Cu-phthalocyanine is widely studied as a hole-transport layer in organic electronic devices. Since Cu-phthalocyanine is a molecular solid, the crystal structure depends on a circumstance to a great extent. Vacuum depo...Cu-phthalocyanine is widely studied as a hole-transport layer in organic electronic devices. Since Cu-phthalocyanine is a molecular solid, the crystal structure depends on a circumstance to a great extent. Vacuum deposited layers were known to consist of two consecutive layers. In this article, Cu-phthalocyanine was deposited on the glass substrate inclined at several angles. The thickness of the first layer was found to be dependent on the substrate angle.展开更多
To improve the effectiveness of control of surrounding rock and the stability of supports on longwall topcoal caving faces in steeply inclined coal seams, the stability of the roof structure and hydraulic supports was...To improve the effectiveness of control of surrounding rock and the stability of supports on longwall topcoal caving faces in steeply inclined coal seams, the stability of the roof structure and hydraulic supports was studied with physical simulation and theoretical analysis. The results show that roof strata in the vicinity of the tail gate subside extensively with small cutting height, while roof subsidence near the main gate is relatively assuasive. With increase of the mining space, the caving angle of the roof strata above the main gate increases. The characteristics of the vertical and horizontal displacement of the roof strata demonstrate that caved blocks rotate around the lower hinged point of the roof structure, which may lead to sliding instability. Large dip angle of the coal seam makes sliding instability of the roof structure easier.A three-hinged arch can be easily formed above both the tail and main gates in steeply inclined coal seams. With the growth in the dip angle, subsidence of the arch foot formed above the main gate decreases significantly, which reduces the probability of the roof structure becoming unstable as a result of large deformation, while the potential of the roof structure's sliding instability above the tail gate increases dramatically.展开更多
According to the structural characteristics of gently inclined thin layer rock mass in which lots of weak interlayer existed,the concept of gently inclined thin layer weakness structure was proposed.If single-borehole...According to the structural characteristics of gently inclined thin layer rock mass in which lots of weak interlayer existed,the concept of gently inclined thin layer weakness structure was proposed.If single-borehole measuring method of the acoustic along the conventional arrangement mode was used in measuring the broken rock zone in this structure,the change of the relationship curves (Vp-L) between acoustic p-wave velocity (Vp) and borehole depth (L) would present the irregular feature due to the mechanical characteristics of layered rock mass and harmful effects of weak interlayers,and the scope of broken rock zone couldn't be defined quickly.Based on the analysis of the me- chanical characteristics of layered rock mass,the propagation rule of acoustic and distri- butions characteristics of plastic zone and slip zone in layered rock mass,new arrange- ment mode of acoustic measuring boreholes for broken rock zone in gently inclined thin layer weakness structure was proposed.Namely,the measuring boreholes in two sides were parallel to the strata,the measuring boreholes in the roof and floor perpendicular to the strata.Besides the controlling depth of the measuring boreholes in the scope of the large plastic zones or the large slip zones should be increased.Engineering example showed that new acoustic measuring boreholes arrangement mode had the better appli- cability and could determine the scope of the broken rock zone in the gently inclined thin layer weakness structure quickly.展开更多
The microstructures of conch shell were observed with scanning electronic microscope (SEM), and a kind of inclined-cross microstructure of aragonite sheets was found. The maximal pull-out force of the inclined-cros...The microstructures of conch shell were observed with scanning electronic microscope (SEM), and a kind of inclined-cross microstructure of aragonite sheets was found. The maximal pull-out force of the inclined-cross microstructure was analyzed based on its representative model and compared with that of a conventional 0 °- structure. The experimental result indicates that the maximal pull-out force of the inclined-cross microstructure is markedly larger than that of the 0°- structure.展开更多
The method to calculate rock pressure to which the lining structure of tunnel with shallow depth is subjected in geologically inclined bedding strata is analyzed and put forward. Both the inclination angle of bedding ...The method to calculate rock pressure to which the lining structure of tunnel with shallow depth is subjected in geologically inclined bedding strata is analyzed and put forward. Both the inclination angle of bedding strata as well as the internal friction angle of bedding plane and its cohesion all exert an influence upon the magnitude of the asymmetric rock pressure applied to tunnel. The feature that rock pressure applied to tunnel structure varies with the incUnation angle of bedding strata is discussed, At last, the safety factor, which is utilized to evaluate the working state of tunnel lining structure, is calculated for both symmetric and asymmetric lining structures. The calculation results elucidate that the asymmetric tunnel structure can be more superior to bear rock pressure in comparison with the symmetric one and should be adopted in engineering as far as possible.展开更多
The stability of inclined shaft lining structure (ISLS) in complex water-rich strata is affected by many factors, suchas water pressure, joint, soft rock, lining corrosion and so on. The instability of the ISLS will a...The stability of inclined shaft lining structure (ISLS) in complex water-rich strata is affected by many factors, suchas water pressure, joint, soft rock, lining corrosion and so on. The instability of the ISLS will affect the safe andefficient coal mine production. Bathe sed on the geological conditions of the Xiaobaodang coal mine, this papertested the evolution characteristics of concrete composition in long-term water seepage areas and revealed theinfluence mechanism of corrosion weakening of shaft lining (SL) in water-rich strata. Meanwhile, transientelectromagnetic, ground penetrating radar, and infrared monitoring are used to detect the water-rich zones, anddamage zones of surrounding rock and lining water seepage zones, and a three-level safety evaluation model forthe instability risk of ISLS is constructed. Water abundance of the surrounding rock, surrounding rock deterioration, and shaft lining seepage were the specific indicators in the model. The main inclined shaft (MIS) in thestudied coal mine is divided into three levels: non instability risk zone, potential instability risk zone, and highinstability risk zone. According to the evaluation results, comprehensive prevention and control measures of“hydrophobic hole drainage” and “back-lining grouting” are adopted for the water inrush source and the surrounding rock micro-crack water channel. The precise prevention and control of ISLS is realized. The researchresults also provide a reference for the stability evaluation of ISLS and the accurate prevention and control undersimilar conditions.展开更多
文摘Cu-phthalocyanine is widely studied as a hole-transport layer in organic electronic devices. Since Cu-phthalocyanine is a molecular solid, the crystal structure depends on a circumstance to a great extent. Vacuum deposited layers were known to consist of two consecutive layers. In this article, Cu-phthalocyanine was deposited on the glass substrate inclined at several angles. The thickness of the first layer was found to be dependent on the substrate angle.
基金the Joint Funds of the National Natural Science Foundation of China (No. U1361209)the National Basic Research Program of China (No. 2013CB227903)
文摘To improve the effectiveness of control of surrounding rock and the stability of supports on longwall topcoal caving faces in steeply inclined coal seams, the stability of the roof structure and hydraulic supports was studied with physical simulation and theoretical analysis. The results show that roof strata in the vicinity of the tail gate subside extensively with small cutting height, while roof subsidence near the main gate is relatively assuasive. With increase of the mining space, the caving angle of the roof strata above the main gate increases. The characteristics of the vertical and horizontal displacement of the roof strata demonstrate that caved blocks rotate around the lower hinged point of the roof structure, which may lead to sliding instability. Large dip angle of the coal seam makes sliding instability of the roof structure easier.A three-hinged arch can be easily formed above both the tail and main gates in steeply inclined coal seams. With the growth in the dip angle, subsidence of the arch foot formed above the main gate decreases significantly, which reduces the probability of the roof structure becoming unstable as a result of large deformation, while the potential of the roof structure's sliding instability above the tail gate increases dramatically.
基金the National Natural Science Foundation of China(50490274)National Key Project of Scientific and Technical Supporting Programs of China(2006BAB02A02)Guangxi University Research Foundation(X061068)
文摘According to the structural characteristics of gently inclined thin layer rock mass in which lots of weak interlayer existed,the concept of gently inclined thin layer weakness structure was proposed.If single-borehole measuring method of the acoustic along the conventional arrangement mode was used in measuring the broken rock zone in this structure,the change of the relationship curves (Vp-L) between acoustic p-wave velocity (Vp) and borehole depth (L) would present the irregular feature due to the mechanical characteristics of layered rock mass and harmful effects of weak interlayers,and the scope of broken rock zone couldn't be defined quickly.Based on the analysis of the me- chanical characteristics of layered rock mass,the propagation rule of acoustic and distri- butions characteristics of plastic zone and slip zone in layered rock mass,new arrange- ment mode of acoustic measuring boreholes for broken rock zone in gently inclined thin layer weakness structure was proposed.Namely,the measuring boreholes in two sides were parallel to the strata,the measuring boreholes in the roof and floor perpendicular to the strata.Besides the controlling depth of the measuring boreholes in the scope of the large plastic zones or the large slip zones should be increased.Engineering example showed that new acoustic measuring boreholes arrangement mode had the better appli- cability and could determine the scope of the broken rock zone in the gently inclined thin layer weakness structure quickly.
文摘The microstructures of conch shell were observed with scanning electronic microscope (SEM), and a kind of inclined-cross microstructure of aragonite sheets was found. The maximal pull-out force of the inclined-cross microstructure was analyzed based on its representative model and compared with that of a conventional 0 °- structure. The experimental result indicates that the maximal pull-out force of the inclined-cross microstructure is markedly larger than that of the 0°- structure.
文摘The method to calculate rock pressure to which the lining structure of tunnel with shallow depth is subjected in geologically inclined bedding strata is analyzed and put forward. Both the inclination angle of bedding strata as well as the internal friction angle of bedding plane and its cohesion all exert an influence upon the magnitude of the asymmetric rock pressure applied to tunnel. The feature that rock pressure applied to tunnel structure varies with the incUnation angle of bedding strata is discussed, At last, the safety factor, which is utilized to evaluate the working state of tunnel lining structure, is calculated for both symmetric and asymmetric lining structures. The calculation results elucidate that the asymmetric tunnel structure can be more superior to bear rock pressure in comparison with the symmetric one and should be adopted in engineering as far as possible.
基金Financial support for this work was provided by the National Natural Science Foundation of China(52104155)Natural Science Foundation of Beijing(8212032)+2 种基金the Postdoctoral Research Foundation of China(2023M733778)an Open Research Grant of Joint National-Local Engineering Research Centre for Safe and Precise Coal Mining(EC2022012)the Fundamental Research Funds for the Central Universities(2023ZKPYNY03).
文摘The stability of inclined shaft lining structure (ISLS) in complex water-rich strata is affected by many factors, suchas water pressure, joint, soft rock, lining corrosion and so on. The instability of the ISLS will affect the safe andefficient coal mine production. Bathe sed on the geological conditions of the Xiaobaodang coal mine, this papertested the evolution characteristics of concrete composition in long-term water seepage areas and revealed theinfluence mechanism of corrosion weakening of shaft lining (SL) in water-rich strata. Meanwhile, transientelectromagnetic, ground penetrating radar, and infrared monitoring are used to detect the water-rich zones, anddamage zones of surrounding rock and lining water seepage zones, and a three-level safety evaluation model forthe instability risk of ISLS is constructed. Water abundance of the surrounding rock, surrounding rock deterioration, and shaft lining seepage were the specific indicators in the model. The main inclined shaft (MIS) in thestudied coal mine is divided into three levels: non instability risk zone, potential instability risk zone, and highinstability risk zone. According to the evaluation results, comprehensive prevention and control measures of“hydrophobic hole drainage” and “back-lining grouting” are adopted for the water inrush source and the surrounding rock micro-crack water channel. The precise prevention and control of ISLS is realized. The researchresults also provide a reference for the stability evaluation of ISLS and the accurate prevention and control undersimilar conditions.