The holographic storage properties of Fe (0.03% (mass fraction) Fe2O3):LiNbO3 doped with Sc at different levels (0, 1%, 2%, 3%) were investigated. The Sc threshold concentration in Fe:LiNbO3 was implied to be ...The holographic storage properties of Fe (0.03% (mass fraction) Fe2O3):LiNbO3 doped with Sc at different levels (0, 1%, 2%, 3%) were investigated. The Sc threshold concentration in Fe:LiNbO3 was implied to be about 3% (mole fraction) because O-H vibration absorption peak of Sc (3%):Fe:LiNbO3 was at 3508 cm^-1, compared with 3484 cm^-1 of crystals with lower Sc doping level. Sc(3%):Fe:LiNbO3 exhibited higher optical damage resistance ability. The threshold intensity (wavelength 488 nm) of Sc (3%):Fe:LiNbO3 was 2.2 ×10^2 W ·cm^-2, two orders of masnitude higher than that of Fe:LiNbO3. Holographic storage properties of the crystals were determined in an extraordinary polarized laser of wavelength 632.8 nm by a two-wave coupling method. It was found that in terms of holographic storage properties, the optimal doping concentration of Sc was 2% (mole fraction) among this crystal series.展开更多
The relationship between temperature and oxygen vacancy concentration is deduced in this paper. Based on the data of thermal weight-loss experiment, the formation enthalpies of congruent and several doped LN crystals ...The relationship between temperature and oxygen vacancy concentration is deduced in this paper. Based on the data of thermal weight-loss experiment, the formation enthalpies of congruent and several doped LN crystals have been calculated. It was found that the formation enthalpy of oxygen vacancies can be decreased evidently by doping valence-changeable ions. The experimental results were discussed and a new reduction process of the photorefractive LN crystal at a relatively low temperature was proposed, and the reduced crystals showed a good effect in practical use.展开更多
基金Project supported by Natural Science Foundation of Heilongjiang Province (E200512)
文摘The holographic storage properties of Fe (0.03% (mass fraction) Fe2O3):LiNbO3 doped with Sc at different levels (0, 1%, 2%, 3%) were investigated. The Sc threshold concentration in Fe:LiNbO3 was implied to be about 3% (mole fraction) because O-H vibration absorption peak of Sc (3%):Fe:LiNbO3 was at 3508 cm^-1, compared with 3484 cm^-1 of crystals with lower Sc doping level. Sc(3%):Fe:LiNbO3 exhibited higher optical damage resistance ability. The threshold intensity (wavelength 488 nm) of Sc (3%):Fe:LiNbO3 was 2.2 ×10^2 W ·cm^-2, two orders of masnitude higher than that of Fe:LiNbO3. Holographic storage properties of the crystals were determined in an extraordinary polarized laser of wavelength 632.8 nm by a two-wave coupling method. It was found that in terms of holographic storage properties, the optimal doping concentration of Sc was 2% (mole fraction) among this crystal series.
文摘The relationship between temperature and oxygen vacancy concentration is deduced in this paper. Based on the data of thermal weight-loss experiment, the formation enthalpies of congruent and several doped LN crystals have been calculated. It was found that the formation enthalpy of oxygen vacancies can be decreased evidently by doping valence-changeable ions. The experimental results were discussed and a new reduction process of the photorefractive LN crystal at a relatively low temperature was proposed, and the reduced crystals showed a good effect in practical use.