In-Situ Composition and Luminescence of Europium and Terbium Coordination Polymers/PEMA Hybrid Thick Films

Europium and terbium coordination polymers of pyridine-3-carboxylic acid were in-situ composed with ethyt methacrylate （ EMA ）. With the polymerization of EMA monomer and the formation of europium and terbium coordination polymers of pyridiae- 3-carboxylic acid, the transparent hybrid thick fihns composed of [ Eu（ NIC ）3 ]n （ [ Tb（ NIC）3 ]n ） and poly ethyl mettuwrylate （ PEMA ） have been prepared. The luminescence properties and energy transfer of these polymeric composites were studied with absorption spectra, fluorescent excitation trod emission spectra in detail. All the hybrid thick films composed of terbium coordination polymer show the characteristic strong green emission of terbium ions, which implies the same energy transfer mechanism as the pure complex and the hybrid composite film is a suitable sabstrate for the luminescence of terbium ions. In the range of camposing concentration of luminescent species （0.01,0.025,0.05,0.1 mmol /15 mL EMA ）, emission intensities increase with the increasing of corresponding composing concentration and the concentration quenching effect does not take place.

面向结构形状控制的驱动器结构参数与控制电压协同优化设计

飞机翼面结构形状的控制设计是提高飞机性能的关键技术。本文以压电纤维复合薄膜(Microfiber Composite,MFC)为驱动器,研究了协同优化设计MFC驱动器结构参数与控制电压以使飞机翼面结构具有理想形状的方法。以MFC的电极宽度、电极指间距、MFC厚度、压电陶瓷体积分数等驱动器结构参数以及控制电压为设计变量,以控制偏差最小为优化目标,以驱动器的击穿电压为约束,建立了驱动器结构参数与控制电压协同优化设计的模型;通过分析MFC驱动器结构参数对驱动性能的影响,给出了最优的驱动器结构参数;针对类似机翼翼面形状的平板扭转型面,给出了驱动器结构参数与控制电压协同的最优控制设计。设计结果表明:对于扭转变形,多个不同控制电压控制的型面均方差是相同控制电压控制均方差的45%,分析结果验证了本文所建立的协同优化设计方法的有效性。

微纳层叠共挤PP/PA6/CNTs原位微纤复合膜的制备及性能研究

采用双转子连续混炼挤出机与微纳层叠共挤出成型设备制备了聚丙烯/聚酰胺6/碳纳米管(PP/PA6/CNTs)复合材料和原位微纤复合膜,通过扫描电子显微镜(SEM)、流变仪、差示扫描量热仪(DSC)、万能拉伸试验机及电阻测试仪对其微观结构、流变性能、结晶性能、力学性能和导电性能进行了表征。结果表明,与共混相比,微纳层叠共挤出法使得分散相PA6/CNTs形成了微纤,微纤的形成不仅提升了复合膜的动态流变性能,并且增加了基体PP相的结晶度,提高了PA6相的结晶温度,提升了复合膜的结晶性能;当CNTs含量为0.5%(质量分数,下同)时,复合膜的拉伸强度和断裂伸长率均达到最大值,分别为42.17 MPa和857.82%,体积电阻率(R)下降到104Ω·cm,综合力学性能和导电性能达到最佳。