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Mechanistically Novel Frontal-Inspired In Situ Photopolymerization:An Efficient Electrode|Electrolyte Interface Engineering Method for High Energy Lithium Metal Polymer Batteries 被引量:1
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作者 Ishamol Shaji Diddo Diddens +1 位作者 Martin Winter Jijeesh Ravi Nair 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2023年第6期273-282,共10页
The solvent-free in situ polymerization technique has the potential to tailor-make conformal interfaces that are essential for developing durable and safe lithium metal polymer batteries(LMPBs).Hence,much attention ha... The solvent-free in situ polymerization technique has the potential to tailor-make conformal interfaces that are essential for developing durable and safe lithium metal polymer batteries(LMPBs).Hence,much attention has been given to the eco-friendly and rapid ultraviolet(UV)-induced in situ photopolymerization process to prepare solid-state polymer electrolytes.In this respect,an innovative method is proposed here to overcome the challenges of UV-induced photopolymerization(UV-curing)in the zones where UV-light cannot penetrate,especially in LMPBs where thick electrodes are used.The proposed frontal-inspired photopolymerization(FIPP)process is a diverged frontal-based technique that uses two classes(dual)of initiators to improve the slow reaction kinetics of allyl-based monomers/oligomers by at least 50%compared with the conventional UV-curing process.The possible reaction mechanism occurring in FIPP is demonstrated using density functional theory calculations and spectroscopic investigations.Indeed,the initiation mechanism identified for the FIPP relies on a photochemical pathway rather than an exothermic propagating front forms during the UV-irradiation step as the case with the classical frontal photopolymerization technique.Besides,the FIPP-based in situ cell fabrication using dual initiators is advantageous over both the sandwich cell assembly and conventional in situ photopolymerization in overcoming the limitations of mass transport and active material utilization in high energy and high power LMPBs that use thick electrodes.Furthermore,the LMPB cells fabricated using the in situ-FIPP process with high mass loading LiFePO_(4)electrodes(5.2 mg cm^(-2))demonstrate higher rate capability,and a 50%increase in specific capacity against a sandwich cell encouraging the use of this innovative process in large-scale solid-state battery production. 展开更多
关键词 cathodelelectrolyte interface frontal-inspired photopolymerization in situ polymerization lithium metal polymer battery solid polymer electrolyte
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In Situ Directional Polymerization of Poly(1,3-dioxolane)Solid Electrolyte Induced by Cellulose Paper-Based Composite Separator for Lithium Metal Batteries 被引量:2
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作者 Jian Ma Yueyue Wu +5 位作者 Hao Jiang Xin Yao Fan Zhang Xianglong Hou Xuyong Feng Hongfa Xiang 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2023年第3期134-143,共10页
In traditional in situ polymerization preparation for solid-state electrolytes,initiators are directly added to the liquid precursor.In this article,a novel cellulose paper-based composite separator is fabricated,whic... In traditional in situ polymerization preparation for solid-state electrolytes,initiators are directly added to the liquid precursor.In this article,a novel cellulose paper-based composite separator is fabricated,which employs alumina as the inorganic reinforcing material and is loaded with polymerization initiator aluminum trifluoromethanesulfonate.Based upon this,a separator-induced in situ directional polymerization technique is demonstrated,and the extra addition of initiators into liquid precursors is no longer required.The polymerization starts from the surface and interior of the separator and extends outward with the gradually dissolving of initiators into the precursor.Compared with its traditional counterpart,the separator-induced poly(1,3-dioxolane)electrolyte shows improved interfacial contact as well as appropriately mitigated polymerization rate,which are conducive to practical applications.Electrochemical measurement results show that the prepared poly(1,3-dioxolane)solid electrolyte possesses an oxidation potential up to 4.4 V and a high Li+transference number of 0.72.After 1000 cycles at 2 C rate(340 mA g^(−1)),the assembled Li||LiFePO_(4)solid battery possesses a 106.8 mAh g^(−1)discharge capacity retention and 83.5%capacity retention ratio,with high average Coulombic efficiency of 99.5%achieved.Our work may provide new ideas for the design and application of in situ polymerization technique for solid electrolytes and solid batteries. 展开更多
关键词 cellulose paper-based composite separator in situ directional polymerization lithium metal battery poly-DOL electrolyte solid-state electrolyte
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High-Performance Quasi-Solid-State Pouch Cells Enabled by in situ Solidification of a Novel Polymer Electrolyte 被引量:2
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作者 Qingwen Lu Changhong Wang +9 位作者 Danni Bao Hui Duan Feipeng Zhao Kieran Doyle-Davis Qiang Zhang Rennian Wang Shangqian Zhao Jiantao Wang Huan Huang Xueliang Sun 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2023年第4期15-21,共7页
Conventional lithium-ion batteries(LIBs)with liquid electrolytes are challenged by their big safety concerns,particularly used in electric vehicles.All-solid-state batteries using solid-state electrolytes have been pr... Conventional lithium-ion batteries(LIBs)with liquid electrolytes are challenged by their big safety concerns,particularly used in electric vehicles.All-solid-state batteries using solid-state electrolytes have been proposed to significantly improve safety yet are impeded by poor interfacial solid–solid contact and fast interface degradation.As a compromising strategy,in situ solidification has been proposed in recent years to fabricate quasi-solid-state batteries,which have great advantages in constructing intimate interfaces and cost-effective mass manufacturing.In this work,quasi-solid-state pouch cells with high loading electrodes(≥3 m Ah cm^(-2))were fabricated via in situ solidification of poly(ethylene glycol)diacrylate-based polymer electrolytes(PEGDA-PEs).Both single-layer and multilayer quasi-solid-state pouch cells(2.0 Ah)have demonstrated stable electrochemical performance over500 cycles.The superb electrochemical stability is closely related to the formation of robust and compatible interphase,which successfully inhibits interfacial side reactions and prevents interfacial structural degradation.This work demonstrates that in situ solidification is a facile and cost-effective approach to fabricate quasi-solid-state pouch cells with both excellent electrochemical performance and safety. 展开更多
关键词 high areal capacity high-energy-density pouch cells in situ solidification poly(ethylene glycol)diacrylate-based polymer electrolyte
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Flame retardant polyamide 6 by in situ polymerization of ε-caprolactam in the presence of melamine derivatives 被引量:15
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作者 Zhi Yong Wu Wei Xu +3 位作者 Jin Kui Xia Yao Chi Liu Qian Xin Wu Wei Jian Xu 《Chinese Chemical Letters》 SCIE CAS CSCD 2008年第2期241-244,共4页
An improved method for preparing melamine cyanurate (MCA) based flame retardant polyamide 6 (FRPA6) materials has been proposed. This processing method, i.e., improved in situ polymerization, was used to synthesiz... An improved method for preparing melamine cyanurate (MCA) based flame retardant polyamide 6 (FRPA6) materials has been proposed. This processing method, i.e., improved in situ polymerization, was used to synthesize flame retardant PA6. In situ formed MCA nanoparticles were supposed to be linked to PA6 chains in the ε-caprolactam hydrolytic polymerization system to obtain startype polymers for the first time. Through TEM photographs, it can be found that the in situ formed MCA nanoparticles with diametric size of less than 50 nm, are nanoscaled, highly uniformly dispersed in the PA6 matrix. Synthesized flame retardant PA6 have good fire performance which can achieve UL-94 V-0 rating at 1.6 mm thickness with the presence of 7.34 wt.% MCA in the matrix. 展开更多
关键词 Polyamide 6 In situ polymerization Melamine cyanurate NANOPARTICLES
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In-situ Polymerization-modification Process and Foaming of Poly(ethylene terephthalate) 被引量:3
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作者 仲华 奚桢浩 +1 位作者 刘涛 赵玲 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2013年第12期1410-1418,共9页
Most of traditional linear poly(ethylene terephthalate)(PET)resins of relatively low molecular mass and narrow molecular mass distribution have low melt strength at foaming temperatures,which are not enough to support... Most of traditional linear poly(ethylene terephthalate)(PET)resins of relatively low molecular mass and narrow molecular mass distribution have low melt strength at foaming temperatures,which are not enough to support and keep cells.An in-situ polymerization-modification process with esterification and polycondensation stages was performed in a 2 L batch stirred reactor using pyromellitic dianhydride(PMDA)or pentaerythritol(PENTA)as modifying monomers to obtain PETs with high melt strength.The influence of amounts of modifying monomers on the properties of modified PET was investigated.It was found that the selected modifying monomers could effectively introduce branched structures into the modified PETs and improve their melt strength.With increasing the amount of the modifying monomer,the melt strength of the modified PET increased.But when the amount of PENTA reached 0.35%or PMDA reached 0.9%,crosslinking phenomenon was observed in the modified PET.Supercritical carbon dioxide(ScCO2)was employed as physical foaming agent to evaluate the foaming ability of modified PETs.The modified PETs had good foaming properties at 14 MPa of CO2pressure with foaming temperature ranging from 265°C to 280°C.SEM micrographs demonstrated that both modified PET foams had homogeneous cellular structures,with cell diameter ranging from 35μm to 49μm for PENTA modified PETs and38μm to 57μm for PMDA modified ones.Correspondingly,the cell density had a range of 3.5×107cells·cm 3to 7×106cells·cm 3for the former and 2.8×107cells·cm 3to 5.8×106cells·cm 3for the latter. 展开更多
关键词 对苯二甲酸乙二醇酯 改性工艺 原位聚合 泡沫材料 超临界二氧化碳 高熔体强度 窄分子量分布 PENTA
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Synthesis of PMA/Eu_2O_3 porous-layered nanocomposite by in situ polymerization and its morphology
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作者 MO Zunli LIU Yanzhi +3 位作者 WANG Kunjie LI Hejun CHEN Hong SUN Yinxia 《Rare Metals》 SCIE EI CAS CSCD 2006年第1期63-67,共5页
The PMA/Eu2O3 porous and layered nanocomposite was prepared by in situ polymerization and characterized by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscope (... The PMA/Eu2O3 porous and layered nanocomposite was prepared by in situ polymerization and characterized by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscope (SEM), and inflared ray (IR). Microscopic investigation of the nanocomposite was carded out by atomic force microscopy (AFM). The results showed that the shape of the composite was layered and porous. Eu2O3 was grafted when methyl acrylate (MA) polymerized; thus Eu2O3 particles appeared on both sides of the chains of polymeric methyl acrylate (PMA). 展开更多
关键词 NANOCOMPOSITE porous-layered nanocomposite in situ polymerization synthesis rare earth
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In situ polymerization preparation and characterization of Li_4Ti_5O_(12)-polyaniline anode material
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作者 何则强 熊利芝 +3 位作者 陈上 吴显明 刘文萍 黄可龙 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第S1期262-266,共5页
Li4Ti5O12 powders were prepared by so-gel method using tetrabutyl titanate,lithium acetate and absolute alcohol as starting materials.Li4Ti5O12-polyaniline(Li4Ti5O12-PAn)composite was prepared by in situ polymerizatio... Li4Ti5O12 powders were prepared by so-gel method using tetrabutyl titanate,lithium acetate and absolute alcohol as starting materials.Li4Ti5O12-polyaniline(Li4Ti5O12-PAn)composite was prepared by in situ polymerization method using aniline, ammonium persulfate and hydrochloricarried as starting materials.Li4Ti5O12-PAn composite was characterized by X-ray diffractometry(XRD),infrared spectrum(IR)combined with electrochemical tests.The results show that the electrical conductivity is enhanced obviously due to the introduction of PAn to Li4Ti5O12.Li4Ti5O12-PAn composite exhibits better high-rate capability and cyclability than Li4Ti5O12.The composite can deliver a specific capacity of 191.3 and 148.9 mA·h/g,only 0.13%and 0.61%of the capacity is lose after being discharged 80 times at 0.1C and 2.0C,respectively. 展开更多
关键词 LI4TI5O12 POLYANILINE in situ polymerization method lithium ion batteries
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Thermoelectric properties of Bi_(0.5)Sb_(1.5)Te_3/polyaniline composites prepared by mechanical blending and in-situ polymerization
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作者 胡淑红 裴浩东 赵新兵 《中国有色金属学会会刊:英文版》 CSCD 2001年第6期876-878,共3页
Bi 0.5 Sb 1.5 Te 3/polyaniline composites were prepared by mechanical blending and in situ polymerization, and their transport properties were measured. It was found that for the composites with 1%, 3%, 5% and 7% poly... Bi 0.5 Sb 1.5 Te 3/polyaniline composites were prepared by mechanical blending and in situ polymerization, and their transport properties were measured. It was found that for the composites with 1%, 3%, 5% and 7% polyaniline (mass fraction) respectively, which were prepared by mechanical blending, the power factors decrease by about 30%, 50%, 55% and 65% compared with the Bi 0.5 Sb 1.5 Te 3 samples, which is mainly due to the remarkable decreases of the electrical conductivity. The electrical conductivity and power factor of the composites samples with 7% polyaniline prepared by in situ polymerization are higher by about 65% and 60%, respectively, than that of the corresponding samples prepared by mechanical blending. 展开更多
关键词 thermoelectric property Bi 0.5 Sb 1.5 Te 3/polyaniline composite mechanical blending in situ polymerization
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Thermal Stability and Crystallinity Study of Polystyrene/SiO2 Nano-Composites Synthesis via Microwave-Assisted In Situ Polymerization
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作者 Nikesh Samarth Linchon Mehta +2 位作者 Vinayak Kamble Malhari Kulkarni Prakash Mahanwar 《Open Journal of Synthesis Theory and Applications》 CAS 2016年第2期15-23,共9页
Serials of polystyrene/SiO<sub>2</sub> Nano composites (PS/SiO<sub>2</sub>) with different content of inorganic fillers were successfully prepared by the in situ bulk radical polymerization of ... Serials of polystyrene/SiO<sub>2</sub> Nano composites (PS/SiO<sub>2</sub>) with different content of inorganic fillers were successfully prepared by the in situ bulk radical polymerization of styrene under microwave irradiation. The effect of the amount of Nano SiO<sub>2</sub> on the properties of the PS/SiO<sub>2</sub> Nanocomposites along with the average relative molecular masses (Mn, Mz and Mw) was investigated by thermal analysis and X-Ray Diffraction (XRD). Their structural model was proposed on the basis of the Optical Microscopy, FTIR (Fourier Transform Infrared) analysis, differential scanning calorimetry (DSC), gel permeation chromatography (GPC) and X-Ray Diffraction (XRD). The dispersion of nanoparticles in Polystyrene is observed in the magnified image. The effect of microwave irradiation power on molecular weight of polystyrene was also studied. It was found that, the microwave assisted reaction needs less time as compare to conventional polymerization and found to be in between 10 to 15 min. 展开更多
关键词 Nanocomposites In situ polymerization Bulk polymerization Nano SiO2
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SYNTHESIS AND CHARACTERIZATION OF POLYPROPYLENE/MONTMORILLONITE NANOCOMPOSITES VIA AN in-situ POLYMERIZATION APPROACH
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作者 张学全 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2003年第4期413-418,共6页
Polypropylene/montmorillonite (PP/MMT)nanocomposites were prepared by in-situ polymerization using aMMT/MgCl_2/TiCl_4-EB Ziegler-Natta catalyst activated by triethylaluminum(TEA). The enlarged layer spacing of MMT was... Polypropylene/montmorillonite (PP/MMT)nanocomposites were prepared by in-situ polymerization using aMMT/MgCl_2/TiCl_4-EB Ziegler-Natta catalyst activated by triethylaluminum(TEA). The enlarged layer spacing of MMT wasconfirmed by X-ray wide angle diffraction (WAXD), demonstrating that MMT were intercalated by the catalyst components.X-ray photoelectron spectrometry (XPS) analysis proved that TiCl_4 was mainly supported on MgCl_2 instead of on the surfaceof MMT The exfoliated structure of MMT layers in the PP matrix of PP/MMT composites was demonstrated by WAXDpatterns and transmission electron microscopy (TEM) observation. The higher glass transition temperature and higher storage modulus of the PP/MMT composites in comparison with pure PP were revealed by dynamic mechanical analysis (DMA). 展开更多
关键词 POLYPROPYLENE NANOCOMPOSITE in-situ polymerization
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Preparation of Polysulfonamide/ZnO Nanocomposite by In-Situ Polymerization
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作者 刘丽 邓捷 +2 位作者 王晓鹏 倪佳华 印杰 《Journal of Shanghai Jiaotong university(Science)》 EI 2007年第4期508-510,516,共4页
Polysulfonamide/zinc oxide(PSA/ZnO) nanocomposite films with w(ZnO)=0.5% were prepared by in-situ polymerization based on 4,4′-diaminodiphenylsulfone and terephthaloyl chloride in the common solvent N,N-Dimethylaceta... Polysulfonamide/zinc oxide(PSA/ZnO) nanocomposite films with w(ZnO)=0.5% were prepared by in-situ polymerization based on 4,4′-diaminodiphenylsulfone and terephthaloyl chloride in the common solvent N,N-Dimethylacetamide(DMAc). Atomic force microscopy (AFM) was employed to observe the microstructure of the composite film. The thermal property was investigated by TGA and mechanical property was characterized by DXLL-1000 electromechanical material testing machine. The results showed that the breaking strength of the film containing 0.5% ZnO was great enhanced. The average size of ZnO particles was below 100 nm. The introduction of ZnO as nano filler in PSA react as UV shield effect and make the composite mechanical property improved. 展开更多
关键词 ZNO polysulfonamide(PSA) NANOCOMPOSITE mechanical property IN-situ polymerization
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PREPARATION OF POLYSULFONAMIDE AND MODIFIED TITANIUM OXIDE NANOCOMPOSITES BY IN-SITU POLYMERIZATION
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作者 WANG Weitao LIU Li +2 位作者 DENG Jie WANG Xiaopeng TANG Zhiyong 《Chinese Journal of Reactive Polymers》 2006年第1期57-59,共3页
关键词 聚磺酰胺 原位聚合 纳米二氧化钛 氧化硅
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In situ polymerization coating and characteristics of coated NPK compound fertilizer 被引量:4
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作者 WANG Zhenghui ZHU Boming 《Journal of Northeast Agricultural University(English Edition)》 CAS 2007年第2期148-152,共5页
Controlled release NPK compound fertilizers were prepared by means of in situ polymerization of monomers on the surface of fertilizer granules at room temperature. Methacrylate, α-methyl acrylic acid, and ethylene di... Controlled release NPK compound fertilizers were prepared by means of in situ polymerization of monomers on the surface of fertilizer granules at room temperature. Methacrylate, α-methyl acrylic acid, and ethylene dimethylacrylate were used as monomers, Dibenzoyl peroxide as initiator, and cobalt naphthenate, and triethyl amine as promoters. The structures of coating materials were characterized by IR spectra. The thermogravimetric analysis result indicated that the coating materials were of good thermal stability. The mean thickness of single coating measured with screw gauge was ca. 140 μm. The morphologies of uncoated and coated fertilizer granules analyzed by using scanning electron microscopy were changed from porosities and gullies to hills and plain. The release rate of coated compound fertilizers in water could be controlled by the hydrophicity and thickness of coating. The increase in coating hydrophicity caused the increase in release rate of fertilizer. The increase in thickness of coating slowed the release rate. 展开更多
关键词 in situ polymerization coated compound fertilizer controlled release
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碳纳米管-聚苯胺/聚乙烯醇复合气凝胶的制备及其吸波性能 被引量:1
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作者 刘德运 朱曜峰 《浙江理工大学学报(自然科学版)》 2024年第2期153-160,共8页
为了获得高性能复合气凝胶吸波材料,以螺旋碳纳米管(Helical carbon nanotubes,HCNTs)和聚苯胺(Polyaniline,PANI)为吸波剂,聚乙烯醇(Polyvinyl alcohol,PVA)为基体,采用定向冷冻法和低温原位聚合法制备了高性能螺旋碳纳米管-聚苯胺/聚... 为了获得高性能复合气凝胶吸波材料,以螺旋碳纳米管(Helical carbon nanotubes,HCNTs)和聚苯胺(Polyaniline,PANI)为吸波剂,聚乙烯醇(Polyvinyl alcohol,PVA)为基体,采用定向冷冻法和低温原位聚合法制备了高性能螺旋碳纳米管-聚苯胺/聚乙烯醇复合气凝胶(HCNTs-PANI/PVA composite aerogels,HPPA)。采用扫描电子显微镜、红外光谱仪、拉曼光谱仪和X射线衍射仪对HPPA复合气凝胶的形貌与结构进行表征,并使用矢量网络分析仪测定HPPA复合气凝胶的电磁参数和吸波特性。结果表明:所制备的HPPA复合气凝胶具有优异的吸波性能,最小的反射损耗为-69.08 dB,有效吸收带宽为4.20 GHz;HPPA复合气凝胶优异的吸波性能主要归因于其定向的多孔结构和非均匀介质界面形成的良好阻抗匹配特性和多重极化协同效应。该文为构建高性能复合气凝胶吸波体系提供了新思路。 展开更多
关键词 复合气凝胶 定向冷冻 低温原位聚合 聚苯胺 吸波性能
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MicroRNA-502-3p regulates GABAergic synapse function in hippocampal neurons 被引量:2
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作者 Bhupender Sharma Melissa MTorres +2 位作者 Sheryl Rodriguez Laxman Gangwani Subodh Kumar 《Neural Regeneration Research》 SCIE CAS CSCD 2024年第12期2698-2707,共10页
Gamma-aminobutyric acid(GABA)ergic neurons,the most abundant inhibitory neurons in the human brain,have been found to be reduced in many neurological disorders,including Alzheimer's disease and Alzheimer's dis... Gamma-aminobutyric acid(GABA)ergic neurons,the most abundant inhibitory neurons in the human brain,have been found to be reduced in many neurological disorders,including Alzheimer's disease and Alzheimer's disease-related dementia.Our previous study identified the upregulation of microRNA-502-3p(miR-502-3p)and downregulation of GABA type A receptor subunitα-1 in Alzheimer's disease synapses.This study investigated a new molecular relationship between miR-502-3p and GABAergic synapse function.In vitro studies were perfo rmed using the mouse hippocampal neuronal cell line HT22 and miR-502-3p agomiRs and antagomiRs.In silico analysis identified multiple binding sites of miR-502-3p at GABA type A receptor subunitα-1 mRNA.Luciferase assay confirmed that miR-502-3p targets the GABA type A receptor subunitα-1 gene and suppresses the luciferase activity.Furthermore,quantitative reve rse transcription-polymerase chain reaction,miRNA in situ hybridization,immunoblotting,and immunostaining analysis confirmed that overexpression of miR-502-3p reduced the GABA type A receptor subunitα-1 level,while suppression of miR-502-3p increased the level of GABA type A receptor subunitα-1 protein.Notably,as a result of the overexpression of miR-502-3p,cell viability was found to be reduced,and the population of necrotic cells was found to be increased.The whole cell patch-clamp analysis of human-GABA receptor A-α1/β3/γ2L human embryonic kidney(HEK)recombinant cell line also showed that overexpression of miR-502-3p reduced the GABA current and overall GABA function,suggesting a negative correlation between miR-502-3p levels and GABAergic synapse function.Additionally,the levels of proteins associated with Alzheimer s disease were high with miR-502-3p overexpression and reduced with miR-502-3p suppression.The present study provides insight into the molecular mechanism of regulation of GABAergic synapses by miR-502-3p.We propose that micro-RNA,in particular miR-502-3p,could be a potential therapeutic to rget to modulate GABAergic synapse function in neurological disorders,including Alzheimer's disease and Alzheimer's diseaserelated dementia. 展开更多
关键词 Alzheimer's disease GABAergic synapse gamma-aminobutyric acid type A receptor subunitα-1(GABRα1) microRNA-502-3p(miR-502-3p) miRNA in situ hybridization PATCH-CLAMP
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Covalent organic frameworks-incorporated thin film composite membranes prepared by interfacial polymerization for efficient CO_(2) separation 被引量:3
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作者 Haoqing Xu Wenyan Feng +4 位作者 Menglong Sheng Ye Yuan Bo Wang Jixiao Wang Zhi Wang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2022年第3期152-160,共9页
Thin film composite(TFC)membranes with nanofillers additives for CO_(2)separation show promising applications in energy and environment-related fields.However,the poor compatibility between nanofillers and polymers in... Thin film composite(TFC)membranes with nanofillers additives for CO_(2)separation show promising applications in energy and environment-related fields.However,the poor compatibility between nanofillers and polymers in TFC membranes is the main problem.In this work,covalent organic frameworks(COFs,TpPa-1)with rich ANHA groups were incorporated into polyamide(PA)segment via in situ interfacial polymerization to prepare defect-free TFC membranes for CO_(2)/N_(2)separation.The formed covalent bonds between TpPa-1 and PA strengthen the interaction between nanofillers and polymers,thereby enhancing compatibility.Besides,the incorporated COFs disturb the rigid structure of the PA layer,and provide fast CO_(2)transfer channels.The incorporated COFs also increase the content of effective carriers,which enhances the CO_(2)facilitated transport.Consequently,in CO_(2)/N_(2)mixed gas separation test,the optimal TFC(TpPa_(0.025)-PIP-TMC/m PSf)membrane exhibits high CO_(2)permeance of 854 GPU and high CO_(2)/N_(2)selectivity of 148 at 0.15 MPa,CO_(2)permeance of 456 GPU(gas permeation unit)and CO_(2)/N_(2)selectivity of 92 at 0.5 MPa.In addition,the Tp Pa_(0.025)-PIP-TMC/m PSf membrane also achieves high permselectivty in CO_(2)/CH_(4)mixed gas separation test.Finally,the optimal TFC membrane showes good stability in the simulated flue gas test,revealing the application potential for CO_(2)capture from flue gas. 展开更多
关键词 Covalent organic frameworks CO_(2)/N_(2)separation In situ interfacial polymerization Compatibility Covalent bonds
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Hydrothermal in situ Ligand Synthesis from 1,10-Phenanthroline-5,6-dione and Characterization of 1D Coordination Polymers [Co(bpdc)(H_2O)_3]·H_2O and [Cu(bpy)V_2O_6] 被引量:1
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作者 WANG Xiu-li BI Yan-feng LIN Hong-yan LIU Guo-cheng 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2007年第3期250-253,共4页
Hydrothermal treatment of MCl2 ( M = Co or Cu ) , NH4 VO3, and 1,10-phenanthroline-5,6-dione (pdon) resulted in the formation of a duplex coordination polymer [ Co ( bpdc ) ( H2O ) 3 ] · H2O ( bpdc = 2,2... Hydrothermal treatment of MCl2 ( M = Co or Cu ) , NH4 VO3, and 1,10-phenanthroline-5,6-dione (pdon) resulted in the formation of a duplex coordination polymer [ Co ( bpdc ) ( H2O ) 3 ] · H2O ( bpdc = 2,2'-bipyridine-3,3'-dicarboxylate) and a chain-like coordination polymer [ Cu (bpy) V2O6 ] ( bpy = 2,2'-bipyridine ). X-ray single-crystal structural analysis shows that under hydrothermal conditions and in the presence of different transition metals, the organic reagent pdon was transformed in situ into bpdc and bpy, respectively. Mechanism of the in situ ligand synthesis reaction has been discussed. 展开更多
关键词 Hydrothermal synthesis In situ Ligand synthesis Coordination polymer Mechanism
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Conjugated polymerized bimetallic phthalocyanine based electrocatalyst with Fe-N_(4)/Co-N_(4) dual-sites synergistic effect for zinc-air battery
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作者 Shuaifeng Wang Zhongfang Li +5 位作者 Wenjie Duan Peng Sun Jigang Wang Qiang Liu Lei Zhang Yanqiong Zhuang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第11期41-53,I0002,共14页
The bifunctional oxygen catalyst is essential for zinc-air batteries(ZABs).Here,an efficient bifunctional oxygen catalyst,PPcFeCo/3D-G,is obtained throughπ-πinteraction between the conjugated polymerized iron-cobalt... The bifunctional oxygen catalyst is essential for zinc-air batteries(ZABs).Here,an efficient bifunctional oxygen catalyst,PPcFeCo/3D-G,is obtained throughπ-πinteraction between the conjugated polymerized iron-cobalt phthalocyanine(PPcFeCo)with excellent thermal stability and three-dimensional graphene(3D-G).The bimetallic synergistic effect of PPcFeCo,verified by DFT(Density functional theory)calculation,andπ-πinteractions enhances the catalytic activity and durability of the PPcFeCo/3D-G.Regarding electrochemical performance,the PPcFeCo/3D-G with a high electron transfer number(3.98,@0.768 V vs.RHE)has excellent half-wave potential(E_(1/2)=0.890 V vs.RHE)and exhibits outstanding reversibility(ΔE=0.700 V,ΔE=Ej=10-E_(1/2)).The liquid ZAB(LZAB)employed PPcFeCo/3D-G displays a high power density(222 m W cm^(-2)),a specific capacity(792 m A h g-1),and excellent durability(120 h).This work has guiding significance for the preparation of high-efficiency bifunctional catalysts. 展开更多
关键词 Zn-airbattery Bifunctional oxygen catalysts polymerized iron-cobalt phthalocyanine Bimetallic synergy π-πinteraction
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In Situ Synthesis, Structural Characterization and Catalytic Properties of a 2D Cu(Ⅰ)-cyanide Coordination Polymer 被引量:1
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作者 杨英杰 王福生 董桂英 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2019年第5期811-818,671,共9页
A new Cu(Ⅰ) coordination polymer(CP) formulated as [Cu2(L)(CN)2]n(1, L =1,1′-bis(5,6-dimethylbenzimidazole)methane) was synthesized, in which the cyanide anions were generated in situ by the cleavage of C–C bond of... A new Cu(Ⅰ) coordination polymer(CP) formulated as [Cu2(L)(CN)2]n(1, L =1,1′-bis(5,6-dimethylbenzimidazole)methane) was synthesized, in which the cyanide anions were generated in situ by the cleavage of C–C bond of acetonitrile under hydrothermal conditions. CP 1 was characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. It crystallizes in the orthorhombic system, Pccn space group, with a = 10.314(3), b = 20.966(7), c =9.432(3)?, V = 2039.5(11)?3, Z = 4, C21 H20 Cu2 N6, Mr = 483.51, Dc = 1.575 g×cm^-3,μ= 2.105 mm-1 and F(000)= 984, the final R = 0.0608 and wR = 0.1942 for 1226 observed reflections with Ⅰ> 2s(Ⅰ)for the CP 1. The CP 1 possesses a 2D {63} layer structure which is composed of Cu(Ⅰ) centers bridged by L and CN– ligands. The thermal stability and luminescence properties of CP 1 are discussed in detail. The complex also displays a remarkable activity for the degradation of methyl orange by hydrogen peroxide in a Fenton-like process. 展开更多
关键词 Cu(Ⅰ) coordination polymer crystal structure CATALYTIC PROPERTY in situ reaction luminescence PROPERTY
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聚脲甲醛-生物油微胶囊的研制及性能探究
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作者 杨耸 朱洪洲 +1 位作者 高俊锋 谭祺琦 《科学技术与工程》 北大核心 2024年第16期6907-6915,共9页
为研究微胶囊对沥青路面微裂纹的愈合效果,首先利用聚脲甲醛(作为微胶囊壁)和生物油(作为微胶囊心)采用原位聚合法制备微胶囊,采用扫描/透射电子显微镜和热重分析探究微胶囊的外观形貌和热稳定性;然后将微胶囊用于制备微胶囊/苯乙烯-丁... 为研究微胶囊对沥青路面微裂纹的愈合效果,首先利用聚脲甲醛(作为微胶囊壁)和生物油(作为微胶囊心)采用原位聚合法制备微胶囊,采用扫描/透射电子显微镜和热重分析探究微胶囊的外观形貌和热稳定性;然后将微胶囊用于制备微胶囊/苯乙烯-丁二烯-苯乙烯(styrene-butadiene-styrene, SBS)复合改性沥青,通过动态剪切流变仪和离析试验探究微胶囊的掺加对复合改性沥青路面性能的影响;最后通过延度愈合率试验验证微胶囊的愈合效果,并结合宏微观试验分析其愈合机理。结果表明:微胶囊呈现类球状,且表面较为粗糙,增大了与沥青的接触面积。微胶囊的热稳定性较好,其囊壁可承受沥青混合料生产过程中的高温环境。随着微胶囊的添加,复合改性沥青的低温塑性和耐热性均有所改善。此外,复合改性沥青的储能模量和损失模量也有所提升,即微胶囊的添加提升了SBS改性沥青的黏弹性能,这可能是由于添加的微胶囊与SBS和基质沥青具有很好的相容性,且微胶囊均匀分散在沥青内部并嵌入SBS呈现的网状结构中,这也在离析试验和荧光显微试验中得以证实。当微胶囊的掺量为0.4%时,复合改性沥青的愈合率达到最高。 展开更多
关键词 道路工程 沥青愈合率 原位聚合法 自愈合微胶囊 黏弹性能
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