Optical-Electrical Characteristics and Carrier Dynamics of Semi-Insulation GaAs by Terahertz Spectroscopic Technique

OaAs has been widely used to fabricate a variety of optoelectronic devices by virtue of its superior performance, and it is very important to accurately measure its electrical and optical properties. In this study, a semi- insulation （SI） GaAs wafer is investigated by the terahertz （THz） non-destructive testing technology. Using an air biased coherent generation and detection THz time domain spectroscopy system, the THz time domain waveform and spectrum of SI-GaAs are obtained by the time domain spectroscopy module, and its optical- electrical characteristics including complex refractive index, permittivity and dielectric loss angle are calculated. Its carrier lifetime is measured by the optical-pump THz-probe module, and the THz pulse induced intervalley scattering in photo-excited SI-GaAs is discussed.

In-situ investigation of atmospheric corrosion behavior of bronze under thin electrolyte layers using electrochemical technique

The atmospheric corrosion behavior of bronze under thin electrolyte layer （TEL） with different thicknesses was monitored using cathodic polarization curves, open circuit potential （OCP） and electrochemical impedance spectroscopy （EIS）. Cathodic polarization result indicates that the cathodic limiting current density increases with decreasing the TEL thickness. EIS result shows that the corrosion rate increases with decreasing the TEL thickness at the initial stage because the corrosion is dominated by the cathodic process, whereas after long immersion time, the corrosion degree with the TEL thickness is in the sequence of 150 μm 〉 310 μm〉 10μm ≈ bulk solution 〉 57 μm. The measurements of OCP and EIS present in-situ electrochemical corrosion information and their results are in good agreement with that of physical characterizations.

In-situ/operando characterization techniques in lithium-ion batteries and beyond

Nowadays,in-situ/operando characterization becomes one of the most powerful as well as available means to monitor intricate reactions and investigate energy-storage mechanisms within advanced batteries.The new applications and novel devices constructed in recent years are necessary to be reviewed for inspiring subsequent studies.Hence,we summarize the progress of in-situ/operando techniques employed in rechargeable batteries.The members of this large family are divided into three sections for introduction,including bulk material,electrolyte/electrode interface and gas evolution.In each part,various energy-storage systems are mentioned and the related experimental details as well as data analysis are discussed.The simultaneous strategies of various in-situ methods are highlighted as well.Finally,current challenges and potential solutions are concluded towards the rising influence and enlarged appliance of in-situ/operando techniques in the battery research.

In-situ/operando techniques to identify active sites for thermochemical conversion of CO_(2) over heterogeneous catalysts

The catalytic conversion of CO_(2) to fuels or chemicals is considered to be an effective pathway to mitigate the greenhouse effect. To develop new types of efficient and durable catalysts, it is critical to identify the catalytic active sites, surface intermediates, and reaction mechanisms to reveal the relationship between the active sites and catalytic performance. However, the structure of a heterogeneous catalyst usually dynamically changes during reaction, bringing a great challenge for the identification of catalytic active sites and reaction pathways. Therefore, in-situ/operando techniques have been employed to real-time monitor the dynamic evolution of the structure of active sites under actual reaction conditions to precisely build the structure–function relationship. Here, we review the recent progress in the application of various in-situ/operando techniques in identifying active sites for catalytic conversion of CO_(2) over heterogeneous catalysts. We systematically summarize the applications of various optical and X-ray spectroscopy techniques, including Raman spectroscopy, Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and X-ray absorption spectroscopy (XAS), in identifying active sites and determining reaction mechanisms of the CO_(2) thermochemical conversion with hydrogen and light alkanes over heterogeneous catalysts. Finally, we discuss challenges and opportunities for the development of in-situ characterization in the future to further enlarge the capability of these powerful techniques.

Dynamic phase transition behavior of a LiMn_(0.5)Fe_(0.5)PO_(4) olivine cathode material for lithium-ion batteries revealed through in-situ X-ray techniques

LiMn_(0.5)Fe_(0.5)PO_(4) has attracted great interest due to its good electrochemical performance and higher operating voltages.This has led to a greater than 30 percent higher energy density than for commercial Li Fe PO4 olivine cathodes.Understanding the phase transition behaviors and kinetics of this material will help researchers to design and develop next generation cathodes for Li-ion batteries.In this study,we investigated non-equilibrium phase transition behaviors in a LiMn_(0.5)Fe_(0.5)PO_(4) cathode material during charge–discharge processes by varying current rates(C-rates)using synchrotron in-situ X-ray techniques.These methods included wide angle X-ray scattering(in-situ WAXS)and X-ray absorption spectroscopy(in-situ XAS).The WAXS spectra indicate that the phase transition of LiMn_(0.5)Fe_(0.5)PO_(4) material at slow C-rates is induced by a two-phase reaction.In contrast,at a high C-rate(5 C),the formation of an intermediate phase upon discharge is clearly observed.Concurrently,the oxidation numbers of the redox reactions of Fe^(2+)/Fe^(3+)and Mn^(2+)/Mn^(3+)were evaluated using in-situ XAS.This combination of synchrotron in-situ X-ray techniques gives clear insights into the non-equilibrium phase transition behavior of a LiMn_(0.5)Fe_(0.5)PO_(4) cathode material.This new understanding will be useful for further developments of this highly promising cathode material for practical commercialization.

Techniques for in-situ stress measurement at great depth

Reliable information of in--situ stress state is necessary for the design andconstruction of most important rock projects. As most rock projects are getting deeper and deeper,traditional techniques of in--situ stress measurement are not very suitable. The current techniquesof in--situ stress measurement and their insufficiency for use at great depth are analyzed. Somebasic ideas of the development of new techniques and the improvement of current techniques for useat great depth are provided.

IN-SITU TIME-RESOLVED RAMAN SPECTROSCOPIC STUDIES OF SILVER ELECTRODE IN NaSCN SOLUTION

In-situ time-resolved Raman spectroscopy(TRRS)has been applied on studies of electrochemical adsorption of thiocyanate at silver electrode during potential cycles and potential step.It is shown that some dynamic information about the adsorption and desorption processes can be obtained.

A Review of In‑Situ Techniques for Probing Active Sites and Mechanisms of Electrocatalytic Oxygen Reduction Reactions

Electrocatalytic oxygen reduction reaction(ORR)is one of the most important reactions in electrochemical energy technologies such as fuel cells and metal–O2/air batteries,etc.However,the essential catalysts to overcome its slow reaction kinetic always undergo a complex dynamic evolution in the actual catalytic process,and the concomitant intermediates and catalytic products also occur continuous conversion and reconstruction.This makes them difficult to be accurately captured,making the identification of ORR active sites and the elucidation of ORR mechanisms difficult.Thus,it is necessary to use extensive in-situ characterization techniques to proceed the real-time monitoring of the catalyst structure and the evolution state of intermediates and products during ORR.This work reviews the major advances in the use of various in-situ techniques to characterize the catalytic processes of various catalysts.Specifically,the catalyst structure evolutions revealed directly by in-situ techniques are systematically summarized,such as phase,valence,electronic transfer,coordination,and spin states varies.In-situ revelation of intermediate adsorption/desorption behavior,and the real-time monitoring of the product nucleation,growth,and reconstruction evolution are equally emphasized in the discussion.Other interference factors,as well as in-situ signal assignment with the aid of theoretical calculations,are also covered.Finally,some major challenges and prospects of in-situ techniques for future catalysts research in the ORR process are proposed.

Growth and Spectroscopic Characteristics of Yb^3+:LiGd(WO_4)_2 Crystal

The Yb3＋：LiGd（WO4）2 crystal with the dimension of Ф15×35 mm3 was grown by Czochralski technique. The spectroscopic characterization and fluorescence dynamics of Yb3＋ in yb3＋：LiGd（WO4）2 crystal were investigated. The yb3＋：LiGd（WO4）2 crystal exhibits a broad absorption band centered near 975 nm with the linewidths of 16 and 11 nm and maximal absorption cross-section of 3.60 × 10-20 and 2.90× 10-20 cm2 for π- and σ-polarization, respectively. The emission broadband has an FWHM of 47 and 45 nm with the emission cross sections of 3.92 × 10-20 and 3.34× 10-2o cm2 at 1020 nm for re- and or-polarization, respectively. The measured fluorescence lifetime is 398 gs. The blue light emission around 480 nm through cooperative upconversion from the de-excitation of excited Yb3＋-Yb3＋ pairs at 4 K was observed under 932-nm excitation and demonstrated.

A star-based method for precise wavelength calibration of the Chinese Space Station Telescope(CSST) slitless spectroscopic survey

The Chinese Space Station Telescope(CSST)spectroscopic survey aims to deliver high-quality low-resolution(R>200)slitless spectra for hundreds of millions of targets down to a limiting magnitude of about 21 mag,distributed within a large survey area(17500 deg2)and covering a wide wavelength range(255-1000 nm by three bands GU,GV,and GI).As slitless spectroscopy precludes the usage of wavelength calibration lamps,wavelength calibration is one of the most challenging issues in the reduction of slitless spectra,yet it plays a key role in measuring precise radial velocities of stars and redshifts of galaxies.In this work,we propose a star-based method that can monitor and correct for possible errors in the CSST wavelength calibration using normal scientific observations,taking advantage of the facts that(ⅰ)there are about ten million stars with reliable radial velocities now available thanks to spectroscopic surveys like LAMOST,(ⅱ)the large field of view of CSST enables efficient observations of such stars in a short period of time,and(ⅲ)radial velocities of such stars can be reliably measured using only a narrow segment of CSST spectra.We demonstrate that it is possible to achieve a wavelength calibration precision of a few km s^(-1) for the GU band,and about 10 to 20 kms^(-1) for the GV and GI bands,with only a few hundred velocity standard stars.Implementations of the method to other surveys are also discussed.

Optical system research of multi-object fiber spectroscopic survey telescope

In the first part of this paper,four different Cassegrain optical systems with their correctors are designed and studied for multi-object fiber slit spectroscopic survey.The aperture in 6.5 m and field of view 3°are taken for these optical systems.Assuming observation wavelength range is 0.365-0.95μm,the maximum zenith distance for observing is 60°,the maximum diameter of these lenses is 1.66 m,the altitude of the telescope site is 2500 m,two correctors are composed of 4-piece lenses and the other two are 5-piece lenses.The results obtained are:f-ratio about 3.7,the image quality for all four systems with EE80D≤0.60″,the linear diameter of the focal surface is about 1.2 m and 11 000 fibers can be set on it.Considering the limit of size of fused silica and optical glass,the maximum diameter for lens is about 1.7 m.Such a 6.5 m telescope is about the largest one if using the above correctors.Considering the multiobject spectroscopic survey is greatly important,we also studied some telescope optical systems having their aperture near or larger than 10 m used for the multi-object fiber spectroscopic survey.Such ideas are introduced in the last section of this paper.

An algorithm for preferential selection of spectroscopic targets in LEGUE

We describe a general target selection algorithm that is applicable to any survey in which the number of available candidates is much larger than the number of objects to be observed. This routine aims to achieve a balance between a smoothly- varying, well-understood selection function and the desire to preferentially select cer- tain types of targets. Some target-selection examples are shown that illustrate differentpossibilities of emphasis functions. Although it is generally applicable, the algorithm was developed specifically for the LAMOST Experiment for Galactic Understanding and Exploration （LEGUE） survey that will be carried out using the Chinese Guo Shou Jing Telescope. In particular, this algorithm was designed for the portion of LEGUE targeting the Galactic halo, in which we attempt to balance a variety of science goals that require stars at fainter magnitudes than can be completely sampled by LAMOST. This algorithm has been implemented for the halo portion of the LAMOST pilot sur- vey, which began in October 2011.

Kinematics and stellar population properties of the Andromeda galaxy by using the spectroscopic observations of the Guoshoujing Telescope

The Andromeda galaxy was observed by the Guoshoujing Telescope （formerly named the Large Sky Area Multi-Object Fiber Spectroscopic Telescope -- LAMOST）, during the 2009 commissioning phase. Due to the absence of standard stars for flux calibration, we use the photometric data of 15 intermediate bands in the Beijing-Arizona-Taipei-Connecticut （BATC） survey to calibrate the spectra. In to- tal, 59 spectra located in the bulge and disk of the galaxy are obtained. Kinematic and stellar population properties of the stellar content are derived with these spectra. We obtain the global velocity field and calculate corresponding rotation velocities out to about 7 kpc along the major axis. These rotation velocity measurements comple- ment those of the gas content, such as the H I and CO. The radial velocity dispersion shows that the stars in the bulge are more dynamically thermal and the disk is more rotationally-supported. The age distribution shows that the bulge was formed about 12 Gyr ago, the disk is relatively younger and the ages of some regions along the spi- ral arms can reach as young as about 1 Gyr. These young stellar populations have a relatively richer abundance and larger reddening. The overall average metallicity of the galaxy approximates the solar metallicity and a very weak abundance gradient is gained. The reddening map gives a picture of a dust-free bulge and a distinct dusty ring in the disk.

Stellar Abundance and Galactic Chemical Evolution through LAMOST Spectroscopic Survey

A project of a spectroscopic survey of Galactic structure and evolution with a Large sky Area Multi-Object fiber Spectroscopic Telescope （LAMOST） is presented. The spectroscopic survey consists of two observational modes for various targets in our Galaxy. One is a major survey of the Milky Way aimed at a systematic study of the stellar abundance and Galactic chemical evolution through low resolution （R = 1000 2000） spectroscopy. Another is a follow-up observation with medium resolution （R = 10000） spectrographs aimed at detailed studies of the selected stars with different chemical composition, kinematics and dynamics.

Spectroscopic study of Be-shell stars:4 Her and 88 Her

We present an optical spectroscopic study based on 41 spectra of 4 Her and 32 spectra of 88 Her, obtained over a period of 6 months. We estimate the rotational velocity of these stars from HeI lines in the blue spectral region （4000-4500 A）. We find that these stars are likely to be rotating at a fractional critical rotation of -0.80. We measure the average Ip/lc ratio to quantify the strength of the Ha line and obtain 1.63 for 4 Her and 2.06 for 88 Her. The radius of the Ha emission region is estimated to be Ra/R. -5.0, assuming a Keplerian disk. These stars are thus found to be fast rotators with a relatively small Hoe emission region. We detect V/R variation of the Ha spectral line during the observed period. We re-estimate the periods for both stars and obtain a period of ,-46 d and its harmonic of 23.095 d for 4 Her, and a period of -86 d for 88 Her. As these two cases are shell stars with binaries and have low Ha EW with the emission region closer to the central star, the V/R variation and a change in period may be an effect of the binary on the circumstellar disk.

In-situ Investigation of BBr_3/benzene Solution by Fourier Transformation Infrared Spectroscopy

By means of the in-situ Fourier transformation infrared spectroscopy（FTIR）, the properties of BBr3/ benzene solution, which is usually used as the reactant and solution to synthesize BN by benzene-thermal method, have been investigated. The results show that there are some side reactions between BBr3 and benzene： （1） BBr3 as an electron-deficient molecule reacts with benzene at room temperature; （2） below 100℃, substitution of Br atom for H atom of benzene（ring-H） dominates in BBr3/benzene solution; （3） cracking of benzene ring occurs at a temperature above 100℃; （4） decomposition of benzene molecules and formation of long-chain aliphatic compounds feature the spectra of BBr3/benzene solution collected at above 160℃, They are unfavor for BN to form when BBr3 is excessive in the synthesis of BN by benzene-thermal route. On the basis of the experimental results, a coordination reaction mechanism via a η^2-C6H6 binding mode in BBr3/benzene solution is suggested.

On the radial velocity calibrations in the LAMOST medium-resolution spectroscopic survey of nebulae

Accurate radial velocity determinations of optical emission lines(i.e.,[NⅡ]λλ6548,6584,Hαand[SⅡ]λλ6717,6731)are very important for investigating the kinematic and dynamic properties of nebulae.The second stage survey program of Large sky Area Multi-Object fiber Spectroscopic Telescope(LAMOST)has started a sub-survey of nebulae(MRS-N)which will spectroscopically observe the optical emission lines of a large sample of nebulae near the Galactic plane.Until now,15 MRS-N plates have been observed from September 2017 to June 2019.Based on fitting the sky emission lines in the red band spectra of MRS-N,we investigate the precision of wavelength calibration and find there are systematic deviations of radial velocities(RVs)from~0.2 to 4 km s^(-1) for different plates.Especially for the plates obtained in March 2018,the systematic deviations of RVs can be as large as~4 km s^(-1),which then go down to~0.2-0.5 kms^(-1) at the end of 2018 and January 2019.An RV calibration function is proposed for these MRS-N plates,which can simultaneously and successfully calibrate the systematic deviations and improve the precision of RVs.

Photometric and Spectroscopic Analysis of LBV Candidate J004341.84+411112.0 in M31

We study Luminous Blue Variable(LBV)candidate J004341.84+411112.0 in the Andromeda galaxy.We present optical spectra of the object obtained with the 6 m telescope of BTA SAO RAS.The candidate shows typical LBV features in its spectra:broad and strong hydrogen lines and the He I lines with P Cygni profiles.Its remarkable spectral resemblance to the well known LBV P Cygni suggests a common nature of the objects and supports LBV classification of J004341.84+411112.0.We estimate the temperature,reddening,radius and luminosity of the star using its spectral energy distribution.Obtained bolometric luminosity of the candidate(M_(bol)=-10.41±0.12 mag)is quite similar to those of known LBV stars in the Andromeda galaxy.We analyzed a ten year light curve of the object in R filter.The candidate demonstrates photometric variations of the order of 0.4 mag,with an overall brightness increasing trendΔR>0.1 mag.Therewith,the corresponding color variations of the object are fully consistent with LBV behavior when a star become cooler and brighter in the optical spectral range with a nearly constant bolometric luminosity.LBV-type variability of the object,similarity of its spectrum and estimated luminosity to those of known LBVs allow us to classify J004341.84+411112.0 as an LBV.

Optical Spectroscopic Monitoring Observations of a Young Binary Z CMa

The results of optical spectroscopic monitoring observations of a young binary system, Z CMa, are presented in this study. Z CMa consists of a Herbig Be star and an FU Orionis object, and it shows irregular light variation in the quiescent phase and exploding brightening in the outburst phase. Medium-resolution spectra were obtained on 21 nights between 2015 and 2019 using the Nayuta telescope in Japan. We also used five high-resolution spectra, obtained between 2008 and 2011, with the Keck Telescope. During the outburst phase, the intensity of the He I absorption line increased with an increase in the luminosity of the system. Because the He I absorption line is a characteristic feature of an early-type star, we considered that the outbursts were caused by the Herbig Be star. The equivalent widths of the [O I] line decreased with an increase in the luminosity of the system. We claim steady mass loss at the rate of The intensities of the Hα and Fe II emission lines did not change during the outbursts. However, the line intensities increased with an increase in the luminosity of the system in the quiescent phase. We consider that those lines are attributed to the FU Orionis object and the light variations in the quiescent phase were caused by the FU Orionis object.

Advance of in-situ stress measurement in China

In-situ stress is an essential parameter for design and construction of most engineering projects that involve excavation in rocks. Progress in in-situ stress measurement from the 1950s in China is briefly introduced. Stress relief by overcoring technique and hydraulic fracturing： technique are the two main techniques for in-situ stress measurement in China at present. To make them suitable for application at great depth and to increase their measuring reliability and accuracy, a series of techniques have been developed. Applications and achievements of in-situ stress measurement in Chinese rock engineering, including mining, geotechnical and hydropower engineering, and earthquake prediction, are introduced. Suggestions for further development of in-situ stress measurement are also proposed.