This brief article reviews a very particular and quite narrowfield,namely what has been done and what is needed to know for tannin adhesives for wood panels to succeed industrially.The present fashionable focus on bio...This brief article reviews a very particular and quite narrowfield,namely what has been done and what is needed to know for tannin adhesives for wood panels to succeed industrially.The present fashionable focus on bioadhe-sives has led to producing chemical adhesive formulations and approaches for tannin adhesives as a subject of academic publications.These,as good and original they might be,are and will still remain a rather empty aca-demic exercise if not put to the test of real industrial trials and industrial use.They will remain so without the“little”secrets and techniques outlined here that show that there is a great gap between developing an adhesive formulation in the laboratory and the hard reality to make it work where it does really count,in its industrial application.It outlines the fact that even more modern and excellent,newly developed bioadhesive formulations might well miserably fail once tried in the industry if the problems that always arise in their upgrading are not identified and solved,and solved well.It also outlines the fact that not only must costs always be taken into account and that a practical and possibly easy-to-handle approach must always be used,but too expensive or complex and unyielding adhesive systems are also often shown to be unusable or unsuitable in industry.展开更多
An industrialized technique of preparation for oxidized com starch using oxygen as oxidant was investigated in this paper. The industrialized preparation parameters were optimized as follows： reaction temperature 85-...An industrialized technique of preparation for oxidized com starch using oxygen as oxidant was investigated in this paper. The industrialized preparation parameters were optimized as follows： reaction temperature 85-95 ℃, oxygen flow rate 8-12 L/min, reaction time 210 min, the ratio of starch to water 1：5, 3.5 wt% of NaOH and 0.1 wt% of catalyst. The experimental results show that the concentration of hydrolysate-oxidaton product is 16-18 wt%. The powdered products were gained through dehydrated and powdered process using quadruple-effect evaporator, spray drying tower and guide shell mixer. The composting test indicates that the degradability of the oxidized corn starch can reach 76.4%. The complexation capacity of calcium ions reaches 108.5 mg per gram oxidized starch, and the detergency ratio （P） reaches 1.30 as builder.展开更多
1920s and 1930s architecture has often been associated with the use of modern materials, such as reinforced concrete, glass and steel, mainly thanks to the role given them by the historiography of the modern, of prese...1920s and 1930s architecture has often been associated with the use of modern materials, such as reinforced concrete, glass and steel, mainly thanks to the role given them by the historiography of the modern, of presenting a break with former tradition and of spreading the need of architectural renewal. The study of architecture from the point of view of construction techniques evidences, instead, how architectural renewal started earlier, during the 19 century and involved the whole realm of building, even tradition-associated materials, such as wood and stone. Indeed, artificial stone （which appeared in early 19 century） represents--above all in France--a link between traditional construction in stone and the newborn reinforced-concrete technique, so as to underline the gradual shift from 19 century construction codes to the new industrial construction techniques, which in the 1920s and 1930s tend to overlap and blend, in this way determining a material continuity of modern and 19 century architecture.展开更多
文摘This brief article reviews a very particular and quite narrowfield,namely what has been done and what is needed to know for tannin adhesives for wood panels to succeed industrially.The present fashionable focus on bioadhe-sives has led to producing chemical adhesive formulations and approaches for tannin adhesives as a subject of academic publications.These,as good and original they might be,are and will still remain a rather empty aca-demic exercise if not put to the test of real industrial trials and industrial use.They will remain so without the“little”secrets and techniques outlined here that show that there is a great gap between developing an adhesive formulation in the laboratory and the hard reality to make it work where it does really count,in its industrial application.It outlines the fact that even more modern and excellent,newly developed bioadhesive formulations might well miserably fail once tried in the industry if the problems that always arise in their upgrading are not identified and solved,and solved well.It also outlines the fact that not only must costs always be taken into account and that a practical and possibly easy-to-handle approach must always be used,but too expensive or complex and unyielding adhesive systems are also often shown to be unusable or unsuitable in industry.
文摘An industrialized technique of preparation for oxidized com starch using oxygen as oxidant was investigated in this paper. The industrialized preparation parameters were optimized as follows： reaction temperature 85-95 ℃, oxygen flow rate 8-12 L/min, reaction time 210 min, the ratio of starch to water 1：5, 3.5 wt% of NaOH and 0.1 wt% of catalyst. The experimental results show that the concentration of hydrolysate-oxidaton product is 16-18 wt%. The powdered products were gained through dehydrated and powdered process using quadruple-effect evaporator, spray drying tower and guide shell mixer. The composting test indicates that the degradability of the oxidized corn starch can reach 76.4%. The complexation capacity of calcium ions reaches 108.5 mg per gram oxidized starch, and the detergency ratio （P） reaches 1.30 as builder.
文摘1920s and 1930s architecture has often been associated with the use of modern materials, such as reinforced concrete, glass and steel, mainly thanks to the role given them by the historiography of the modern, of presenting a break with former tradition and of spreading the need of architectural renewal. The study of architecture from the point of view of construction techniques evidences, instead, how architectural renewal started earlier, during the 19 century and involved the whole realm of building, even tradition-associated materials, such as wood and stone. Indeed, artificial stone （which appeared in early 19 century） represents--above all in France--a link between traditional construction in stone and the newborn reinforced-concrete technique, so as to underline the gradual shift from 19 century construction codes to the new industrial construction techniques, which in the 1920s and 1930s tend to overlap and blend, in this way determining a material continuity of modern and 19 century architecture.
