A simple and effective way to prepare poly（acrylate）s, such as poly（methacrylate）, poly（butyl acrylate） and poly（butyl methacrylate）, has been achieved by using the single component aluminum-based compounds, s...A simple and effective way to prepare poly（acrylate）s, such as poly（methacrylate）, poly（butyl acrylate） and poly（butyl methacrylate）, has been achieved by using the single component aluminum-based compounds, such as modified methylaluminoxane （MMAO）, triisobutylaluminium （TIBA） and triethylaluminium （TEA） as initiators. Effective initiations and high molecular weight polymers with unimodal molecular weight distributions could be easily obtained by varying the reaction parameters of systems under mild conditions. Although these aluminum compounds were inefficient initiators for methyl methacrylate （MMA） polymerization, they exhibited remarkable catalytic activity for butyl methacrylate （BMA） polymerization, affording high molecular weight poly（BMA）s.展开更多
In this paper, the helix-sense-selective polymerization of N,N-diphenyl acrylamide (DPAA) and N,N-diphenyl methacrylamide(DPMAA) were studied with living helix prepolymer as anionic initiator, and the chiral optical p...In this paper, the helix-sense-selective polymerization of N,N-diphenyl acrylamide (DPAA) and N,N-diphenyl methacrylamide(DPMAA) were studied with living helix prepolymer as anionic initiator, and the chiral optical properties of the obtained polymers were investigated too. It was shown that optically active polymers of DPAA and DPMAA could be obtained under the experimental condition, and exhibited the same screw sense as that of the prepolymer.展开更多
This paper discusses the application of the boundary contour method fo r resolving plate bending problems. The exploitation of the integrand divergence free property of the plate bending boundary integral equation bas...This paper discusses the application of the boundary contour method fo r resolving plate bending problems. The exploitation of the integrand divergence free property of the plate bending boundary integral equation based on the Kirc hhoff hypothesis and a very useful application of Stokes' Theorem are presented to convert surface integrals on boundary elements to the computation of bending potential functions on the discretized boundary points,even for curved surface elements of arbitrary shape. Singularity and treatment of the discontinued corne r point are not needed at all. The evaluation of the physics variant at internal points is also shown in this article. Numerical results are presented for some plate bending problems and compared against analytical and previous solutions.展开更多
A dissolution method with robust high performance liquid chromatographic （HPLC） analysis for im- mediate release tablet formulation was developed and validated to meet the requirement as per Inter- national Conferen...A dissolution method with robust high performance liquid chromatographic （HPLC） analysis for im- mediate release tablet formulation was developed and validated to meet the requirement as per Inter- national Conference on Harmonization （ICH） and United States Food and Drug Administration （USFDA） guidelines. The method involved the use of Agilent ZORBAX Eclipse XDB C18 column, and temperature was maintained at 30 ℃. After optimization, the mobile phase was selected as phosphate buffer （KH2PO4, 30 mM） ： ACN （60：40, v/v） with pH 3.0, and retention time Rt was found as 3.24, 4.16, and 2.55 min for paracetamol （PCM）, chlorpheniramine maleate （CPM） and phenylephrine hydrochloride （PH） respec- tively at 265 nm and at a flow rate of 1 mL/min. The relative standard deviation （%RSD） for 6 replicate measurements was found to be less than 2%. Furthermore net analyte signal standard addition method （NASSAM） with spectrophotometer was performed for standard and liquid oral suspension. On the basis of selectivity, sensitivity and accuracy analysis, it was confirmed that this novel method could be useful for simultaneous estimation of the given drug combinations. Two-way analysis of variance （ANOVA） was applied for evaluating the statistical difference between the assay results obtained via both NASSAM and RP-HPLC methods and ultimately no significant difference was found between both the methods. All the methods and results were acceptable and confirmed that the method was suitable for intended use.展开更多
Objective Improving the traditional Tennsion method to explore more reasonable re pair method for unilateral cleft lip.Methods37cases were operated to reconstruct the ala nasi and upper lip philtrum r idge form with r...Objective Improving the traditional Tennsion method to explore more reasonable re pair method for unilateral cleft lip.Methods37cases were operated to reconstruct the ala nasi and upper lip philtrum r idge form with rotatory alae nasi triangle flap plus improved Tennsion method,and compared the operational results with that of traditional Tennsion method.Results The improved Tennison method acquir ed a more beautiful nose and upper lip,it rehabilitated the ala nasi and restored t he physiological function of the orb iculars muscle.Conclusion Improved Tennsion method wins an essentially satisfactory operational result of unilateral cleft lip.展开更多
With the increasing of globalization on social life and economic activities,English has already become one of the basic and essential accomplishments for citizens all over the world.English education,in five-year high...With the increasing of globalization on social life and economic activities,English has already become one of the basic and essential accomplishments for citizens all over the world.English education,in five-year higher vocational education,not only need adapt to the requirements of social and economic development,giving service in order to cultivate high-quality and high-skilled talents,but also should consider students' mental and emotional attitude as well as other factors,thereby meeting their stainable needs in employment and life after graduated.Therefore,the English education of five-year higher vocational education possesses multiply social and cultural significance.Though the analysis and understanding of the course objectives,ideas,contents and implementation suggestions brought up by The English Curriculum Standards of the Five-year Higher Vocational Education in Jiangsu Province,this paper explores the educational methods of higher vocational English reading lessons.展开更多
基金supported by the Special Funds for Major State Basic Research Projects(No.2005CB623800) from the Ministry of Science and Technology of China
文摘A simple and effective way to prepare poly（acrylate）s, such as poly（methacrylate）, poly（butyl acrylate） and poly（butyl methacrylate）, has been achieved by using the single component aluminum-based compounds, such as modified methylaluminoxane （MMAO）, triisobutylaluminium （TIBA） and triethylaluminium （TEA） as initiators. Effective initiations and high molecular weight polymers with unimodal molecular weight distributions could be easily obtained by varying the reaction parameters of systems under mild conditions. Although these aluminum compounds were inefficient initiators for methyl methacrylate （MMA） polymerization, they exhibited remarkable catalytic activity for butyl methacrylate （BMA） polymerization, affording high molecular weight poly（BMA）s.
基金The authors are grateful to the National Natural Science Foundation of China for financial support.
文摘In this paper, the helix-sense-selective polymerization of N,N-diphenyl acrylamide (DPAA) and N,N-diphenyl methacrylamide(DPMAA) were studied with living helix prepolymer as anionic initiator, and the chiral optical properties of the obtained polymers were investigated too. It was shown that optically active polymers of DPAA and DPMAA could be obtained under the experimental condition, and exhibited the same screw sense as that of the prepolymer.
文摘This paper discusses the application of the boundary contour method fo r resolving plate bending problems. The exploitation of the integrand divergence free property of the plate bending boundary integral equation based on the Kirc hhoff hypothesis and a very useful application of Stokes' Theorem are presented to convert surface integrals on boundary elements to the computation of bending potential functions on the discretized boundary points,even for curved surface elements of arbitrary shape. Singularity and treatment of the discontinued corne r point are not needed at all. The evaluation of the physics variant at internal points is also shown in this article. Numerical results are presented for some plate bending problems and compared against analytical and previous solutions.
文摘A dissolution method with robust high performance liquid chromatographic （HPLC） analysis for im- mediate release tablet formulation was developed and validated to meet the requirement as per Inter- national Conference on Harmonization （ICH） and United States Food and Drug Administration （USFDA） guidelines. The method involved the use of Agilent ZORBAX Eclipse XDB C18 column, and temperature was maintained at 30 ℃. After optimization, the mobile phase was selected as phosphate buffer （KH2PO4, 30 mM） ： ACN （60：40, v/v） with pH 3.0, and retention time Rt was found as 3.24, 4.16, and 2.55 min for paracetamol （PCM）, chlorpheniramine maleate （CPM） and phenylephrine hydrochloride （PH） respec- tively at 265 nm and at a flow rate of 1 mL/min. The relative standard deviation （%RSD） for 6 replicate measurements was found to be less than 2%. Furthermore net analyte signal standard addition method （NASSAM） with spectrophotometer was performed for standard and liquid oral suspension. On the basis of selectivity, sensitivity and accuracy analysis, it was confirmed that this novel method could be useful for simultaneous estimation of the given drug combinations. Two-way analysis of variance （ANOVA） was applied for evaluating the statistical difference between the assay results obtained via both NASSAM and RP-HPLC methods and ultimately no significant difference was found between both the methods. All the methods and results were acceptable and confirmed that the method was suitable for intended use.
文摘Objective Improving the traditional Tennsion method to explore more reasonable re pair method for unilateral cleft lip.Methods37cases were operated to reconstruct the ala nasi and upper lip philtrum r idge form with rotatory alae nasi triangle flap plus improved Tennsion method,and compared the operational results with that of traditional Tennsion method.Results The improved Tennison method acquir ed a more beautiful nose and upper lip,it rehabilitated the ala nasi and restored t he physiological function of the orb iculars muscle.Conclusion Improved Tennsion method wins an essentially satisfactory operational result of unilateral cleft lip.
文摘With the increasing of globalization on social life and economic activities,English has already become one of the basic and essential accomplishments for citizens all over the world.English education,in five-year higher vocational education,not only need adapt to the requirements of social and economic development,giving service in order to cultivate high-quality and high-skilled talents,but also should consider students' mental and emotional attitude as well as other factors,thereby meeting their stainable needs in employment and life after graduated.Therefore,the English education of five-year higher vocational education possesses multiply social and cultural significance.Though the analysis and understanding of the course objectives,ideas,contents and implementation suggestions brought up by The English Curriculum Standards of the Five-year Higher Vocational Education in Jiangsu Province,this paper explores the educational methods of higher vocational English reading lessons.
