We observe the spectra of molybdenum for the first time since the first wall of our experimental advanced superconducting tokamak （EAST） was changed mainly to molybdenum tiles. A large amount of molybdenum accumulat...We observe the spectra of molybdenum for the first time since the first wall of our experimental advanced superconducting tokamak （EAST） was changed mainly to molybdenum tiles. A large amount of molybdenum accumulated in the central plasma where the long-lived m = 1 mode instability bursts is shown. Molybdenum is proved to be the main impurity species observed during the formation and lifetime of impurity-induced long-lived m= 1 mode. This may indicate that a close relationship exists between the high-Z impurity accumulation and the occurrence of long-lived m = 1 mode in EAST plasmas.展开更多
The unusual room-temperature phosphorescence(RTP)from the n electron-rich systems(without regular conjugated structure)has aroused great attention for structural designing and application development of RTP materials....The unusual room-temperature phosphorescence(RTP)from the n electron-rich systems(without regular conjugated structure)has aroused great attention for structural designing and application development of RTP materials.Such emission has been ascribed to clusterization-triggered emission(CTE)via weak through-space conjugation of n electrons in the heteroatoms.However,there was suspicion on such RTP as impurity-induced result.Therefore,in-depth photophysical investigation and effective proof methods are needed to trace the origin of such RTP.Here,using the recently reported CTE phosphor boric acid as the example,a Jablonski diagram-based verification protocol was proposed to confirm the intrinsic luminescence of the n electrons-rich systems.Meanwhile,some other types of luminophores,that is,traditional phosphors,already reported impurity-induced and host-guest doping luminophores,were included for comparison.Overall,this work provides a basic paradigm for differentiating between the impurity-involved and the n electron-rich phosphors and will further deepen the understanding of nonconventional luminescence.展开更多
基金Supported by the National Magnetic Confinement Fusion Science Program of China under Grant Nos 2013GB112004 and 2015GB103002the Natural Science Research Key Project of Education Department of Anhui Province under Grant No KJ2016A434+3 种基金the Doctoral Scientific Research Foundation of Anqing Normal University under Grant No 044-140001000024the National Natural Science Foundation of China under Grant Nos 11275231,11305212,11405212 and 11261140328the Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology under Grant No 2014FXCX003the Hefei Science Center CAS Users with Potential Project under Grant No 2015HSC-UP007
文摘We observe the spectra of molybdenum for the first time since the first wall of our experimental advanced superconducting tokamak （EAST） was changed mainly to molybdenum tiles. A large amount of molybdenum accumulated in the central plasma where the long-lived m = 1 mode instability bursts is shown. Molybdenum is proved to be the main impurity species observed during the formation and lifetime of impurity-induced long-lived m= 1 mode. This may indicate that a close relationship exists between the high-Z impurity accumulation and the occurrence of long-lived m = 1 mode in EAST plasmas.
基金National Natural Science Foundation of China,Grant/Award Number:22325403Sichuan University,Grant/Award Number:2022SCUNL104。
文摘The unusual room-temperature phosphorescence(RTP)from the n electron-rich systems(without regular conjugated structure)has aroused great attention for structural designing and application development of RTP materials.Such emission has been ascribed to clusterization-triggered emission(CTE)via weak through-space conjugation of n electrons in the heteroatoms.However,there was suspicion on such RTP as impurity-induced result.Therefore,in-depth photophysical investigation and effective proof methods are needed to trace the origin of such RTP.Here,using the recently reported CTE phosphor boric acid as the example,a Jablonski diagram-based verification protocol was proposed to confirm the intrinsic luminescence of the n electrons-rich systems.Meanwhile,some other types of luminophores,that is,traditional phosphors,already reported impurity-induced and host-guest doping luminophores,were included for comparison.Overall,this work provides a basic paradigm for differentiating between the impurity-involved and the n electron-rich phosphors and will further deepen the understanding of nonconventional luminescence.
