通过分别在水稻季(R)和小麦季(W)设置对照(RB0-N0、WB0-N0)、单施氮肥(RB0-N1、WB0-N1)、20 t hm-2生物炭与氮配施(RB1-N1、WB1-N1)、40 t hm-2生物炭与氮配施(RB2-N1、WB2-N1)等8个处理,研究稻麦轮作周年系统N2O和CH4排放规律及其引起...通过分别在水稻季(R)和小麦季(W)设置对照(RB0-N0、WB0-N0)、单施氮肥(RB0-N1、WB0-N1)、20 t hm-2生物炭与氮配施(RB1-N1、WB1-N1)、40 t hm-2生物炭与氮配施(RB2-N1、WB2-N1)等8个处理,研究稻麦轮作周年系统N2O和CH4排放规律及其引起的综合温室效应(Global warming potential,GWP)和温室气体强度(Greenhouse gas intensity,GHGI)特征。结果表明:稻季配施20 t hm-2生物炭对N2O和CH4的排放、作物产量及GWP和GHGI均都无明显影响;稻季配施40 t hm-2生物炭能显著降低8.6%的CH4的排放和9.3%的GWP,显著增加作物产量17.2%。麦季配施20 t hm-2生物炭虽然对温室气体及GWP影响不明显,但显著增加21.6%的作物产量,从而显著降低21.7%的GHGI;麦季配施40 t hm-2生物炭能显著降低20.9%和11.3%的N2O和CH4排放,显著降低15.7%和23.5%的GWP和GHGI。因此麦季配施生物炭对减少N2O和CH4的排放、增加稻麦轮作产量及降低GWP和GHGI的效果较稻季配施生物炭效果更好。展开更多
The separation between methane and nitrogen is an inevitable and important task in the C1 chemicaltechnology and the utilization of methane from coalbed, yet it is considered to be one of the tough tasks in thefield o...The separation between methane and nitrogen is an inevitable and important task in the C1 chemicaltechnology and the utilization of methane from coalbed, yet it is considered to be one of the tough tasks in thefield of separation. Pressure swing adsorption is a preferable technology if an adsorbent that allowing a largecoefficient of separation for the CH4/N2 system is available. The separation coefficients between CH4 and N2were obtained on analyzing the breakthrough curves measured experimentally with nine adsorbents. A technique ofmeasuring the temperature-pulse was incorporated in the experiments, and the reliability of the result was improved.Superactivated carbon with large surface area and plenty of micropores was shown to have the largest separationcoefficient and to be promising for the commercial utilization.展开更多
Samples of methane molecules grade diameter channel CHA-type molecular sieves(Chabazite-K, SAPO-34 and SSZ-13) were investigated using the adsorption separation of CH4/N2 mixtures. The isotherms recorded for CH4 and N...Samples of methane molecules grade diameter channel CHA-type molecular sieves(Chabazite-K, SAPO-34 and SSZ-13) were investigated using the adsorption separation of CH4/N2 mixtures. The isotherms recorded for CH4 and N2 follow a typical type-Ι behavior, which were fitted well with the Sips model(R2>0.999) and the selectivity was calculated using IAST theory. The results reveal that Chabazite-K has the highest selectivity(SCH4/N= 5.5).2 SSZ-13 has the largest capacity, which can adsorb up to a maximum of 30.957 cm3·g-1(STP) of CH4, due to it having the largest pore volume and surface area, but the lowest selectivity(SCH4/N2= 2.5). From the breakthrough test, we can conclude that SSZ-13 may be a suitable candidate for the recovery of CH4 from low concentration methane(CH4<20%) based on its larger pore volume and higher CH4 capacity. Chabazite-K is more suited to the separation of high concentration methane(CH4>50%) due to its higher selectivity.展开更多
文摘通过分别在水稻季(R)和小麦季(W)设置对照(RB0-N0、WB0-N0)、单施氮肥(RB0-N1、WB0-N1)、20 t hm-2生物炭与氮配施(RB1-N1、WB1-N1)、40 t hm-2生物炭与氮配施(RB2-N1、WB2-N1)等8个处理,研究稻麦轮作周年系统N2O和CH4排放规律及其引起的综合温室效应(Global warming potential,GWP)和温室气体强度(Greenhouse gas intensity,GHGI)特征。结果表明:稻季配施20 t hm-2生物炭对N2O和CH4的排放、作物产量及GWP和GHGI均都无明显影响;稻季配施40 t hm-2生物炭能显著降低8.6%的CH4的排放和9.3%的GWP,显著增加作物产量17.2%。麦季配施20 t hm-2生物炭虽然对温室气体及GWP影响不明显,但显著增加21.6%的作物产量,从而显著降低21.7%的GHGI;麦季配施40 t hm-2生物炭能显著降低20.9%和11.3%的N2O和CH4排放,显著降低15.7%和23.5%的GWP和GHGI。因此麦季配施生物炭对减少N2O和CH4的排放、增加稻麦轮作产量及降低GWP和GHGI的效果较稻季配施生物炭效果更好。
文摘The separation between methane and nitrogen is an inevitable and important task in the C1 chemicaltechnology and the utilization of methane from coalbed, yet it is considered to be one of the tough tasks in thefield of separation. Pressure swing adsorption is a preferable technology if an adsorbent that allowing a largecoefficient of separation for the CH4/N2 system is available. The separation coefficients between CH4 and N2were obtained on analyzing the breakthrough curves measured experimentally with nine adsorbents. A technique ofmeasuring the temperature-pulse was incorporated in the experiments, and the reliability of the result was improved.Superactivated carbon with large surface area and plenty of micropores was shown to have the largest separationcoefficient and to be promising for the commercial utilization.
基金financial support from the National Natural Science Foundation of China (Nos. 51672186, 21676175)
文摘Samples of methane molecules grade diameter channel CHA-type molecular sieves(Chabazite-K, SAPO-34 and SSZ-13) were investigated using the adsorption separation of CH4/N2 mixtures. The isotherms recorded for CH4 and N2 follow a typical type-Ι behavior, which were fitted well with the Sips model(R2>0.999) and the selectivity was calculated using IAST theory. The results reveal that Chabazite-K has the highest selectivity(SCH4/N= 5.5).2 SSZ-13 has the largest capacity, which can adsorb up to a maximum of 30.957 cm3·g-1(STP) of CH4, due to it having the largest pore volume and surface area, but the lowest selectivity(SCH4/N2= 2.5). From the breakthrough test, we can conclude that SSZ-13 may be a suitable candidate for the recovery of CH4 from low concentration methane(CH4<20%) based on its larger pore volume and higher CH4 capacity. Chabazite-K is more suited to the separation of high concentration methane(CH4>50%) due to its higher selectivity.
