The distribution and treatment of harmful gas (H2S) in the Liaohe Oilfield, Northeast China, were investigated in this study. It was found that abundant toxic gas (H2S) is generated in thermal recovery of heavy oi...The distribution and treatment of harmful gas (H2S) in the Liaohe Oilfield, Northeast China, were investigated in this study. It was found that abundant toxic gas (H2S) is generated in thermal recovery of heavy oil. The H2S gas is mainly formed during thermochemical sulfate reduction (TSR) occurring in oil reservoirs or the thermal decomposition of sulfocompounds (TDS) in crude oil. H2S generation is controlled by thermal recovery time, temperature and the injected chemical compounds. The quantity of SO4^2- in the injected compounds is the most influencing factor for the rate of TSR reaction. Therefore, for prevention of H2S formation, periodic and effective monitoring should be undertaken and adequate H2S absorbent should also be provided during thermal recovery of heavy oil. The result suggests that great efforts should be made to reduce the SO4^2- source in heavy oil recovery, so as to restrain H2S generation in reservoirs. In situ burning or desulfurizer adsorption are suggested to reduce H2S levels. Prediction and prevention of H2S are important in heavy oil production. This will minimize environmental and human health risks, as well as equipment corrosion.展开更多
This paper summarizes the important progress in the field of oil and gas production engineering during the"Thirteenth Five-Year Plan"period of China,analyzes the challenges faced by the current oil and gas p...This paper summarizes the important progress in the field of oil and gas production engineering during the"Thirteenth Five-Year Plan"period of China,analyzes the challenges faced by the current oil and gas production engineering in terms of technological adaptability,digital construction,energy-saving and emission reduction,and points out the future development direction.During the"Thirteenth Five-Year Plan"period,series of important progresses have been made in five major technologies,including separated-layer injection,artificial lift,reservoir stimulation,gas well de-watering,and workover,which provide key technical support for continuous potential tapping of mature oilfields and profitable production of new oilfields.Under the current complex international political and economic situation,oil and gas production engineering is facing severe challenges in three aspects:technical difficulty increases in oil and gas production,insignificant improvements in digital transformation,and lack of core technical support for energy-saving and emission reduction.This paper establishes three major strategic directions and implementation paths,including oil stabilization and gas enhancement,digital transformation,and green and low-carbon development.Five key research areas are listed including fine separated-layer injection technology,high efficiency artificial lift technology,fine reservoir stimulation technology,long term gas well de-watering technology and intelligent workover technology,so as to provide engineering technical support for the transformation,upgrading and high-quality development of China’s oil and gas industry.展开更多
This paper summarizes the latest achievements and technological progress in oil and gas production engineering of China National Petroleum Corporation(CNPC) and discusses the main four challenges faced: developing low...This paper summarizes the latest achievements and technological progress in oil and gas production engineering of China National Petroleum Corporation(CNPC) and discusses the main four challenges faced: developing low quality resource at low oil price; keeping stable production of mature oilfields when well oil production drops year by year; low systematic efficiency, high cost, prominent environmental protection issue and short of technological strategy for high water cut ratio and high oil recovery ratio oilfields; and lacking of high level horizontal well drilling and completion technology to develop unconventional and deep reservoirs. Three technological development directions to address these challenges are put forward: developing fracture controlling stimulation and well factory to produce low quality resource economically, developing re-fracturing technology for old wells in mature oilfields, promoting the fourth generation separate layer water injection technology to stabilize the production of mature oilfields; innovating new technologies of water flooding with nano-material, injecting and producing through one well.展开更多
This study reviews the development history of PetroChina’s overseas oil and gas field development technologies, summarizes the characteristic technologies developed, and puts forward the development goals and technol...This study reviews the development history of PetroChina’s overseas oil and gas field development technologies, summarizes the characteristic technologies developed, and puts forward the development goals and technological development directions of overseas business to overcome the challenges met in overseas oil and gas production. In the course of PetroChina’s overseas oil and gas field production practice of more than 20 years, a series of characteristic technologies suitable for overseas oil and gas fields have been created by combining the domestic mature oil and gas field production technologies with the features of overseas oil and gas reservoirs, represented by the technology for high-speed development and stabilizing oil production and controlling water rise for overseas sandstone oilfields, high efficiency development technology for large carbonate oil and gas reservoirs and foamy oil depletion development technology in use of horizontal wells for extra-heavy oil reservoirs. Based on in-depth analysis of the challenges faced by overseas oil and gas development and technological requirements, combined with the development trends of oil and gas development technologies in China and abroad, overseas oil and gas development technologies in the future are put forward, including artificial intelligence reservoir prediction and 3 D geological modeling, secondary development and enhanced oil recovery(EOR) of overseas sandstone oilfields after high speed development, water and gas injection to improve oil recovery in overseas carbonate oil and gas reservoirs, economic and effective development of overseas unconventional oil and gas reservoirs, efficient development of marine deep-water oil and gas reservoirs. The following goals are expected to be achieved: keep the enhanced oil recovery(EOR) technology for high water-cut sandstone oilfield at international advanced level, and make the development technology for carbonate oil and gas reservoirs reach the international advanced level, and the development technologies for unconventional and marine deep-water oil and gas reservoirs catch up the level of international leading oil companies quickly.展开更多
With the petroleum industry endeavoring to develop promising oil and gas in deeper water, gas hydrates prevention is a serious concern for oil and gas producing companies producing at conditions in the hydrate region....With the petroleum industry endeavoring to develop promising oil and gas in deeper water, gas hydrates prevention is a serious concern for oil and gas producing companies producing at conditions in the hydrate region. This paper details lessons learned from the successful field deployment of AA LDHI and proper implementation strategies used for 3 different practical fields as case studies in the Gulf of Mexico. From the 3 field experiences, the AA LDHI has been used to replace the conventional thermodynamic hydrate inhibitor due to its numerous benefits during steady state operations and transition operations where AA LDHI is injected prior to extended shut in and restart for fields producing at low water cut. However, the strategy to develop a cost effective chemical management of hydrates for fields producing at high water cut is by pumping methanol or diesel to push down the wellbore fluid below the mud line during planned and unplanned shut-ins to delay water production, it also secures the riser with non hydrate fluids. This illustrates how the AA LDHIs are used in conjunction with more conventional hydrate management approaches to reach an optimal cost effective field hydrate management solution. However, this shows that the key to overall success of hydrate prevention is a full integration of a good front end design, a comprehensive deployment and an effective down hole monitoring system.展开更多
The shale oil and gas exploitation in China is technically benchmarked with the United States in terms of development philosophy,reservoir stimulation treatment,fracturing parameters,fracturing equipment and materials...The shale oil and gas exploitation in China is technically benchmarked with the United States in terms of development philosophy,reservoir stimulation treatment,fracturing parameters,fracturing equipment and materials,oil/gas production technology,and data/achievements sharing.It is recognized that the shale oil and gas exploitation in China is weak in seven aspects:understanding of flow regimes,producing of oil/gas reserves,monitoring of complex fractures,repeated stimulation technology,oil/gas production technology,casing deformation prevention technology,and wellbore maintenance technology.Combined with the geological and engineering factors of shale oil and gas in China,the development suggestions of four projects are proposed from the macro-and micro-perspective,namely,basic innovation project,exploitation technology project,oil/gas production stabilization project,and supporting efficiency-improvement project,so as to promote the rapid,efficient,stable,green and extensive development of shale oil and gas industry chain and innovation chain and ultimately achieve the goal of“oil volume stabilizing and gas volume increasing”.展开更多
This paper presents a theoretical method and a finite element method to describe wellhead movement and uncemented casing strength in offshore oil and gas wells.Parameters considered in the theoretical method include o...This paper presents a theoretical method and a finite element method to describe wellhead movement and uncemented casing strength in offshore oil and gas wells.Parameters considered in the theoretical method include operating load during drilling and completion and the temperature field,pressure field and the end effect of pressure during gas production.The finite element method for multistring analysis is developed to simulate random contact between casings.The relevant finite element analysis scheme is also presented according to the actual procedures of drilling,completion and gas production.Finally,field cases are presented and analyzed using the proposed methods.These are four offshore wells in the South China Sea.The calculated wellhead growths during gas production are compared with measured values.The results show that the wellhead subsides during drilling and completion and grows up during gas production.The theoretical and finite element solutions for wellhead growth are in good agreement with measured values and the deviations of calculation are within 10%.The maximum von Mises stress on the uncemented intermediate casing occurs during the running of the oil tube.The maximum von Mises stress on the uncemented production casing,calculated with the theoretical method occurs at removing the blow-out-preventer (BOP) while that calculated with the finite element method occurs at gas production.Finite element solutions for von Mises stress are recommended and the uncemented casings of four wells satisfy strength requirements.展开更多
In the fall of 2016, a field study was conducted in the Uinta Basin Utah to improve information on oil and natural gas well pad pneumatic controllers (PCs) and emission measurement methods. A total of 80 PC systems at...In the fall of 2016, a field study was conducted in the Uinta Basin Utah to improve information on oil and natural gas well pad pneumatic controllers (PCs) and emission measurement methods. A total of 80 PC systems at five oil sites (supporting six wells) and three gas sites (supporting 12 wells) were surveyed, and emissions data were produced using a combination of measurements and engineering emission estimates. Ninety-six percent of the PCs surveyed were low actuation frequency intermittent vent type. The overall whole gas emission rate for the study was estimated at 0.36 scf/h with the majority of emissions occurring from three continuous vent PCs (1.1 scf/h average) and eleven (14%) malfunctioning intermittent vent PC systems (1.6 scf/h average). Oil sites employed, on average 10.3 PC systems per well compared to 1.5 for gas sites. Oil and gas sites had group average PC emission rates of 0.28 scf/h and 0.67 scf/h, respectively. This difference was due in part to differing site selection procedures used for oil and gas sites. The PC system types encountered, the engineering emissions estimate approach, and comparisons to measurements are described. Survey methods included identification of malfunctioning PC systems and emission measurements with augmented high volume sampling and installed mass flow meters, each providing a somewhat different representation of emissions that are elucidated through example cases.展开更多
The fundamental equation of mineral production allows to model and design the dynamics of mineral production, however complex they are or could be. It considers not only the case of a constant production to reserves r...The fundamental equation of mineral production allows to model and design the dynamics of mineral production, however complex they are or could be. It considers not only the case of a constant production to reserves ratio for given intervals of time, but with a piecewise approach, it is also enabled to account the variation on time of this ratio. With a constant production to reserves ratio, the limit expression of the fundamental equation takes the form of an Erlang distribution with a fixed shape parameter. The rate parameter equals the scale factor. The discrete piecewise version, instead of considering the reserves and the production to reserves ratio being constant through certain intervals of time, updates both variables by units of time. This version, using either lineal or non lineal functions for the variables involved, let to model known production profiles or to forecast them by experimental design. The Hubbert’s linearization updated with recent data and the p-box method applied to determine ultimate recovery of U.S. crude oil reserves indicate official accounts underestimate them. The analysis of the ideal model of production based on Hubbert’s linearization and curve, can be made by decomposing it in the distribution with time of the reserves and of the production to reserves ratio. The distribution of reserves with time is synchronized for both the ideal Hubbert’s curve and real profiles, disregarding whether they match or not. The departure of real profiles from the ideal Hubbert’s curve lies on the differences or correspondences of the distribution with time of the production to reserves ratio. The MonteCarlo simulation applied to forecast US crude oil production for the next five years points to a slow decline, with average annual yields presenting a difference lower than 10% between the start and the end of the simulation.展开更多
In the fall of 2016, a field study was conducted in the Uinta Basin Utah to improve information on oil and natural gas well pad pneumatic controllers (PCs) and emission measurement methods. A total of 80 PC systems at...In the fall of 2016, a field study was conducted in the Uinta Basin Utah to improve information on oil and natural gas well pad pneumatic controllers (PCs) and emission measurement methods. A total of 80 PC systems at five oil sites (supporting six wells) and three gas sites (supporting 12 wells) were surveyed, and emissions data were produced using a combination of measurements and engineering emission estimates. Ninety-six percent of the PCs surveyed were low actuation frequency intermittent vent type. The overall whole gas emission rate for the study was estimated at 0.36 scf/h with the majority of emissions occurring from three continuous vent PCs (1.1 scf/h average) and eleven (14%) malfunctioning intermittent vent PC systems (1.6 scf/h average). Oil sites employed, on average 10.3 PC systems per well compared to 1.5 for gas sites. Oil and gas sites had group average PC emission rates of 0.28 scf/h and 0.67 scf/h, respectively. This difference was due in part to differing site selection procedures used for oil and gas sites. The PC system types encountered, the engineering emissions estimate approach, and comparisons to measurements are described. Survey methods included identification of malfunctioning PC systems and emission measurements with augmented high volume sampling and installed mass flow meters, each providing a somewhat different representation of emissions that are elucidated through example cases.展开更多
Environmentally unfriendly Oil exploration activities have been ongoing in the Soku area of the Niger Delta of Nigeria since 1956. This study evaluated the concentration of hydrocarbons and heavy metals in Shellfish a...Environmentally unfriendly Oil exploration activities have been ongoing in the Soku area of the Niger Delta of Nigeria since 1956. This study evaluated the concentration of hydrocarbons and heavy metals in Shellfish and drinking water sources in the study area. It revealed the absence (<0.001 mg/l) of most heavy metals (Ni, Ch, Cd, Pb mg/l) in the water column;a high concentration of the major ion composition of seawater (sulphates 5 - 1018;calcium 0.502 - 53.502;sodium 1.247 - 63.337;potassium 0.508 - 102.745;magnesium 0.354 - 42.574 mg/l);and high PAHs (<0.001 - 0.032 mg/l) levels occurring above WHO limits (0.007 mg/l) with some risk of exposure to cancer. Results from the analysis of shellfish showed that concentrations of chromium and zinc were below permissible limits while cadmium concentrations were slightly above permissible limits of the European Community. Nickel and lead were above permissible limits in the fish samples in all standards while PAHs occurred at the cancer risk levels of 10?6. A review of the public health situation in the Soku area with a view to understanding current trends, sources of perturbations and preferable solutions to the potential public health challenges raised in this study is hereby recommended. Also, this study recommends that relevant agencies and developmental partners should launch a national drive to create awareness among people/environmental/public health professionals’/health workers/administrators on this regional concern.展开更多
The distributed acoustic sensor(DAS)uses a single optical cable as the sensing unit,which can capture the acoustic and vibration signals along the optical cable in real-time.So it is suitable for monitoring downhole p...The distributed acoustic sensor(DAS)uses a single optical cable as the sensing unit,which can capture the acoustic and vibration signals along the optical cable in real-time.So it is suitable for monitoring downhole production activities in the process of oil and gas development.The authors applied the DAS system in a gas production well in the South China Sea for in situ monitoring of the whole wellbore for the first time and obtained the distributed acoustic signals along the whole wellbore.These signals can clearly distinguish the vertical section,curve section,and horizontal production section.The collected acoustic signal with the frequency of approximately 50 Hz caused by the electric submersible pump exhibit a signal-to-noise ratio higher than 27 dB.By analyzing the acoustic signals in the production section,it can be located the layers with high gas production rates.Once an accurate physical model is built in the future,the gas production profile will be obtained.In addition,the DAS system can track the trajectory of downhole tools in the wellbore to guide the operation.Through the velocity analysis of the typical signals,the type of fluids in the wellbore can be distinguished.The successful application of the system provides a promising whole wellbore acoustic monitoring tool for the production of marine gas hydrate,with a good application prospect.展开更多
Traditional suction anchor technology is mainly used in the fields of subsea structure bearing foundations,single-point mooring systems and offshore wind power.It is characterized by providing sufficient lateral and v...Traditional suction anchor technology is mainly used in the fields of subsea structure bearing foundations,single-point mooring systems and offshore wind power.It is characterized by providing sufficient lateral and vertical bearing capacities and lateral bending moment.The anchor structure of a traditional suction anchor structure is improved with wellhead suction anchor technology,where a central pipe is added as a channel for drilling and completion operations.To solve the technical problems of a low wellhead bearing capacity,shallow built-up depth,and limited application of conductor jetting in the second production test of natural gas hydrates(NGHs)in the South China Sea(SCS),the China Geological Survey(CGS)took the lead in independently designing and manufacturing a wellhead suction anchor,which fulfilled the requirements of the production test.This novel anchor was successfully implemented in the second production test for the first time,providing a stable wellhead foundation for the success of the second production test of NGHs in the SCS.展开更多
[Objectives]To study the volatile components and antibacterial effects of 11 kinds of Aurantii Fructus Immaturus processed products.[Methods]11 kinds of Aurantii Fructus Immaturus processed products were obtained acco...[Objectives]To study the volatile components and antibacterial effects of 11 kinds of Aurantii Fructus Immaturus processed products.[Methods]11 kinds of Aurantii Fructus Immaturus processed products were obtained according to the traditional processing method,the volatile oil was extracted by steam distillation,and the composition of volatile oil in the 11 kinds of processed products was analyzed by gas chromatography-mass spectrometry(GC-MS).the relative percentage content of each component in these 11 kinds of processed products was determined using the peak area normalization.The drug sensitivity activity of the volatile oil of these 11 kinds of processed products was tested using the K-B paper diffusion method and the minimum inhibition volume fraction of volatile oil of these 11 kinds of processed products was tested using the microdilution method.[Results]The highest yield of volatile oil of 11 kinds of these processed products was baking(5.193%),and the lowest was stir-bake to scorch(1.998%).A total of 36 chemical components were identified from the volatile oils of these 11 kinds of processed products.The components with the most volatile oil were stir-bake to scorch(24 kinds),and the components with the least volatile oil were the method of processing with rice-washed water(15 kinds).They contain 8 kinds of common chemical components,such as limonene,linalool,myrcene,α-pinene.The highest content of limonene came from processing with honey(60.93%),the lowest came from processing with rice-washed water(55.25%);the highest content of linalool came from processing with rice-washed water(7.139%),the lowest came from processing with honey(5.436%);the highest content of myrcene came from processing with honey(1.899%),the lowest came from stir-bake to scorch(1.632%);the highest content ofα-pinene came from raw Aurantii Fructus Immaturus(2.355%),and the lowest came from stir-bake to scorch(1.618%).The volatile oil of these 11 kinds of Aurantii Fructus Immaturus processed products has good antibacterial effect on Escherichia coli and Staphylococcus aureus.[Conclusions]The oil yields of volatile oils of 11 kinds of Aurantii Fructus Immaturus processed products are different,the content of limonene is significantly different,and the changes of other chemical components and their contents are not significantly different.The volatile oil of 11 kinds of Aurantii Fructus Immaturus processed products has certain antibacterial effect.展开更多
In this work,the authors monitored the formation and dissociation process of methane hydrate in four different rock core samples through nuclear magnetic resonance(NMR)relaxation time(T_(2))and 2D imaging measurement....In this work,the authors monitored the formation and dissociation process of methane hydrate in four different rock core samples through nuclear magnetic resonance(NMR)relaxation time(T_(2))and 2D imaging measurement.The result shows that the intensity of T_(2) spectra and magnetic resonance imaging(MRI)signals gradually decreases in the hydrate formation process,and at the same time,the T_(2) spectra move toward the left domain as the growth of hydrate in the pores of the sample accelerates the decay rate.The hydrate grows and dissociates preferentially in the purer sandstone samples with larger pore size and higher porosity.Significantly,for the sample with lower porosity and higher argillaceous content,the intensity of the T_(2) spectra also shows a trend of a great decrease in the hydrate formation process,which means that high-saturation gas hydrate can also be formed in the sample with higher argillaceous content.The changes in MRI of the sample in the process show that the formation and dissociation of methane hydrate can reshape the distribution of water in the pores.展开更多
基金supported by the National Natural Science Foundation of China (Grant No. 4060201640773032)the National Basic Research Program of China (Contract No. 2007CB209500)
文摘The distribution and treatment of harmful gas (H2S) in the Liaohe Oilfield, Northeast China, were investigated in this study. It was found that abundant toxic gas (H2S) is generated in thermal recovery of heavy oil. The H2S gas is mainly formed during thermochemical sulfate reduction (TSR) occurring in oil reservoirs or the thermal decomposition of sulfocompounds (TDS) in crude oil. H2S generation is controlled by thermal recovery time, temperature and the injected chemical compounds. The quantity of SO4^2- in the injected compounds is the most influencing factor for the rate of TSR reaction. Therefore, for prevention of H2S formation, periodic and effective monitoring should be undertaken and adequate H2S absorbent should also be provided during thermal recovery of heavy oil. The result suggests that great efforts should be made to reduce the SO4^2- source in heavy oil recovery, so as to restrain H2S generation in reservoirs. In situ burning or desulfurizer adsorption are suggested to reduce H2S levels. Prediction and prevention of H2S are important in heavy oil production. This will minimize environmental and human health risks, as well as equipment corrosion.
基金Supported by the Basic Science Center Project of National Natural Science Foundation of China(72088101)National Natural Science Funded Project(52074345)CNPC Scientific Research and Technology Development Project(2020D-5001-21)。
文摘This paper summarizes the important progress in the field of oil and gas production engineering during the"Thirteenth Five-Year Plan"period of China,analyzes the challenges faced by the current oil and gas production engineering in terms of technological adaptability,digital construction,energy-saving and emission reduction,and points out the future development direction.During the"Thirteenth Five-Year Plan"period,series of important progresses have been made in five major technologies,including separated-layer injection,artificial lift,reservoir stimulation,gas well de-watering,and workover,which provide key technical support for continuous potential tapping of mature oilfields and profitable production of new oilfields.Under the current complex international political and economic situation,oil and gas production engineering is facing severe challenges in three aspects:technical difficulty increases in oil and gas production,insignificant improvements in digital transformation,and lack of core technical support for energy-saving and emission reduction.This paper establishes three major strategic directions and implementation paths,including oil stabilization and gas enhancement,digital transformation,and green and low-carbon development.Five key research areas are listed including fine separated-layer injection technology,high efficiency artificial lift technology,fine reservoir stimulation technology,long term gas well de-watering technology and intelligent workover technology,so as to provide engineering technical support for the transformation,upgrading and high-quality development of China’s oil and gas industry.
基金Supported by the China National Science and Technology Major Project(2016ZX05023 2017ZX05013-005)
文摘This paper summarizes the latest achievements and technological progress in oil and gas production engineering of China National Petroleum Corporation(CNPC) and discusses the main four challenges faced: developing low quality resource at low oil price; keeping stable production of mature oilfields when well oil production drops year by year; low systematic efficiency, high cost, prominent environmental protection issue and short of technological strategy for high water cut ratio and high oil recovery ratio oilfields; and lacking of high level horizontal well drilling and completion technology to develop unconventional and deep reservoirs. Three technological development directions to address these challenges are put forward: developing fracture controlling stimulation and well factory to produce low quality resource economically, developing re-fracturing technology for old wells in mature oilfields, promoting the fourth generation separate layer water injection technology to stabilize the production of mature oilfields; innovating new technologies of water flooding with nano-material, injecting and producing through one well.
文摘This study reviews the development history of PetroChina’s overseas oil and gas field development technologies, summarizes the characteristic technologies developed, and puts forward the development goals and technological development directions of overseas business to overcome the challenges met in overseas oil and gas production. In the course of PetroChina’s overseas oil and gas field production practice of more than 20 years, a series of characteristic technologies suitable for overseas oil and gas fields have been created by combining the domestic mature oil and gas field production technologies with the features of overseas oil and gas reservoirs, represented by the technology for high-speed development and stabilizing oil production and controlling water rise for overseas sandstone oilfields, high efficiency development technology for large carbonate oil and gas reservoirs and foamy oil depletion development technology in use of horizontal wells for extra-heavy oil reservoirs. Based on in-depth analysis of the challenges faced by overseas oil and gas development and technological requirements, combined with the development trends of oil and gas development technologies in China and abroad, overseas oil and gas development technologies in the future are put forward, including artificial intelligence reservoir prediction and 3 D geological modeling, secondary development and enhanced oil recovery(EOR) of overseas sandstone oilfields after high speed development, water and gas injection to improve oil recovery in overseas carbonate oil and gas reservoirs, economic and effective development of overseas unconventional oil and gas reservoirs, efficient development of marine deep-water oil and gas reservoirs. The following goals are expected to be achieved: keep the enhanced oil recovery(EOR) technology for high water-cut sandstone oilfield at international advanced level, and make the development technology for carbonate oil and gas reservoirs reach the international advanced level, and the development technologies for unconventional and marine deep-water oil and gas reservoirs catch up the level of international leading oil companies quickly.
文摘With the petroleum industry endeavoring to develop promising oil and gas in deeper water, gas hydrates prevention is a serious concern for oil and gas producing companies producing at conditions in the hydrate region. This paper details lessons learned from the successful field deployment of AA LDHI and proper implementation strategies used for 3 different practical fields as case studies in the Gulf of Mexico. From the 3 field experiences, the AA LDHI has been used to replace the conventional thermodynamic hydrate inhibitor due to its numerous benefits during steady state operations and transition operations where AA LDHI is injected prior to extended shut in and restart for fields producing at low water cut. However, the strategy to develop a cost effective chemical management of hydrates for fields producing at high water cut is by pumping methanol or diesel to push down the wellbore fluid below the mud line during planned and unplanned shut-ins to delay water production, it also secures the riser with non hydrate fluids. This illustrates how the AA LDHIs are used in conjunction with more conventional hydrate management approaches to reach an optimal cost effective field hydrate management solution. However, this shows that the key to overall success of hydrate prevention is a full integration of a good front end design, a comprehensive deployment and an effective down hole monitoring system.
基金Supported by the CNPC Basic and Prospective Project (2021DJ45)。
文摘The shale oil and gas exploitation in China is technically benchmarked with the United States in terms of development philosophy,reservoir stimulation treatment,fracturing parameters,fracturing equipment and materials,oil/gas production technology,and data/achievements sharing.It is recognized that the shale oil and gas exploitation in China is weak in seven aspects:understanding of flow regimes,producing of oil/gas reserves,monitoring of complex fractures,repeated stimulation technology,oil/gas production technology,casing deformation prevention technology,and wellbore maintenance technology.Combined with the geological and engineering factors of shale oil and gas in China,the development suggestions of four projects are proposed from the macro-and micro-perspective,namely,basic innovation project,exploitation technology project,oil/gas production stabilization project,and supporting efficiency-improvement project,so as to promote the rapid,efficient,stable,green and extensive development of shale oil and gas industry chain and innovation chain and ultimately achieve the goal of“oil volume stabilizing and gas volume increasing”.
基金financial support from the National Key Sci-Tech Major Special Item(No.2011ZX05026-001)Program for Changjiang Scholars and Innovative Research Team in University(IRT1086)
文摘This paper presents a theoretical method and a finite element method to describe wellhead movement and uncemented casing strength in offshore oil and gas wells.Parameters considered in the theoretical method include operating load during drilling and completion and the temperature field,pressure field and the end effect of pressure during gas production.The finite element method for multistring analysis is developed to simulate random contact between casings.The relevant finite element analysis scheme is also presented according to the actual procedures of drilling,completion and gas production.Finally,field cases are presented and analyzed using the proposed methods.These are four offshore wells in the South China Sea.The calculated wellhead growths during gas production are compared with measured values.The results show that the wellhead subsides during drilling and completion and grows up during gas production.The theoretical and finite element solutions for wellhead growth are in good agreement with measured values and the deviations of calculation are within 10%.The maximum von Mises stress on the uncemented intermediate casing occurs during the running of the oil tube.The maximum von Mises stress on the uncemented production casing,calculated with the theoretical method occurs at removing the blow-out-preventer (BOP) while that calculated with the finite element method occurs at gas production.Finite element solutions for von Mises stress are recommended and the uncemented casings of four wells satisfy strength requirements.
文摘In the fall of 2016, a field study was conducted in the Uinta Basin Utah to improve information on oil and natural gas well pad pneumatic controllers (PCs) and emission measurement methods. A total of 80 PC systems at five oil sites (supporting six wells) and three gas sites (supporting 12 wells) were surveyed, and emissions data were produced using a combination of measurements and engineering emission estimates. Ninety-six percent of the PCs surveyed were low actuation frequency intermittent vent type. The overall whole gas emission rate for the study was estimated at 0.36 scf/h with the majority of emissions occurring from three continuous vent PCs (1.1 scf/h average) and eleven (14%) malfunctioning intermittent vent PC systems (1.6 scf/h average). Oil sites employed, on average 10.3 PC systems per well compared to 1.5 for gas sites. Oil and gas sites had group average PC emission rates of 0.28 scf/h and 0.67 scf/h, respectively. This difference was due in part to differing site selection procedures used for oil and gas sites. The PC system types encountered, the engineering emissions estimate approach, and comparisons to measurements are described. Survey methods included identification of malfunctioning PC systems and emission measurements with augmented high volume sampling and installed mass flow meters, each providing a somewhat different representation of emissions that are elucidated through example cases.
文摘The fundamental equation of mineral production allows to model and design the dynamics of mineral production, however complex they are or could be. It considers not only the case of a constant production to reserves ratio for given intervals of time, but with a piecewise approach, it is also enabled to account the variation on time of this ratio. With a constant production to reserves ratio, the limit expression of the fundamental equation takes the form of an Erlang distribution with a fixed shape parameter. The rate parameter equals the scale factor. The discrete piecewise version, instead of considering the reserves and the production to reserves ratio being constant through certain intervals of time, updates both variables by units of time. This version, using either lineal or non lineal functions for the variables involved, let to model known production profiles or to forecast them by experimental design. The Hubbert’s linearization updated with recent data and the p-box method applied to determine ultimate recovery of U.S. crude oil reserves indicate official accounts underestimate them. The analysis of the ideal model of production based on Hubbert’s linearization and curve, can be made by decomposing it in the distribution with time of the reserves and of the production to reserves ratio. The distribution of reserves with time is synchronized for both the ideal Hubbert’s curve and real profiles, disregarding whether they match or not. The departure of real profiles from the ideal Hubbert’s curve lies on the differences or correspondences of the distribution with time of the production to reserves ratio. The MonteCarlo simulation applied to forecast US crude oil production for the next five years points to a slow decline, with average annual yields presenting a difference lower than 10% between the start and the end of the simulation.
文摘In the fall of 2016, a field study was conducted in the Uinta Basin Utah to improve information on oil and natural gas well pad pneumatic controllers (PCs) and emission measurement methods. A total of 80 PC systems at five oil sites (supporting six wells) and three gas sites (supporting 12 wells) were surveyed, and emissions data were produced using a combination of measurements and engineering emission estimates. Ninety-six percent of the PCs surveyed were low actuation frequency intermittent vent type. The overall whole gas emission rate for the study was estimated at 0.36 scf/h with the majority of emissions occurring from three continuous vent PCs (1.1 scf/h average) and eleven (14%) malfunctioning intermittent vent PC systems (1.6 scf/h average). Oil sites employed, on average 10.3 PC systems per well compared to 1.5 for gas sites. Oil and gas sites had group average PC emission rates of 0.28 scf/h and 0.67 scf/h, respectively. This difference was due in part to differing site selection procedures used for oil and gas sites. The PC system types encountered, the engineering emissions estimate approach, and comparisons to measurements are described. Survey methods included identification of malfunctioning PC systems and emission measurements with augmented high volume sampling and installed mass flow meters, each providing a somewhat different representation of emissions that are elucidated through example cases.
文摘Environmentally unfriendly Oil exploration activities have been ongoing in the Soku area of the Niger Delta of Nigeria since 1956. This study evaluated the concentration of hydrocarbons and heavy metals in Shellfish and drinking water sources in the study area. It revealed the absence (<0.001 mg/l) of most heavy metals (Ni, Ch, Cd, Pb mg/l) in the water column;a high concentration of the major ion composition of seawater (sulphates 5 - 1018;calcium 0.502 - 53.502;sodium 1.247 - 63.337;potassium 0.508 - 102.745;magnesium 0.354 - 42.574 mg/l);and high PAHs (<0.001 - 0.032 mg/l) levels occurring above WHO limits (0.007 mg/l) with some risk of exposure to cancer. Results from the analysis of shellfish showed that concentrations of chromium and zinc were below permissible limits while cadmium concentrations were slightly above permissible limits of the European Community. Nickel and lead were above permissible limits in the fish samples in all standards while PAHs occurred at the cancer risk levels of 10?6. A review of the public health situation in the Soku area with a view to understanding current trends, sources of perturbations and preferable solutions to the potential public health challenges raised in this study is hereby recommended. Also, this study recommends that relevant agencies and developmental partners should launch a national drive to create awareness among people/environmental/public health professionals’/health workers/administrators on this regional concern.
基金jointly supported by the Science and Technology Program of Guangzhou (202103040003)the offshore NGHs production test projects under the Marine Geological Survey Program initiated by the China Geological Survey (DD20190226, DD20190218 and DD20221706)+2 种基金the Key Program of Marine Economy Development Special Foundation of Department of Natural Resources of Guangdong Province (GDNRC [2020] 045)the financial support from China Geological Survey (DD20221703)the National Natural Science Foundation of China (NSFC) (6210030553)。
文摘The distributed acoustic sensor(DAS)uses a single optical cable as the sensing unit,which can capture the acoustic and vibration signals along the optical cable in real-time.So it is suitable for monitoring downhole production activities in the process of oil and gas development.The authors applied the DAS system in a gas production well in the South China Sea for in situ monitoring of the whole wellbore for the first time and obtained the distributed acoustic signals along the whole wellbore.These signals can clearly distinguish the vertical section,curve section,and horizontal production section.The collected acoustic signal with the frequency of approximately 50 Hz caused by the electric submersible pump exhibit a signal-to-noise ratio higher than 27 dB.By analyzing the acoustic signals in the production section,it can be located the layers with high gas production rates.Once an accurate physical model is built in the future,the gas production profile will be obtained.In addition,the DAS system can track the trajectory of downhole tools in the wellbore to guide the operation.Through the velocity analysis of the typical signals,the type of fluids in the wellbore can be distinguished.The successful application of the system provides a promising whole wellbore acoustic monitoring tool for the production of marine gas hydrate,with a good application prospect.
基金jointly supported by the Natural Gas Hydrate Exploration and Production Test Project of China Geological Survey (DD20221700)Key-Area Research and Development Program of Guangdong Province (2020B1111030003)Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering G uangdong Laboratory (Guangzhou) (GML2019ZD0504)。
文摘Traditional suction anchor technology is mainly used in the fields of subsea structure bearing foundations,single-point mooring systems and offshore wind power.It is characterized by providing sufficient lateral and vertical bearing capacities and lateral bending moment.The anchor structure of a traditional suction anchor structure is improved with wellhead suction anchor technology,where a central pipe is added as a channel for drilling and completion operations.To solve the technical problems of a low wellhead bearing capacity,shallow built-up depth,and limited application of conductor jetting in the second production test of natural gas hydrates(NGHs)in the South China Sea(SCS),the China Geological Survey(CGS)took the lead in independently designing and manufacturing a wellhead suction anchor,which fulfilled the requirements of the production test.This novel anchor was successfully implemented in the second production test for the first time,providing a stable wellhead foundation for the success of the second production test of NGHs in the SCS.
基金the First Phase of Teaching Ability Training Program for Young Backbone Teachers of Guangxi University of Chinese Medicine(04B1805815)Program of Key Laboratory for Extraction and Purification and Quality Analysis of TCM in 2014(Gui Jiao Ke Yan[2014]No.6)。
文摘[Objectives]To study the volatile components and antibacterial effects of 11 kinds of Aurantii Fructus Immaturus processed products.[Methods]11 kinds of Aurantii Fructus Immaturus processed products were obtained according to the traditional processing method,the volatile oil was extracted by steam distillation,and the composition of volatile oil in the 11 kinds of processed products was analyzed by gas chromatography-mass spectrometry(GC-MS).the relative percentage content of each component in these 11 kinds of processed products was determined using the peak area normalization.The drug sensitivity activity of the volatile oil of these 11 kinds of processed products was tested using the K-B paper diffusion method and the minimum inhibition volume fraction of volatile oil of these 11 kinds of processed products was tested using the microdilution method.[Results]The highest yield of volatile oil of 11 kinds of these processed products was baking(5.193%),and the lowest was stir-bake to scorch(1.998%).A total of 36 chemical components were identified from the volatile oils of these 11 kinds of processed products.The components with the most volatile oil were stir-bake to scorch(24 kinds),and the components with the least volatile oil were the method of processing with rice-washed water(15 kinds).They contain 8 kinds of common chemical components,such as limonene,linalool,myrcene,α-pinene.The highest content of limonene came from processing with honey(60.93%),the lowest came from processing with rice-washed water(55.25%);the highest content of linalool came from processing with rice-washed water(7.139%),the lowest came from processing with honey(5.436%);the highest content of myrcene came from processing with honey(1.899%),the lowest came from stir-bake to scorch(1.632%);the highest content ofα-pinene came from raw Aurantii Fructus Immaturus(2.355%),and the lowest came from stir-bake to scorch(1.618%).The volatile oil of these 11 kinds of Aurantii Fructus Immaturus processed products has good antibacterial effect on Escherichia coli and Staphylococcus aureus.[Conclusions]The oil yields of volatile oils of 11 kinds of Aurantii Fructus Immaturus processed products are different,the content of limonene is significantly different,and the changes of other chemical components and their contents are not significantly different.The volatile oil of 11 kinds of Aurantii Fructus Immaturus processed products has certain antibacterial effect.
基金supported by the Guangdong Province Marine Economic Development(Six Major Marine Industries)Special Fund Project([2021]56)the Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory(Guangzhou)(GML2019ZD0105)+1 种基金the Guangzhou Science and Technology Project(202201011463)project of the China Geological Survey(DD20211350).
文摘In this work,the authors monitored the formation and dissociation process of methane hydrate in four different rock core samples through nuclear magnetic resonance(NMR)relaxation time(T_(2))and 2D imaging measurement.The result shows that the intensity of T_(2) spectra and magnetic resonance imaging(MRI)signals gradually decreases in the hydrate formation process,and at the same time,the T_(2) spectra move toward the left domain as the growth of hydrate in the pores of the sample accelerates the decay rate.The hydrate grows and dissociates preferentially in the purer sandstone samples with larger pore size and higher porosity.Significantly,for the sample with lower porosity and higher argillaceous content,the intensity of the T_(2) spectra also shows a trend of a great decrease in the hydrate formation process,which means that high-saturation gas hydrate can also be formed in the sample with higher argillaceous content.The changes in MRI of the sample in the process show that the formation and dissociation of methane hydrate can reshape the distribution of water in the pores.