Wulong gold deposit hosted in granite and fine-grained d io rite dikes, is a typical gold deposit of quartz vein type. Granite and fine-gra ined diorite dikes in the ore deposit were altered by metallogenic fluid. Bas...Wulong gold deposit hosted in granite and fine-grained d io rite dikes, is a typical gold deposit of quartz vein type. Granite and fine-gra ined diorite dikes in the ore deposit were altered by metallogenic fluid. Based on the altered zoning, the samples of petrochemistry were collected and major an d trace elements were analyzed systematically. Calculation of rock mass balance shows that the major elements (SiO 2, K 2O, P 2O 5, Fe 2O 3) in the two ty pical altered rocks are clearly added into the altered system, and that trace el ements (V, Y, Zr, Ni, Co, Sr) assume an increasing and decreasing tendencies in the altered granite and altered diorite dike, respectively. The fluid/rock ratio s are 30.17-181.00 and 115.44-692.67 respectively for altered granite and alte red diorite dike, they have profoundly effects on metallogenesis.展开更多
The Jinjiazhuang gold deposit occurs in the Zhangjiakou gold field, Northwest Hebei. The ore bodies are mostly hosted in Xiaozhangjiakou ultrabasic rocks dominated by diopsidite. Electron microprobe analyses indicate ...The Jinjiazhuang gold deposit occurs in the Zhangjiakou gold field, Northwest Hebei. The ore bodies are mostly hosted in Xiaozhangjiakou ultrabasic rocks dominated by diopsidite. Electron microprobe analyses indicate that the deposit is characterized by the enrichment of some platinum group elements in principal metallic minerals such as chalcopyrite, galena, sphalerite and pyrite, and the presence of millerite. Stable isotope studies show that carbon, sulfur and most of the metallogenic elements were probably derived largely from the host Xiaozhangjiakou ultrabasic rocks and that it is possible that the ore\|forming fluid was predominated by meteoric water.展开更多
Mineral assemblages formed during hydrothermal alteration reflect the geochemical composition of ore-forming fluids. Gold is mainly transported in solution as Au-CI and Au-S complexes. The change of physicochemical co...Mineral assemblages formed during hydrothermal alteration reflect the geochemical composition of ore-forming fluids. Gold is mainly transported in solution as Au-CI and Au-S complexes. The change of physicochemical conditions such as temperature, pressure, oxygen fugacity, and sulfur fugacity are effective mechanisms for gold precipitation. Gold tends to be concentrated in the vapor phase of fluids at high temperatures and pressures. Au-As and Au-Sb associations are common in gold deposit. Native antimony and/or arsenic -- native gold assemblages may precipitate from hydrothermal fluids with low sulfur fugacity. Hydrothermal fluids forming epithermal gold deposits are Au-saturated in most cases, whereas fluids of Carlin-type are Au-undersaturated. Quasi-steady As-bearing pyrite extracts solid solution Au from hydrothermal fluids through absorption. The capability of As-bearing pyrite to absorb An from under-saturated fluid is the key to the formation of large-scale Carlin-type deposits. With increasing new data, studies on the geochemistry of gold deposits can be used to trace the origin of ore-forming fluids, the source of gold, and the transporting form of Au and other ore-forming elements, such as Si, S, F, Cl, As and Ag.展开更多
The Tongling ore district is one of the most economically important ore areas in the Middle–Lower Yangtze River Metallogenic Belt, eastern China. It contains hundreds of polymetallic copper–gold deposits and occurre...The Tongling ore district is one of the most economically important ore areas in the Middle–Lower Yangtze River Metallogenic Belt, eastern China. It contains hundreds of polymetallic copper–gold deposits and occurrences. Those deposits are mainly clustered(from west to east) within the Tongguanshan, Shizishan, Xinqiao, Fenghuangshan, and Shatanjiao orefields. Until recently, the majority of these deposits were thought to be skarn-or porphyry–skarn-type deposits; however there have been recent discoveries of numerous vein-type Au, Ag, and Pb-Zn deposits that do not fall into either of these categories. This indicates that there is some uncertainty over this classification. Here, we present the results of several systematic geological studies of representative deposits in the Tongling ore district. From investigation of the ore-controlling structures, lithology of the host rock, mineral assemblages, and the characteristics of the mineralization and alteration within these deposits, three genetic types of deposits(skarn-, porphyry-, and vein-type deposits) have been identified. The spatial and temporal relationships between the orebodies and Yanshanian intrusions combined with the sources of the ore-forming fluids and metals, as well as the geodynamic setting of this ore district, indicate that all three deposit types are genetically related each other and constitute a magmatic–hydrothermal system. This study outlines a model that relates the polymetallic copper–gold porphyry-, skarn-, and vein-type deposits within the Tongling ore district. This model provides a theoretical basis to guide exploration for deep-seated and concealed porphyry-type Cu(–Mo, –Au) deposits as well as shallow vein-type Au, Ag, and Pb–Zn deposits in this area and elsewhere.展开更多
Hydrothermal alteration with bleaching of host rocks is the most important prospecting indicator for gold deposits in the Jiangnan Orogen Belt.The alteration has been identified as pre-ore carbonate(siderite)-sericiti...Hydrothermal alteration with bleaching of host rocks is the most important prospecting indicator for gold deposits in the Jiangnan Orogen Belt.The alteration has been identified as pre-ore carbonate(siderite)-sericitization and the Fe of siderite in the alteration zone is derived from the host rocks rather than fluids.In addition,such alteration decreases in intensity and width with depth and gold mineralization also occur in the non-bleached rocks,casting doubt on the reliability of the prospecting indicator.Detailed petrographic work and SEM analysis on the Wangu deposit indicate that there are two types of siderites,i.e.,Sd1 and Sd2.Among them,Sd1 grains are relatively small and distributed along the planes of unaltered host rocks,while Sd2 grains,only occurring in the altered slates,are commonly larger.Both types of siderites were altered by auriferous fluids,producing porous cores and minerals such as pyrite,quartz,and ankerite.Compared with unaltered parts,the altered parts have lower Fe,but higher U,Pb,and REE.In addition,Sd1 and Sd2 are similar in Mn,Na,V,and Sr concentrations but different in Fe and Mg.The occurrence and geochemical compositions of both siderites indicate that Sd1 could be transformed into Sd2 by pre-mineralization alteration through dissolution-reprecipitation.Chlorite is another important Fe-bearing mineral in the host rocks,and EPMA analysis suggests that it is ripidolite with relatively high Fe contents.Consequently,chlorite can also provide Fe to form the pre-ore carbonate(siderite)-sericitization.Geochemical modeling demonstrates that both ripidolite and siderite can result in sulfidation and therefore gold precipitation.As a result,this study demonstrates that pre-ore alteration with characterized bleaching is not a prerequisite for gold mineralization despite of its prominent features.Due to the presence of Fe-bearing Sd1 and chlorite,gold mineralization could still occur through sulfidation in the unaltered rocks.展开更多
The Shewushan gold deposit is located 16 km southwest of Jiayu County, Hubei Province, eastern China, which is the largest lateritic gold deposit in Asia, consisting of a series of mineralized faults containing gold g...The Shewushan gold deposit is located 16 km southwest of Jiayu County, Hubei Province, eastern China, which is the largest lateritic gold deposit in Asia, consisting of a series of mineralized faults containing gold grades of 1.0–19.5 g/t set within a larger, lower-grade(0.2–1.0 g/t) zone. According to the fluid inclusions study, the homogenization temperature ranges from 70–350℃, and concentrates between 140–220℃. The laser Rama results show that the CO2 and CH4 exist in mineralized fluid. In addition, the major and trace element and REE geochemical data show that the genesis of the siliceous rocks is hydrothermal genesis, formed by mineralized fluid bearing SiO2 transmitted along faults to the surface, and replace the carbonate rocks to begin deposition. Primary gold mineralization is attributed to hydrothermal activity that followed the main period of tectonic deformation of the Indosinian orogeny, which caused the regional detachment regime in southeast Hubei. The reversed fold and the fault system formed the fluid migration channel in the Shewushan area. EPMA results show that Au exists in arsenopyrite(850×10-6–1550×10-6 Au) and pyrite(470×10-6–1340×10-6 Au). Therefore, based on the above results and combined with the field observation, we suggest that the genesis of primary orebody in Shewushan deposit is carlin type, while not weathered residual type.展开更多
Abstract The Shibangou gold deposit in western Henan is associated with irregular quartz veinlets occurring in altered shear zones dissecting a dioritic intrusion. The altered shear zones are characterized by silicifi...Abstract The Shibangou gold deposit in western Henan is associated with irregular quartz veinlets occurring in altered shear zones dissecting a dioritic intrusion. The altered shear zones are characterized by silicification, pyritization, sericilization, chloritization and K-feldspar alteration. Zoning of altered rocks adjacent to the Au-bearing quartz veins is obviously exhibited. Fine-grained sulphides and quartz veinlets of different ages and small-scale fissures are widely distributed in the central part of the altered zones. Major mineralization types in this gold deposit are Au-bearing quartz veinlets and altered rocks in the shear zones. Samples were collected from drilling cores according to the alteration zoning and mineralization type and all samples were analyzed for major and trace elements. Mass balance, volume change (fv=97.3–71.9%) and major element variation sequences are studied in terms of major elements. The changes of mobile components (SiO2, K2O, Fe2O3) and CaO) and immobile component (Al2O3) in the wall-rock alteration are discussed. The gold mineralization is associated with the enrichment of As, Ag, Hg and Pb and depletion of Cu and Zn. The study of compositional variation of altered rocks proves to be a very efficient method for defining the extent of wall-rock alteration, fluid activity and mineralization and enrichment.展开更多
The Jinsha River-Lancang River-Nujiang River area is one of the important prospect areas for noble metal and nonferous metal deposits of China. Of a great variety of gold deposits present in this area, the following t...The Jinsha River-Lancang River-Nujiang River area is one of the important prospect areas for noble metal and nonferous metal deposits of China. Of a great variety of gold deposits present in this area, the following types seem to be economically most valuable and promising: tectonic alteration type in ophiolitic melange; polymetallic quartz vein type related to intermediate-acid intrusions; finely disseminated type in fracture zones; mixed hydrothermal type in tectonic fractures of carbonate rocks; hydrothermal type related to subvolcanic rocks; volcanic-hot spring type; submarine volcano exhalation-sedimentary-hydrothermal reformation type. Metallogenic epochs are exclusively Mesozoic and Cenozoic, and ore deposits and orebodies are controlled by linear structures. Magmatic activity has affected gold mineralization in varying degrees, and gold deposits are basically of mesothermal-epithermal type with ubiquitous and intense alterations. Ore-forming materials and hydrothermal solutions show multi-source character.展开更多
Irbiben is a small gold deposit of the Precambrian inlier Tagragra d’Akka located in the Moroccan western Anti-Atlas, approximately 160 km southeast from Tiznit. Petrographic study shows that host rocks of Irbiben de...Irbiben is a small gold deposit of the Precambrian inlier Tagragra d’Akka located in the Moroccan western Anti-Atlas, approximately 160 km southeast from Tiznit. Petrographic study shows that host rocks of Irbiben deposit are green schist facies metamorphic rocks, like metamorphic sandstone and schist, meta-pelite and quartzite. Gold is located in quartz veins or host rock with frequent injections of quartz. The petrographic characterization of alteration through the description of the alteration profiles and the comparative study of protolith and altered rocks showed a development of dominant quartz and calcite in mineralization wall-rocks. In moving away from it, there is rather sericite and chlorite. These phenomena are materialized respectively by the development of SiO2 and CaO in the wall-rocks but rather that ferromagnesian elements (FeO, MgO) and K2O away from the mineralization. These trends were demonstrated by the geochemical study through Harker diagrams, description of alteration profiles, comparative study of protolith and altered rocks, and use of a new alteration index, MIA, elaborated during this work.展开更多
Most gold deposits in intrusive rocks were formed as a result of reworking processes.The intrusive rocks containing gold deposits and consisting of ultramafic-mafic, intermediate-acid and alkaline rocks of the Archean...Most gold deposits in intrusive rocks were formed as a result of reworking processes.The intrusive rocks containing gold deposits and consisting of ultramafic-mafic, intermediate-acid and alkaline rocks of the Archean, Proterozoic, Caledonian, Hercynian and Yenshanian periods occur in cratons, activated zones of cratons and fold belts. Among them, ultramafic-mafic rocks, diorite, alkaline rocks, and anorthosite are products of remelting in the mantle or mantle-crust or mantle with crustal contamination. However, auriferous intermediate-acid rocks are products of metasomatic-remelting in auriferous volcanic rocks or auriferous volcano-sedimentary rocks in the deep crust.展开更多
The Shangzhuang altered-rock type gold ore deposit is located in the middle segment of and controlled by the Wang'ershan fault zone in the northwestern part of the Jiaodong gold province, China. The deformation evolu...The Shangzhuang altered-rock type gold ore deposit is located in the middle segment of and controlled by the Wang'ershan fault zone in the northwestern part of the Jiaodong gold province, China. The deformation evolution, the structure of strain and stress fields and its ore-controlling effect in the Shangzhuang deposit are discussed in this paper. It is revealed that the deformation evolution has mainly undergone four phases: the early ductile deformation, the second NE-striking horizontal simple shear, the third NE-striking compression-shear and the final NW-striking compression. The mineralization happened during the third stage in which the maximum principal stress gradually transited from NE to NW. The 3-D numerical simulations of the stress field show that, on the condition that the maximum principal stress is NE-striking, the fracture development in the fault zone is favored, while when the maximum principal stress is NW-striking, the fault zone is relatively extensional and it is suitable for the influx and emplacement of ore-forming fluids. The compression-shear strain field during the mineralization is characterized by the λ-type structure, the positive flower structure, etc. Orebodies are mostly equidistantly located in the dilatational spaces, which are distributed in the integral compressional circumstances. And the dilatational spaces are developed where the fault attitude changes or shear joint systems develop. In the overall compression-shear stress field, the strain field bears self-similarity at multiple scales, including the orebody, ore deposit and orefield. The selfsimilarity of the structure comprises the subequidistant distribution of fractures at the same scale and the similar shape of the fractures at various scales. Yet, due to the special geological structure, the orebodies are mostly located in the hanging wall in the Shangzhuang deposit, which is different from most deposits in the Jiaodong gold province. Analyses of the ore-controlling stress and strain fields in the deposit provide an important basis for deposit seeking.展开更多
Orogenic disseminated and Carlin gold deposits share much similarity in alteration and mineralization.The disseminated orogenic Zhenyuan Au deposit along the Ailaoshan shear zone,southeastern Tibet,was selected to cla...Orogenic disseminated and Carlin gold deposits share much similarity in alteration and mineralization.The disseminated orogenic Zhenyuan Au deposit along the Ailaoshan shear zone,southeastern Tibet,was selected to clarify their difference.The alteration and mineralization from the different lithologies,including meta-quartz sandstone,carbonaceous slate,meta-(ultra)mafic rock,quartz porphyry and lamprophyre were researched.According to the mineral assemblage and replacement relationship in all types of host rocks,two reactions show general control on gold deposition:(1) replacement of earlier magnetite by pyrite and carbonaceous material;(2) alteration of biotite and phlogopite phenocrysts in quartz porphyry and lamprophyre into dolomite/ankerite and sericite.Despite the lamprophyre is volumetrically minor and much less fractured than other host rocks,it contains a large portion of Au reserve,indicating that the chemically active lithology has played a more important role in gold precipitation compared to structure.LA-ICP-MS analysis shows that Au mainly occurs as invisible gold in fine-grained pyrite disseminated in the host rocks,with Au content reaching to 258.95 ppm.The diagenetic core of pyrite in meta-quartz sandstone enriched in Co,Ni,Mo,Ag and Hg is wrapped by hydrothermal pyrite enriched in Cu,As,Sb,Au,Tl,Pb and Bi.Different host rock lithology has much impact on the alteration and mineralization features.Carbonate and sericite in altered lamprophyre show they have higher Mg than those developed in other of host rocks denoting that the carbonate and sericite incorporated Mg from phlogopite phenocrysts in the primary lamprophyre during alteration.The ore fluid activated the diagenetic pyrite in meta-quartz sandstone leading the hydrothermal pyrite enriched in Cu,Mo,Ag,Sb,Te,Hg,Tl,Pb and Bi,but the hydrothermal pyrite in meta-(ultra)mafic rock is enriched in Co and Ni as the meta-(ultra)mafic rock host rock contain high content of Co and Ni.However,Au and As shear similar range in both types of host rocks indicating that these two elements most likely come from the deep source fluid rather than the host rocks.It was shown in the disseminated orogenic gold deposit that similar hydrothermal alteration with mineral assemblage of carbonate (mainly dolomite and ankerite),sericite,pyrite and arsenopyrite develops in all types of host rocks.This is different from the Nevada Carlin type,in which alteration is mainly dissolution and silicification of carbonate host rock.On the other hand,Au mainly occur as invisible gold in both disseminated orogenic and Carlin gold deposits.展开更多
The Nyasirori gold deposit,located in the middle-western end of the Musoma-Mara Archean greenstone belt in Tanzania,is a tectonic altered rock type gold deposit controlled by shear tectonic zone.This work conducted hi...The Nyasirori gold deposit,located in the middle-western end of the Musoma-Mara Archean greenstone belt in Tanzania,is a tectonic altered rock type gold deposit controlled by shear tectonic zone.This work conducted high-precision ground magnetic measurements to delineate fault structures and favorable prospecting targets,utilized induced polarization(IP)intermediate gradient to roughly determine the distribution and extension of the tectonic altered zone and gold ore(mineralized)bodies,and further carried out IP sounding and magnetotelluric sounding to locate the tectonic altered zone and gold ore(mineralized)bodies.The anomalous gradient belt of the combination of positive and negative micromagnetic measurements reflects the detail of shallow surface tectonic alteration zone and gold mineralization body.Micromagnetic profile anomalies indicate the spatial location and occurrence of concealed tectonic alteration zone and gold(mineralized)ore bodies.Soil geochemical measurements indicate that the ore-forming element Au correlates well with As and Sb,and As and Sb anomalies have a good indication to gold orebodies.Based on the multi-source geological-geophysical-geochemical information of the Nyasirori gold deposit,this work established an integrated prospecting model and proposed a set of geophysical and geochemical methods for optimizing prospecting targets.展开更多
The Baguamiao gold deposit in Fengxian County, Shaanxi Province, is a recentlyexplored super-large gold ore deposit. A comprehensive and deep-going study has revealedthat it is a polygenetic deposit: early-stage miner...The Baguamiao gold deposit in Fengxian County, Shaanxi Province, is a recentlyexplored super-large gold ore deposit. A comprehensive and deep-going study has revealedthat it is a polygenetic deposit: early-stage mineralization due to shearing, middle-stagemineralization due to hydrothermal alteration, and late-stage mineralization due toweathering, leaching and concentration at shallow depths. Shearing played a dominant role inthe formation of gold orebodies.展开更多
The Baoban gold field, located in the area of Hainan Island, South China, bears three gold de-posits: Tuwaishan, Baoban, and Erjia, which belong to the wall-rock alteration type. In terms of the petrography data, four...The Baoban gold field, located in the area of Hainan Island, South China, bears three gold de-posits: Tuwaishan, Baoban, and Erjia, which belong to the wall-rock alteration type. In terms of the petrography data, four alteration zones can be recognized from the ore-vein outwards: (1) the silicification zone; (2) the sericitization zone, (3) the chloritization zone; and (4) the calcitization zone. The geochemical kinetic simulation was carried out on sericitization and chloritization . Results of the study showed that the formation of the alteration zones is connected with the properties of hydrothermal fluids: the initial concentration of Al (O H)3, the diffusion coefficient and the velocity of fluid flow. The alteration zones in this field are the result of multiple interaction between hydrothermal fluids and wall rocks.展开更多
The Gacun Kuroko-type deposit, Southwestern China, is hosted in rhyolitic rocks associated with the underlying mafic rocks occurred in the - 1000 m deep fault - bounded basin within the intra -arc rifting zone which f...The Gacun Kuroko-type deposit, Southwestern China, is hosted in rhyolitic rocks associated with the underlying mafic rocks occurred in the - 1000 m deep fault - bounded basin within the intra -arc rifting zone which formed on the Triassic Yidun island - arc. Two vertically separated alteration systems are recognized: one is conformable or semiconformable alteration zone developed in - 150 m thick mafic unit 1-1.5 km below the massive sulfide ore body; the other is discordant alteration pipe directly surrounded around stockwork ore within rhyolitic unit. The lower conformable alteration zone extending for several kilometers along strike is characterized by silicification and epidotization which result in the development of quartz vein and quartz-epidote vein systems in mafic lava flows and replacement of primary minerals and groundmass in spilitized mafic volcanics and dikes by quartz, epidote - group minerals and sodic plagioclase. Sulfides often occur in the vein system and altered mafic volcanics. Quartz solubility relation indicates that silicification is a consequence of interaction of Si- saturated fluids with mafic rocks in a higher temperature system (T>340℃), intensifying by intrusion of mafic dike or high-level acidic magma chamber. The alteration pipe of diameter about 2 km shows a similar mineralogical zoning to Kuroko deposits of Japan. The sequence is quartz + hyalophane; sericite + chlorite + quartz and zeolite-like zones from core to margins of the pipe. The chlorite core only occurs in the root part of the alteration pipe and downwards transfers into epidote - chlorite and epidote - quartz vein swarm extending 500 m downwards. The felsic rocks away from the orebody and alteration pipe took place district-scale alteration, which has typical low-temperature mineral association: illite + albite + quartz + calcite. Whole -rock and quartz δ18O values indicate that district - scale alteration is a result of interaction of seawater with rocks at lower temperature (T<200℃)under water-dominated condition. However, the altered rocks from the pipe show remarkably δ18O enrichment, and bulk -rock δ18O values decreased gradually toward stockwork orebody from 15.1‰-l5. 75‰ in zeolite-like zone and 12. 05‰-14. 2‰ in sericite - quartz zone to 11.3 ‰ - 14. 4‰ in quartz - hyalophane zone. The filled temperatures of fluid inclusions in quartz and sphalerite lie in the ranges of 280 -320 ℃ for quartz - hyalophane zone and 250 ℃ to 297 ℃ for sericite-quartz zone. The estimated δ18O values of hydrothermal fluids are 7. 98‰ and3.2‰, respectively, based on quartz δ18O data in the deposit. The lower conformable alteration is considered to be approximately coeval with the alteration pipe, based on the SiO2 concentration in the fluids, which restrict the main fluid - rock reaction zone to be located in mafic horizon by quartz barometer, and metal element flux calculation and sulfide - epidote vein system developed both in alteration systems. High - salinity fluid inclusions in gangue quartz (>8% eq. NaCl) from stockwork ore and in quartz phenocryst (>40% eq. NaCl) in footwall rhyolite strongly suggest the existence of hot-saline brine to react with mafic complex and leach metal components, which probably originates mainly from magmatic fluid derived from high-level acidic magma chamber. The brine layer located in mafic unit possibly heats and drives the overlying single -pass convective seawater reacting with felsic rocks. The 'density window' may be expected to occur on the interface between seawater and brine layer, when the brine becomes to be gravitationally instability by the turbulent entrainment of seawater during magmatic and/or tectonic activities. The sulfide mineralization and alteration pipe is inter preted as an effect of the 'density window' through which the mixed fluids of brine with seawater adiabatically discharges upwards.展开更多
The major gold deposits in East China are characterized by their occurrence in pre-Cambrian host metamorphic rocks, restriction in some specific stratigraphic-structural terranes,tendentious localization in ductile or...The major gold deposits in East China are characterized by their occurrence in pre-Cambrian host metamorphic rocks, restriction in some specific stratigraphic-structural terranes,tendentious localization in ductile or ductile-brittle shear zones, association with the syntexis-type granitoids, and significant remobilization, superimposition and enrichment by the later-stage Mesozoic tectono-magmatic activities.展开更多
Calculations based on the available thermodynamic data of AuCl2^- and Au(HS)2^- indicate that AuCl2^- is responsible for the transport and enrichment of gold during the stage of pre-concentration in the source bed whi...Calculations based on the available thermodynamic data of AuCl2^- and Au(HS)2^- indicate that AuCl2^- is responsible for the transport and enrichment of gold during the stage of pre-concentration in the source bed while Au(HS)2^- is the main gold species involved in the formation of gold deposits in response to hydrothermal reworking .Acid chloride solutions with αcl^->10° and sulfur-rich solutions with a∑s in excess of 10^-2 are held as important criteria for gold enrichment in the source bed and for the formation of gold deposits by subsequent hydrothermal event, respectively.展开更多
基金TheKeyProgramofMinistryofSciencesandTechnologyofChina(No .95 pre 39)
文摘Wulong gold deposit hosted in granite and fine-grained d io rite dikes, is a typical gold deposit of quartz vein type. Granite and fine-gra ined diorite dikes in the ore deposit were altered by metallogenic fluid. Based on the altered zoning, the samples of petrochemistry were collected and major an d trace elements were analyzed systematically. Calculation of rock mass balance shows that the major elements (SiO 2, K 2O, P 2O 5, Fe 2O 3) in the two ty pical altered rocks are clearly added into the altered system, and that trace el ements (V, Y, Zr, Ni, Co, Sr) assume an increasing and decreasing tendencies in the altered granite and altered diorite dike, respectively. The fluid/rock ratio s are 30.17-181.00 and 115.44-692.67 respectively for altered granite and alte red diorite dike, they have profoundly effects on metallogenesis.
文摘The Jinjiazhuang gold deposit occurs in the Zhangjiakou gold field, Northwest Hebei. The ore bodies are mostly hosted in Xiaozhangjiakou ultrabasic rocks dominated by diopsidite. Electron microprobe analyses indicate that the deposit is characterized by the enrichment of some platinum group elements in principal metallic minerals such as chalcopyrite, galena, sphalerite and pyrite, and the presence of millerite. Stable isotope studies show that carbon, sulfur and most of the metallogenic elements were probably derived largely from the host Xiaozhangjiakou ultrabasic rocks and that it is possible that the ore\|forming fluid was predominated by meteoric water.
基金the National Natural Science Foundation of China(Nos.41072041,40821002) for financial support
文摘Mineral assemblages formed during hydrothermal alteration reflect the geochemical composition of ore-forming fluids. Gold is mainly transported in solution as Au-CI and Au-S complexes. The change of physicochemical conditions such as temperature, pressure, oxygen fugacity, and sulfur fugacity are effective mechanisms for gold precipitation. Gold tends to be concentrated in the vapor phase of fluids at high temperatures and pressures. Au-As and Au-Sb associations are common in gold deposit. Native antimony and/or arsenic -- native gold assemblages may precipitate from hydrothermal fluids with low sulfur fugacity. Hydrothermal fluids forming epithermal gold deposits are Au-saturated in most cases, whereas fluids of Carlin-type are Au-undersaturated. Quasi-steady As-bearing pyrite extracts solid solution Au from hydrothermal fluids through absorption. The capability of As-bearing pyrite to absorb An from under-saturated fluid is the key to the formation of large-scale Carlin-type deposits. With increasing new data, studies on the geochemistry of gold deposits can be used to trace the origin of ore-forming fluids, the source of gold, and the transporting form of Au and other ore-forming elements, such as Si, S, F, Cl, As and Ag.
基金funded by the National Natural Science Foundation of China(NSFC)(grant numbers 41472066,40972063 and 41672038)the Program of the Deep Exploration in China(SinoProb-03-05)+1 种基金the National KeyR&S Program of China(2016 YFC0600209)the Land and Resources Science and Techonolgy Foundation of Anhui Province(2016-K-03 and No.2014-K-03)
文摘The Tongling ore district is one of the most economically important ore areas in the Middle–Lower Yangtze River Metallogenic Belt, eastern China. It contains hundreds of polymetallic copper–gold deposits and occurrences. Those deposits are mainly clustered(from west to east) within the Tongguanshan, Shizishan, Xinqiao, Fenghuangshan, and Shatanjiao orefields. Until recently, the majority of these deposits were thought to be skarn-or porphyry–skarn-type deposits; however there have been recent discoveries of numerous vein-type Au, Ag, and Pb-Zn deposits that do not fall into either of these categories. This indicates that there is some uncertainty over this classification. Here, we present the results of several systematic geological studies of representative deposits in the Tongling ore district. From investigation of the ore-controlling structures, lithology of the host rock, mineral assemblages, and the characteristics of the mineralization and alteration within these deposits, three genetic types of deposits(skarn-, porphyry-, and vein-type deposits) have been identified. The spatial and temporal relationships between the orebodies and Yanshanian intrusions combined with the sources of the ore-forming fluids and metals, as well as the geodynamic setting of this ore district, indicate that all three deposit types are genetically related each other and constitute a magmatic–hydrothermal system. This study outlines a model that relates the polymetallic copper–gold porphyry-, skarn-, and vein-type deposits within the Tongling ore district. This model provides a theoretical basis to guide exploration for deep-seated and concealed porphyry-type Cu(–Mo, –Au) deposits as well as shallow vein-type Au, Ag, and Pb–Zn deposits in this area and elsewhere.
基金co-founded by the National Natural Science Foundation of China(42002090,41930428)National Key Research and Development Program of China(No.2018YFC0604200)+3 种基金Open Research Fund Program of State Key Laboratory of Nuclear Resources and Environment,East China University of Technology(No.NRE1915)Open Research Fund Program of Jiangxi Engineering Laboratory on Radioactive Geoscience and Big Data Technology(JELRGBDT202006)International Geoscience Programme(IGCP675)Jiangxi province graduate student innovation special fund project(YC2019-S271,DHYC-202001)。
文摘Hydrothermal alteration with bleaching of host rocks is the most important prospecting indicator for gold deposits in the Jiangnan Orogen Belt.The alteration has been identified as pre-ore carbonate(siderite)-sericitization and the Fe of siderite in the alteration zone is derived from the host rocks rather than fluids.In addition,such alteration decreases in intensity and width with depth and gold mineralization also occur in the non-bleached rocks,casting doubt on the reliability of the prospecting indicator.Detailed petrographic work and SEM analysis on the Wangu deposit indicate that there are two types of siderites,i.e.,Sd1 and Sd2.Among them,Sd1 grains are relatively small and distributed along the planes of unaltered host rocks,while Sd2 grains,only occurring in the altered slates,are commonly larger.Both types of siderites were altered by auriferous fluids,producing porous cores and minerals such as pyrite,quartz,and ankerite.Compared with unaltered parts,the altered parts have lower Fe,but higher U,Pb,and REE.In addition,Sd1 and Sd2 are similar in Mn,Na,V,and Sr concentrations but different in Fe and Mg.The occurrence and geochemical compositions of both siderites indicate that Sd1 could be transformed into Sd2 by pre-mineralization alteration through dissolution-reprecipitation.Chlorite is another important Fe-bearing mineral in the host rocks,and EPMA analysis suggests that it is ripidolite with relatively high Fe contents.Consequently,chlorite can also provide Fe to form the pre-ore carbonate(siderite)-sericitization.Geochemical modeling demonstrates that both ripidolite and siderite can result in sulfidation and therefore gold precipitation.As a result,this study demonstrates that pre-ore alteration with characterized bleaching is not a prerequisite for gold mineralization despite of its prominent features.Due to the presence of Fe-bearing Sd1 and chlorite,gold mineralization could still occur through sulfidation in the unaltered rocks.
基金financially supported jointly by the National Natural Science Foundation of China (No. 40902026 No 41272097)+4 种基金the State Key Laboratory of Geological Processes and Mineral Resources (No. GPMR 201006)the Special Fund for Basic Scientific Research of Central Colleges China University of Geosciences (Wuhan) (No. CUG120702)the Shewushan Gold Mine Co. Ltd and No. 4 Geological PartyHubei Bureau of Geology and Mineral Resources for the field support
文摘The Shewushan gold deposit is located 16 km southwest of Jiayu County, Hubei Province, eastern China, which is the largest lateritic gold deposit in Asia, consisting of a series of mineralized faults containing gold grades of 1.0–19.5 g/t set within a larger, lower-grade(0.2–1.0 g/t) zone. According to the fluid inclusions study, the homogenization temperature ranges from 70–350℃, and concentrates between 140–220℃. The laser Rama results show that the CO2 and CH4 exist in mineralized fluid. In addition, the major and trace element and REE geochemical data show that the genesis of the siliceous rocks is hydrothermal genesis, formed by mineralized fluid bearing SiO2 transmitted along faults to the surface, and replace the carbonate rocks to begin deposition. Primary gold mineralization is attributed to hydrothermal activity that followed the main period of tectonic deformation of the Indosinian orogeny, which caused the regional detachment regime in southeast Hubei. The reversed fold and the fault system formed the fluid migration channel in the Shewushan area. EPMA results show that Au exists in arsenopyrite(850×10-6–1550×10-6 Au) and pyrite(470×10-6–1340×10-6 Au). Therefore, based on the above results and combined with the field observation, we suggest that the genesis of primary orebody in Shewushan deposit is carlin type, while not weathered residual type.
文摘Abstract The Shibangou gold deposit in western Henan is associated with irregular quartz veinlets occurring in altered shear zones dissecting a dioritic intrusion. The altered shear zones are characterized by silicification, pyritization, sericilization, chloritization and K-feldspar alteration. Zoning of altered rocks adjacent to the Au-bearing quartz veins is obviously exhibited. Fine-grained sulphides and quartz veinlets of different ages and small-scale fissures are widely distributed in the central part of the altered zones. Major mineralization types in this gold deposit are Au-bearing quartz veinlets and altered rocks in the shear zones. Samples were collected from drilling cores according to the alteration zoning and mineralization type and all samples were analyzed for major and trace elements. Mass balance, volume change (fv=97.3–71.9%) and major element variation sequences are studied in terms of major elements. The changes of mobile components (SiO2, K2O, Fe2O3) and CaO) and immobile component (Al2O3) in the wall-rock alteration are discussed. The gold mineralization is associated with the enrichment of As, Ag, Hg and Pb and depletion of Cu and Zn. The study of compositional variation of altered rocks proves to be a very efficient method for defining the extent of wall-rock alteration, fluid activity and mineralization and enrichment.
文摘The Jinsha River-Lancang River-Nujiang River area is one of the important prospect areas for noble metal and nonferous metal deposits of China. Of a great variety of gold deposits present in this area, the following types seem to be economically most valuable and promising: tectonic alteration type in ophiolitic melange; polymetallic quartz vein type related to intermediate-acid intrusions; finely disseminated type in fracture zones; mixed hydrothermal type in tectonic fractures of carbonate rocks; hydrothermal type related to subvolcanic rocks; volcanic-hot spring type; submarine volcano exhalation-sedimentary-hydrothermal reformation type. Metallogenic epochs are exclusively Mesozoic and Cenozoic, and ore deposits and orebodies are controlled by linear structures. Magmatic activity has affected gold mineralization in varying degrees, and gold deposits are basically of mesothermal-epithermal type with ubiquitous and intense alterations. Ore-forming materials and hydrothermal solutions show multi-source character.
文摘Irbiben is a small gold deposit of the Precambrian inlier Tagragra d’Akka located in the Moroccan western Anti-Atlas, approximately 160 km southeast from Tiznit. Petrographic study shows that host rocks of Irbiben deposit are green schist facies metamorphic rocks, like metamorphic sandstone and schist, meta-pelite and quartzite. Gold is located in quartz veins or host rock with frequent injections of quartz. The petrographic characterization of alteration through the description of the alteration profiles and the comparative study of protolith and altered rocks showed a development of dominant quartz and calcite in mineralization wall-rocks. In moving away from it, there is rather sericite and chlorite. These phenomena are materialized respectively by the development of SiO2 and CaO in the wall-rocks but rather that ferromagnesian elements (FeO, MgO) and K2O away from the mineralization. These trends were demonstrated by the geochemical study through Harker diagrams, description of alteration profiles, comparative study of protolith and altered rocks, and use of a new alteration index, MIA, elaborated during this work.
文摘Most gold deposits in intrusive rocks were formed as a result of reworking processes.The intrusive rocks containing gold deposits and consisting of ultramafic-mafic, intermediate-acid and alkaline rocks of the Archean, Proterozoic, Caledonian, Hercynian and Yenshanian periods occur in cratons, activated zones of cratons and fold belts. Among them, ultramafic-mafic rocks, diorite, alkaline rocks, and anorthosite are products of remelting in the mantle or mantle-crust or mantle with crustal contamination. However, auriferous intermediate-acid rocks are products of metasomatic-remelting in auriferous volcanic rocks or auriferous volcano-sedimentary rocks in the deep crust.
基金This paper is supported by the National Natural Science Foundation of China (Grant Nos. 40572063 and 40272051);the Fostering Plan Fund for Trans-Century Excellent Talents and the Project 111 (No. B07011).
文摘The Shangzhuang altered-rock type gold ore deposit is located in the middle segment of and controlled by the Wang'ershan fault zone in the northwestern part of the Jiaodong gold province, China. The deformation evolution, the structure of strain and stress fields and its ore-controlling effect in the Shangzhuang deposit are discussed in this paper. It is revealed that the deformation evolution has mainly undergone four phases: the early ductile deformation, the second NE-striking horizontal simple shear, the third NE-striking compression-shear and the final NW-striking compression. The mineralization happened during the third stage in which the maximum principal stress gradually transited from NE to NW. The 3-D numerical simulations of the stress field show that, on the condition that the maximum principal stress is NE-striking, the fracture development in the fault zone is favored, while when the maximum principal stress is NW-striking, the fault zone is relatively extensional and it is suitable for the influx and emplacement of ore-forming fluids. The compression-shear strain field during the mineralization is characterized by the λ-type structure, the positive flower structure, etc. Orebodies are mostly equidistantly located in the dilatational spaces, which are distributed in the integral compressional circumstances. And the dilatational spaces are developed where the fault attitude changes or shear joint systems develop. In the overall compression-shear stress field, the strain field bears self-similarity at multiple scales, including the orebody, ore deposit and orefield. The selfsimilarity of the structure comprises the subequidistant distribution of fractures at the same scale and the similar shape of the fractures at various scales. Yet, due to the special geological structure, the orebodies are mostly located in the hanging wall in the Shangzhuang deposit, which is different from most deposits in the Jiaodong gold province. Analyses of the ore-controlling stress and strain fields in the deposit provide an important basis for deposit seeking.
基金jointly supported by the National Key Research and Development Project of China (Grant No.2016YFC0600307)the National Key Basic Research Development Program (973 Program+1 种基金 Grant No.2015CB452606)the fundamental research funds of university teachers(No.53200959708 and No.2-9-2018-126)
文摘Orogenic disseminated and Carlin gold deposits share much similarity in alteration and mineralization.The disseminated orogenic Zhenyuan Au deposit along the Ailaoshan shear zone,southeastern Tibet,was selected to clarify their difference.The alteration and mineralization from the different lithologies,including meta-quartz sandstone,carbonaceous slate,meta-(ultra)mafic rock,quartz porphyry and lamprophyre were researched.According to the mineral assemblage and replacement relationship in all types of host rocks,two reactions show general control on gold deposition:(1) replacement of earlier magnetite by pyrite and carbonaceous material;(2) alteration of biotite and phlogopite phenocrysts in quartz porphyry and lamprophyre into dolomite/ankerite and sericite.Despite the lamprophyre is volumetrically minor and much less fractured than other host rocks,it contains a large portion of Au reserve,indicating that the chemically active lithology has played a more important role in gold precipitation compared to structure.LA-ICP-MS analysis shows that Au mainly occurs as invisible gold in fine-grained pyrite disseminated in the host rocks,with Au content reaching to 258.95 ppm.The diagenetic core of pyrite in meta-quartz sandstone enriched in Co,Ni,Mo,Ag and Hg is wrapped by hydrothermal pyrite enriched in Cu,As,Sb,Au,Tl,Pb and Bi.Different host rock lithology has much impact on the alteration and mineralization features.Carbonate and sericite in altered lamprophyre show they have higher Mg than those developed in other of host rocks denoting that the carbonate and sericite incorporated Mg from phlogopite phenocrysts in the primary lamprophyre during alteration.The ore fluid activated the diagenetic pyrite in meta-quartz sandstone leading the hydrothermal pyrite enriched in Cu,Mo,Ag,Sb,Te,Hg,Tl,Pb and Bi,but the hydrothermal pyrite in meta-(ultra)mafic rock is enriched in Co and Ni as the meta-(ultra)mafic rock host rock contain high content of Co and Ni.However,Au and As shear similar range in both types of host rocks indicating that these two elements most likely come from the deep source fluid rather than the host rocks.It was shown in the disseminated orogenic gold deposit that similar hydrothermal alteration with mineral assemblage of carbonate (mainly dolomite and ankerite),sericite,pyrite and arsenopyrite develops in all types of host rocks.This is different from the Nevada Carlin type,in which alteration is mainly dissolution and silicification of carbonate host rock.On the other hand,Au mainly occur as invisible gold in both disseminated orogenic and Carlin gold deposits.
基金This work is financially supported by the Special Fund for Foreign Mineral Resources Risk Exploration(201210B01600234).
文摘The Nyasirori gold deposit,located in the middle-western end of the Musoma-Mara Archean greenstone belt in Tanzania,is a tectonic altered rock type gold deposit controlled by shear tectonic zone.This work conducted high-precision ground magnetic measurements to delineate fault structures and favorable prospecting targets,utilized induced polarization(IP)intermediate gradient to roughly determine the distribution and extension of the tectonic altered zone and gold ore(mineralized)bodies,and further carried out IP sounding and magnetotelluric sounding to locate the tectonic altered zone and gold ore(mineralized)bodies.The anomalous gradient belt of the combination of positive and negative micromagnetic measurements reflects the detail of shallow surface tectonic alteration zone and gold mineralization body.Micromagnetic profile anomalies indicate the spatial location and occurrence of concealed tectonic alteration zone and gold(mineralized)ore bodies.Soil geochemical measurements indicate that the ore-forming element Au correlates well with As and Sb,and As and Sb anomalies have a good indication to gold orebodies.Based on the multi-source geological-geophysical-geochemical information of the Nyasirori gold deposit,this work established an integrated prospecting model and proposed a set of geophysical and geochemical methods for optimizing prospecting targets.
基金This paper represents partial results of a major project(No,49290100)supported by the National Natural Science Foundation of China.
文摘The Baguamiao gold deposit in Fengxian County, Shaanxi Province, is a recentlyexplored super-large gold ore deposit. A comprehensive and deep-going study has revealedthat it is a polygenetic deposit: early-stage mineralization due to shearing, middle-stagemineralization due to hydrothermal alteration, and late-stage mineralization due toweathering, leaching and concentration at shallow depths. Shearing played a dominant role inthe formation of gold orebodies.
文摘The Baoban gold field, located in the area of Hainan Island, South China, bears three gold de-posits: Tuwaishan, Baoban, and Erjia, which belong to the wall-rock alteration type. In terms of the petrography data, four alteration zones can be recognized from the ore-vein outwards: (1) the silicification zone; (2) the sericitization zone, (3) the chloritization zone; and (4) the calcitization zone. The geochemical kinetic simulation was carried out on sericitization and chloritization . Results of the study showed that the formation of the alteration zones is connected with the properties of hydrothermal fluids: the initial concentration of Al (O H)3, the diffusion coefficient and the velocity of fluid flow. The alteration zones in this field are the result of multiple interaction between hydrothermal fluids and wall rocks.
基金The study is supported by Agence of International Science and Technology, Japan
文摘The Gacun Kuroko-type deposit, Southwestern China, is hosted in rhyolitic rocks associated with the underlying mafic rocks occurred in the - 1000 m deep fault - bounded basin within the intra -arc rifting zone which formed on the Triassic Yidun island - arc. Two vertically separated alteration systems are recognized: one is conformable or semiconformable alteration zone developed in - 150 m thick mafic unit 1-1.5 km below the massive sulfide ore body; the other is discordant alteration pipe directly surrounded around stockwork ore within rhyolitic unit. The lower conformable alteration zone extending for several kilometers along strike is characterized by silicification and epidotization which result in the development of quartz vein and quartz-epidote vein systems in mafic lava flows and replacement of primary minerals and groundmass in spilitized mafic volcanics and dikes by quartz, epidote - group minerals and sodic plagioclase. Sulfides often occur in the vein system and altered mafic volcanics. Quartz solubility relation indicates that silicification is a consequence of interaction of Si- saturated fluids with mafic rocks in a higher temperature system (T>340℃), intensifying by intrusion of mafic dike or high-level acidic magma chamber. The alteration pipe of diameter about 2 km shows a similar mineralogical zoning to Kuroko deposits of Japan. The sequence is quartz + hyalophane; sericite + chlorite + quartz and zeolite-like zones from core to margins of the pipe. The chlorite core only occurs in the root part of the alteration pipe and downwards transfers into epidote - chlorite and epidote - quartz vein swarm extending 500 m downwards. The felsic rocks away from the orebody and alteration pipe took place district-scale alteration, which has typical low-temperature mineral association: illite + albite + quartz + calcite. Whole -rock and quartz δ18O values indicate that district - scale alteration is a result of interaction of seawater with rocks at lower temperature (T<200℃)under water-dominated condition. However, the altered rocks from the pipe show remarkably δ18O enrichment, and bulk -rock δ18O values decreased gradually toward stockwork orebody from 15.1‰-l5. 75‰ in zeolite-like zone and 12. 05‰-14. 2‰ in sericite - quartz zone to 11.3 ‰ - 14. 4‰ in quartz - hyalophane zone. The filled temperatures of fluid inclusions in quartz and sphalerite lie in the ranges of 280 -320 ℃ for quartz - hyalophane zone and 250 ℃ to 297 ℃ for sericite-quartz zone. The estimated δ18O values of hydrothermal fluids are 7. 98‰ and3.2‰, respectively, based on quartz δ18O data in the deposit. The lower conformable alteration is considered to be approximately coeval with the alteration pipe, based on the SiO2 concentration in the fluids, which restrict the main fluid - rock reaction zone to be located in mafic horizon by quartz barometer, and metal element flux calculation and sulfide - epidote vein system developed both in alteration systems. High - salinity fluid inclusions in gangue quartz (>8% eq. NaCl) from stockwork ore and in quartz phenocryst (>40% eq. NaCl) in footwall rhyolite strongly suggest the existence of hot-saline brine to react with mafic complex and leach metal components, which probably originates mainly from magmatic fluid derived from high-level acidic magma chamber. The brine layer located in mafic unit possibly heats and drives the overlying single -pass convective seawater reacting with felsic rocks. The 'density window' may be expected to occur on the interface between seawater and brine layer, when the brine becomes to be gravitationally instability by the turbulent entrainment of seawater during magmatic and/or tectonic activities. The sulfide mineralization and alteration pipe is inter preted as an effect of the 'density window' through which the mixed fluids of brine with seawater adiabatically discharges upwards.
文摘The major gold deposits in East China are characterized by their occurrence in pre-Cambrian host metamorphic rocks, restriction in some specific stratigraphic-structural terranes,tendentious localization in ductile or ductile-brittle shear zones, association with the syntexis-type granitoids, and significant remobilization, superimposition and enrichment by the later-stage Mesozoic tectono-magmatic activities.
文摘Calculations based on the available thermodynamic data of AuCl2^- and Au(HS)2^- indicate that AuCl2^- is responsible for the transport and enrichment of gold during the stage of pre-concentration in the source bed while Au(HS)2^- is the main gold species involved in the formation of gold deposits in response to hydrothermal reworking .Acid chloride solutions with αcl^->10° and sulfur-rich solutions with a∑s in excess of 10^-2 are held as important criteria for gold enrichment in the source bed and for the formation of gold deposits by subsequent hydrothermal event, respectively.