolution level with wavelet packet transform (WPT), its whole scaling space (with frequencies in the interval (0Hz, 500Hz]) was divided into16 frequency bands (FB). Then wavelet coefficient entropy (WCE) of every FB was calculated and corre-spondingly marked with WCE(n) (from the nth FB, n=1,2,…16). Lastly, some WCE(n) were chosen to form WCE feature vector, which was used to distinguish FS surface EMG signals from FP surface EMG signals. The result showed that the WCE feather vector consisted of WCE(7) (187.25Hz, 218.75Hz) and WCE(8) (218.75Hz, 250Hz) can more effectively recog-nize FS and FP patterns than other WCE feature vector or the WPT feature vector which was gained by the combination of WPT and principal components analysis.

Dominant patterns of winter Arctic surface wind variability

Dominant statistical patterns of winter Arctic surface wind （WASW） variability and their impacts on Arctic sea ice motion are investigated using the complex vector empirical orthogonal function （CVEOF） method. The results indicate that the leading CVEOF of Arctic surface wind variability, which accounts for 33% of the covariance, is characterized by two different and alternating spatial patterns （WASWP1 and WASWP2）. Both WASWP1 and WASWP2 show strong interannual and decadal variations, superposed on their declining trends over past decades. Atmospheric circulation anomalies associated with WASWPI and WASWP2 exhibit, respectively, equivalent barotropic and some baroclinic characteristics, differing from the Arctic dipole anomaly and the seesaw structure anomaly between the Barents Sea and the Beaufort Sea. On decadal time scales, the decline trend of WASWP2 can be attributed to persistent warming of sea surface temperature in the Greenland--Barents--Kara seas from autunm to winter, reflecting the effect of the Arctic warming. The second CVEOF, which accounts for 18% of the covariance, also contains two different spatial patterns （WASWP3 and WASWP4）. Their time evolutions are significantly correlated with the North Atlantic Oscillation （NAO） index and the central Arctic Pattern, respectively, measured by the leading EOF of winter sea level pressure （SLP） north of 70~N. Thus, winter anomalous surface wind pattern associated with the NAO is not the most important surface wind pattern. WASWP3 and WASWP4 primarily reflect natural variability of winter surface wind and neither exhibits an apparent trend that differs from WASWP1 or WASWP2. These dominant surface wind patterns strongly influence Arctic sea ice motion and sea ice exchange between the western and eastern Arctic. Furthermore, the Fram Strait sea ice volume flux is only significantly correlated with WASWP3. The results demonstrate that surface and geostrophic winds are not interchangeable in terms of describing wind field variability over the Arctic Ocean. The results have important implications for understanding and investigating Arctic sea ice variations： Dominant patterns of Arctic surface wind variability, rather than simply whether there are the Arctic dipole anomaly and the Arctic Oscillation （or NAO）, effectively affect the spatial distribution of Arctic sea ice anomalies.

Surface warming patterns dominate the uncertainty in global water vapor plus lapse rate feedback

Climate feedbacks have been usually estimated using changes in radiative effects associated with increased global-mean surface temperature. Feedback uncertainties, however, are not only functions of global-mean surface temperature increase. In projections by global climate models, it has been demonstrated that the geographical variation of sea surface temperature change brings significant uncertainties into atmospheric circulation and precipitation responses at regional scales. Here we show that the spatial pattern of surface warming is a major contributor to uncertainty in the combined water vapour-lapse rate feedback. This is demonstrated by computing the global-mean radiative effects of changes in air temperature and relative humidity simulated by 31 climate models using a methodology based on radiative kernels. Our results highlight the important contribution of regional climate change to the uncertainty in climate feedbacks, and identify the regions of the world where constraining surface warming patterns would be most effective for higher skill of climate projections.

Pulsed microwave-driven argon plasma jet with distinctive plume patterns resonantly excited by surface plasmon polaritons

Atmospheric lower-power pulsed microwave argon cold plasma jets are obtained by using coaxial transmission line resonators in ambient air.The plasma jet plumes are generated at the end of a metal wire placed in the middle of the dielectric tubes.The electromagnetic model analyses and simulation results suggest that the discharges are excited resonantly by the enhanced electric field of surface plasmon polaritons.Moreover,for conquering the defect of atmospheric argon filamentation discharges excited by 2.45-GHz of continued microwave,the distinctive patterns of the plasma jet plumes can be maintained by applying different gas flow rates of argon gas,frequencies of pulsed modulator,duty cycles of pulsed microwave,peak values of input microwave power,and even by using different materials of dielectric tubes.In addition,the emission spectrum,the plume temperature,and other plasma parameters are measured,which shows that the proposed pulsed microwave plasma jets can be adjusted for plasma biomedical applications.

Surface Water Pollution in the Yangtze River Delta:Patterns and Countermeasures

On the basis of field investigations, observations and experimental data combined with environmentalmonitoring information, the status and the spatial and temporal patterns of surface water pollution over thepast ten years in the Yangtze River Delta have been assessed. The water quality of large rivers is still verygood but most of the medium-sized and small rivers have been very seriously polluted. The appearance ofblack and odorous conditions in rivers in the urban areas has increased due to serious pollution by organicmatter with consequent high oxygen demand. Annual increases in N and P concentrations in lakes haveaccelerated eutrophication. The water quality of rivers in small towns is rapidly deteriorating. The mainsources of surface water pollution include industrial and domestic sewage, animal manures, chemical fertilizersin farmland, and polluted sediments in rivers and lakes.Countermeasures against these sources of pollution are presented. Regional laws and regulations

Experimental Investigation of Laser Surface Hardening of AISI 4340 Steel Using Different Laser Scanning Patterns

Laser surface transformation hardening becomes one of the most modern processes used to improve fatigue and wear properties of steel surfaces. In this process, the material properties and the heating parameters are the factors that present the most significant effects on the hardened surface attributes. The control of these factors using predictive modeling approaches to achieve desired surface properties leads to conclusive results. However, when the dimensions of the surface to be treated are larger than the cross-section of the laser beam, various laser-scanning patterns are involved. This paper presents an experimental investigation of laser surface hardening of AISI 4340 steel using different laser scanning patterns. This investigation is based on a structured experimental design using the Taguchi method and improved statistical analysis tools. Experiments are carried out using a 3 kW Nd: YAG laser source in order to evaluate the effects of the heating parameters and patterns design parameters on the physical and geometrical characteristics of the hardened surface. Laser power, scanning speed and scanning patterns (linear, sinusoidal, triangular and trochoid) are the factors used to evaluate the hardened depth and the hardened width variations and to identify the possible relationship between these factors and the hardened zone attributes. Various statistical tools such as ANOVA, correlations analysis and response surfaces are applied in order to examine the effects of the experimental factors on the hardened surface characteristics. The results reveal that the scanning patterns do not modify the nature of the laser parameters’ effects on the hardened depth and the hardened width. But they can accentuate or reduce these effects depending on the type of the considered pattern. The results show also that the sinusoidal and the triangular patterns are relevant when a maximum hardened width with an acceptable hardened depth is desired.

Surface property variations in flotation performance of calcite particles under different grinding patterns

基于料层粉碎工作方式,高压辊磨制备的矿物颗粒具有区别于其他磨矿方式制备颗粒的表面特性,对矿物浮选会产生较大的影响。本文研究了高压辊磨、颚式破碎、干式球磨、湿式球磨及湿式棒磨下方解石纯矿物颗粒的浮选行为,并通过比表面积、粒径分布、原子力学显微镜、表面电子能谱及动电位等手段表征了不同磨矿方式制备颗粒的表面特性以揭示其浮选机理。结果表明:当磨矿细度较低时,相比于其他磨矿方式高压辊磨制备的方解石颗粒在油酸钠和十二胺体系均能够获得更好的浮选指标;由磨矿方式导致的矿物颗粒比表面积、粒度分布、表面粗糙度、Fe^(3+)沾染物、键合能及Zeta电位差异是其浮选行为差异化的主要原因。

Effects of Surface-Active Elements Sulfur on Flow Patterns of Welding Pool

A 3D mathematical model is developed to calculate the temperature and velocity distributions in a moving gas tungsten arc (GTA) welding pool with different sulfur concentrations. It has been shown that, the weld penetration increases sharply with increasing sulfur content. When sulfur content increases beyond 80 × 10-6, the increase in sulfur content does not have an appreciable difference on the welding pool size and shape, and the depth/width remains constant. Sulfur changes the temperature dependence of surface tension coefficient from a negative value to a positive value and causes significant changes on flow patterns. The increase in soluble sulfur content and the decrease at free surface temperature can extend the region of positive surface tension coefficient. As sulfur content exceeds 125×10-6, the sign of surface tension coefficient is positive. Depending upon the sulfur concentrations, three, one or two vortexes that have different positions, strength and directions may be found in the welding pool. The contrary vortexes can efficiently transfer the thermal energy from the arc, creating a deep welding pool. An optimum range of sulfur content is 20-150×10-6.

Surface circulation patterns observed by drifters in the Yellow Sea in summer of 2001,2002 and 2003

In summer of 2001, 2002 and 2003, ten, six and seventeen satellite-tracked surface drifters with drogues centered at 15 and 4 m were deployed, respectively, in the southern Yellow Sea (YS). 23 drifters of them transmitted useful data of at least 30 days. The wind-driven component of the drift was removed from the original drift velocity of drifters. The wind data used are from NCEP (National Center for Environmental Prediction), USA.Trajectories and drift velocities of the 23 drifters depicted the upper circulation structure in the southern YS.There exists an anti-cyclonic eddy with a mean speed and radius of 0.063 m/s and 50km in the central southern YS, whose center lingered within 35.3-36.0°N / 123.5-124.0°E. Showed by 6 drifters, a basin-scale elliptic cyclonic gyre with a mean speed of 0.114 m/s, long and short radius of 250 and 200 km surrounds the anti-cyclonic eddy. In the southwestern part of the southern YS has obvious frontal eddy activities within about100 km with a mean speed about 0.076 m/s. All the drifters passing Korean coast were staggering for more than10 days west of a protruding cape of central Korea. A small-scale cyclonic eddy centered at around 120.5°E/35.1°N with a mean speed of 0.048 m/s was observed in western part of the southern YS.

Distribution Pattern of Heavy Metals in the Surface Sediments of the Jiaozhou Bay

Grain size analysis and chemical analysis of heavy metals are made for 312 surface samples of the Jiaozhou Bay. Nineteen samples of the waste water taken from the sewage discharge outlets along the eastern coast of the bay are also analyzed for heavy metals. Results show that heavy metals are richer in the east and poorer in the west of the bay. Sedimentary dynamic studies reveal that the distribution of heavy metals in the surface sediments of the Jiaozhou Bay is under the control of hydrodynamics.

Photodetachment microscopy of H^- in the magnetic field near different dielectric surfaces

We study the photo-detachment interference patterns of a hydrogen negative ion in the magnetic field near different dielectric surfaces with a semi-classical open orbit theory. We give a clear physical picture describing the photo-detachment of H- in this case. The electron flux distributions are calculated at various dielectric surfaces with unchanged magnetic field strength. It is found that the electron flux distributions of H- are very different in a magnetic field near different dielectric surfaces, namely the dielectric surface has a great influence on the photo-detachment interference pattern of the negative ion. Therefore, the interference pattern in the detached-electron flux distribution can be controlled by changing the dielectric constant. We hope that our studies may guide the future experimental research in photo-detachment microscopy.