The occurrence and evolution of an oceanic tropical squall line observed on 22 February 1993 during TOGA-COARE over the equatorial Pacific Ocean were simulated by use of a three-dimensional, nonhydrostatic storm-scale...The occurrence and evolution of an oceanic tropical squall line observed on 22 February 1993 during TOGA-COARE over the equatorial Pacific Ocean were simulated by use of a three-dimensional, nonhydrostatic storm-scale numerical model ARPS. The capacity of ARPS to simulate such tropical squall line was verified. The structure and dynamic mechanism of the squall line were discussed in details as well The impacts of the different microphysical process that including the ice phase and warm rain schemes on structure and evolution of the squall line were investigated by the sensitive experiment. The simulations of the three-dimensional structure and evolution of the squall line are closely related with the observations when the proper microphysical processes were employed. The more latent heating released in the ice phase processes associated with the freezing process leads to strengthening deep convection due to the vertical gradient of buoyancy, which results in a long life of the convective system. In contrast, the warm rain process is characterized by short life period, more pronounced rearward tilt structure and extension of stratiform cloud.展开更多
An on-line solid phase extraction-high performance liquid chromatography-tandem mass spectrometry method for the analysis of perfluoroalkyl substances（PFASs） in water samples was developed.The optimal analytical con...An on-line solid phase extraction-high performance liquid chromatography-tandem mass spectrometry method for the analysis of perfluoroalkyl substances（PFASs） in water samples was developed.The optimal analytical conditions were obtained through the optimization of the extraction efficiency of online solid phase extraction column,sample loading rate and loading volume,and the concentration of ammonium acetate in mobile phase.Under the optimal condition,the analytical method displayed good linearity（r^2〉0.99） for 12 PFASs（C5-C14 perfluoroalkyl carboxylic acids and C6/C8 perfluoroalkyl sulfonic acids） over a concentration range of 0.5-100 ng/L.The limits of quantitation for samples were between 0.025 ng/L and 0.5 ng/L and the relative standard deviations（RSD） of five consecutive analyses were less than 10%for 1 ng/L standard solution.Satisfactory results were obtained using this analytical method for the analysis of perfluoroalkyl substances in Antarctic ice core samples.The recoveries of all perfluoroalkyl substances were in a range of 73%-117%when the samples were spiked with standards at the concentrations of 2.5 ng/L and 25 ng/L.展开更多
基金the National Natural Science Foundation of China under the grant !Nos. 49605064 and 49735180by State Key Basic Research Prog
文摘The occurrence and evolution of an oceanic tropical squall line observed on 22 February 1993 during TOGA-COARE over the equatorial Pacific Ocean were simulated by use of a three-dimensional, nonhydrostatic storm-scale numerical model ARPS. The capacity of ARPS to simulate such tropical squall line was verified. The structure and dynamic mechanism of the squall line were discussed in details as well The impacts of the different microphysical process that including the ice phase and warm rain schemes on structure and evolution of the squall line were investigated by the sensitive experiment. The simulations of the three-dimensional structure and evolution of the squall line are closely related with the observations when the proper microphysical processes were employed. The more latent heating released in the ice phase processes associated with the freezing process leads to strengthening deep convection due to the vertical gradient of buoyancy, which results in a long life of the convective system. In contrast, the warm rain process is characterized by short life period, more pronounced rearward tilt structure and extension of stratiform cloud.
基金supported by the National Natural Science Foundation of China(Nos.21377145,21321004)the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB01020300)
文摘An on-line solid phase extraction-high performance liquid chromatography-tandem mass spectrometry method for the analysis of perfluoroalkyl substances（PFASs） in water samples was developed.The optimal analytical conditions were obtained through the optimization of the extraction efficiency of online solid phase extraction column,sample loading rate and loading volume,and the concentration of ammonium acetate in mobile phase.Under the optimal condition,the analytical method displayed good linearity（r^2〉0.99） for 12 PFASs（C5-C14 perfluoroalkyl carboxylic acids and C6/C8 perfluoroalkyl sulfonic acids） over a concentration range of 0.5-100 ng/L.The limits of quantitation for samples were between 0.025 ng/L and 0.5 ng/L and the relative standard deviations（RSD） of five consecutive analyses were less than 10%for 1 ng/L standard solution.Satisfactory results were obtained using this analytical method for the analysis of perfluoroalkyl substances in Antarctic ice core samples.The recoveries of all perfluoroalkyl substances were in a range of 73%-117%when the samples were spiked with standards at the concentrations of 2.5 ng/L and 25 ng/L.
