Compared to other structural alloys,magnesium alloys have a relatively poor corrosion resistance and low mechanical strength,which can be further deteriorated when these alloys are subjected to joining processes using...Compared to other structural alloys,magnesium alloys have a relatively poor corrosion resistance and low mechanical strength,which can be further deteriorated when these alloys are subjected to joining processes using the existing joining methods.Herein,we propose for the first time an additive friction stir-welding(AFSW)using fine Al powder as an additive to improve the mechanical strength as well as corrosion resistance of AZ31B weld joints.AFSW is a solid-state welding method of forming a high-Al AZ31B joint via an in-situ reaction between pure Al powders filled in a machined groove and the AZ31B matrix.To optimize the process parameters,AFSW was performed under different rotational and transverse speeds,and number of passes,using tools with a square or screw pin.In particular,to fabricate a weld zone,where the Al was homogenously dispersed,the effects of the groove shape were investigated using three types of grooves:surface one-line groove,surface-symmetric grooves,and inserted symmetric grooves.The homogenous and defect-less AFS-welded AZ31B joint was successfully fabricated with the following optimal parameters:1400 rpm,25 mm/min,four passes,inserted symmetric grooves,and the tool with a square pin.The AFSW fully dissolved the additive Al intoα-Mg and in-situ precipitated Mg_(17)Al_(12)particles,which was confirmed via scanning electron microscopy,transmission electron microscope,and X-ray diffraction analyses.The microhardness,joint efficiency,and elongation at the fracture point of the AFS-welded AZ31B joint were 80 HV,101%,and 8.9%,respectively.These values are higher than those obtained for the FS-welded AZ31 joint in previous studies.The corrosion resistance of the AFS-welded AZ31B joint,evaluated via hydrogen evolution measurements and potentiodynamic polarization tests,was enhanced to 55%relative to the FS-welded AZ31B joint.展开更多
The fatigue life evaluation of the girth butt weld within the welded cast steel joint was studied based on the extrapolation notch stress method.Firstly,the mesh sensitivity of the finite element model of the welded c...The fatigue life evaluation of the girth butt weld within the welded cast steel joint was studied based on the extrapolation notch stress method.Firstly,the mesh sensitivity of the finite element model of the welded cast steel joint was analyzed to determine the optimal mesh size.Based on the stress field analysis of the finite element model of the welded cast steel joint at the weld toe and weld root,the sharp model of the extrapolation notch stress method was applied to derive the effective notch stress of the rounded model belonging to the effective notch stress method,in which the key problem is to calculate the extrapolation point C,and the extrapolation point C has an exponential function relationship with the geometric parameters of the welded cast steel joint.By setting different values of geometric parameters,the corresponding value of parameter C is calculated,and then the functional relationship between the extrapolation point C and the geometric parameters can be obtained by the multiple linear regression analysis.Meanwhile,the fatigue life evaluation of the girth butt weld within welded cast steel joints based on the effective notch stress was performed according to the guideline recommended by the IIW(International Institute of Welding).The results indicate that the extrapolation notch stress method can effectively simplify the process of calculating the effective notch stress and accurately evaluate the fatigue life of the girth butt weld within welded cast steel joints.展开更多
An aluminum-based in-situ composites reinforced with Mg2Si and Si particles were produced by centrifugal casting A1-20Si-5Mg alloy. The microstructure of the composites was examined, and the effects of temperature on ...An aluminum-based in-situ composites reinforced with Mg2Si and Si particles were produced by centrifugal casting A1-20Si-5Mg alloy. The microstructure of the composites was examined, and the effects of temperature on fracture behavior of the composite were investigated. The results show that the average fraction of primary Si and Mg2Si particles in the composites is as high as 38%, and ultimate tensile strengths (UTS) of the composites first increase then decrease with the increase of test temperature. Microstructures of broken specimens show that both the particle fracture and the interface debonding affect the fracture behavior of the composites, and the interface debonding becomes the dominant fracture mechanism with increasing test temperature. Comparative results indicate that rich particles in the composites and excellent interface strength play great roles in enhancing tensile property by preventing the movement of dislocations.展开更多
During dislocation,a tunnel crossing the active fault will be damaged to varying degrees due to its permanent stratum displacement.Most previous studies did not consider the influence of the tunnel’s deep burial and ...During dislocation,a tunnel crossing the active fault will be damaged to varying degrees due to its permanent stratum displacement.Most previous studies did not consider the influence of the tunnel’s deep burial and the high in-situ stress,so the results were not entirely practical.In this paper,the necessity of solving the anti-dislocation problem of deep-buried tunnels is systemically discussed.Through the model test of tunnels across active faults,the differences in failures between deep-buried tunnels and shallow-buried tunnels were compared,and the dislocation test of deep-buried segmental tunnels was carried out to analyze the external stress change,lining strain,and failure mode of tunnels.The results are as follows.(1)The overall deformation of deep-buried and shallow-buried tunnels is both Sshaped.The failure mode of deep-buried tunnels is primarily characterized by shear and tensile failure,resulting in significant compressive deformation and a larger damaged area.In contrast,shallow-buried tunnels mainly experience shear failure,with the tunnel being sheared apart at the fault crossing,leading to more severe damage.(2)After the segmental structure design of the deep-buried tunnel,the‘‘S”deformation pattern is transformed into a‘‘ladder”pattern,and the strain of the tunnel and the peak stress of the external rock mass are reduced;therefore,damages are significantly mitigated.(3)Through the analysis of the distribution of cracks in the tunnel lining,it is found that the tunnel without a segmental structure design has suffered from penetrating failure and that cracks affect the entire lining.The cracks in a flexible segmental tunnel affect about 66.6%of the entire length of the tunnel,and cracks in a tunnel with a short segmental tunnel only affect about 33.3%of the entire length of the tunnel.Therefore,a deep-buried tunnel with a short segmental tunnel can yield a better anti-dislocation effect.(4)By comparing the shallow-buried segmental tunnel in previous studies,it is concluded that the shallow-buried segmental tunnel will also suffer from deformation outside the fault zone,while the damages to the deep-buried segmental tunnel are concentrated in the fault zone,so the anti-dislocation protection measures of the deep-buried tunnel shall be provided mainly in the fault zone.The results of the above study can provide theoretical reference and technical support for the design and reinforcement measures of the tunnel crossing active fault under high in-situ stress conditions.展开更多
The corrosion behavior of friction-stir-welded 2A14-T6 aluminum alloy was investigated by immersion testing in immersion exfoliation corrosion(EXCO) solution. Electrochemical measurements(open circuit potential, po...The corrosion behavior of friction-stir-welded 2A14-T6 aluminum alloy was investigated by immersion testing in immersion exfoliation corrosion(EXCO) solution. Electrochemical measurements(open circuit potential, potentiodynamic polarization curves, and electrochemical impedance spectroscopy), scanning electron microscopy, and energy dispersive spectroscopy were employed for analyzing the corrosion mechanism. The results show that, compared to the base material, the corrosion resistance of the friction-stir welds is greatly improved, and the weld nugget has the highest corrosion resistance. The pitting susceptibility originates from the edge of Al-Cu-Fe-Mn-Si phase particles as the cathode compared to the matrix due to their high self-corrosion potential. No corrosion activity is observed around the θ phase(Al2Cu) after 2 h of immersion in EXCO solution.展开更多
In-situ observation of porosity formation during directional solidification of two Al-Si alloys (7%Si and 13%Si) was made by using of micro-focus X-ray imaging.In both alloys,small spherical pores initially form in th...In-situ observation of porosity formation during directional solidification of two Al-Si alloys (7%Si and 13%Si) was made by using of micro-focus X-ray imaging.In both alloys,small spherical pores initially form in the melt far away from the eutectic solid-liquid (S/L) interface and then grow and coagulate during solidification.Some pores can float and escape from the solidifying melt front at a relatively high velocity.At the end of solidification,the remaining pores maintain spherical morphology in the near eutectic alloy but become irregular in the hypoeutectic alloy.This is attributed to different solidification modes and aluminum dendrite interactions between the two alloys.The mechanism of the porosity formation is briefly discussed in this paper.展开更多
Heat transfer behaviors of AZ80?1%Y alloy during low frequency electromagnetic casting (LFEC) and direct chilling casting were studied by in-situ temperature measurement. The results demonstrated that the low frequenc...Heat transfer behaviors of AZ80?1%Y alloy during low frequency electromagnetic casting (LFEC) and direct chilling casting were studied by in-situ temperature measurement. The results demonstrated that the low frequency electromagnetic field (EM) caused forced convection in the melt during LFEC. The forced convection led to uniform solidification velocity and temperature field. EM frequency, excitation current intensity and casting temperature could control the heat transfer behavior. The forced convection could improve the microstructure and degrade the difference in microstructure between the edge and center of billet. Appropriate parameters of low frequency EM for casting Mg alloy are 20 Hz of frequency and 60 A of electric current intensity.展开更多
Sn/ENIG has recently been used in flexible interconnects to form a more stable micron-sized metallurgical joint,due to high power capability which causes solder joints to heat up to 200℃.However,Cu_(6)Sn_(5)which is ...Sn/ENIG has recently been used in flexible interconnects to form a more stable micron-sized metallurgical joint,due to high power capability which causes solder joints to heat up to 200℃.However,Cu_(6)Sn_(5)which is critical for a microelectronic interconnection,will go through a phase transition at temperatures between 186 and 189℃.This research conducted an in-situ TEM study of a micro Cu/ENIG/Sn solder joint under isothermal aging test and proposed a model to illustrate the mechanism of the microstructural evolution.The results showed that part of the Sn solder reacted with Cu diffused from the electrode to formη´-Cu_(6)Sn_(5)during the ultrasonic bonding process,while the rest of Sn was left and enriched in a region in the solder joint.But the enriched Sn quickly diffused to both sides when the temperature reached 100℃,reacting with the ENIG coating and Cu to form(Ni_(x)Cu_(1-x))_(3)Sn_(4),AuSn_(4),and Cu_(6)Sn_(5)IMCs.After entering the heat preservation process,the diffusion of Cu from the electrode to the joint became more intense,resulting in the formation of Cu_(3)Sn.The scallop-type Cu_(6)Sn_(5)and the seahorse-type Cu_(3)Sn constituted a typical two-layered structure in the solder joint.Most importantly,the transition betweenηandη’was captured near the phase transition temperature for Cu_(6)Sn_(5)during both the heating and cooling process,which was accompanied by a volume shifting,and the transition process was further studied.This research is expected to serve as a reference for the service of micro Cu/ENIG/Sn solder joints in the electronic industry.展开更多
基金This study was supported by the Research Program funded by the SeoulTech(Seoul National University of Science and Technology,Republic of Korea).
文摘Compared to other structural alloys,magnesium alloys have a relatively poor corrosion resistance and low mechanical strength,which can be further deteriorated when these alloys are subjected to joining processes using the existing joining methods.Herein,we propose for the first time an additive friction stir-welding(AFSW)using fine Al powder as an additive to improve the mechanical strength as well as corrosion resistance of AZ31B weld joints.AFSW is a solid-state welding method of forming a high-Al AZ31B joint via an in-situ reaction between pure Al powders filled in a machined groove and the AZ31B matrix.To optimize the process parameters,AFSW was performed under different rotational and transverse speeds,and number of passes,using tools with a square or screw pin.In particular,to fabricate a weld zone,where the Al was homogenously dispersed,the effects of the groove shape were investigated using three types of grooves:surface one-line groove,surface-symmetric grooves,and inserted symmetric grooves.The homogenous and defect-less AFS-welded AZ31B joint was successfully fabricated with the following optimal parameters:1400 rpm,25 mm/min,four passes,inserted symmetric grooves,and the tool with a square pin.The AFSW fully dissolved the additive Al intoα-Mg and in-situ precipitated Mg_(17)Al_(12)particles,which was confirmed via scanning electron microscopy,transmission electron microscope,and X-ray diffraction analyses.The microhardness,joint efficiency,and elongation at the fracture point of the AFS-welded AZ31B joint were 80 HV,101%,and 8.9%,respectively.These values are higher than those obtained for the FS-welded AZ31 joint in previous studies.The corrosion resistance of the AFS-welded AZ31B joint,evaluated via hydrogen evolution measurements and potentiodynamic polarization tests,was enhanced to 55%relative to the FS-welded AZ31B joint.
基金The National Key Research and Development Program of China(No.2017YFC0805100),the National Natural Science Foundation of China(No.51578137)the Priority Academic Program Development of Jiangsu Higher Education Institutions,the Open Research Fund Program of Jiangsu Key Laboratory of Engineering Mechanics.
文摘The fatigue life evaluation of the girth butt weld within the welded cast steel joint was studied based on the extrapolation notch stress method.Firstly,the mesh sensitivity of the finite element model of the welded cast steel joint was analyzed to determine the optimal mesh size.Based on the stress field analysis of the finite element model of the welded cast steel joint at the weld toe and weld root,the sharp model of the extrapolation notch stress method was applied to derive the effective notch stress of the rounded model belonging to the effective notch stress method,in which the key problem is to calculate the extrapolation point C,and the extrapolation point C has an exponential function relationship with the geometric parameters of the welded cast steel joint.By setting different values of geometric parameters,the corresponding value of parameter C is calculated,and then the functional relationship between the extrapolation point C and the geometric parameters can be obtained by the multiple linear regression analysis.Meanwhile,the fatigue life evaluation of the girth butt weld within welded cast steel joints based on the effective notch stress was performed according to the guideline recommended by the IIW(International Institute of Welding).The results indicate that the extrapolation notch stress method can effectively simplify the process of calculating the effective notch stress and accurately evaluate the fatigue life of the girth butt weld within welded cast steel joints.
基金Project(51174244) supported by the National Natural Science Foundation of ChinaProject(CDJZR11130005) supported by the Fundamental Research Funds for the Central Universities,China
文摘An aluminum-based in-situ composites reinforced with Mg2Si and Si particles were produced by centrifugal casting A1-20Si-5Mg alloy. The microstructure of the composites was examined, and the effects of temperature on fracture behavior of the composite were investigated. The results show that the average fraction of primary Si and Mg2Si particles in the composites is as high as 38%, and ultimate tensile strengths (UTS) of the composites first increase then decrease with the increase of test temperature. Microstructures of broken specimens show that both the particle fracture and the interface debonding affect the fracture behavior of the composites, and the interface debonding becomes the dominant fracture mechanism with increasing test temperature. Comparative results indicate that rich particles in the composites and excellent interface strength play great roles in enhancing tensile property by preventing the movement of dislocations.
基金supported by the National Key R&D Programs for Young Scientists of China(Grant No.2023YFB2390400)the National Natural Science Foundation of China(Grant Nos.U21A20159,52079133,52379112,and 41902288)+2 种基金Key Research Program of First Survey and Design Institute(Grant No.2022KY56(ZDZX)-02)Key Research Program of the Ministry of Water Resources of China(Grant No.SKS-2022103)Yunnan Major Science and Technology Special Program(Grant No.202102AF080001).
文摘During dislocation,a tunnel crossing the active fault will be damaged to varying degrees due to its permanent stratum displacement.Most previous studies did not consider the influence of the tunnel’s deep burial and the high in-situ stress,so the results were not entirely practical.In this paper,the necessity of solving the anti-dislocation problem of deep-buried tunnels is systemically discussed.Through the model test of tunnels across active faults,the differences in failures between deep-buried tunnels and shallow-buried tunnels were compared,and the dislocation test of deep-buried segmental tunnels was carried out to analyze the external stress change,lining strain,and failure mode of tunnels.The results are as follows.(1)The overall deformation of deep-buried and shallow-buried tunnels is both Sshaped.The failure mode of deep-buried tunnels is primarily characterized by shear and tensile failure,resulting in significant compressive deformation and a larger damaged area.In contrast,shallow-buried tunnels mainly experience shear failure,with the tunnel being sheared apart at the fault crossing,leading to more severe damage.(2)After the segmental structure design of the deep-buried tunnel,the‘‘S”deformation pattern is transformed into a‘‘ladder”pattern,and the strain of the tunnel and the peak stress of the external rock mass are reduced;therefore,damages are significantly mitigated.(3)Through the analysis of the distribution of cracks in the tunnel lining,it is found that the tunnel without a segmental structure design has suffered from penetrating failure and that cracks affect the entire lining.The cracks in a flexible segmental tunnel affect about 66.6%of the entire length of the tunnel,and cracks in a tunnel with a short segmental tunnel only affect about 33.3%of the entire length of the tunnel.Therefore,a deep-buried tunnel with a short segmental tunnel can yield a better anti-dislocation effect.(4)By comparing the shallow-buried segmental tunnel in previous studies,it is concluded that the shallow-buried segmental tunnel will also suffer from deformation outside the fault zone,while the damages to the deep-buried segmental tunnel are concentrated in the fault zone,so the anti-dislocation protection measures of the deep-buried tunnel shall be provided mainly in the fault zone.The results of the above study can provide theoretical reference and technical support for the design and reinforcement measures of the tunnel crossing active fault under high in-situ stress conditions.
基金financially supported by the National Natural Science Foundation of China (No. 51105030)
文摘The corrosion behavior of friction-stir-welded 2A14-T6 aluminum alloy was investigated by immersion testing in immersion exfoliation corrosion(EXCO) solution. Electrochemical measurements(open circuit potential, potentiodynamic polarization curves, and electrochemical impedance spectroscopy), scanning electron microscopy, and energy dispersive spectroscopy were employed for analyzing the corrosion mechanism. The results show that, compared to the base material, the corrosion resistance of the friction-stir welds is greatly improved, and the weld nugget has the highest corrosion resistance. The pitting susceptibility originates from the edge of Al-Cu-Fe-Mn-Si phase particles as the cathode compared to the matrix due to their high self-corrosion potential. No corrosion activity is observed around the θ phase(Al2Cu) after 2 h of immersion in EXCO solution.
基金funded by the Natural Science Foundation of China under grant No:50771031GM Research Funding under contract No:GM-RP-07-211
文摘In-situ observation of porosity formation during directional solidification of two Al-Si alloys (7%Si and 13%Si) was made by using of micro-focus X-ray imaging.In both alloys,small spherical pores initially form in the melt far away from the eutectic solid-liquid (S/L) interface and then grow and coagulate during solidification.Some pores can float and escape from the solidifying melt front at a relatively high velocity.At the end of solidification,the remaining pores maintain spherical morphology in the near eutectic alloy but become irregular in the hypoeutectic alloy.This is attributed to different solidification modes and aluminum dendrite interactions between the two alloys.The mechanism of the porosity formation is briefly discussed in this paper.
基金Project(2013CB632203)supported by the National Basic Research and Development Program of ChinaProject(2014028027)supported by the Liaoning Provincial Natural Science Foundation,China
文摘Heat transfer behaviors of AZ80?1%Y alloy during low frequency electromagnetic casting (LFEC) and direct chilling casting were studied by in-situ temperature measurement. The results demonstrated that the low frequency electromagnetic field (EM) caused forced convection in the melt during LFEC. The forced convection led to uniform solidification velocity and temperature field. EM frequency, excitation current intensity and casting temperature could control the heat transfer behavior. The forced convection could improve the microstructure and degrade the difference in microstructure between the edge and center of billet. Appropriate parameters of low frequency EM for casting Mg alloy are 20 Hz of frequency and 60 A of electric current intensity.
基金supported by the opening fund of National Key Research and Development Program of China(No.2020YFE0205300)Key Laboratory of Science and Technology on Silicon Devices,Chinese Academy of Sciences(No.KLSDTJJ2022-5)+1 种基金Chongqing Natural Science Foundation of China(No.cstc2021jcyj-msxmX1002)the Fundamental Research Funds for the Central Universities(No.AUGA5710051221).
文摘Sn/ENIG has recently been used in flexible interconnects to form a more stable micron-sized metallurgical joint,due to high power capability which causes solder joints to heat up to 200℃.However,Cu_(6)Sn_(5)which is critical for a microelectronic interconnection,will go through a phase transition at temperatures between 186 and 189℃.This research conducted an in-situ TEM study of a micro Cu/ENIG/Sn solder joint under isothermal aging test and proposed a model to illustrate the mechanism of the microstructural evolution.The results showed that part of the Sn solder reacted with Cu diffused from the electrode to formη´-Cu_(6)Sn_(5)during the ultrasonic bonding process,while the rest of Sn was left and enriched in a region in the solder joint.But the enriched Sn quickly diffused to both sides when the temperature reached 100℃,reacting with the ENIG coating and Cu to form(Ni_(x)Cu_(1-x))_(3)Sn_(4),AuSn_(4),and Cu_(6)Sn_(5)IMCs.After entering the heat preservation process,the diffusion of Cu from the electrode to the joint became more intense,resulting in the formation of Cu_(3)Sn.The scallop-type Cu_(6)Sn_(5)and the seahorse-type Cu_(3)Sn constituted a typical two-layered structure in the solder joint.Most importantly,the transition betweenηandη’was captured near the phase transition temperature for Cu_(6)Sn_(5)during both the heating and cooling process,which was accompanied by a volume shifting,and the transition process was further studied.This research is expected to serve as a reference for the service of micro Cu/ENIG/Sn solder joints in the electronic industry.