An effective surface enhanced Raman scattering（SERS） substrate is designed and fabricated by synthesis of Si O2 nanorods array via glancing angle deposition, followed by coating Au nanoparticles onto Si O2 surface i...An effective surface enhanced Raman scattering（SERS） substrate is designed and fabricated by synthesis of Si O2 nanorods array via glancing angle deposition, followed by coating Au nanoparticles onto Si O2 surface in order to create numerous ＂hot spots＂. The detecting sensitivity of such substrate could be optimized by simply adjusting the deposition time of Au. Thus, it can be used for detection of Rhodamine 6G at concentration as low as 10^-9M. Furthermore, our SERS substrate is applied to detect 5 μg/g polychlorinated biphenyls in soil sample, which proves its potential for trace environmental pollutants detection.展开更多
The hazard of Hg ion pollution triggers the motivation to explore a fast, sensitive, and reliable detection method. Here, we design and fabricate novel 36-nm-thick Ag-Au composite layers alternately deposited on three...The hazard of Hg ion pollution triggers the motivation to explore a fast, sensitive, and reliable detection method. Here, we design and fabricate novel 36-nm-thick Ag-Au composite layers alternately deposited on three-dimensional （3D） periodic SiO2 nanogrids as surface-enhanced Raman scattering （SERS） probes. The SERS effects of the probes depend mainly on the positions and intensities of their localized surface plasmon resonance （LSPR） peaks, which is confirmed by the absorption spectra from finite-difference time-domain （FDTD） calculations. By optimizing the structure and material to maximize the intrinsic electric field enhancement based on the design method of 3D periodic SERS probes proposed, high performance of the Ag-Au/SiO2 nanogrid probes is achieved with the stability further enhanced by annealing. The optimized probes show the outstanding stability with only 4.0% SERS intensity change during 10-day storage, the excellent detection uniformity of 5.78% （RSD）, the detection limit of 5.0 × 10-12 M （1 ppt）, and superior selectivity for Hg ions. The present study renders it possible to realize the rapid and reliable detection of trace heavy metal ions by developing high- performance 3D periodic structure SERS probes by designing novel 3D structure and optimizing plasmonic material.展开更多
文中采用一种基于微悬臂梁传感器的检测系统,实现了对Au-半导体复合纳米材料的微热量检测。根据光杠杆检测的方法研究了Au-半导体复合纳米材料光热转换散发热量对微悬臂梁挠度的影响。为验证系统对此类材料微热量检测的适用性,实验选用...文中采用一种基于微悬臂梁传感器的检测系统,实现了对Au-半导体复合纳米材料的微热量检测。根据光杠杆检测的方法研究了Au-半导体复合纳米材料光热转换散发热量对微悬臂梁挠度的影响。为验证系统对此类材料微热量检测的适用性,实验选用了已知在530 nm处光热吸收峰的Au-ZnO粉末样品材料,分别取多组不同质量的样品材料进行检测,通过最小二乘法拟合出温度变化与微悬臂梁偏移量之间的关系。结果显示:温度变化与微悬臂梁偏移量呈线性关系,且0.1 mm 2面积的样品薄膜拟合曲线的线性相关系数为0.9961。比较温度检测值与实验系统的拟合值,结果基本一致,验证了系统的可靠性。展开更多
基金supported by the National Basic Research Program of China(Grant No.2013CB934301)the National Natural Science Foundation of China(Grant No.50931002)+1 种基金the Research Project of Chinese Ministry of Education(Grant No.113007A)the Initiative Scientific Research Program of Tsinghua University,China
文摘An effective surface enhanced Raman scattering（SERS） substrate is designed and fabricated by synthesis of Si O2 nanorods array via glancing angle deposition, followed by coating Au nanoparticles onto Si O2 surface in order to create numerous ＂hot spots＂. The detecting sensitivity of such substrate could be optimized by simply adjusting the deposition time of Au. Thus, it can be used for detection of Rhodamine 6G at concentration as low as 10^-9M. Furthermore, our SERS substrate is applied to detect 5 μg/g polychlorinated biphenyls in soil sample, which proves its potential for trace environmental pollutants detection.
基金Project supported by the National Key Research and Development Program of China(Grant No.2017YFA0207104)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDA09040101)+2 种基金the National Natural Science Foundation of China(Grant No.Y6061111JJ)the Youth Innovation Promotion Association of Chinese Academy of Sciences(Grant No.2015030)the Key Technology Talent Program of Chinese Academy of Sciences(Grant Nos.Y8482911ZX and Y7602921ZX)
文摘The hazard of Hg ion pollution triggers the motivation to explore a fast, sensitive, and reliable detection method. Here, we design and fabricate novel 36-nm-thick Ag-Au composite layers alternately deposited on three-dimensional （3D） periodic SiO2 nanogrids as surface-enhanced Raman scattering （SERS） probes. The SERS effects of the probes depend mainly on the positions and intensities of their localized surface plasmon resonance （LSPR） peaks, which is confirmed by the absorption spectra from finite-difference time-domain （FDTD） calculations. By optimizing the structure and material to maximize the intrinsic electric field enhancement based on the design method of 3D periodic SERS probes proposed, high performance of the Ag-Au/SiO2 nanogrid probes is achieved with the stability further enhanced by annealing. The optimized probes show the outstanding stability with only 4.0% SERS intensity change during 10-day storage, the excellent detection uniformity of 5.78% （RSD）, the detection limit of 5.0 × 10-12 M （1 ppt）, and superior selectivity for Hg ions. The present study renders it possible to realize the rapid and reliable detection of trace heavy metal ions by developing high- performance 3D periodic structure SERS probes by designing novel 3D structure and optimizing plasmonic material.
文摘文中采用一种基于微悬臂梁传感器的检测系统,实现了对Au-半导体复合纳米材料的微热量检测。根据光杠杆检测的方法研究了Au-半导体复合纳米材料光热转换散发热量对微悬臂梁挠度的影响。为验证系统对此类材料微热量检测的适用性,实验选用了已知在530 nm处光热吸收峰的Au-ZnO粉末样品材料,分别取多组不同质量的样品材料进行检测,通过最小二乘法拟合出温度变化与微悬臂梁偏移量之间的关系。结果显示:温度变化与微悬臂梁偏移量呈线性关系,且0.1 mm 2面积的样品薄膜拟合曲线的线性相关系数为0.9961。比较温度检测值与实验系统的拟合值,结果基本一致,验证了系统的可靠性。
