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基于Blending-Clustering集成学习的大坝变形预测模型
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作者 冯子强 李登华 丁勇 《水利水电技术(中英文)》 北大核心 2024年第4期59-70,共12页
【目的】变形是反映大坝结构性态最直观的效应量,构建科学合理的变形预测模型是保障大坝安全健康运行的重要手段。针对传统大坝变形预测模型预测精度低、误报率高等问题导致的错误报警现象,【方法】选取不同预测模型和聚类算法集成,构... 【目的】变形是反映大坝结构性态最直观的效应量,构建科学合理的变形预测模型是保障大坝安全健康运行的重要手段。针对传统大坝变形预测模型预测精度低、误报率高等问题导致的错误报警现象,【方法】选取不同预测模型和聚类算法集成,构建了一种Blending-Clustering集成学习的大坝变形预测模型,该模型以Blending对单一预测模型集成提升预测精度为核心,并通过Clustering聚类优选预测值改善模型稳定性。以新疆某面板堆石坝变形监测数据为实例分析,通过多模型预测性能比较,对所提出模型的预测精度和稳定性进行全面评估。【结果】结果显示:Blending-Clustering模型将预测模型和聚类算法集成,均方根误差(RMSE)和归一化平均百分比误差(nMAPE)明显降低,模型的预测精度得到显著提高;回归相关系数(R~2)得到提升,模型具备更强的拟合能力;在面板堆石坝上22个测点变形数据集上的预测评价指标波动范围更小,模型的泛化性和稳定性得到有效增强。【结论】结果表明:Blending-Clustering集成预测模型对于预测精度、泛化性和稳定性均有明显提升,在实际工程具有一定的应用价值。 展开更多
关键词 大坝 变形 预测模型 blending集成 Clustering集成 模型融合
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基于Prophet算法和Blending集成学习的实时负荷中期预测
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作者 郇嘉嘉 李代猛 +6 位作者 杜云飞 沈欣炜 张璇 乔百豪 何春庚 蓝晓东 罗澍忻 《电力自动化设备》 EI CSCD 北大核心 2024年第4期178-183,共6页
目前的中期负荷预测一般未考虑负荷实时状态,而负荷数据的非线性、季节性、随机性、时序性特征将影响实时负荷的中期预测。构建一个实时负荷中期预测的框架,采用Prophet算法提取负荷数据的季节性部分,采用Blending集成学习对负荷数据的... 目前的中期负荷预测一般未考虑负荷实时状态,而负荷数据的非线性、季节性、随机性、时序性特征将影响实时负荷的中期预测。构建一个实时负荷中期预测的框架,采用Prophet算法提取负荷数据的季节性部分,采用Blending集成学习对负荷数据的非季节部分进行滚动预测,将季节性部分和非季节性部分合成中期负荷实时数据。爱尔兰电力系统的算例结果验证了模型的有效性和稳定性。 展开更多
关键词 负荷预测 Prophet算法 blending集成学习 季节性
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基于Blending集成学习的多源信息液压系统多类故障诊断研究
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作者 杜凯乐 朱为全 +1 位作者 陈瑞宝 刘丽珊 《模具制造》 2024年第2期229-231,共3页
针对传统故障诊断方法准确性不高、耗时长问题,研究通过多个EfficientNet模型对传感器数据进行预训练,并使用XGBoost作为元学习器,提出了一种基于Blending集成学习的多源信息液压系统多类故障诊断方法。实验结果表明,各个子分类器在训... 针对传统故障诊断方法准确性不高、耗时长问题,研究通过多个EfficientNet模型对传感器数据进行预训练,并使用XGBoost作为元学习器,提出了一种基于Blending集成学习的多源信息液压系统多类故障诊断方法。实验结果表明,各个子分类器在训练次数达到300次后趋于收敛,准确率均达到95%左右。该方法具有较高的准确性和鲁棒性,为液压系统故障诊断提供了一种有效的解决方案。 展开更多
关键词 blending集成学习 液压系统 故障诊断
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基于Blending集成学习模型的电力市场日前出清电价预测 被引量:1
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作者 卢凯灵 李盼扉 +2 位作者 何振锋 王勇 薛书倩 《电力需求侧管理》 2023年第3期27-32,共6页
精准的掌握未来电价信息对把握市场的运行状态、支撑市场参与各方进行有效决策、推动市场主体合理优化资源配置具有重要意义。因此基于Blending集成学习机制构建了一种面向于日前电价预测的综合模型。该模型充分考虑电价的高波动性特点... 精准的掌握未来电价信息对把握市场的运行状态、支撑市场参与各方进行有效决策、推动市场主体合理优化资源配置具有重要意义。因此基于Blending集成学习机制构建了一种面向于日前电价预测的综合模型。该模型充分考虑电价的高波动性特点,采用Ashin变换,减小了输入数据波动性对预测模型的影响;选取SVM、LightGBM、EWNN、SARIMAX 4种较为成熟的单一电价预测模型作为初级学习器,进而保证了基于Blending集成学习模型的预测精度。选用美国PJM电力市场实际运行数据对上述构建的电价预测模型进行验证,通过对预测结果的对比分析,表明构建的基于Blending集成学习机制的电价综合预测模型集成了多种传统预测模型的优点,具有较好的准确性与稳定性。 展开更多
关键词 电力市场 日前电价预测 多时间尺度 blending集成学习 Asinh变换
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基于FPFF-Blending模型融合的个体工商户信用评价研究 被引量:1
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作者 任军霞 陈瑞勇 +3 位作者 叶宇轩 孙秀文 唐嘉成 李响 《征信》 北大核心 2023年第4期64-71,共8页
个体工商户信用评价研究往往通过单一机器学习模型建立,其预测精确率较低,抗干扰能力较弱。基于特征金字塔的FPFF特征融合算法,应用于Blending模型融合框架,建立个体工商户信用评价异质融合模型,并赋予模型可解释性,综合解决单一模型稳... 个体工商户信用评价研究往往通过单一机器学习模型建立,其预测精确率较低,抗干扰能力较弱。基于特征金字塔的FPFF特征融合算法,应用于Blending模型融合框架,建立个体工商户信用评价异质融合模型,并赋予模型可解释性,综合解决单一模型稳定性较差、原有Blending框架融合模型过拟合、融合模型缺乏可解释性的问题。通过对个体工商户数据集进行实证实验,结果表明:融合模型较单一机器学习模型在个体工商户信用评价场景下具有更优的预测性能和泛化能力。 展开更多
关键词 个体工商户 信用评价 特征金字塔 FPFF特征融合算法 blending融合框架 SHAP可解释性
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Closed-loop scheduling optimization strategy based on particle swarm optimization with niche technology and soft sensor method of attributes-applied to gasoline blending process
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作者 Jian Long Kai Deng Renchu He 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第9期43-57,共15页
Gasoline blending scheduling optimization can bring significant economic and efficient benefits to refineries.However,the optimization model is complex and difficult to build,which is a typical mixed integer nonlinear... Gasoline blending scheduling optimization can bring significant economic and efficient benefits to refineries.However,the optimization model is complex and difficult to build,which is a typical mixed integer nonlinear programming(MINLP)problem.Considering the large scale of the MINLP model,in order to improve the efficiency of the solution,the mixed integer linear programming-nonlinear programming(MILP-NLP)strategy is used to solve the problem.This paper uses the linear blending rules plus the blending effect correction to build the gasoline blending model,and a relaxed MILP model is constructed on this basis.The particle swarm optimization algorithm with niche technology(NPSO)is proposed to optimize the solution,and the high-precision soft-sensor method is used to calculate the deviation of gasoline attributes,the blending effect is dynamically corrected to ensure the accuracy of the blending effect and optimization results,thus forming a prediction-verification-reprediction closed-loop scheduling optimization strategy suitable for engineering applications.The optimization result of the MILP model provides a good initial point.By fixing the integer variables to the MILPoptimal value,the approximate MINLP optimal solution can be obtained through a NLP solution.The above solution strategy has been successfully applied to the actual gasoline production case of a refinery(3.5 million tons per year),and the results show that the strategy is effective and feasible.The optimization results based on the closed-loop scheduling optimization strategy have higher reliability.Compared with the standard particle swarm optimization algorithm,NPSO algorithm improves the optimization ability and efficiency to a certain extent,effectively reduces the blending cost while ensuring the convergence speed. 展开更多
关键词 blend Optimization algorithm Neural networks Particle swarm optimization Mixed integer programming
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Feasibility Investigation of Bitumen Properties by Blending of Coal Tar Pitch
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作者 Bat-Erdene Erdenetsogt Zoltuya Khashbaatar +1 位作者 Ilchgerel Dash Battsetseg Tsog 《Advances in Chemical Engineering and Science》 CAS 2023年第2期93-104,共12页
There are numerous methods and additives available to improve the durability and quality of road bitumen. A coal tar obtained by coal coking was distilled in a laboratory into fractions of initial boiling point IBP-18... There are numerous methods and additives available to improve the durability and quality of road bitumen. A coal tar obtained by coal coking was distilled in a laboratory into fractions of initial boiling point IBP-180℃ (gasoline-like fuel), 180℃ - 360℃ (diesel-like fuel), and >360℃ (residue or coal tar pitch). The coal tar pitch was added into road bitumen by up to 1 - 5 wt% and investigated the alteration of physical and chemical properties. The physico-mechanical properties of coal tar pitch and bitumen blends, as well as the chemical group composition, were determined using standard techniques (MNS) and the SARA method, respectively. Results of 3% coal tar pitch addition into bitumen enhanced ductility by 12.4% and softening point by 1.6℃. We found that blending with bitumen coal tar pitch as a modifier could improve bitumen properties. 展开更多
关键词 Modified Bitumen blending Coal Tar Pitch DUCTILITY Softening Point
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Conceptual Blending and Meme Humor on the Internet:The Example of COVID-19 Publicity Posters in Chinese Microblogging
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作者 WANG Lei 《Sino-US English Teaching》 2023年第6期217-226,共10页
Internet memes,as multimodal cultural products disseminated through the Internet,usually take the form of short videos or images that express humor or satire.The creation and dissemination of humor in memes are both c... Internet memes,as multimodal cultural products disseminated through the Internet,usually take the form of short videos or images that express humor or satire.The creation and dissemination of humor in memes are both creative and complex,and the successful perception of meme humor reflects humans’universal thinking capacity.Based on the theoretical framework of conceptual blending,this paper selects a set of COVID-19 publicity posters from the official Weibo account of China Guangzhou Fabu(Guangzhou Internet Information Office),analyses the multi-level structure of Internet memes,and explores the dynamic cognitive process in the interpretation of humorous memes to reveal people’s ability to make simultaneous analogies and integration between elements in different mental spaces. 展开更多
关键词 conceptual blending Internet meme HUMOR COVID-19 prevention and control
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The application study of dual-energy CT nonlinearblending technique in pulmonary angiography
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作者 Siqi Yi Peng Zhou +2 位作者 Yakun He Changjiu He Shibei Hu 《Oncology and Translational Medicine》 CAS 2023年第1期22-27,共6页
Objective This study aimed to explore the feasibility of enhancing image quality in computed tomography(CT) pulmonary angiography (CTPA) and reducing radiation dose using the nonlinear blending (NLB)technique of dual-... Objective This study aimed to explore the feasibility of enhancing image quality in computed tomography(CT) pulmonary angiography (CTPA) and reducing radiation dose using the nonlinear blending (NLB)technique of dual-energy CT.Methods A total of 61 patients scheduled for CTPA were enrolled, and 30 patients underwent dual-energyscanning. Nonlinear blending images (NLB group) and three groups of linear blending images (LB group,80 kV group, and 140 kV group) were reconstructed after scanning;31 patients underwent single-energyscanning (120 kV group). The CT values and standard deviations of the pulmonary trunk, left and rightpulmonary arteries, and ipsilateral back muscle at the bifurcation level of the left and right pulmonaryarteries were measured. The signal-to-noise ratio (SNR) and contrast-to-noise ratio (CNR) of the fivegroups were calculated. The subjective image quality of the five groups was assessed. The radiation dosesof the dual- and single-energy groups were recorded and calculated.Results The CNR and SNR values of blood vessels in the NLB group were significantly higher than thosein the LB, 140 kV, and 80 kV groups (CNR of pulmonary artery trunk: t = 3.50, 4.06, 7.17, all P < 0.05;SNRof pulmonary trunk: t = 3.76, 4.71, 6.92, all P < 0.05). There were no statistical differences in the CNR andSNR values between the NLB group and 120 kV group (P > 0.05). The effective radiation dose of the dualenergygroup was lower than that of the single-energy group (t = –4.52, P < 0.05). The subjective scores ofimages in the NLB group were the highest (4.28 ± 0.74).Conclusion The NLB technique of dual-energy CT can improve the image quality of CTPA and reducethe radiation dose, providing more reliable imaging data for the clinical diagnosis of pulmonary embolism. 展开更多
关键词 dual-energy computed tomography(CT) CT pulmonary angiography(CTPA) non-linear blending(NLB) image quality radiation dose
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Assessing the conservation impact of Chinese indigenous chicken populations between ex-situ and in-situ using genome-wide SNPs
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作者 Wenting Li Chaoqun Gao +7 位作者 Zhao Cai Sensen Yan Yanru Lei Mengya Wei Guirong Sun Yadong Tian Kejun Wang Xiangtao Kang 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2024年第3期975-987,共13页
Conservation programs require rigorous evaluation to ensure the preservation of genetic diversity and viability of conservation populations. In this study, we conducted a comparative analysis of two indigenous Chinese... Conservation programs require rigorous evaluation to ensure the preservation of genetic diversity and viability of conservation populations. In this study, we conducted a comparative analysis of two indigenous Chinese chicken breeds, Gushi and Xichuan black-bone, using whole-genome SNPs to understand their genetic diversity, track changes over time and population structure. The breeds were divided into five conservation populations(GS1, 2010, ex-situ;GS2, 2019, ex-situ;GS3, 2019, in-situ;XB1, 2010, in-situ;and XB2, 2019, in-situ) based on conservation methods and generations. The genetic diversity indices of three conservation populations of Gushi chicken showed consistent trends, with the GS3 population under in-situ strategy having the highest diversity and GS2 under ex-situ strategy having the lowest. The degree of inbreeding of GS2 was higher than that of GS1 and GS3. Conserved populations of Xichuan black-bone chicken showed no obvious changes in genetic diversity between XB1 and XB2. In terms of population structure, the GS3 population were stratified relative to GS1 and GS2. According to the conservation priority, GS3 had the highest contribution to the total gene and allelic diversity in GS breed, whereas the contribution of XB1 and XB2 were similar. We also observed that the genetic diversity of GS2 was lower than GS3, which were from the same generation but under different conservation programs(in-situ and ex-situ). While XB1 and XB2 had similar levels of genetic diversity. Overall, our findings suggested that the conservation programs performed in ex-situ could slow down the occurrence of inbreeding events, but could not entirely prevent the loss of genetic diversity when the conserved population size was small, while in-situ conservation populations with large population size could maintain a relative high level of genetic diversity. 展开更多
关键词 genome-wide SNPs CONSERVATION genetic diversity ex-situ in-situ
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In-situ AFM and quasi-in-situ studies for localized corrosion in Mg-9Al-1Fe-(Gd) alloys under 3.5 wt.% NaCl environment
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作者 Junping Shen Tao Lai +7 位作者 Zheng Yin Yang Chen Kun Wang Hong Yan Honggun Song Ruiliang Liu Chao Luo Zhi Hu 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第3期1170-1185,共16页
Revealing the localized corrosion process of Mg alloy is considered as one of the most significant ways for improving its corrosion resistance.The reliable monitor should be high distinguishability and real-time in li... Revealing the localized corrosion process of Mg alloy is considered as one of the most significant ways for improving its corrosion resistance.The reliable monitor should be high distinguishability and real-time in liquid environment.Herein,Mg-9Al-1Fe and Mg-9Al-1Fe-1Gd alloys were designed to highlight the impact of intermetallic on the corrosion behaviour.In-situ AFM with a special electrolyte circulation system and quasi-in-situ SEM observation were used to monitor the corrosion process of the designed alloys.SEM-EDS and TEM-SAED were applied to identify the intermetallic in the designed alloys,and their volta potentials were measured by SKPFM.According to the real-time and real-space in-situ AFM monitor,the corrosion process consisted of dissolution of anodicα-Mg phase,accumulation of corrosion products around cathodic phase and shedding of some fine cathodic phase.Then,the localized corrosion process of Mg alloy was revealed combined with the results of the monitor of corrosion process and Volta potential difference. 展开更多
关键词 Magnesium Localized corrosion in-situ AFM SKPFM Corrosion behaviour.
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An in-situ study of static recrystallization in Mg using high temperature EBSD
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作者 Xu Ye Zhe Suo +5 位作者 Zhonghao Heng Biao Chen Qiuming Wei Junko Umeda Katsuyoshi Kondoh Jianghua Shen 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第4期1419-1430,共12页
It has been a common method to improve the mechanical properties of metals by manipulating their microstructures via static recrystallization,i.e.,through heat treatment.Therefore,the knowledge of recrystallization an... It has been a common method to improve the mechanical properties of metals by manipulating their microstructures via static recrystallization,i.e.,through heat treatment.Therefore,the knowledge of recrystallization and grain growth is critical to the success of the technique.In the present work,by using in-situ high temperature EBSD,the mechanisms that control recrystallization and grain growth of an extruded pure Mg were studied.The experimental results revealed that the grains of priority for dynamic recrystallization exhibit fading competitiveness under static recrystallization.It is also found that grain boundary movement or grain growth is likely to show an inverse energy gradient effect,i.e.,low energy grains tend to swallow or grow into high energy grains,and grain boundaries of close to 30°exhibit superior growth advantage to others.Another finding is that{10-12}tensile twin boundaries are sites of hardly observed for recrystallization,and are finally swallowed by adjacent recrystallized grains.The above findings may give comprehensive insights of static recrystallization and grain growth of Mg,and may guide the design of advanced materials processing in microstructural engineering. 展开更多
关键词 Pure Mg in-situ HT-EBSD RECRYSTALLIZATION Grain growth
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A continuous and long-term in-situ stress measuring method based on fiber optic. Part I: Theory of inverse differential strain analysis
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作者 Kun-Peng Zhang Mian Chen +2 位作者 Chang-Jun Zhao Su Wang Yong-Dong Fan 《Petroleum Science》 SCIE EI CAS CSCD 2024年第2期1171-1189,共19页
A method for in-situ stress measurement via fiber optics was proposed. The method utilizes the relationship between rock mass elastic parameters and in-situ stress. The approach offers the advantage of long-term stres... A method for in-situ stress measurement via fiber optics was proposed. The method utilizes the relationship between rock mass elastic parameters and in-situ stress. The approach offers the advantage of long-term stress measurements with high spatial resolution and frequency, significantly enhancing the ability to measure in-situ stress. The sensing casing, spirally wrapped with fiber optic, is cemented into the formation to establish a formation sensing nerve. Injecting fluid into the casing generates strain disturbance, establishing the relationship between rock mass properties and treatment pressure.Moreover, an optimization algorithm is established to invert the elastic parameters of formation via fiber optic strains. In the first part of this paper series, we established the theoretical basis for the inverse differential strain analysis method for in-situ stress measurement, which was subsequently verified using an analytical model. This paper is the fundamental basis for the inverse differential strain analysis method. 展开更多
关键词 in-situ stress Fiber optic Orthotropic elastic Differential evolution ABAQUS
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Microstructural characterization and mechanical properties of(TiC+TiB)/TA15 composites prepared by an in-situ synthesis method
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作者 Zhi-yong Zhang Jiao-jiao Cheng +3 位作者 Jia-qi Xie Shi-bing Liu Kun Shi Jun Zhao 《China Foundry》 SCIE EI CAS CSCD 2024年第2期168-174,共7页
Titanium matrix composites reinforced with ceramic particles are considered a promising engineering material due to their combination of high specific strength,low density,and high modulus.In this study,the TA15-based... Titanium matrix composites reinforced with ceramic particles are considered a promising engineering material due to their combination of high specific strength,low density,and high modulus.In this study,the TA15-based composites reinforced with a volume fraction of 10% to 25%(TiB+TiC)were prepared using powder metallurgy and casting technique.Microstructural characterization and phase constitution were examined using optical microscopy(OM),scanning electron microscopy(SEM),and X-ray diffraction(XRD).In addition,the microhardness,room temperature(RT)and high temperature(HT)tensile properties of the composites were evaluated.Results revealed that the reinforcements are distributed uniformly even in the composites with a high volume of TiB and TiC.However,as the volume fraction exceeds 15%,TiB and TiC particles become coarsening and exhibit rod-like and dendritic-like morphology.Microhardness increases gradually from 321.2 HV for the base alloy to a maximum of 473.3 HV as the reinforcement increases to 25vol.%.Tensile test results indicate that a reinforcement volume fraction above 20% is beneficial for enhancing tensile strength and yield strength at high temperatures,but it has an adverse effect on room temperature elongation.Conversely,if the reinforcement volume fraction is below 20%,it can improve high-temperature elongation when the temperature exceeds 600℃. 展开更多
关键词 titanium matrix composites microstucture MICROHARDNESS tensile properties in-situ synthesis
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An in-situ self-etching enabled high-power electrode for aqueous zinc-ion batteries
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作者 Shuang Hou Dingtao Ma +5 位作者 Yanyi Wang Kefeng Ouyang Sicheng Shen Hongwei Mi Lingzhi Zhao Peixin Zhang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第1期399-408,I0009,共11页
Sluggish storage kinetics is considered as the main bottleneck of cathode materials for fast-charging aqueous zinc-ion batteries(AZIBs).In this report,we propose a novel in-situ self-etching strategy to unlock the Pal... Sluggish storage kinetics is considered as the main bottleneck of cathode materials for fast-charging aqueous zinc-ion batteries(AZIBs).In this report,we propose a novel in-situ self-etching strategy to unlock the Palm tree-like vanadium oxide/carbon nanofiber membrane(P-VO/C)as a robust freestanding electrode.Comprehensive investigations including the finite element simulation,in-situ X-ray diffraction,and in-situ electrochemical impedance spectroscopy disclosed it an electrochemically induced phase transformation mechanism from VO to layered Zn_(x)V_(2)O_5·nH_(2)O,as well as superior storage kinetics with ultrahigh pseudocapacitive contribution.As demonstrated,such electrode can remain a specific capacity of 285 mA h g^(-1)after 100 cycles at 1 A g^(-1),144.4 mA h g^(-1)after 1500 cycles at 30 A g^(-1),and even 97 mA h g^(-1)after 3000 cycles at 60 A g^(-1),respectively.Unexpectedly,an impressive power density of 78.9 kW kg^(-1)at the super-high current density of 100 A g^(-1)also can be achieved.Such design concept of in-situ self-etching free-standing electrode can provide a brand-new insight into extending the pseudocapacitive storage limit,so as to promote the development of high-power energy storage devices including but not limited to AZIBs. 展开更多
关键词 in-situ self-etching Free-standing electrode Pseudocapacitive storage HIGH-POWER Zinc-ion batteries
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In-situ electrochemical study on the eff ects of Fe(Ⅲ)on kinetics of pyrite acidic pressure oxidation
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作者 Yu Zhang Can Cui +7 位作者 Sen Lin Heping Li Lian Yang Yadian Xie Hailiang Hu Lingyun Zhou Huanjiang Wang Chunyan Li 《Acta Geochimica》 EI CAS CSCD 2024年第4期814-825,共12页
Fe(Ⅲ)has been proved to be a more eff ective oxidant than dissolved oxygen at ambient temperature,however,the role of Fe(Ⅲ)in pyrite acidic pressure oxidation was rarely discussed so far.In this paper,in-situ electr... Fe(Ⅲ)has been proved to be a more eff ective oxidant than dissolved oxygen at ambient temperature,however,the role of Fe(Ⅲ)in pyrite acidic pressure oxidation was rarely discussed so far.In this paper,in-situ electrochemical investigation was performed using a flow-through autoclave system in acidic pressure oxidation environment.The results illustrated that increasing Fe(Ⅲ)concentrations led to raising in redox potential of the solution,and decreased passivation of pyrite caused by deposition of elemental sulfur.Reduction of Fe(Ⅲ)at pyrite surface was a fast reaction with low activation energy,it was only slightly promoted by rising temperatures.While,the oxidation rate of pyrite at all investigated Fe(Ⅲ)concentrations increased obviously with rising temperatures,the anodic reaction was the rate-limiting step in the overall reaction.Activation energy of pyrite oxidation decreased from 47.74 to 28.79 kJ/mol when Fe(Ⅲ)concentration was increased from 0.05 to 0.50 g/L,showing that the reaction kinetics were limited by the rate of electrochemical reaction at low Fe(Ⅲ)concentrations,while,it gradually turned to be diffusion control with increasing Fe(Ⅲ)concentrations. 展开更多
关键词 PYRITE Pressure oxidation Fe(Ⅲ) in-situ electrochemistry Hydrothermal experiment
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A review:Health benefits and physicochemical characteristics of blended vegetable oils
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作者 Hina Daud Memon Sarfaraz Ahmed Mahesar +3 位作者 Sirajuddin Huseyin Kara Syed Tufail Hussain Sherazi Mohammad Younis Talpur 《Grain & Oil Science and Technology》 CAS 2024年第2期113-123,共11页
Oil blending is the method of choice used worldwide to improve oxidative stability and nutritional value.There is no such edible oil/fat that meets all the recommendations from the health point of view.The fatty acid ... Oil blending is the method of choice used worldwide to improve oxidative stability and nutritional value.There is no such edible oil/fat that meets all the recommendations from the health point of view.The fatty acid composition of vegetable oils decides the fate of the oil.Pure single oil is unable to provide a balanced amount of fatty acids(FAs)required/recommended on a daily intake basis.Blending oils/fats is an appropriate procedure of physically mixing multiple oils in suitable proportions which may provide functional lipids with improved antioxidant potential and desirable physical and chemical properties.This review piled up the accessible data on the blending of diverse oils/fats in the combination of binary,ternary,quaternary,or other types of oils into a single blended oil.Blending can be found very convincing towards appropriate FA profile,enhancement in physicochemical characteristics,and augmented stability for the period of storage or when used as cooking/frying processes which could ultimately serve as an effectual dietary intervention towards the health protectiveness. 展开更多
关键词 Vegetable oil Oil blending Physicochemical properties Nutritional benefits
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Probing the Nucleation and Growth Kinetics of Bismuth Nanoparticles via In-situ Transmission Electron Microscopy
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作者 王浪 李超凡 +3 位作者 RAN Maojin YUAN Manman 胡执一 LI Yu 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第4期877-887,共11页
The nucleation and growth mechanism of nanoparticles is an important theory,which can guide the preparation of nanomaterials.However,it is still lacking in direct observation on the details of the evolution of interme... The nucleation and growth mechanism of nanoparticles is an important theory,which can guide the preparation of nanomaterials.However,it is still lacking in direct observation on the details of the evolution of intermediate state structure during nucleation and growth.In this work,the evolution process of bismuth nanoparticles induced by electron beam was revealed by in-situ transmission electron microscopy(TEM)at atomic scale.The experimental results demonstrate that the size,stable surface and crystallographic defect have important influences on the growth of Bi nanoparticles.Two non-classical growth paths including single crystal growth and polycrystalline combined growth,as well as,corresponding layer-by-layer growth mechanism along{012}stable crystal plane of Bi nanoparticles with dodecahedron structure were revealed by in-situ TEM directly.These results provide important guidance and a new approach for in-depth understanding of the nucleation and growth kinetics of nanoparticles. 展开更多
关键词 bismuth nanoparticles crystal growth transmission electron microscopy in-situ electron microscopy
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Development review and the prospect of oil shale in-situ catalysis conversion technology
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作者 Li Wang Chen-Hao Gao +2 位作者 Rui-Ying Xiong Xiao-Jun Zhang Ji-Xiang Guo 《Petroleum Science》 SCIE EI CAS CSCD 2024年第2期1385-1395,共11页
As an unconventional resource, oil shale possesses abundant reserves and significant potential for industrial applications. The rational and efficient development of oil shale resources holds immense importance in red... As an unconventional resource, oil shale possesses abundant reserves and significant potential for industrial applications. The rational and efficient development of oil shale resources holds immense importance in reducing national energy demand. In-situ catalytic technology, characterized by its high efficiency, low pollution, and minimal energy consumption, represents a key direction for future oil shale development. This paper provides a comprehensive review of research progress in in-situ oil shale mining technology, oil shale pyrolysis catalysts, the pyrolysis mechanism of kerogen, and the compatibility of different heating processes and catalysts. Furthermore, the paper proposes future research directions and prospects for oil shale in-situ catalytic technology, including reservoir modification, highefficiency catalyst synthesis, injection processes, and high-efficiency heating technology. These insights serve as valuable technical references for the advancement of oil shale in-situ catalytic technology. 展开更多
关键词 Oil shale in-situ catalytic technology Pyrolysis catalyst Kerogen pyrolysis mechanism
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Progress in in-situ electrochemical nuclear magnetic resonance for battery research
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作者 Yong Jiang Mengmeng Zhao +1 位作者 Zhangquan Peng Guiming Zhong 《Magnetic Resonance Letters》 2024年第2期13-21,共9页
A thorough understanding of the fundamental electrochemical and chemical processes in batteries is crucial to advancing energy density and power density.However,the characterizations of such processes are complex.In-s... A thorough understanding of the fundamental electrochemical and chemical processes in batteries is crucial to advancing energy density and power density.However,the characterizations of such processes are complex.In-situ electrochemical nuclear magnetic resonance(EC-NMR)offers the capability to collect real-time data during battery operation,furnishing insights into the local structures and ionic dynamics of materials by monitoring changes in the chemical environment around the nuclei.EC-NMR also has the advantages of being both quantitative and non-destructive.This paper systematically reviews the design of EC-NMR approach,and delves into the applications and progress of EC-NMR concerning battery reaction mechanisms,failure mechanisms,and overall battery systems.The review culminates in a comprehensive summary of the perspective and challenges associated with EC-NMR. 展开更多
关键词 in-situ NMR Reaction mechanism Failure mechanism Battery systems Ionic dynamics
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