Allophane as a Nanotechnological Additive in Masonry Materials to Increase Resistance and Waterproofing

The constant need for high-strength materials in the construction industry promotes the research of additives that improve the properties of masonry materials. The use of allophane as an additive in concrete and mortar mixtures was implemented to improve their strength and waterproofing, respectively, using compression and water absorption tests according to their corresponding standards (ASTM C1231, ASTM D2938, and ASTM C1585). The samples were evaluated at different concentrations and curing ages. In addition, different sand/cement ratios were considered for the mortar. The results revealed that there was a 9.4% increase in compressive strength in concrete and a 23.7% reduction in water absorption in mortar for the 5:1 ratio. These changes would be the result of the interaction of the nanoporous additive in the atomic crystal structure of the material demonstrating the nanotechnological nature of allophane.

Preparation and Performance Study of Cementitious Capillary Crystalline Waterproof Materials

Cementitious capillary crystalline waterproof materials(CCCW for short)offer durability and excellent waterproofing properties,making them a popular option for building waterproofing.Some scholars have studied the proportioning of such materials.However,these studies lack the relationship between the impermeability pressure of mortar and the components,and the mechanism of action is somewhat debatable.Therefore,we adopted a two-step method in our experiments.Firstly,we screened out the components that significantly impact impermeability from a variety of active components by orthogonal test.We then optimized the design of the active group ratio using the simplex lattice method.Lastly,we conducted a performance test of the optimal ratio and explored the waterproofing mechanism of homemade CCCW.

Redefining the properties of an osmotic agent in an intestinal-specific preservation solution

AIM: To investigate the effects of dextrans of various molecular weights (Mw) during a 12 h cold storage time-course on energetics, histology and mucosal infiltration of fluorescein isothiocyanate (FITC)-dextran. METHODS: Rodent intestines were isolated and received a standard University of Wisconsin vascular flush followed by intraluminal administration of a nutrientrich preservation solution containing dextrans of varying Mw: Group D1, 73 kdal; Group D2, 276 kdal; Group D3, 534 kdal; Group D4, 1185 kdal; Group D5, 2400 kdal. RESULTS: Using FITC-labeled dextrans, fluorescent micrographs demonstrated varying degrees of mucosal infiltration; lower Mw (groups D1-D3: 73-534 kdal) dextrans penetrated the mucosa as early as 2 h, whereas the largest dextran (D5: 2400 kdal) remained captive within the lumen and exhibited no permeability even after 12 h. After 12 h, median injury grades ranged from 6.5 to 7.5 in groups D1-D4 (73-1185 kdal) representing injury of the regenerative cryptal regions and submucosa; this was in contrast to group D5 (2400 kdal) which exhibited villus denudation (with intact crypts) corresponding to a median injury grade of 4 (P < 0.05). Analysis of tissue energetics reflected a strong positive correlation between Mw and adenosine triphosphate (r 2 = 0.809), total adenylates (r 2 = 0.865) and energy charge (r 2 = 0.667).CONCLUSION: Our data indicate that dextrans of Mw > 2400 kdal act as true impermeant agents during 12 h ischemic storage when incorporated into an intraluminal preservation solution.

Self-healing Action of Permeable Crystalline Coating on Pores and Cracks in Cement-based Materials

The self-healing action of a permeable crystalline coating on the po rous mortar was investigated by two times impermeability test. Moreover, the sel f-healing mechanism of cement-based materials with the permeable crystalline c oating was studied by SEM. The results indicate that the permeable crystalline c oating not only seals the pores and cracks in mortar during its curing process, but also heals the permeable pathway caused by first impermeability test or crac ks produced by freeze-thaw cycles. Therefore, cement-based materials can be im proved by the permeable crystalline coating for the self-healing function. SEM images prove that the self-healing function is realized by generating a great q uantity of non-soluble dendritic crystalline within the pores and cracks, which prevents the penetration of water and other liquids.

Preparation of High Impermeable and Crack-resistance Chemical Admixture and Its Mechanism

A kind of high impermeable and crack-resistance chemical admixture ( HICRCA) was prepared , which is a compound chemical admixture composed of an expansion ingredient, density ingredient, and organic hydrophobic poreblocking ingredient. The results of the experiments indicate that the addition of HICRCA improves mortar and concrete in the following performances: (1) perfect workability: slump is more than 22cm, theslump afar 3h is about 16cm; (2) high impermeability:for the mortar, the pervious height under a water pressure of 1.5MPa is 1.5cm,for the concrete, the pervious height under a water pressure of 5.0MPa is 2. 2cm;(3) high crack-resistance: there is a micro-expansion at the age of 90d; (4) high compressivestrength: compared with the controlled concrete, the compressive strengths at the age of 3d and 2Sd are improved by 66.4% and 62.0% , respectively. At the same time, the effects of different curing condition on mortar and concrete expansive andshrinkage performance were studied. In addition, the impermeable and crack-resistance mechanism, was investigatedin the present paper.

Analysis of flow around impermeable groynes on one side of symmetrical compound channel:An experimental study

This paper presents the results of an experimental study on the influences of floodplain impermeable groynes on flow structure, velocity, and water depth around the groyne（s）. A wooden symmetrical compound channel was used. Groyne models with three different groyne relative lengths, 0.5, 0.75, and 1.0, were used on one floodplain with single and series arrangements. Analysis of the experimental results using the measured flow velocity and water depth values showed that flow structure, velocity, and water depth mainly depend on groyne relative length and the relative distance between series groynes. The flow velocity at the main channel centerline increased by about 40%, 60%, and 85%, and in other parts on the horizontal plane at the floodplain mid-water, depth by about 75%, 125%, and 175% of its original value in eases of one-side floodplain groyne（s） with relative lengths of 0.5, 0.75, and 1.0, respectively. The effective distance between two groynes in series arrangement ranges from 3 to 4 times the groyne length. Using an impermeable groyne with a large relative length in river floodplains increases the generation of eddy and roller zones downstream of the groyne, leading to more scouring and deposition. To avoid that, the groyne relative length must be kept below half the floodplain width,

Risk assessment of fault water inrush during deep mining

With the gradual depletion of shallow coal resources,the Yanzhou mine in China will enter the lower coal seam mining phase.However,as mining depth increases,lower coal seam mining in Yanzhou is threatened by water inrush in the Benxi Formation limestone and Ordovician limestone.The existing prediction models for the water burst at the bottom of the coal seam are less accurate than expected owing to various controlling factors and their intrinsic links.By analyzing the hydrogeological exploration data of the Baodian lower seam and combining the results of the water inrush coefficient method and the Yanzhou mine pressure seepage test,an evaluation model of the seepage barrier capacity of the fault was established.The evaluation results show the water of the underlying limestone aquifer in the Baodian mine area mainly threatens the lower coal mining through the fault fracture zone.The security of mining above confined aquifer in the Baodian mine area gradually decreases from southwest to northeast.By comparing the water inrush coefficient method and the evaluation model of fault impermeability,the results show the evaluation model based on seepage barrier conditions is closer to the actual situation when analyzing the water breakout situation at the working face.

GLOBAL EXISTENCE OF SOLUTIONS FOR ONE-DIMENSIONAL COMPRESSIBLE NAVIER-STOKES EQUATIONS IN THE HALF SPACE

We prove the existence of global solutions to the initial-boundary-value problem on the half space R＋ for a one-dimensional viscous ideal polytropic gas. Some suitable assumptions are made to guarantee the existence of smooth solutions. Employing the L2- energy estimate, we prove that the impermeable problem has a unique global solutionis.

The Impermeability Mechanism of Self-compacting Water Proof Concrete

The impermeability mechanism of water-proof self-compacting concrete (WPSCC )w as studied. The mechanism and influential factors, such as water-cement ratio(w /c), dosage of powder, superplasticizer, sand content, aggregate conte nt, fly ash, UEA, PP fiber, on compactibility and crack resistance of WPSCC were analyzed. A type of WPSCC successfully applied in tunnel liner with its validit ies, conveniences and economies by mockup test was developed and optimized. Expe rimental results show that the WPSCC has good workability, mechanical properties and impermeability when reasonable requirements are fulfilled.

Maternal and burial environment determine the physical dormancy release in tropical Senna auriculata(Fabaceae) seeds

In tropical ecosystems,species with an impermeable seed coat,i.e.physical dormancy(PY),are large in number and their seed coat is considered to be an adaptive trait for species persistence and colonization.However,only little is known about their mechanisms for breaking dormancy.The objective of this study was to understand the importance of seed maturation site and burial location in determining the PY release of Senna auriculata.Freshly collected seeds of S.auriculata from Vellore and Coimbatore,Tamil Nadu,India,germinated to 11±1.5%and19±2.5%respectively and remaining seeds did not imbibe water,thus had PY.Germination of seeds from both sites following hot-water treatment for 30 s and mechanical scarification increased significantly and seeds were able to germinate at a wide-range of temperatures(5–35℃)both in light and darkness.When incubated at 15/60℃for 3 months,dormancy release for seeds collected from Coimbatore(72%)was greater than seeds matured in Vellore(53%).Following 1 year of burial at three different locations,seeds from Coimbatore germinated to higher percentage than Vellore seeds at all locations.In particular,the higher temperature sites released dormancy to greater extent than the lower temperature site.Our results suggest that summer temperatures(>60℃)prevailing in the tropics provide appropriate cues for breaking PY,but this could be greatly affected by the initial state of seeds and the burial environment.

Impermeability Research of Autoclaved Propylene Oxide Sludge Shell-aggregate Concrete

We aimed to reuse the propylene oxide sludge(POS).Propylene oxide sludge shell-aggregate(POSS-A)and propylene oxide sludge gradient shell-aggregate(POSGS-A)whose main hydrated phase is tobermorite were successfully manufactured by the hydrothermal synthesis of POS and silica materials under the condition of autoclaved(180℃,1.0 MPa)curing.Influences of pre-wetting time of coarse aggregate and pressure application mode on the different concretes were investigated.The experimental results show that the concrete with POSS-A as coarse aggregate(POSS-A concrete),the concrete with POS gradient shell-aggregate as coarse aggregate(POSGS-A concrete),sintered aggregate concrete and common concrete,all have excellent impermeability performance whatever the pre-wetting time of coarse aggregate is 0.5 h or 24 h,and the pre-wetting time of coarse aggregate has a negligible influence on the concrete.The influence degree of pressure application mode on the impermeability performance of the sintered aggregate concrete is the greatest among three kinds of concrete,which has a negligible influence on impermeability performance of the other concretes.POSGS-A can be used as a green building light aggregate in hydraulic concrete.

Is the Isentropic Surface Always Impermeable to the Potential Vorticity Substance?

The impermeability of isentropic surfaces by the potential vorticity substance （PVS） has often been used to help understand the generation of potential vorticity in the presence of diabatic heating and friction. In this study, we examined singularities of isentropic surfaces that may develop in the presence of diabatic heating and the fictitious movements of the isentropic surfaces that are involved in deriving the PVS impermeability theorem. Our results show that such singularities could occur in the upper troposphere as a result of intense convective-scale motion, at the cloud top due to radiative cooling, or within the well-mixed boundary layer. These locally ill-defined conditions allow PVS to penetrate across an isentropic surface. We conclude that the PVS impermeability theorem is generally valid for the stably stratified atmosphere in the absence of diabatic heating.

ASYMPTOTIC STABILITY OF THE RAREFACTION WAVE FOR THE NON-VISCOUS AND HEAT-CONDUCTIVE IDEAL GAS IN HALF SPACE

This article is concerned with the impermeable wall problem for an ideal polytropic model of non-viscous and heat-conductive gas in one-dimensional half space. It is shown that the 3-rarefaction wave is stable under some smallness conditions. The proof is given by an elementary energy method and the key point is to do the higher order derivative estimates with respect to t because of the less dissipativity of the system and the higher order derivative boundary terms.

THE IMPERMEABILITY OF CEMENT MORTAR BY DRYTHERMAL CURING

The relationship of unstable osmosis coefficient to time and osmosis deep is derived from the osmosis equation in this paper. Mercury porosimeter is used to study the pore structure of cement mortar. The method of volume density is used to determine the changes of specific pore volume, and therelation between pore structure and impermeability is analyzed. Although the drythermal curing method has many advantages over other curing method, the directional pore along the direction of evaporization of water is formed inside concrete. The harmful pore above 2000(?) is increased and the average diameter of pore rises. As a result, the mortar impermeability loses seriously.

Impermeability of Tunnel Structural material after Exposure to High Temperature

Impermeability of tunnel structural material after exposure to high temperature determines residual service life and security. The present study explores impermeability deterioration and water absorption change (expressed as w(T, t)) of tunnel structural material after exposure to 200℃, 300℃, 400℃, 500℃, and 600℃respectively. Structural cementitious material was devised according to the requirements of segment used in Yangtze River tunnel of Wuhan which has been in constructing. Effect of high temperature on impermeability is evaluated by impermeability deterioration factor (abbr. IDF) and w(T, t).Testing results indicate that impermeability of concrete decreases with the increase of temperature up to 600℃, and serious impermeability deterioration occurs at temperature above 300℃. Furthermore, concrete with higher impermeability is more sensitive to high temperature above 400℃.

ELECTROELASTIC FIELD FOR AN IMPERMEABLE ANTI-PLANE SHEAR CRACK IN A PIEZOELECTRIC CERAMICS PLATE

Electroelastic behavior of a cracked piezoelectric ceramics plate subjected to four Cases of combined mechanical-electrical loads is analyzed. The integral transform method is applied to convert the problem involving an impermeable anti-plane crack to dual integral equations. Solving the resulting equations, the explicit analytic expressions for electroelastic field along the crack line and the intensity factors of relevant quantities near the crack tip and the mechanical strain energy release rate we obtained, The known results for an infinite piezoelectric ceramics plane containing an impermeable anti-plane crack are recovered from the present results only if the thickness of the plate h --> infinity.

Characterisation of Bacteria⁃Based Concrete Crack Rejuvenation by Externally Applied Repair

Microbiologically⁃induced calcite⁃precipitation(MICP)has been increasingly studied in structural repair including self⁃healing and external applications.Among various MICP pathways,enzymatic urea hydrolysis is suggested to be applied as external repair instead of self⁃healing.This study comprehensively characterised the enzymatic urea hydrolysis pathway in physical,impermeable,and mechanical rejuvenation of concrete cracks.The visual quality of repaired structures was presented,and the importance of humidity in the remediation of cracks was demonstrated.Moreover,this study investigated the differences in the effectiveness of repair between premixing bacteria with urea and without any premixing.With premixing,there was a concern that the accelerated reactions would precipitate calcite in the shallow spaces of the cracks and impede deeper healing.However,the observed results indicated that neither physical nor impermeable rejuvenation of concrete cracks repair would be detrimentally affected.The results obtained from this study will allow further development in commercialisation since the effectiveness of repair has been confirmed with an improvement in its efficiency.

Dynamic anti-plane interaction between an impermeable crack and a circular cavity in an infinite piezoelectric medium

Wave propagation in an infinite elastic piezoelectric medium with a circular cavity and an impermeable crack subjected to steady-state anti-plane shearing was studied based on Green's function and the crack-division technique.Theoretical solutions were derived for the whole elastic displacement and electric potential field in the interaction between the circular cavity and the impermeable crack.Expressions were obtained on the dynamic stress concentration factor(DSCF) at the cavity's edge,the dynamic stress intensity factor(DSIF) and the dynamic electric displacement intensity factor(DEDIF) at the crack tip.Numerical solutions were performed and plotted with different incident wave numbers,parameters of piezoelectric materials and geometries of the structure.Finally,some of the calculation results were compared with the case of dynamic anti-plane interaction of a permeable crack and a circular cavity in an infinite piezoelectric medium.This paper can provide a valuable reference for the design of piezoelectric actuators and sensors widely used in marine structures.

Somatic Polymorphism Variation in <i>Crotalaria retusa</i>L. Seeds

The article describes the somatic polymorphism in Crotalaria retusa L. seeds. Each individual may produce yellow dormant seeds, brown quiescent seeds and unviable dark brown ones. Therefore, regarding physiology it is a dimorphism. We show that autogamy reduces dimorphism, favoring the formation of dormant seeds. However, the significant variation in dimorphism is seasonal as consequence of increased viability of dormant seeds under drier weather conditions. The variation is a phenotypic response to changes of humidity in the environment during plant reproduction, a mechanism inducing the prevalence of dormant seeds in the dry season and quiescent seeds during the rainy season. The seasonal alternation between dormancy and quiescence in seasonally dry environments has an apparent adaptive value. The chromatic polymorphism increases on the more humid coast and during the rainy season, due to increased mortality of dormant seeds under wetter weather conditions. Unviable seeds accumulate oxidized phenols in their seed coat that possibly act as induced chemical defenses. Its proportion increases with humidity, accentuating polymorphism, also in response to the increase in the predation rate by larvae of U. ornatrix during the rainy season.

Torsional Vibrations of Coated Hollow Poroelastic Spheres

Torsional vibrations of coated hollow poroelastic spheres are studied employing Biot’s theory of wave propagation in poroelastic solid. The dilatations of solid and liquid media are zero, therefore the frequency equation of torsional vibrations is same both for a permeable and an impermeable surface. The coated poroelastic sphere consists of an inner hollow poroelastic sphere bounded by and bonded to a sphere made of distinct poroelastic material. The inner sphere is designated as core and outer sphere as casing. Core and casing are bonded at the curved surfaces. The inner and outer boundaries of the coated hollow poroelastic sphere are free from stress and at the interface of core and casing the displacement and stresses are continuous. It is assumed that the each material of coated sphere is homogeneous and isotropic. The frequency equation of torsional vibrations of a coated poroelastic hollow sphere is obtained when the material of the core vanishes. Also a coated poroelastic solid sphere is obtained as the limiting case of the frequency equation of coated hollow poroelastic sphere when the inner radius of core approaches to zero. Non-dimensional frequency as a function of ratio of thickness of core to that of inner radius of core is determined and analyzed. It is observed that the frequency and dispersion increase with the increase of the thickness of the coating.