The new approaches to construct deep blue aggregation-induced emission （ALE） materials have been explored, which control the conjugation by two different strategies, to make a great step for the commercialization of...The new approaches to construct deep blue aggregation-induced emission （ALE） materials have been explored, which control the conjugation by two different strategies, to make a great step for the commercialization of organic light-emitting diodes. In order to shorten the intramolecular conjugation length, triphenylethylene （tPE） was utilized to construct blue AIEgens as peripheral groups, instead of tetraphenylethylene （TPE）, the famous AIE star molecule, to yield three blue AIEgens of 3,4-BtPE-PI, 4,4- BtPE-PI and 4,4-BtPE-PPI. Nondoped electroluminescence devices are fabricated by using these three AIEgens as the emitting material layer, the best performance of 3.8 cd/A as the maximum current efficiency achieved at the commission internationale de l＇Eclairage coordinates of （0.17, 0.18）.展开更多
基金supported by the National Natural Science Foundation of China (21325416 and 51573140)the National Basic Research Program of China (2013CB834701)
文摘The new approaches to construct deep blue aggregation-induced emission （ALE） materials have been explored, which control the conjugation by two different strategies, to make a great step for the commercialization of organic light-emitting diodes. In order to shorten the intramolecular conjugation length, triphenylethylene （tPE） was utilized to construct blue AIEgens as peripheral groups, instead of tetraphenylethylene （TPE）, the famous AIE star molecule, to yield three blue AIEgens of 3,4-BtPE-PI, 4,4- BtPE-PI and 4,4-BtPE-PPI. Nondoped electroluminescence devices are fabricated by using these three AIEgens as the emitting material layer, the best performance of 3.8 cd/A as the maximum current efficiency achieved at the commission internationale de l＇Eclairage coordinates of （0.17, 0.18）.
