Water is essential to life and to the sustainable socio-economic development of a nation, It is therefore interesting to have a better knowledge of the quality of this water. The aim was to determine the degree of mic...Water is essential to life and to the sustainable socio-economic development of a nation, It is therefore interesting to have a better knowledge of the quality of this water. The aim was to determine the degree of microbiological and physico-chemical pollution of the water of the “Mamouwol” river in the town of Mamou. To do this, we chose four (4) sampling sites spread throughout the town of Mamou. During the month of March (2024), 4 water samples were analyzed to monitor the water quality of this river. The average values of the flora analyzed show that these water are heavily contaminated with bacteria indicative of fecal and metal pollution. This study showed that sites: Mam4;Mam2 and Mam1 contain the highest loads, with Total Coliform counts ranging from 1534 CFU/100 ml to 2100 CFU/100 ml, the number of faecal coliforms varies between 526 and 1240 CFU/100 ml, and that of faecal streptococci between 526 and 841 CFU/100 ml. Metal content, BOD5 and COD all comply with the laboratory’s analysis criteria, although they vary from point to point.展开更多
Oil spills continue to generate various issues and concerns regarding their effect and behavior in the marine environment,owing to the related potential for detrimental environmental,economic and social implications.I...Oil spills continue to generate various issues and concerns regarding their effect and behavior in the marine environment,owing to the related potential for detrimental environmental,economic and social implications.It is essential to have a solid understanding of the ways in which oil interacts with the water and the coastal ecosystems that are located nearby.This study proposes a simplified model for predicting the plume-like transport behavior of heavy Bunker C fuel oil discharging downward from an acutely-angled broken pipeline located on the water surface.The results show that the spill overall profile is articulated in three major flow areas.The first,is the source field,i.e.,a region near the origin of the initial jet,followed by the intermediate or transport field,namely,the region where the jet oil flow transitions into an underwater oil plume flow and starts to move horizontally,and finally,the far-field,where the oil re-surface and spreads onto the shore at a significant distance from the spill site.The behavior of the oil in the intermediate field is investigated using a simplified injection-type oil spill model capable of mimicking the undersea trapping and lateral migration of an oil plume originating from a negatively buoyant jet spill.A rectangular domain with proper boundary conditions is used to implement the model.The Projection approach is used to discretize a modified version of the Navier-Stokes equations in two dimensions.A benchmark fluid flow issue is used to verify the model and the results indicate a reasonable relationship between specific gravity and depth as well as agreement with the aerial data and a vertical temperature profile plot.展开更多
To better understand the community patterns mediated by connectivity in artificial reefs of coastal areas, it is necessary to understand the distribution and coexistence of organisms with artificial reefs area and adj...To better understand the community patterns mediated by connectivity in artificial reefs of coastal areas, it is necessary to understand the distribution and coexistence of organisms with artificial reefs area and adjacent waters. This study was conducted to examine main catches assemblages collected by trawls in Haizhou Bay,which included five habitats: the artificial reef area(AR), aquaculture area(AA), natural area(NA), estuary area(EA) and comprehensive effect area(CEA). The result shows that the total abundances of species in the five habitats were highly different(univariate PERMANOVA: P = 0.001, n = 24), but some species were also unique in their habitat(e.g. Scapharca subcrenata and Glossaulax didyma in AA). The body size distribution of specific species between habitats are different. For Collichthys lucidus, their body size in AR(14.63 cm ± 1.64 cm) and EA(14.3 cm ± 0.85 cm) is higher than that in NA(10.65 cm ± 1.64 cm), CEA(11.28 cm ± 1.85 cm) and AA(12.1 cm ±0.43 cm), which indicates the potential connection from AR to EA mediated by their adult population. We concluded that artificial reefs in AR can be considered key components that have the ability to support species assemblages in adjacent habitats. This study has implications for the conservation and monitoring of species assemblages in coastal areas in terms of that artificial reefs can be applied in different stages of habitat protection implementation and in different combinations of scenarios.展开更多
The degradation of micropollutants in water via ultraviolet(UV)-based advanced oxidation processes(AOPs)is strongly dependent on the water matrix.Various reactive radicals(RRs)formed in UV-AOPs have different reaction...The degradation of micropollutants in water via ultraviolet(UV)-based advanced oxidation processes(AOPs)is strongly dependent on the water matrix.Various reactive radicals(RRs)formed in UV-AOPs have different reaction selectivities toward water matrices and degradation efficiencies for target micropollutants.Hence,process selection and optimization are crucial.This study developed a facilitated prediction method for the photon fluence-based rate constant for micropollutant degradation(K′_(p,MP))in various UV-AOPs by combining model simulation with portable measurement.Portable methods for measuring the scavenging capacities of the principal RRs(RRSCs)involved in UV-AOPs(i.e.,HO^(·),SO_(4)^(·-),and Cl^(·))using a mini-fluidic photoreaction system were proposed.The simulation models consisted of photochemical,quantitative structure–activity relationship,and radical concentration steady-state approximation models.The RRSCs were determined in eight test waters,and a higher RRSC was found to be associated with a more complex water matrix.Then,by taking sulfamethazine,caffeine,and carbamazepine as model micropollutants,the k′_(p,MP) values in various UV-AOPs were predicted and further verified experimentally.A lower k′_(p,MP) was found to be associated with a higher RRSC for a stronger RR competition;for example,k′_(p,MP) values of 130.9 and 332.5 m^(2) einstein^(–1),respectively,were obtained for carbamazepine degradation by UV/H_(2)O_(2) in the raw water(RRSC=9.47×10^(4) s^(-1))and sand-filtered effluent(RRSC=2.87×10^(4) s^(-1))of a drinking water treatment plant.The developed method facilitates process selection and optimization for UV-AOPs,which is essential for increasing the efficiency and cost-effectiveness of water treatment.展开更多
Sairme mineral water, one of the famous mineral waters in Georgia, is renowned for its exceptional healing properties. The distinctiveness and therapeutic benefits of the naturally sourced mineral water, known as “Sa...Sairme mineral water, one of the famous mineral waters in Georgia, is renowned for its exceptional healing properties. The distinctiveness and therapeutic benefits of the naturally sourced mineral water, known as “Sairme”, stem from its rich array of microelements, notably including iron and manganese. Since 1948, the bottling of Sairme mineral water has been a prominent activity. Named after the Sairme deposit, this mineral water is packaged in various formats to cater to diverse consumer preferences. The bottling process involves transporting the mineral water from wells to the bottling plant through pipelines. Prior to bottling, the mineral water undergoes meticulous processing stages in adherence to current Georgian and international regulations. This process ensures that the concentration of trace elements in the bottled water is minimized, maintaining its purity and quality. Given the importance of preserving the microelements present in bottled mineral water, our research is dedicated to optimizing the technological process. Our objective is to safeguard the valuable microelements while ensuring the highest standards of quality and safety in the final product.展开更多
The study carried out on the waters of the Méné River led to an overall assessment of its water quality during the dry season and the rainy season. The analysis focused on eight (8) water samples taken from ...The study carried out on the waters of the Méné River led to an overall assessment of its water quality during the dry season and the rainy season. The analysis focused on eight (8) water samples taken from the river during a period of dry season (January-February) and a period of rainy season (June and September). The various physicochemical parameters were measured according to Afnor standardized methods. The readings of temperature, turbidity, pH and conductivity made it possible to account for the disturbances occurring in water quality. A temporal variation correlated with the seasons (dry or rainy) is noted. Turbidity depends on the concentration of suspended solids (SS) in the water and drained particles and therefore on the seasons. Just like the temperature, the conductivity changes with the season. The waters of the Méné River are generally acidic. The results obtained show that there is a low level of pollution by chlorides, phosphates, nitrites and nitrates. A slight pollution of the waters of Méné in organic matter (chemical oxygen demand values are less than 25 mg∙L−1 during dry season and 32.33 ± 4.73 mg∙L−1 during rainy season) was observed. The concentrations of metallic trace elements such as iron, manganese and aluminum indicate significant pollution of these waters by these elements. Overall, the waters of the Méné River are of satisfactory quality because all the physicochemical parameters analyzed have values below standards during the dry season as well as during the rainy season with the exception of COD and a few metallic trace elements.展开更多
This study aims to analyze the spatio-temporal variability of the characteristics of water resources in the Diani watershed,located in the southeast of the Republic of Guinea.The objective is to assess the availabilit...This study aims to analyze the spatio-temporal variability of the characteristics of water resources in the Diani watershed,located in the southeast of the Republic of Guinea.The objective is to assess the availability and quantity of water for sustainable management of this essential resource.The results obtained show a slight variability of hydro-climatic parameters.The most remarkable wet periods by their intensity of(1982-1998)and(2005-2012)are moderate and that of 1986-1990 is extremely severe during which they are felt on all the stations of the South of Guinea.In addition,the dry years,the end of 1970 and 1980 to 1987 recognized by the WMO(World Meteorological Organization)as drought years were highlighted in the Diani watershed in the South of the Republic of Guinea.展开更多
Water is one of the most important elements on which our daily lives depend,because of its many uses in various fields.To ensure that people have the right of access to water,the authorities must provide them with tre...Water is one of the most important elements on which our daily lives depend,because of its many uses in various fields.To ensure that people have the right of access to water,the authorities must provide them with treated water that complies with the regulations and standards in force,particularly from a physico-chemical point of view,for all possible uses to avoid any health problems for consumers.The aim of this research is to study the water in the Mamouwol River by measuring physico-chemical parameters:(1)pH,it varies from 5.2“Mam3”to 7.8“Mam4”in August 2021 then from 5.5“Mam3”to 7.7“Mam4”in March 2022,i.e.an average of 6.9 for all sampling points;(2)Turbidity varies from 0.3 NTU“Mam1”to 26.3 NTU“Mam4”in August 2021,then from 0.3 NTU“Mam1”to 30.6 NTU“Mam4”in March 2022,i.e.an average of 9.0 NTU for all sampling points;(3)Suspended matter,varying from 0.6 mg/L“Mam1”to 17.6 mg/L“Mam4”in August 2021,then from 0.6 mg/L“Mam1”to 30.0 mg/L“Mam4”in March 2022,i.e.an average of 8.8 mg/L for all the sampling points“Mam1”,“Mam2”,“Mam3”and“Mam4”;(4)Dissolved oxygen,varying from 2.07 mg/L“Mam3”to 6.12 mg/L“Mam1”in August 2021,then from 1.05 mg/L“Mam3”to 5.05 mg/L“Mam1”in March 2022,i.e.an average of 2.77 mg/L for all sampling points;(5)Nitrates vary from 1.32 mg/L“Mam1”to 3.96 mg/L“Mam4”in August 2021,then from 1.49 mg/L“Mam1”to 5.27 mg/L“Mam3”in March 2022,i.e.an average of 5.53 mg/L for all sampling points;(6)Nitrites,varying from 0 mg/L“Mam1”and“Mam2”to 0.06 mg/L“Mam3”in August 2021,then from 0 mg/L“Mam1”and“Mam2”to 0.13 mg/L“Mam3”in March 2022,i.e.an average of 0.03 mg/L for all sampling points.The results show the presence of organic pollution.展开更多
The properties of salinity in the South China Sea(SCS),a significant marginal sea connecting the Pacific and Indian Oceans,are greatly influenced by the transport of fresh water flux between the two oceans.However,the...The properties of salinity in the South China Sea(SCS),a significant marginal sea connecting the Pacific and Indian Oceans,are greatly influenced by the transport of fresh water flux between the two oceans.However,the long-term changes in the intermediate water in the SCS have not been thoroughly studied due to limited data,particularly in relation to its thermodynamic variations.This study utilized reanalysis data products to identify a 60-year trend of freshening in the intermediate waters of the northern South China Sea(NSCS),accompanied by an expansion of low-salinity water.The study also constructed salinity budget terms,including advection and entrainment processes,and conducted an analysis of the salinity budget to understand the impacts of external and internal dynamic processes on the freshening trend of the intermediate water in the NSCS.The analysis revealed that the freshening in the northwest Pacific Ocean and the intensification of intrusion through the Luzon Strait at intermediate levels are the primary drivers of the salinity changes in the NSCS.Additionally,a weakened trend in the intensity of vertical entrainment also contributes to the freshening in the NSCS.This study offers new insights into the understanding of regional deep sea changes in response to variations in both thermodynamics and oceanic dynamic processes.展开更多
Objective: The main objective of this study was to assess the degree of contamination of surface waters by heavy metals and pesticides. Method: To this end, data were collected in December 2022 from four specific samp...Objective: The main objective of this study was to assess the degree of contamination of surface waters by heavy metals and pesticides. Method: To this end, data were collected in December 2022 from four specific sampling stations: Okpara, Térou, Affon and Adjiro. Levels of heavy metals, including cadmium, chromium, copper, iron, mercury, nickel and lead, were measured and subjected to in-depth statistical analysis using graphical summation models. In addition, the concentrations of pesticide active ingredients present in the samples were interpreted and evaluated. The statistical data collected during this study were processed using R software, version 3.5.0. Results: The values obtained at the different stations Okpara, Térou, Affon and Adjiro are respectively Arsenic (2 × 10<sup>-4</sup> mg/L;2.2 × 10<sup>-1</sup> mg/L;1.2 × 10<sup>-4</sup> mg/L;2 × 10<sup>-4</sup> mg/L), Cadmium (4.4 × 10<sup>-5</sup> mg/L;1.1 × 10<sup>-2</sup> mg/L;10<sup>-4</sup> mg/L;4 × 10<sup>-4</sup> mg/L). Then Copper (7 × 10<sup>-4</sup> mg/L;3 × 10<sup>-3</sup> mg/L;7 × 10<sup>-4</sup> mg/L;1 × 10<sup>-4</sup> mg/L), Iron (1.51 mg/L;6.4 × 10<sup>-1</sup> mg/L;2.0012 mg/L;2.9 × 10<sup>-1</sup> mg/L), Lead (0 mg/L;0 mg/L;1.5 × 10<sup>-3</sup> mg/L;1.5 × 10<sup>-3</sup> mg/L). Mercury, nickel and chromium were not detected in surface waters. It is important to note that the values obtained for trace metals (Cadmium, Chromium, Copper, Iron, Mercury, nickel and chromium were not detected in surface waters. It is important to note that the values obtained for trace metals (cadmium, chromium, copper, iron, mercury, nickel and lead) were all below the guideline standards set by the WHO in 2006 for uncontaminated surface waters. This indicates that the surface waters of the Upper Ouémé were below acceptable contamination thresholds in terms of heavy metals. However, the presence of pesticide active ingredients such as cyfluthrin, endosulfan-alpha, endosulfan-beta, profenosfos, tihan, atrazine, gala super and glycel clearly indicates that these surface waters are subject to agricultural contamination.展开更多
Water erosion is a serious problem that leads to soil degradation,loss,and the destruction of structures.Assessing the risk of erosion and determining the affected areas has become crucial in order to understand the m...Water erosion is a serious problem that leads to soil degradation,loss,and the destruction of structures.Assessing the risk of erosion and determining the affected areas has become crucial in order to understand the main factors influencing its evolution and to minimize its impacts.This study focuses on evaluating the risk of erosion in the Assif el mal watershed,which is located in the High Atlas Mountains.The Erosion Potential Model(EPM)is used to estimate soil losses depending on various parameters such as lithology,hydrology,topography,and morphometry.Geographic information systems and remote sensing techniques are employed to map areas with high erosive potential and their relationship with the distribution of factors involved.Different digital elevation models are also used in this study to highlight the impact of data quality on the accuracy of the results.The findings reveal that approximately 59%of the total area in the Assif el mal basin has low to very low potential for soil losses,while 22%is moderately affected and 19.9%is at high to very high risk.It is therefore crucial to implement soil conservation measures to mitigate and prevent erosion risks.展开更多
Green hydrogen from water splitting has emerged as a critical energy vector with the potential to spearhead the global transition to a fossil fuel-independent society.The field of catalysis has been revolutionized by ...Green hydrogen from water splitting has emerged as a critical energy vector with the potential to spearhead the global transition to a fossil fuel-independent society.The field of catalysis has been revolutionized by single-atom catalysts(SACs),which exhibit unique and intricate interactions between atomically dispersed metal atoms and their supports.Recently,bimetallic SACs(bimSACs)have garnered significant attention for leveraging the synergistic functions of two metal ions coordinated on appropriately designed supports.BimSACs offer an avenue for rich metal–metal and metal–support cooperativity,potentially addressing current limitations of SACs in effectively furnishing transformations which involve synchronous proton–electron exchanges,substrate activation with reversible redox cycles,simultaneous multi-electron transfer,regulation of spin states,tuning of electronic properties,and cyclic transition states with low activation energies.This review aims to encapsulate the growing advancements in bimSACs,with an emphasis on their pivotal role in hydrogen generation via water splitting.We subsequently delve into advanced experimental methodologies for the elaborate characterization of SACs,elucidate their electronic properties,and discuss their local coordination environment.Overall,we present comprehensive discussion on the deployment of bimSACs in both hydrogen evolution reaction and oxygen evolution reaction,the two half-reactions of the water electrolysis process.展开更多
The water content of cut flowers is a significant factor in their post-harvest quality.In this study,we examine the efficacy of silver nanoparticles(NS)on the longevity of cut gladiolus,with a focus on water state and...The water content of cut flowers is a significant factor in their post-harvest quality.In this study,we examine the efficacy of silver nanoparticles(NS)on the longevity of cut gladiolus,with a focus on water state and distribution.We used Low-field nuclear magnetic resonance(LF-NMR)technology to identify three water fractions with different transverse relaxation times(T2)values:bound water T21(<10 ms),intermediate immobilized water T22(10-100 ms),and the slowest component free water T23(>10 ms).During the opening process,T23increased at stages 2 and 3 and then decreased,T22 decreased slowly,and T21 remained unchanged.Free water values were consistently higher than bound water and immobilized water and reached their maximum from stage 2 until stage 4,when the petals were extended and began to wilt.The vascular bundles responsible for transporting water had higher water content,as detected by proton density-weighted magnetic resonance imaging(MRI).Bound water and free water with NS pretreatments in bracts were initially lower but then two days later the signal amplitude of each water state exceeded those of the control,indicating that the treatment enhanced the water-holding capacity over time.Furthermore,NS pretreatments reduced the free water mobility of the cut flowers and inhibited stem decay.Additionally,we found that NS can enter the stem and are primarily transported upward along the xylem with water using scanning electron microscopy(SEM)and energy-dispersive X-ray spectroscopy(EDS)technology.Overall,our findings indicate that NS pretreatment reduces free water in gladiolus cut flowers,enhancing their water retention and prolonging their vase life.展开更多
The stable nanobubbles adhered to mineral surfaces may facilitate their efficient separation via flotation in the mining industry.However,the state of nanobubbles on mineral solid surfaces is still elusive.In this stu...The stable nanobubbles adhered to mineral surfaces may facilitate their efficient separation via flotation in the mining industry.However,the state of nanobubbles on mineral solid surfaces is still elusive.In this study,molecular dynamics(MD)simulations are employed to examine mineral-like model surfaces with varying degrees of hydrophobicity,modulated by surface charges,to elucidate the adsorption behavior of nanobubbles at the interface.Our findings not only contribute to the fundamental understanding of nanobubbles but also have potential applications in the mining industry.We observed that as the surface charge increases,the contact angle of the nanobubbles increases accordingly with shape transformation from a pancake-like gas film to a cap-like shape,and ultimately forming a stable nanobubble upon an ordered water monolayer.When the solid–water interactions are weak with a small partial charge,the hydrophobic gas(N_(2))molecules accumulate near the solid surfaces.However,we have found,for the first time,that gas molecules assemble a nanobubble on the water monolayer adjacent to the solid surfaces with large partial charges.Such phenomena are attributed to the formation of a hydrophobic water monolayer with a hydrogen bond network structure near the surface.展开更多
Investigating the ecological impact of land use change in the context of the construction of national water network project is crucial,as it is imperative for achieving the sustainable development goals of the nationa...Investigating the ecological impact of land use change in the context of the construction of national water network project is crucial,as it is imperative for achieving the sustainable development goals of the national water network and guaranteeing regional ecological stability.Using the Danjiangkou Reservoir Area(DRA),China as the study area,this paper first examined the spatiotemporal dynamics of natural landscape patterns and ecosystem service values(ESV)in the DRA from 2000 to 2018 and then investigated the spatial clustering characteristics of the ESV using spatial statistical analysis tools.Finally,the patch-generating land use simulation(PLUS)model was used to simulate the natural landscape and future changes in the ESV of the DRA from 2018 to 2028 under four different development scenarios:business as usual(BAU),economic development(ED),ecological protection(EP),and shoreline protection(SP).The results show that:during 2000-2018,the construction of water facilities had a significant impact on regional land use/land cover(LULC)change,with a 24830 ha increase in watershed area.ESV exhibited an increasing trend,with a significant and growing spatial clustering effect.The transformation of farmland to water bodies led to accelerated ESV growth,while the transformation of forest land to farmland led to a decrease in the ESV.Normalized difference vegetation index(NDVI)had the strongest effect on the ESV.ESV exhibited a continuous increase from 2018 to 2028 under all the simulation scenarios.The EP scenario had the greatest increase in ESV,while the ED scenario had the smallest increase.The findings suggest that projected land use patterns under different scenarios have varied impacts on ecosystem services(ESs)and that the management and planning of the DRA should balance social,economic,ecological,and security benefits.nomic,ecological,and security benefits.展开更多
The Yangtze River economic belt(YREB),China is important to the Chinese economy and for supporting sustainable development.Clarifying the relationship between water quality indices and socioeconomic indicators could h...The Yangtze River economic belt(YREB),China is important to the Chinese economy and for supporting sustainable development.Clarifying the relationship between water quality indices and socioeconomic indicators could help improve aquatic environment management in the YREB and our understanding of the causes and effects of water quality variations in other large river basins.In this study,river water quality,factors affecting water quality,and management strategies,and correlations between water quality indices and socioeconomic indicators in the YREB during the 13th Five-Year Plan period(2016-2020)were assessed.The single-factor evaluation method,constant price for GDP,and correlation analyses were adopted.The results showed that:1)water quality in the YREB improved during the 13th Five-Year Plan period.The number of aquatic environment sections meeting GradeⅠ-Ⅲwater quality standards increased by 13.1%and the number below Grade V decreased by 2.9%.2)The values of 12 indicators in the YREB exceeded relevant standards.The indicators with highest concentreation were the total phosphorus,chemical oxygen demand,ammonia nitrogen,and permanganate index,which were relatively high in downstream regions in Anhui Province,Jiangsu Province,and Shanghai Municipality.3)Ammonia nitrogen,chemical oxygen demand,and total phosphorus emissions per unit area and water extraction per unit area are relatively high in the three downstream regions mentioned above.4)Increased domestic sewage discharges have increased total wastewater discharges in the YREB.5)River water quality in the YREB strongly correlated with population,economic,and water resource indices and less strongly correlated with government investment,agriculture,meteorology,energy,and forestry indices.This confirmed the need to decrease wastewater discharges and non-point-source pollutant emissions.The aquatic environment could be improved by taking reasonable measures to control population growth,adjusting the industrial structure to accelerate industrial transformation and increase the proportion of tertiary industries,and investing in technological innovations to protect the environment.展开更多
Grouting has been the most effective approach to mitigate water inrush disasters in underground engineering due to its ability to plug groundwater and enhance rock strength.Nevertheless,there is a lack of potent numer...Grouting has been the most effective approach to mitigate water inrush disasters in underground engineering due to its ability to plug groundwater and enhance rock strength.Nevertheless,there is a lack of potent numerical tools for assessing the grouting effectiveness in water-rich fractured strata.In this study,the hydro-mechanical coupled discontinuous deformation analysis(HM-DDA)is inaugurally extended to simulate the grouting process in a water-rich discrete fracture network(DFN),including the slurry migration,fracture dilation,water plugging in a seepage field,and joint reinforcement after coagulation.To validate the capabilities of the developed method,several numerical examples are conducted incorporating the Newtonian fluid and Bingham slurry.The simulation results closely align with the analytical solutions.Additionally,a set of compression tests is conducted on the fresh and grouted rock specimens to verify the reinforcement method and calibrate the rational properties of reinforced joints.An engineering-scale model based on a real water inrush case of the Yonglian tunnel in a water-rich fractured zone has been established.The model demonstrates the effectiveness of grouting reinforcement in mitigating water inrush disaster.The results indicate that increased grouting pressure greatly affects the regulation of water outflow from the tunnel face and the prevention of rock detachment face after excavation.展开更多
Accurate estimation of evapotranspiration(ET)is crucial for efficient water resource management,particularly in the face of climate change and increasing water scarcity.This study performs a bibliometric analysis of 3...Accurate estimation of evapotranspiration(ET)is crucial for efficient water resource management,particularly in the face of climate change and increasing water scarcity.This study performs a bibliometric analysis of 352 articles and a systematic review of 35 peer-reviewed papers,selected according to PRISMA guidelines,to evaluate the performance of Hybrid Artificial Neural Networks(HANNs)in ET estimation.The findings demonstrate that HANNs,particularly those combining Multilayer Perceptrons(MLPs),Recurrent Neural Networks(RNNs),and Convolutional Neural Networks(CNNs),are highly effective in capturing the complex nonlinear relationships and tem-poral dependencies characteristic of hydrological processes.These hybrid models,often integrated with optimization algorithms and fuzzy logic frameworks,significantly improve the predictive accuracy and generalization capabilities of ET estimation.The growing adoption of advanced evaluation metrics,such as Kling-Gupta Efficiency(KGE)and Taylor Diagrams,highlights the increasing demand for more robust performance assessments beyond traditional methods.Despite the promising results,challenges remain,particularly regarding model interpretability,computational efficiency,and data scarcity.Future research should prioritize the integration of interpretability techniques,such as attention mechanisms,Local Interpretable Model-Agnostic Explanations(LIME),and feature importance analysis,to enhance model transparency and foster stakeholder trust.Additionally,improving HANN models’scalability and computational efficiency is crucial,especially for large-scale,real-world applications.Approaches such as transfer learning,parallel processing,and hyperparameter optimization will be essential in overcoming these challenges.This study underscores the transformative potential of HANN models for precise ET estimation,particularly in water-scarce and climate-vulnerable regions.By integrating CNNs for automatic feature extraction and leveraging hybrid architectures,HANNs offer considerable advantages for optimizing water management,particularly agriculture.Addressing challenges related to interpretability and scalability will be vital to ensuring the widespread deployment and operational success of HANNs in global water resource management.展开更多
Research on the ecohydrological processes of terrestrial plants is a frontier field comprising ecology,hydrology and global change research,yielding the key theoretical foundations of ecohydrology.In karst areas,due t...Research on the ecohydrological processes of terrestrial plants is a frontier field comprising ecology,hydrology and global change research,yielding the key theoretical foundations of ecohydrology.In karst areas,due to its unique geological background,the karst landscape is strongly developed,with high bedrock exposure,high permeability,fragmented soils,shallow soils,and high spatial heterogeneity,resulting in very limited water storage for plant uptake and growth in rock fissures and shallow soils.Therefore,water conditions are an important ecological factor influencing plant growth.To comprehensively understand the current progress and development trends in plant water use research focusing on karst areas,this paper uses the VOSviewer software to analyze the literature on plant water use in karst areas between 1984 and 2022.The results showed that:(1)Research on plant water use in karst areas has developed rapidly worldwide,and the number of relevant studies in the literature have increased year by year,which together means that it is attracting more and more attention.(2)The investigation of plant water sources,geological background of karst areas,seasonal arid tropical climates,the relationship betweenδ13C values and plant water use efficiency,karst plant water use in karst savannas and subtropical areas,and ecosystems under climate change yields the knowledge base in this field.(3)Most studies in this area focus on the division of water sources of plants in karst areas,the methods of studying the water use sources of plants,and the water use strategies and efficiency of plants.(4)Future research will focus on how plant water use in karst areas is influenced by Earth’s critical zones,climate change,and ecohydrological separation.These studies will provide a key scientific basis for guiding ecological restoration and promoting sustainable development in karst areas.展开更多
To identify the root causes of heavy metal contamination in soils as well as prevent and control such contamination from its sources,this study explored the accumulation patterns and ecological risks of heavy metals l...To identify the root causes of heavy metal contamination in soils as well as prevent and control such contamination from its sources,this study explored the accumulation patterns and ecological risks of heavy metals like Cd and Pb in solid waste in mining areas and across the water body,sediment,soil and agricultural product ecosystem surrounding the mining areas.Focusing on the residual solid waste samples in lead-zinc deposits in a certain area of Guizhou Province,along with samples of topsoils,irrigation water,river sediments,and crops from surrounding areas.This study analyzed the distributions of eight heavy metals,i.e.,Cd,As,Cr,Hg,Pb,Zn,Cu,and Ni,in the samples through field surveys and sample tests.Furthermore,this study assessed the contamination levels and ecological risks of heavy metals in soils,sediments,and agricultural products using methods such as the single-factor index,Nemerow composite index,and potential ecological risk assessment.The results indicate that heavy metals in the solid waste samples all exhibited concentrations exceeding their risk screening values,with 60%greater than their risk intervention values.The soils and sediments demonstrate slight and moderate comprehensive ecological risks of heavy metals.The single-factor potential ecological risks of heavy metals in both the soil and sediment samples decreased in the order of Hg,Cd,Pb,As,Cu,Zn,Cr,and Ni,suggesting the same sources of heavy metals in the soils and sediments.Most of the agricultural product samples exhibited over-limit concentrations of heavy metals dominated by Cd,Pb,Ni,and Cr,excluding Hg and As.The agricultural product assessment using the Nemerow composite index reveals that 35%of the agricultural product samples reached the heavy metal contamination level,implying that the agricultural products from farmland around the solid waste dumps have been contaminated with heavy metals.The eight heavy metals in the soil,sediment,and agricultural product samples manifested high coefficients of variation(CVs),indicating pronounced spatial variability.This suggests that their concentrations in soils,sediments,and agricultural products are significantly influenced by human mining activities.Additionally,the agricultural products exhibit strong transport and accumulation capacities for Cd,Cu,and Zn.展开更多
文摘Water is essential to life and to the sustainable socio-economic development of a nation, It is therefore interesting to have a better knowledge of the quality of this water. The aim was to determine the degree of microbiological and physico-chemical pollution of the water of the “Mamouwol” river in the town of Mamou. To do this, we chose four (4) sampling sites spread throughout the town of Mamou. During the month of March (2024), 4 water samples were analyzed to monitor the water quality of this river. The average values of the flora analyzed show that these water are heavily contaminated with bacteria indicative of fecal and metal pollution. This study showed that sites: Mam4;Mam2 and Mam1 contain the highest loads, with Total Coliform counts ranging from 1534 CFU/100 ml to 2100 CFU/100 ml, the number of faecal coliforms varies between 526 and 1240 CFU/100 ml, and that of faecal streptococci between 526 and 841 CFU/100 ml. Metal content, BOD5 and COD all comply with the laboratory’s analysis criteria, although they vary from point to point.
文摘Oil spills continue to generate various issues and concerns regarding their effect and behavior in the marine environment,owing to the related potential for detrimental environmental,economic and social implications.It is essential to have a solid understanding of the ways in which oil interacts with the water and the coastal ecosystems that are located nearby.This study proposes a simplified model for predicting the plume-like transport behavior of heavy Bunker C fuel oil discharging downward from an acutely-angled broken pipeline located on the water surface.The results show that the spill overall profile is articulated in three major flow areas.The first,is the source field,i.e.,a region near the origin of the initial jet,followed by the intermediate or transport field,namely,the region where the jet oil flow transitions into an underwater oil plume flow and starts to move horizontally,and finally,the far-field,where the oil re-surface and spreads onto the shore at a significant distance from the spill site.The behavior of the oil in the intermediate field is investigated using a simplified injection-type oil spill model capable of mimicking the undersea trapping and lateral migration of an oil plume originating from a negatively buoyant jet spill.A rectangular domain with proper boundary conditions is used to implement the model.The Projection approach is used to discretize a modified version of the Navier-Stokes equations in two dimensions.A benchmark fluid flow issue is used to verify the model and the results indicate a reasonable relationship between specific gravity and depth as well as agreement with the aerial data and a vertical temperature profile plot.
基金The China Scholarship Council under contract No.202308310175the China Postdoctoral Science Foundation under contract No.E-6005-00-0042-39+6 种基金Postdoctoral Fellowship Program of CPSF under contract No. GZC20231539the Jiangsu Haizhou Bay National Sea Ranching Demonstration Project under contract No. D–8005–18–0188Shanghai Municipal Science and Technology Commission Local Capacity Construction Project under contract No. 21010502200the Science Foundation for Youths of Jiangsu ProvinceChina under contract No. BK20170438the Science and Technology Projects in Nantong under contract No. JC2018014the Social Livelihood Key Projects of Nantong under contract No. MS22021015。
文摘To better understand the community patterns mediated by connectivity in artificial reefs of coastal areas, it is necessary to understand the distribution and coexistence of organisms with artificial reefs area and adjacent waters. This study was conducted to examine main catches assemblages collected by trawls in Haizhou Bay,which included five habitats: the artificial reef area(AR), aquaculture area(AA), natural area(NA), estuary area(EA) and comprehensive effect area(CEA). The result shows that the total abundances of species in the five habitats were highly different(univariate PERMANOVA: P = 0.001, n = 24), but some species were also unique in their habitat(e.g. Scapharca subcrenata and Glossaulax didyma in AA). The body size distribution of specific species between habitats are different. For Collichthys lucidus, their body size in AR(14.63 cm ± 1.64 cm) and EA(14.3 cm ± 0.85 cm) is higher than that in NA(10.65 cm ± 1.64 cm), CEA(11.28 cm ± 1.85 cm) and AA(12.1 cm ±0.43 cm), which indicates the potential connection from AR to EA mediated by their adult population. We concluded that artificial reefs in AR can be considered key components that have the ability to support species assemblages in adjacent habitats. This study has implications for the conservation and monitoring of species assemblages in coastal areas in terms of that artificial reefs can be applied in different stages of habitat protection implementation and in different combinations of scenarios.
基金supported by the National Natural Science Foundation of China(52222002)Bureau of International Cooperation of Chinese Academy of Sciences(032GJHZ2022035MI)State Key Laboratory of Environmental Aquatic Chemistry(23Z01ESPCR).
文摘The degradation of micropollutants in water via ultraviolet(UV)-based advanced oxidation processes(AOPs)is strongly dependent on the water matrix.Various reactive radicals(RRs)formed in UV-AOPs have different reaction selectivities toward water matrices and degradation efficiencies for target micropollutants.Hence,process selection and optimization are crucial.This study developed a facilitated prediction method for the photon fluence-based rate constant for micropollutant degradation(K′_(p,MP))in various UV-AOPs by combining model simulation with portable measurement.Portable methods for measuring the scavenging capacities of the principal RRs(RRSCs)involved in UV-AOPs(i.e.,HO^(·),SO_(4)^(·-),and Cl^(·))using a mini-fluidic photoreaction system were proposed.The simulation models consisted of photochemical,quantitative structure–activity relationship,and radical concentration steady-state approximation models.The RRSCs were determined in eight test waters,and a higher RRSC was found to be associated with a more complex water matrix.Then,by taking sulfamethazine,caffeine,and carbamazepine as model micropollutants,the k′_(p,MP) values in various UV-AOPs were predicted and further verified experimentally.A lower k′_(p,MP) was found to be associated with a higher RRSC for a stronger RR competition;for example,k′_(p,MP) values of 130.9 and 332.5 m^(2) einstein^(–1),respectively,were obtained for carbamazepine degradation by UV/H_(2)O_(2) in the raw water(RRSC=9.47×10^(4) s^(-1))and sand-filtered effluent(RRSC=2.87×10^(4) s^(-1))of a drinking water treatment plant.The developed method facilitates process selection and optimization for UV-AOPs,which is essential for increasing the efficiency and cost-effectiveness of water treatment.
文摘Sairme mineral water, one of the famous mineral waters in Georgia, is renowned for its exceptional healing properties. The distinctiveness and therapeutic benefits of the naturally sourced mineral water, known as “Sairme”, stem from its rich array of microelements, notably including iron and manganese. Since 1948, the bottling of Sairme mineral water has been a prominent activity. Named after the Sairme deposit, this mineral water is packaged in various formats to cater to diverse consumer preferences. The bottling process involves transporting the mineral water from wells to the bottling plant through pipelines. Prior to bottling, the mineral water undergoes meticulous processing stages in adherence to current Georgian and international regulations. This process ensures that the concentration of trace elements in the bottled water is minimized, maintaining its purity and quality. Given the importance of preserving the microelements present in bottled mineral water, our research is dedicated to optimizing the technological process. Our objective is to safeguard the valuable microelements while ensuring the highest standards of quality and safety in the final product.
文摘The study carried out on the waters of the Méné River led to an overall assessment of its water quality during the dry season and the rainy season. The analysis focused on eight (8) water samples taken from the river during a period of dry season (January-February) and a period of rainy season (June and September). The various physicochemical parameters were measured according to Afnor standardized methods. The readings of temperature, turbidity, pH and conductivity made it possible to account for the disturbances occurring in water quality. A temporal variation correlated with the seasons (dry or rainy) is noted. Turbidity depends on the concentration of suspended solids (SS) in the water and drained particles and therefore on the seasons. Just like the temperature, the conductivity changes with the season. The waters of the Méné River are generally acidic. The results obtained show that there is a low level of pollution by chlorides, phosphates, nitrites and nitrates. A slight pollution of the waters of Méné in organic matter (chemical oxygen demand values are less than 25 mg∙L−1 during dry season and 32.33 ± 4.73 mg∙L−1 during rainy season) was observed. The concentrations of metallic trace elements such as iron, manganese and aluminum indicate significant pollution of these waters by these elements. Overall, the waters of the Méné River are of satisfactory quality because all the physicochemical parameters analyzed have values below standards during the dry season as well as during the rainy season with the exception of COD and a few metallic trace elements.
文摘This study aims to analyze the spatio-temporal variability of the characteristics of water resources in the Diani watershed,located in the southeast of the Republic of Guinea.The objective is to assess the availability and quantity of water for sustainable management of this essential resource.The results obtained show a slight variability of hydro-climatic parameters.The most remarkable wet periods by their intensity of(1982-1998)and(2005-2012)are moderate and that of 1986-1990 is extremely severe during which they are felt on all the stations of the South of Guinea.In addition,the dry years,the end of 1970 and 1980 to 1987 recognized by the WMO(World Meteorological Organization)as drought years were highlighted in the Diani watershed in the South of the Republic of Guinea.
文摘Water is one of the most important elements on which our daily lives depend,because of its many uses in various fields.To ensure that people have the right of access to water,the authorities must provide them with treated water that complies with the regulations and standards in force,particularly from a physico-chemical point of view,for all possible uses to avoid any health problems for consumers.The aim of this research is to study the water in the Mamouwol River by measuring physico-chemical parameters:(1)pH,it varies from 5.2“Mam3”to 7.8“Mam4”in August 2021 then from 5.5“Mam3”to 7.7“Mam4”in March 2022,i.e.an average of 6.9 for all sampling points;(2)Turbidity varies from 0.3 NTU“Mam1”to 26.3 NTU“Mam4”in August 2021,then from 0.3 NTU“Mam1”to 30.6 NTU“Mam4”in March 2022,i.e.an average of 9.0 NTU for all sampling points;(3)Suspended matter,varying from 0.6 mg/L“Mam1”to 17.6 mg/L“Mam4”in August 2021,then from 0.6 mg/L“Mam1”to 30.0 mg/L“Mam4”in March 2022,i.e.an average of 8.8 mg/L for all the sampling points“Mam1”,“Mam2”,“Mam3”and“Mam4”;(4)Dissolved oxygen,varying from 2.07 mg/L“Mam3”to 6.12 mg/L“Mam1”in August 2021,then from 1.05 mg/L“Mam3”to 5.05 mg/L“Mam1”in March 2022,i.e.an average of 2.77 mg/L for all sampling points;(5)Nitrates vary from 1.32 mg/L“Mam1”to 3.96 mg/L“Mam4”in August 2021,then from 1.49 mg/L“Mam1”to 5.27 mg/L“Mam3”in March 2022,i.e.an average of 5.53 mg/L for all sampling points;(6)Nitrites,varying from 0 mg/L“Mam1”and“Mam2”to 0.06 mg/L“Mam3”in August 2021,then from 0 mg/L“Mam1”and“Mam2”to 0.13 mg/L“Mam3”in March 2022,i.e.an average of 0.03 mg/L for all sampling points.The results show the presence of organic pollution.
基金National Natural Science Foundation of China(92158204,42076019)Innovation Group Project of the Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)(31020004)Open Project of the State Key Laboratory of Tropical Oceanography(LTOZZ2001)。
文摘The properties of salinity in the South China Sea(SCS),a significant marginal sea connecting the Pacific and Indian Oceans,are greatly influenced by the transport of fresh water flux between the two oceans.However,the long-term changes in the intermediate water in the SCS have not been thoroughly studied due to limited data,particularly in relation to its thermodynamic variations.This study utilized reanalysis data products to identify a 60-year trend of freshening in the intermediate waters of the northern South China Sea(NSCS),accompanied by an expansion of low-salinity water.The study also constructed salinity budget terms,including advection and entrainment processes,and conducted an analysis of the salinity budget to understand the impacts of external and internal dynamic processes on the freshening trend of the intermediate water in the NSCS.The analysis revealed that the freshening in the northwest Pacific Ocean and the intensification of intrusion through the Luzon Strait at intermediate levels are the primary drivers of the salinity changes in the NSCS.Additionally,a weakened trend in the intensity of vertical entrainment also contributes to the freshening in the NSCS.This study offers new insights into the understanding of regional deep sea changes in response to variations in both thermodynamics and oceanic dynamic processes.
文摘Objective: The main objective of this study was to assess the degree of contamination of surface waters by heavy metals and pesticides. Method: To this end, data were collected in December 2022 from four specific sampling stations: Okpara, Térou, Affon and Adjiro. Levels of heavy metals, including cadmium, chromium, copper, iron, mercury, nickel and lead, were measured and subjected to in-depth statistical analysis using graphical summation models. In addition, the concentrations of pesticide active ingredients present in the samples were interpreted and evaluated. The statistical data collected during this study were processed using R software, version 3.5.0. Results: The values obtained at the different stations Okpara, Térou, Affon and Adjiro are respectively Arsenic (2 × 10<sup>-4</sup> mg/L;2.2 × 10<sup>-1</sup> mg/L;1.2 × 10<sup>-4</sup> mg/L;2 × 10<sup>-4</sup> mg/L), Cadmium (4.4 × 10<sup>-5</sup> mg/L;1.1 × 10<sup>-2</sup> mg/L;10<sup>-4</sup> mg/L;4 × 10<sup>-4</sup> mg/L). Then Copper (7 × 10<sup>-4</sup> mg/L;3 × 10<sup>-3</sup> mg/L;7 × 10<sup>-4</sup> mg/L;1 × 10<sup>-4</sup> mg/L), Iron (1.51 mg/L;6.4 × 10<sup>-1</sup> mg/L;2.0012 mg/L;2.9 × 10<sup>-1</sup> mg/L), Lead (0 mg/L;0 mg/L;1.5 × 10<sup>-3</sup> mg/L;1.5 × 10<sup>-3</sup> mg/L). Mercury, nickel and chromium were not detected in surface waters. It is important to note that the values obtained for trace metals (Cadmium, Chromium, Copper, Iron, Mercury, nickel and chromium were not detected in surface waters. It is important to note that the values obtained for trace metals (cadmium, chromium, copper, iron, mercury, nickel and lead) were all below the guideline standards set by the WHO in 2006 for uncontaminated surface waters. This indicates that the surface waters of the Upper Ouémé were below acceptable contamination thresholds in terms of heavy metals. However, the presence of pesticide active ingredients such as cyfluthrin, endosulfan-alpha, endosulfan-beta, profenosfos, tihan, atrazine, gala super and glycel clearly indicates that these surface waters are subject to agricultural contamination.
文摘Water erosion is a serious problem that leads to soil degradation,loss,and the destruction of structures.Assessing the risk of erosion and determining the affected areas has become crucial in order to understand the main factors influencing its evolution and to minimize its impacts.This study focuses on evaluating the risk of erosion in the Assif el mal watershed,which is located in the High Atlas Mountains.The Erosion Potential Model(EPM)is used to estimate soil losses depending on various parameters such as lithology,hydrology,topography,and morphometry.Geographic information systems and remote sensing techniques are employed to map areas with high erosive potential and their relationship with the distribution of factors involved.Different digital elevation models are also used in this study to highlight the impact of data quality on the accuracy of the results.The findings reveal that approximately 59%of the total area in the Assif el mal basin has low to very low potential for soil losses,while 22%is moderately affected and 19.9%is at high to very high risk.It is therefore crucial to implement soil conservation measures to mitigate and prevent erosion risks.
基金support from the Czech Science Foundation,project EXPRO,No 19-27454Xsupport by the European Union under the REFRESH—Research Excellence For Region Sustainability and High-tech Industries project number CZ.10.03.01/00/22_003/0000048 via the Operational Programme Just Transition from the Ministry of the Environment of the Czech Republic+1 种基金Horizon Europe project EIC Pathfinder Open 2023,“GlaS-A-Fuels”(No.101130717)supported from ERDF/ESF,project TECHSCALE No.CZ.02.01.01/00/22_008/0004587).
文摘Green hydrogen from water splitting has emerged as a critical energy vector with the potential to spearhead the global transition to a fossil fuel-independent society.The field of catalysis has been revolutionized by single-atom catalysts(SACs),which exhibit unique and intricate interactions between atomically dispersed metal atoms and their supports.Recently,bimetallic SACs(bimSACs)have garnered significant attention for leveraging the synergistic functions of two metal ions coordinated on appropriately designed supports.BimSACs offer an avenue for rich metal–metal and metal–support cooperativity,potentially addressing current limitations of SACs in effectively furnishing transformations which involve synchronous proton–electron exchanges,substrate activation with reversible redox cycles,simultaneous multi-electron transfer,regulation of spin states,tuning of electronic properties,and cyclic transition states with low activation energies.This review aims to encapsulate the growing advancements in bimSACs,with an emphasis on their pivotal role in hydrogen generation via water splitting.We subsequently delve into advanced experimental methodologies for the elaborate characterization of SACs,elucidate their electronic properties,and discuss their local coordination environment.Overall,we present comprehensive discussion on the deployment of bimSACs in both hydrogen evolution reaction and oxygen evolution reaction,the two half-reactions of the water electrolysis process.
基金financially supported by the Natural Science Foundation of Guangdong Province(Grant Nos.2023A1515030023,2022B0202110003,2021TQ06N115,2020B121201008)the Special Fund for Scientific Innovation Strategy-Construction of High Level Academy of Agriculture Science(R2023PY-JG025)。
文摘The water content of cut flowers is a significant factor in their post-harvest quality.In this study,we examine the efficacy of silver nanoparticles(NS)on the longevity of cut gladiolus,with a focus on water state and distribution.We used Low-field nuclear magnetic resonance(LF-NMR)technology to identify three water fractions with different transverse relaxation times(T2)values:bound water T21(<10 ms),intermediate immobilized water T22(10-100 ms),and the slowest component free water T23(>10 ms).During the opening process,T23increased at stages 2 and 3 and then decreased,T22 decreased slowly,and T21 remained unchanged.Free water values were consistently higher than bound water and immobilized water and reached their maximum from stage 2 until stage 4,when the petals were extended and began to wilt.The vascular bundles responsible for transporting water had higher water content,as detected by proton density-weighted magnetic resonance imaging(MRI).Bound water and free water with NS pretreatments in bracts were initially lower but then two days later the signal amplitude of each water state exceeded those of the control,indicating that the treatment enhanced the water-holding capacity over time.Furthermore,NS pretreatments reduced the free water mobility of the cut flowers and inhibited stem decay.Additionally,we found that NS can enter the stem and are primarily transported upward along the xylem with water using scanning electron microscopy(SEM)and energy-dispersive X-ray spectroscopy(EDS)technology.Overall,our findings indicate that NS pretreatment reduces free water in gladiolus cut flowers,enhancing their water retention and prolonging their vase life.
基金supported by the National Natural Science Foundation of China(Grant Nos.12022508,12074394,and 22125604)Shanghai Supercomputer Center of ChinaShanghai Snowlake Technology Co.Ltd.
文摘The stable nanobubbles adhered to mineral surfaces may facilitate their efficient separation via flotation in the mining industry.However,the state of nanobubbles on mineral solid surfaces is still elusive.In this study,molecular dynamics(MD)simulations are employed to examine mineral-like model surfaces with varying degrees of hydrophobicity,modulated by surface charges,to elucidate the adsorption behavior of nanobubbles at the interface.Our findings not only contribute to the fundamental understanding of nanobubbles but also have potential applications in the mining industry.We observed that as the surface charge increases,the contact angle of the nanobubbles increases accordingly with shape transformation from a pancake-like gas film to a cap-like shape,and ultimately forming a stable nanobubble upon an ordered water monolayer.When the solid–water interactions are weak with a small partial charge,the hydrophobic gas(N_(2))molecules accumulate near the solid surfaces.However,we have found,for the first time,that gas molecules assemble a nanobubble on the water monolayer adjacent to the solid surfaces with large partial charges.Such phenomena are attributed to the formation of a hydrophobic water monolayer with a hydrogen bond network structure near the surface.
基金Under the auspices of National Natural Science Foundation of China(No.42371315,41901213)Natural Science Foundation of Hubei Province(No.2020CFB856)Project of Changjiang Survey,Planning,Design and Research Co.,Ltd(No.CX2022Z23)。
文摘Investigating the ecological impact of land use change in the context of the construction of national water network project is crucial,as it is imperative for achieving the sustainable development goals of the national water network and guaranteeing regional ecological stability.Using the Danjiangkou Reservoir Area(DRA),China as the study area,this paper first examined the spatiotemporal dynamics of natural landscape patterns and ecosystem service values(ESV)in the DRA from 2000 to 2018 and then investigated the spatial clustering characteristics of the ESV using spatial statistical analysis tools.Finally,the patch-generating land use simulation(PLUS)model was used to simulate the natural landscape and future changes in the ESV of the DRA from 2018 to 2028 under four different development scenarios:business as usual(BAU),economic development(ED),ecological protection(EP),and shoreline protection(SP).The results show that:during 2000-2018,the construction of water facilities had a significant impact on regional land use/land cover(LULC)change,with a 24830 ha increase in watershed area.ESV exhibited an increasing trend,with a significant and growing spatial clustering effect.The transformation of farmland to water bodies led to accelerated ESV growth,while the transformation of forest land to farmland led to a decrease in the ESV.Normalized difference vegetation index(NDVI)had the strongest effect on the ESV.ESV exhibited a continuous increase from 2018 to 2028 under all the simulation scenarios.The EP scenario had the greatest increase in ESV,while the ED scenario had the smallest increase.The findings suggest that projected land use patterns under different scenarios have varied impacts on ecosystem services(ESs)and that the management and planning of the DRA should balance social,economic,ecological,and security benefits.nomic,ecological,and security benefits.
基金National Key Research and Development Program of China(No.2022YFC3204404,2023YFF1303705)National Natural Science Foundation of China(No.U2243206)。
文摘The Yangtze River economic belt(YREB),China is important to the Chinese economy and for supporting sustainable development.Clarifying the relationship between water quality indices and socioeconomic indicators could help improve aquatic environment management in the YREB and our understanding of the causes and effects of water quality variations in other large river basins.In this study,river water quality,factors affecting water quality,and management strategies,and correlations between water quality indices and socioeconomic indicators in the YREB during the 13th Five-Year Plan period(2016-2020)were assessed.The single-factor evaluation method,constant price for GDP,and correlation analyses were adopted.The results showed that:1)water quality in the YREB improved during the 13th Five-Year Plan period.The number of aquatic environment sections meeting GradeⅠ-Ⅲwater quality standards increased by 13.1%and the number below Grade V decreased by 2.9%.2)The values of 12 indicators in the YREB exceeded relevant standards.The indicators with highest concentreation were the total phosphorus,chemical oxygen demand,ammonia nitrogen,and permanganate index,which were relatively high in downstream regions in Anhui Province,Jiangsu Province,and Shanghai Municipality.3)Ammonia nitrogen,chemical oxygen demand,and total phosphorus emissions per unit area and water extraction per unit area are relatively high in the three downstream regions mentioned above.4)Increased domestic sewage discharges have increased total wastewater discharges in the YREB.5)River water quality in the YREB strongly correlated with population,economic,and water resource indices and less strongly correlated with government investment,agriculture,meteorology,energy,and forestry indices.This confirmed the need to decrease wastewater discharges and non-point-source pollutant emissions.The aquatic environment could be improved by taking reasonable measures to control population growth,adjusting the industrial structure to accelerate industrial transformation and increase the proportion of tertiary industries,and investing in technological innovations to protect the environment.
基金supported by the China Scholarship Council(CSC,Grant No.202108050072)JSPS KAKENHI(Grant No.JP19KK0121)。
文摘Grouting has been the most effective approach to mitigate water inrush disasters in underground engineering due to its ability to plug groundwater and enhance rock strength.Nevertheless,there is a lack of potent numerical tools for assessing the grouting effectiveness in water-rich fractured strata.In this study,the hydro-mechanical coupled discontinuous deformation analysis(HM-DDA)is inaugurally extended to simulate the grouting process in a water-rich discrete fracture network(DFN),including the slurry migration,fracture dilation,water plugging in a seepage field,and joint reinforcement after coagulation.To validate the capabilities of the developed method,several numerical examples are conducted incorporating the Newtonian fluid and Bingham slurry.The simulation results closely align with the analytical solutions.Additionally,a set of compression tests is conducted on the fresh and grouted rock specimens to verify the reinforcement method and calibrate the rational properties of reinforced joints.An engineering-scale model based on a real water inrush case of the Yonglian tunnel in a water-rich fractured zone has been established.The model demonstrates the effectiveness of grouting reinforcement in mitigating water inrush disaster.The results indicate that increased grouting pressure greatly affects the regulation of water outflow from the tunnel face and the prevention of rock detachment face after excavation.
文摘Accurate estimation of evapotranspiration(ET)is crucial for efficient water resource management,particularly in the face of climate change and increasing water scarcity.This study performs a bibliometric analysis of 352 articles and a systematic review of 35 peer-reviewed papers,selected according to PRISMA guidelines,to evaluate the performance of Hybrid Artificial Neural Networks(HANNs)in ET estimation.The findings demonstrate that HANNs,particularly those combining Multilayer Perceptrons(MLPs),Recurrent Neural Networks(RNNs),and Convolutional Neural Networks(CNNs),are highly effective in capturing the complex nonlinear relationships and tem-poral dependencies characteristic of hydrological processes.These hybrid models,often integrated with optimization algorithms and fuzzy logic frameworks,significantly improve the predictive accuracy and generalization capabilities of ET estimation.The growing adoption of advanced evaluation metrics,such as Kling-Gupta Efficiency(KGE)and Taylor Diagrams,highlights the increasing demand for more robust performance assessments beyond traditional methods.Despite the promising results,challenges remain,particularly regarding model interpretability,computational efficiency,and data scarcity.Future research should prioritize the integration of interpretability techniques,such as attention mechanisms,Local Interpretable Model-Agnostic Explanations(LIME),and feature importance analysis,to enhance model transparency and foster stakeholder trust.Additionally,improving HANN models’scalability and computational efficiency is crucial,especially for large-scale,real-world applications.Approaches such as transfer learning,parallel processing,and hyperparameter optimization will be essential in overcoming these challenges.This study underscores the transformative potential of HANN models for precise ET estimation,particularly in water-scarce and climate-vulnerable regions.By integrating CNNs for automatic feature extraction and leveraging hybrid architectures,HANNs offer considerable advantages for optimizing water management,particularly agriculture.Addressing challenges related to interpretability and scalability will be vital to ensuring the widespread deployment and operational success of HANNs in global water resource management.
基金This work was supported by the National Key Research and Development Program of China(2021YFE0107100)Guangxi Key Research and Development Program(GuikeAB22035004)Guangxi Science and Technology Base and Talent Special Project(Guike AD20297090).
文摘Research on the ecohydrological processes of terrestrial plants is a frontier field comprising ecology,hydrology and global change research,yielding the key theoretical foundations of ecohydrology.In karst areas,due to its unique geological background,the karst landscape is strongly developed,with high bedrock exposure,high permeability,fragmented soils,shallow soils,and high spatial heterogeneity,resulting in very limited water storage for plant uptake and growth in rock fissures and shallow soils.Therefore,water conditions are an important ecological factor influencing plant growth.To comprehensively understand the current progress and development trends in plant water use research focusing on karst areas,this paper uses the VOSviewer software to analyze the literature on plant water use in karst areas between 1984 and 2022.The results showed that:(1)Research on plant water use in karst areas has developed rapidly worldwide,and the number of relevant studies in the literature have increased year by year,which together means that it is attracting more and more attention.(2)The investigation of plant water sources,geological background of karst areas,seasonal arid tropical climates,the relationship betweenδ13C values and plant water use efficiency,karst plant water use in karst savannas and subtropical areas,and ecosystems under climate change yields the knowledge base in this field.(3)Most studies in this area focus on the division of water sources of plants in karst areas,the methods of studying the water use sources of plants,and the water use strategies and efficiency of plants.(4)Future research will focus on how plant water use in karst areas is influenced by Earth’s critical zones,climate change,and ecohydrological separation.These studies will provide a key scientific basis for guiding ecological restoration and promoting sustainable development in karst areas.
文摘To identify the root causes of heavy metal contamination in soils as well as prevent and control such contamination from its sources,this study explored the accumulation patterns and ecological risks of heavy metals like Cd and Pb in solid waste in mining areas and across the water body,sediment,soil and agricultural product ecosystem surrounding the mining areas.Focusing on the residual solid waste samples in lead-zinc deposits in a certain area of Guizhou Province,along with samples of topsoils,irrigation water,river sediments,and crops from surrounding areas.This study analyzed the distributions of eight heavy metals,i.e.,Cd,As,Cr,Hg,Pb,Zn,Cu,and Ni,in the samples through field surveys and sample tests.Furthermore,this study assessed the contamination levels and ecological risks of heavy metals in soils,sediments,and agricultural products using methods such as the single-factor index,Nemerow composite index,and potential ecological risk assessment.The results indicate that heavy metals in the solid waste samples all exhibited concentrations exceeding their risk screening values,with 60%greater than their risk intervention values.The soils and sediments demonstrate slight and moderate comprehensive ecological risks of heavy metals.The single-factor potential ecological risks of heavy metals in both the soil and sediment samples decreased in the order of Hg,Cd,Pb,As,Cu,Zn,Cr,and Ni,suggesting the same sources of heavy metals in the soils and sediments.Most of the agricultural product samples exhibited over-limit concentrations of heavy metals dominated by Cd,Pb,Ni,and Cr,excluding Hg and As.The agricultural product assessment using the Nemerow composite index reveals that 35%of the agricultural product samples reached the heavy metal contamination level,implying that the agricultural products from farmland around the solid waste dumps have been contaminated with heavy metals.The eight heavy metals in the soil,sediment,and agricultural product samples manifested high coefficients of variation(CVs),indicating pronounced spatial variability.This suggests that their concentrations in soils,sediments,and agricultural products are significantly influenced by human mining activities.Additionally,the agricultural products exhibit strong transport and accumulation capacities for Cd,Cu,and Zn.