Assessing mixing uniformity in microreactors via in-line spectroscopy

Mixing behavior is critical for enhancing the selectivity of fast chemical reactions in microreactors.A high Reynolds number(Re)improves the mixing rate and selectivity of the reactions,but some exceptions of increasing side product yield with the higher Re have been reported.This study investigated the mixing uniformity in microreactors with in-line UV-vis spectroscopy to clarify the relationship between reaction selectivity and chaotic mixing with the higher Re.A colorization experiment of thymolphthalein in an acidic solution was conducted with an excess acid amount to the base to indicate a non-uniformly mixed region.Non-uniformity significantly increased with Re.At the same time,the degree of mixing,which was measured by a usual decolorization experiment,showed that the mixing rate increased with Re.The in-line analysis of the Villermaux-Dushman reaction during the mixing clarified that side product yield significantly increased with Re at around 300 and then decreased at around 1100.These results suggest the compensation effect between the mixing uniformity and mixing rate on the selectivity of the mixing-sensitive reactions.Faster mixing,characterized by a larger Re,can disturb mixing uniformity and,in some cases,decrease reaction selectivity.

Iterative projection meets sparsity regularization:towards practical single-shot quantitative phase imaging with in-line holography

Holography provides access to the optical phase.The emerging compressive phase retrieval approach can achieve in-line holographic imaging beyond the information-theoretic limit or even from a single shot by exploring the signal priors.However,iterative projection methods based on physical knowledge of the wavefield suffer from poor imaging quality,whereas the regularization techniques sacrifice robustness for fidelity.In this work,we present a unified compressive phase retrieval framework for in-line holography that encapsulates the unique advantages of both physical constraints and sparsity priors.In particular,a constrained complex total variation(CCTV)regularizer is introduced that explores the well-known absorption and support constraints together with sparsity in the gradient domain,enabling practical high-quality in-line holographic imaging from a single intensity image.We developed efficient solvers based on the proximal gradient method for the non-smooth regularized inverse problem and the corresponding denoising subproblem.Theoretical analyses further guarantee the convergence of the algorithms with prespecified parameters,obviating the need for manual parameter tuning.As both simulated and optical experiments demonstrate,the proposed CCTV model can characterize complex natural scenes while utilizing physically tractable constraints for quality enhancement.This new compressive phase retrieval approach can be extended,with minor adjustments,to various imaging configurations,sparsifying operators,and physical knowledge.It may cast new light on both theoretical and empirical studies.

Terahertz synthetic aperture in-line holography with intensity correction and sparsity autofocusing reconstruction

We demonstrate high-resolution and high-quality terahertz(THz)in-line digital holography based on the synthetic aperture method.The setup is built on a self-developed THz quantum cascade laser,and a lateral resolution better than 70μm(~λ)is achieved at 4.3 THz.To correct intensity differences between sub-holograms before aperture stitching,a practical algorithm with global optimization is proposed.To address the twin-image problem for in-line holography,a sparsity-based phase retrieval algorithm is applied to perform the high-quality reconstruction.Furthermore,a new autofocusing criterion termed"reconstruction objective function"is introduced to obtain the best in-focus reconstruction distance,so the autofocusing procedure and the reconstruction are unified within the same framework.Both simulation and experiment prove its accuracy and robustness.Note that all the methods proposed here can be applied to other wavebands as well.We demonstrate the success of this THz synthetic aperture in-line holography on biological and semiconductor samples,showing its potential applications in bioimaging and materials analysis.

Phase retrieval from double axially displaced holograms for dual-wavelength in-line holography

A phase retrieval method for dual-wavelength in-line digital holography is presented with double axially displaced holograms.A synthetic wavelength is used during iterative propagations to retrieve wrap-free phase distributions with a much extended measurement range.The simulation and experimental results demonstrate a better elimination of the twin image,a faster rate of convergence of the iterative routine and less number of wavelengths are compared with previously reported multiple-wavelength in-line holography.

Bessel–Gaussian beam-based orbital angular momentum holography

Orbital angular momentum(OAM), as a new degree of freedom, has recently been applied in holography technology.Due to the infinite helical mode index of OAM mode, a large number of holographic images can be reconstructed from an OAM-multiplexing hologram. However, the traditional design of an OAM hologram is constrained by the helical mode index of the selected OAM mode, for a larger helical mode index OAM mode has a bigger sampling distance, and the crosstalk is produced for different sampling distances for different OAM modes. In this paper, we present the design of the OAM hologram based on a Bessel–Gaussian beam, which is non-diffractive and has a self-healing property during its propagation. The Fourier transform of the Bessel–Gaussian beam is the perfect vortex mode that has the fixed ring radius for different OAM modes. The results of simulation and experiment have demonstrated the feasibility of the generation of the OAM hologram with the Bessel–Gaussian beam. The quality of the reconstructed holographic image is increased, and the security is enhanced. Additionally, the anti-interference property is improved owing to its self-healing property of the Bessel-OAM holography.

Tailoring electron vortex beams with customizable intensity patterns by electron diffraction holography

An electron vortex beam(EVB) carrying orbital angular momentum(OAM) plays a key role in a series of fundamental scientific researches, such as chiral energy-loss spectroscopy and magnetic dichroism spectroscopy. So far, almost all the experimentally created EVBs manifest isotropic doughnut intensity patterns. Here, based on the correlation between local divergence angle of electron beam and phase gradient along azimuthal direction, we show that free electrons can be tailored to EVBs with customizable intensity patterns independent of the carried OAM. As proof-of-concept, by using computer generated hologram and designing phase masks to shape the incident free electrons in the transmission electron microscope, three structured EVBs carrying identical OAM are tailored to exhibit completely different intensity patterns. Furthermore, through the modal decomposition, we quantitatively investigate their OAM spectral distributions and reveal that structured EVBs present a superposition of a series of different eigenstates induced by the locally varied geometries. These results not only generalize the concept of EVB, but also demonstrate an extra highly controllable degree of freedom for electron beam manipulation in addition to OAM.

A holographic optical communication system based on RSA algorithm and quaternion function

A facile encryption way was successfully applied to the holographic optical encryption system with high speed,multidimensionality,and high capacity,which provided a better security solution for underwater communication.The reconstructed optical security system for information transmission was based on wavelengthλand focal length f that were keys to encryption and decryption.To finish the secure data transmission(λ,f)between sender and receiver,an extended Rivest-Shamir-Adleman(ERSA)algorithm for the encryption was achieved based on three-dimension quaternion function.Therein,the Pollard’s rho method was used for the evaluation and comparison of RSA and ERSA algorithms.The results demonstrate that the message encrypted by the ERSA algorithm has better security than that by RSA algorithm in the face of unpredictability and complexity of information transmission on the unsecure acoustic channel.

用Michelson光路结构实现IN-LINE数字全息实验

文献[1]介绍了用CCD作为探测接收装置记录了离轴全息图,利用抽样理论和数字处理技术再现了物体的实像.利用上述原理设计了一种方法实现同轴全息图的记录和再现.

The prediction on in-line vortex-induced vibration of slender marine structures

The in-line （IL） vortex-induced vibration （VIV） that occurs frequently in ocean engineering may cause severe fatigue damage in slender marine structures. To the best knowledge of the authors, in existing literatures, there is no efficient analytical model for predicting pure IL VIV. In this paper, a wake oscillator model capable of analyzing the IL VIV of slender marine structures has been developed. Two different kinds of van der Pol equations are used to describe the near wake dynamics related to the fluctuating nature of symmetric vortex shedding in the first excitation region and alternate vortex shedding in the second one. Some comparisons are carried out between the present model results and experimental data. It is found that many phenomena observed in experiments could be reproduced by the present wake oscillator model.

Experimental Study on Coupled Cross-Flow and in-Line Vortex-Induced Vibration of Flexible Risers

In this work, we study the coupled cross-flow and in-line vortex-induced vibration （VIV） of a fixedly mounted flexible pipe, which is free to move in cross-flow （ Y- ） and in-line （ X- ） direction in a fluid flow where the mass and natural frequencies are precisely the same in both X- and Y-direction. The fluid speed varies from low to high with the corresponding vortex shedding frequency varying from below the first natural frequency to above the second natural frequency of the flexible pipe. Particular emphasis was placed on the investigation of the relationship between in-line and cross-flow vibration. The experimental results analyzed by using these measurements exhibits several valuable features.

Ultrafiltration with in-line coagulation for the removal of natural humic acid and membrane fouling mechanism

Experimental and theoretical analysis were made on the natural humic acid removal and the membrane fouling of ultrafiltration （UF） with in-line coagulation. The results showed dissolved organic carbon （DOC） and UV254 removals by the UF with in-line coagulation at pH 7 were increased from 28% to 53% and 40% to 78% in comparison with direct UF treatment respectively. At the same time, the analysis of high performance liquid chromatography showed that UF with coagulation had significant improvement of removal of humic acid with molecular weights less than 6000 Da in particular. Compared to direct UF, the in-line coagulation UF also kept more constant permeate flux and very slight increase oftransmembrane pressure during a filtration circle. Two typical membrane fouling models were used by inducing two coefficients Kc and Kp corresponding to cake filtration model and pore narrowing model respectively. It was found that membrane fouling by pore-narrowing effect was effectively alleviated and that by cake-filtration was much decreased by in-line coagulation. Under the condition of coagulation prior to ultrafiltration at pH 7, the cake layer formed on the membrane surface became thicker, but the membrane filtration resistance was lower than that at pH 5 with the extension of operation time.

In-line response of vertical cylinders in regular and random waves

The in-line response of a vertical flexibly mounted cylinder in regular and random waves is reported. Both theoretical analyses and experimental measurements have been performed. The theoretical predictions are based on the Morison equation which is solved by the incremental harmonic balance method. Experiments are then performed in a wave flume to determine the accuracy of the Morison equation in predicting the in-line response of the cylinder in regular and random waves. The interaction between waves and vibrating cylinders are investigated.

Three-axis magnetic flux leakage in-line inspection simulation based on finite-element analysis

With the increase of pipelines, corrosion leakage accidents happen frequently. Therefore, nondestructive testing technology is important for ensuring the safe operation of the pipelines and energy mining. In this paper, the structure and principle of magnetic flux leakage （MFL） in-line inspection system is introduced first. Besides, a mathematic model of the system according to the ampere circuit rule, flux continuity theorem, and column coordinate transform is built, and the magnetic flux density in every point of space is calculated based on the theory of finite element analysis. Then we analyze and design the disposition of measurement section probes and sensors combining both three-axis MFL in-line inspection and multi-sensor fusion technology. Its advantage is that the three-axis changes of magnetic flux leakage field are measured by the multi-probes at the same time, so we can determine various defects accurately. Finally, the theory of finite element analysis is used to build a finite element simulation model, and the relationship between defects and MFL inspection signals is studied. Simulation and experiment results verify that the method not only enhances the detection ability to different types of defects but also improves the precision and reliability of the inspection system.

Nonlinear Coupled in-Line and Cross-Flow Vortex-Induced Vibration Analysis of Top Tensioned Riser

The fluctuating furces of the fluid exerted on the top terrsioned riser （＇FIR） in the in-line and cross-flow directions are both modeled by van del Pol wake oscillator model and the nonlinear coupled dynamics of the in-line and cross-flow vortex-induced vibrations （VIV） of the riser are analyzed in time domain in this papar. The numencal shnulation results of the riser＇s in-line and cross-flow displacements and curvatures are compared with experimental measurements and the comparison shows the validity of this method in modeling some main features of the riser＇s VIV. Finally, the effects of the riser＇s top tensions and internal flow velocities on the coupled vibrations of the riser are investigated.

Anisotropic total variation minimization approach in in-line phase-contrast tomography and its application to correction of ring artifacts

In-line phase-contrast computed tomography（IL-PC-CT） imaging is a new physical and biochemical imaging method.IL-PC-CT has advantages compared to absorption CT when imaging soft tissues. In practical applications, ring artifacts which will reduce the image quality are commonly encountered in IL-PC-CT, and numerous correction methods exist to either pre-process the sinogram or post-process the reconstructed image. In this study, we develop an IL-PC-CT reconstruction method based on anisotropic total variation（TV） minimization. Using this method, the ring artifacts are corrected during the reconstruction process. This method is compared with two methods： a sinogram preprocessing correction technique based on wavelet-FFT filter and a reconstruction method based on isotropic TV. The correction results show that the proposed method can reduce visible ring artifacts while preserving the liver section details for real liver section synchrotron data.

Determination of inorganic anions in ethyl acetate by in-line hollow fiber membrane extraction with ion chromatography

In this work, a novel hollow fiber membrane extractor was set up to extract inorganic anions from ethyl acetate using deionized water. Inorganic anions in slightly soluble organic solvents can be determined by the in-line hollow fiber membrane extractor coupled with ion chromatography at first time. Different aspects of the extraction procedure such as magnetic stirring speed, extraction flow rate and extraction time were optimized to achieve high extraction efficiency and good separation results. Satisfactory linear range, limits of detection and good repeatability were obtained. The procedure was applied to analyze inorganic anions in two commercial ethyl acetate samples.

Time-sequential color code division multiplexing holographic display with metasurface

Color metasurface holograms are powerful and versatile platforms for modulating the amplitude,phase,polarization,and other properties of light at multiple operating wavelengths.However,the current color metasurface holography can only realize static manipulation.In this study,we propose and demonstrate a multiplexing metasurface technique combined with multiwavelength code-division multiplexing(CDM)to realize dynamic manipulation.Multicolor code references are utilized to record information within a single metasurface and increase the information capacity and security for anticracks.A total of 48 monochrome images consisting of pure color characters and multilevel color video frames were reconstructed in dual polarization channels of the birefringent metasurface to exhibit high information density,and a video was displayed via sequential illumination of the corresponding code patterns to verify the ability of dynamic manipulation.Our approach demonstrates significant application potential in optical data storage,optical encryption,multiwavelengthversatile diffractive optical elements,and stimulated emission depletion microscopy.

4K-DMDNet:diffraction model-driven network for 4K computer-generated holography

Deep learning offers a novel opportunity to achieve both high-quality and high-speed computer-generated holography(CGH).Current data-driven deep learning algorithms face the challenge that the labeled training datasets limit the training performance and generalization.The model-driven deep learning introduces the diffraction model into the neural network.It eliminates the need for the labeled training dataset and has been extensively applied to hologram generation.However,the existing model-driven deep learning algorithms face the problem of insufficient constraints.In this study,we propose a model-driven neural network capable of high-fidelity 4K computer-generated hologram generation,called 4K Diffraction Model-driven Network(4K-DMDNet).The constraint of the reconstructed images in the frequency domain is strengthened.And a network structure that combines the residual method and sub-pixel convolution method is built,which effectively enhances the fitting ability of the network for inverse problems.The generalization of the 4K-DMDNet is demonstrated with binary,grayscale and 3D images.High-quality full-color optical reconstructions of the 4K holograms have been achieved at the wavelengths of 450 nm,520 nm,and 638 nm.

Direct field-to-pattern monolithic design of holographic metasurface via residual encoderdecoder convolutional neural network

Complex-amplitude holographic metasurfaces(CAHMs)with the flexibility in modulating phase and amplitude profiles have been used to manipulate the propagation of wavefront with an unprecedented level,leading to higher image-reconstruction quality compared with their natural counterparts.However,prevailing design methods of CAHMs are based on Huygens-Fresnel theory,meta-atom optimization,numerical simulation and experimental verification,which results in a consumption of computing resources.Here,we applied residual encoder-decoder convolutional neural network to directly map the electric field distributions and input images for monolithic metasurface design.A pretrained network is firstly trained by the electric field distributions calculated by diffraction theory,which is subsequently migrated as transfer learning framework to map the simulated electric field distributions and input images.The training results show that the normalized mean pixel error is about 3%on dataset.As verification,the metasurface prototypes are fabricated,simulated and measured.The reconstructed electric field of reverse-engineered metasurface exhibits high similarity to the target electric field,which demonstrates the effectiveness of our design.Encouragingly,this work provides a monolithic field-to-pattern design method for CAHMs,which paves a new route for the direct reconstruction of metasurfaces.

STUDY ON AUTOMATIC IN-LINE MEASUREMENT OF FeO CONTENT IN AGGLOMERATE

In this paper, the mechanism of physical method for measuring the FeO content in agglomerate replacing the chemical method is proposed after studying the electromagnetic property of the agglomerate. The microcomputer-measuring system for FeO content is provided. Attention is also paid to introducing the working principle of the H-type compensation sensor and the processing method of the measured data. This system has been successfully applied in practice to in-line measure the FeO content.