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Tetrahydrofolate coenzyme models I·Synthesis of l-methyl-2-phenyl-3-aryl imidazoliniumiodide and benzylildyne(phenyl-substitutef one carbon unit)transfer reactions
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作者 XIA, Chi-Zhong ZHOU, Pei-Wen DING, Jing-Fan The Institute of Molecular Science, Department of Chemistry,Shanxi University, Taiyuan, 030006 《Chinese Journal of Chemistry》 SCIE CAS CSCD 1990年第4期333-339,共10页
Four 1, 2, 3-trisubstituted imidazolinium iodides which were used as 5,10-^+CPh-THF model (7-10) at formic acid oxidation level were synthesized. The benzylidyne group (phenyl- substituted one carbon unit)transfer rea... Four 1, 2, 3-trisubstituted imidazolinium iodides which were used as 5,10-^+CPh-THF model (7-10) at formic acid oxidation level were synthesized. The benzylidyne group (phenyl- substituted one carbon unit)transfer reactions from these compounds to Grignard reagent were in- vestigated, and the reactions of these compounds with KBH_4 and NaOH were also studied. 展开更多
关键词 Synthesis of l-methyl-2-phenyl-3-aryl imidazoliniumiodide and benzylildyne Tetrahydrofolate coenzyme models I phenyl-substitutef one carbon unit)transfer reactions
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