Bismuth selenide(Bi_(2)Se_(3))is an attractive visible-light-responsive semiconductor that can absorb a full range of visible and near-infrared light.However,its poor redox capacity and rapid carrier recombination lim...Bismuth selenide(Bi_(2)Se_(3))is an attractive visible-light-responsive semiconductor that can absorb a full range of visible and near-infrared light.However,its poor redox capacity and rapid carrier recombination limit its application in photocatalytic oxidation.In this study,we adopted Bi_(2)Se_(3)as the couple part of graphitic carbon nitride(g-C_(3)N_(4))to construct a Bi_(2)Se_(3)/g-C_(3)N_(4)composite photocatalyst.Through in situ fabrication,the self-developed Bi2O3/g-C_(3)N_(4)precursor was transformed into a Bi_(2)Se_(3)/g-C_(3)N_(4)heterojunction.The as-prepared Bi_(2)Se_(3)/g-C_(3)N_(4)composite exhibited much higher visible-light-driven photocatalytic activity than pristine Bi_(2)Se_(3)and g-C_(3)N_(4)in the removal of phenol.The enhanced photocatalytic activity was ascribed to the S-scheme configuration of Bi_(2)Se_(3)/g-C_(3)N_(4);this was confirmed by the energy-level shift,photoluminescence analysis,computational structure study,and reactive-radical testing.In the S-scheme heterojunction,photo-excited electrons in the conduction band of g-C_(3)N_(4)migrate to the valence band of Bi_(2)Se_(3)and combine with the excited holes therein.By consuming less reactive carriers,the S-scheme heterojunction can not only effectively promote charge separation,but also preserve more reactive photo-generated carriers.This property enhances the photocatalytic activity.展开更多
Ordered ZnS semiconductor nanoparticles were in situ synthesized in metal halide perovskite organic/inorganic layered hybrids (CnH2n+1NH3)2ZnCl4 (n=10 and 12) by reaction of their spin-casting films with H2S gas. Tra...Ordered ZnS semiconductor nanoparticles were in situ synthesized in metal halide perovskite organic/inorganic layered hybrids (CnH2n+1NH3)2ZnCl4 (n=10 and 12) by reaction of their spin-casting films with H2S gas. Transmission electron microscopy, UV-vis spectroscopy and small-angle X-ray diffraction were used to characterize the morphology and the structure of formed nanoparticles. Obtained results indicate an effective way to incorporate functional inorganic nanoparticles into structured organic matrices.展开更多
There is an urgent need for novel processes that can integrate different functional nanostructures onto specific substrates,so as to meet the fast-growing need for broad applications in nanoelectronics,nanophotonics,a...There is an urgent need for novel processes that can integrate different functional nanostructures onto specific substrates,so as to meet the fast-growing need for broad applications in nanoelectronics,nanophotonics,and fexible optoelectronics.Existing direct-lithography methods are difficult to use on fexible,nonplanar,and biocompatible surfaces.Therefore,this fabrication is usually accomplished by nanotransfer printing.However,large-scale integration of multiscale nanostructures with unconventional substrates remains challenging because fabrication yields and quality are often limited by the resolution,uniformity,adhesivity,and integrity of the nanostructures formed by direct transfer.Here,we proposed a resist-based transfer strategy enabled by near-zero adhesion,which was achieved by molecular modification to attain a critical surface energy interval.This approach enabled the intact transfer of wafer-scale,ultrathin-resist nanofilms onto arbitrary substrates with mitigated cracking and wrinkling,thereby facilitating the in situ fabrication of nanostructures for functional devices.Applying this approach,fabrication of three-dimensional-stacked multilayer structures with enhanced functionalities,nanoplasmonic structures with~10 nm resolution,and MoS2-based devices with excellent performance was demonstrated on specific substrates.These results collectively demonstrated the high stability,reliability,and throughput of our strategy for optical and electronic device applications.展开更多
Quantum dots color conversion(QDCC)is considered as a facial and versatile way to achieve full-color organic light emitting diode(OLED)and micro-LED display due to the wide color gamut performance and easy integration...Quantum dots color conversion(QDCC)is considered as a facial and versatile way to achieve full-color organic light emitting diode(OLED)and micro-LED display due to the wide color gamut performance and easy integration.However,the aggregation of QDs and coffee-ring effects after solvent evaporation lowers the light conversion efficiency and emission uniformity in QDs microarrays,raising blue-light leakage or optical crosstalk.Here,we report the fabrication of perovskite quantum dots(PQDs)microarrays by combining the inkjet printing and in situ fabrication of PQDs during the photopolymerization of precursor ink.The resulting PQDs microarrays exhibit three-dimensional(3D)morphology with hemisphere shape as well as strong photoluminescence,which is desirable for QDCC applications.We demonstrate the dominant role of ultraviolet(UV)curable precursors and surface functionalized substrate in controlling the shape of microarrays,where significantly increased contact angle(100°)and large height to diameter ratio(0.42)can be achieved.We further demonstrate the potential use of the in situ direct print photopolymerization method for fabricating large-area multicolor patterned pixel microarrays with a wide color gamut and high resolution.The fabrication of 3D PQDs microarrays opens up new opportunities in a variety of applications including photonics integration,micro-LED,and near-field display.展开更多
A multi-dimensional conductive heterojunction structure,composited by TiO2,SnO2,and Ti3C2TX MXene,is facilely designed and applied as electron transport layer in efficient and stable planar perovskite solar cells.Base...A multi-dimensional conductive heterojunction structure,composited by TiO2,SnO2,and Ti3C2TX MXene,is facilely designed and applied as electron transport layer in efficient and stable planar perovskite solar cells.Based on an oxygen vacancy scramble effect,the zero-dimensional anatase TiO2 quantum dots,surrounding on two-dimensional conductive Ti3C2TX sheets,are in situ rooted on three-dimensional SnO2 nanoparticles,constructing nanoscale TiO2/SnO2 heterojunctions.The fabrication is implemented in a controlled lowtemperature anneal method in air and then in N2 atmospheres.With the optimal MXene content,the optical property,the crystallinity of perovskite layer,and internal interfaces are all facilitated,contributing more amount of carrier with effective and rapid transferring in device.The champion power conversion efficiency of resultant perovskite solar cells achieves 19.14%,yet that of counterpart is just 16.83%.In addition,it can also maintain almost 85%of its initial performance for more than 45 days in 30–40%humidity air;comparatively,the counterpart declines to just below 75%of its initial performance.展开更多
文摘Bismuth selenide(Bi_(2)Se_(3))is an attractive visible-light-responsive semiconductor that can absorb a full range of visible and near-infrared light.However,its poor redox capacity and rapid carrier recombination limit its application in photocatalytic oxidation.In this study,we adopted Bi_(2)Se_(3)as the couple part of graphitic carbon nitride(g-C_(3)N_(4))to construct a Bi_(2)Se_(3)/g-C_(3)N_(4)composite photocatalyst.Through in situ fabrication,the self-developed Bi2O3/g-C_(3)N_(4)precursor was transformed into a Bi_(2)Se_(3)/g-C_(3)N_(4)heterojunction.The as-prepared Bi_(2)Se_(3)/g-C_(3)N_(4)composite exhibited much higher visible-light-driven photocatalytic activity than pristine Bi_(2)Se_(3)and g-C_(3)N_(4)in the removal of phenol.The enhanced photocatalytic activity was ascribed to the S-scheme configuration of Bi_(2)Se_(3)/g-C_(3)N_(4);this was confirmed by the energy-level shift,photoluminescence analysis,computational structure study,and reactive-radical testing.In the S-scheme heterojunction,photo-excited electrons in the conduction band of g-C_(3)N_(4)migrate to the valence band of Bi_(2)Se_(3)and combine with the excited holes therein.By consuming less reactive carriers,the S-scheme heterojunction can not only effectively promote charge separation,but also preserve more reactive photo-generated carriers.This property enhances the photocatalytic activity.
文摘Ordered ZnS semiconductor nanoparticles were in situ synthesized in metal halide perovskite organic/inorganic layered hybrids (CnH2n+1NH3)2ZnCl4 (n=10 and 12) by reaction of their spin-casting films with H2S gas. Transmission electron microscopy, UV-vis spectroscopy and small-angle X-ray diffraction were used to characterize the morphology and the structure of formed nanoparticles. Obtained results indicate an effective way to incorporate functional inorganic nanoparticles into structured organic matrices.
基金supported by the National Key Research and Development Program of China(No.2022YFB4602600)the National Natural Science Foundation of China(No.52221001)Hunan Provincial Innovation Foundation for Postgraduate(No.CX20220406)。
文摘There is an urgent need for novel processes that can integrate different functional nanostructures onto specific substrates,so as to meet the fast-growing need for broad applications in nanoelectronics,nanophotonics,and fexible optoelectronics.Existing direct-lithography methods are difficult to use on fexible,nonplanar,and biocompatible surfaces.Therefore,this fabrication is usually accomplished by nanotransfer printing.However,large-scale integration of multiscale nanostructures with unconventional substrates remains challenging because fabrication yields and quality are often limited by the resolution,uniformity,adhesivity,and integrity of the nanostructures formed by direct transfer.Here,we proposed a resist-based transfer strategy enabled by near-zero adhesion,which was achieved by molecular modification to attain a critical surface energy interval.This approach enabled the intact transfer of wafer-scale,ultrathin-resist nanofilms onto arbitrary substrates with mitigated cracking and wrinkling,thereby facilitating the in situ fabrication of nanostructures for functional devices.Applying this approach,fabrication of three-dimensional-stacked multilayer structures with enhanced functionalities,nanoplasmonic structures with~10 nm resolution,and MoS2-based devices with excellent performance was demonstrated on specific substrates.These results collectively demonstrated the high stability,reliability,and throughput of our strategy for optical and electronic device applications.
基金the National Key Research and Development Program of China(No.2020YFB2009303)the National Natural Science Foundation of China(Nos.62105025 and 61935001)Beijing Institute of Technology Research Fund Program for Young Scholars(No.3040011182113)。
文摘Quantum dots color conversion(QDCC)is considered as a facial and versatile way to achieve full-color organic light emitting diode(OLED)and micro-LED display due to the wide color gamut performance and easy integration.However,the aggregation of QDs and coffee-ring effects after solvent evaporation lowers the light conversion efficiency and emission uniformity in QDs microarrays,raising blue-light leakage or optical crosstalk.Here,we report the fabrication of perovskite quantum dots(PQDs)microarrays by combining the inkjet printing and in situ fabrication of PQDs during the photopolymerization of precursor ink.The resulting PQDs microarrays exhibit three-dimensional(3D)morphology with hemisphere shape as well as strong photoluminescence,which is desirable for QDCC applications.We demonstrate the dominant role of ultraviolet(UV)curable precursors and surface functionalized substrate in controlling the shape of microarrays,where significantly increased contact angle(100°)and large height to diameter ratio(0.42)can be achieved.We further demonstrate the potential use of the in situ direct print photopolymerization method for fabricating large-area multicolor patterned pixel microarrays with a wide color gamut and high resolution.The fabrication of 3D PQDs microarrays opens up new opportunities in a variety of applications including photonics integration,micro-LED,and near-field display.
基金supported by the Science & Technology Project of Anhui Province (16030701091)the Natural Science Research Project of Anhui Provincial Education Department (KJ2019A0030)+2 种基金the Support Project of Outstanding Young Talents in Anhui Provincial Universities (gxyqZD2018006)the National Natural Science Foundation of China(11704002, 31701323)the Anhui Provincial Natural Science Foundation (1908085QF251,1808085MF185)
文摘A multi-dimensional conductive heterojunction structure,composited by TiO2,SnO2,and Ti3C2TX MXene,is facilely designed and applied as electron transport layer in efficient and stable planar perovskite solar cells.Based on an oxygen vacancy scramble effect,the zero-dimensional anatase TiO2 quantum dots,surrounding on two-dimensional conductive Ti3C2TX sheets,are in situ rooted on three-dimensional SnO2 nanoparticles,constructing nanoscale TiO2/SnO2 heterojunctions.The fabrication is implemented in a controlled lowtemperature anneal method in air and then in N2 atmospheres.With the optimal MXene content,the optical property,the crystallinity of perovskite layer,and internal interfaces are all facilitated,contributing more amount of carrier with effective and rapid transferring in device.The champion power conversion efficiency of resultant perovskite solar cells achieves 19.14%,yet that of counterpart is just 16.83%.In addition,it can also maintain almost 85%of its initial performance for more than 45 days in 30–40%humidity air;comparatively,the counterpart declines to just below 75%of its initial performance.