SnO_(2)/Co_(3)O_(4)nanofibers(NFs)are synthesized by using a homopolar electrospinning system with double jets of positive polarity electric fields.The morphology and structure of SnO_(2)/Co_(3)O_(4)hetero-nanofibers ...SnO_(2)/Co_(3)O_(4)nanofibers(NFs)are synthesized by using a homopolar electrospinning system with double jets of positive polarity electric fields.The morphology and structure of SnO_(2)/Co_(3)O_(4)hetero-nanofibers are characterized by using field emission scanning electron microscope(FE-SEM),transmission electron microscope(TEM),x-ray diffraction(XRD),and x-ray photoelectron spectrometer(XPS).The analyses of SnO_(2)/Co_(3)O_(4)NFs by EDS and HRTEM show that the cobalt and tin exist on one nanofiber,which is related to the homopolar electrospinning and the crystallization during sintering.As a typical n-type semiconductor,Sn O_(2)has the disadvantages of high optimal operating temperature and poor reproducibility.Comparing with Sn O_(2),the optimal operating temperature of SnO_(2)/Co_(3)O_(4)NFs is reduced from 350℃to 250℃,which may be related to the catalysis of Co_(2)O_(2).The response of SnO_(2)/Co_(3)O_(4)to 100-ppm ethanol at 250℃is 50.9,9 times higher than that of pure Sn O_(2),which may be attributed to the p–n heterojunction between the n-type Sn O_(2)crystalline grain and the p-type Co_(2)O_(2)crystalline grain.The nanoscale p–n heterojunction promotes the electron migration and forms an interface barrier.The synergy effects between Sn O_(2)and Co_(2)O_(2),the crystalline grain p–n heterojunction,the existence of nanofibers and the large specific surface area all jointly contribute to the improved gas sensing performance.展开更多
The multi-point simultaneous long-term measurement of CO_(2) concentration in seawater can provide more-valuable data for further understanding of the spatial and temporal distribution of CO_(2).Thus,the requirement f...The multi-point simultaneous long-term measurement of CO_(2) concentration in seawater can provide more-valuable data for further understanding of the spatial and temporal distribution of CO_(2).Thus,the requirement for a low-cost sensor with high precision,low power consumption,and a small size is becoming urgent.In this work,an in-situ sensor for CO_(2) detection in seawater,based on a permeable membrane and non-dispersive infrared(NDIR)technology,is developed.The sensor has a small size(Ф66 mm×124 mm),light weight(0.7 kg in air),low power consumption(<0.9 W),low cost(<US$1000),and high-pressure tolerance(<200 m).After laboratory performance tests,the sensor was found to have a measurement range of(0–2000)×10^(-6),and the gas linear correlation R^(2) is 0.99,with a precision of about 0.98%at a sampling rate of 1 s.A comparison measurement was carried out with a commercial sensor in a pool for 7 days,and the results showed a consistent trend.Further,the newly developed sensor was deployed in Qingdao nearshore water for 35 days.The results proved that the sensor could measure the dynamic changes of CO_(2) concentration in seawater continuously,and had the potential to carry out long-term observations on an oceanic platform.It is hoped that the sensor could be applied to field ocean observations in near future.展开更多
This research utilizes geospatial methodologies to investigate the influence of gas flaring and carbon dioxide emissions on precipitation patterns within the Niger Delta region of Nigeria.The study relies on average m...This research utilizes geospatial methodologies to investigate the influence of gas flaring and carbon dioxide emissions on precipitation patterns within the Niger Delta region of Nigeria.The study relies on average mean precipitation data sourced from CHRS at the University of Arizona and carbon dioxide emissions data from NASA’s AIRS in Giovanni,spanning from July 2002 to November 2011.To carry out the analysis,ArcGIS 5.0 and SPSS 25,employing Inverse Distance Weighting(IDW),were employed to assess CO_(2) emissions and rainfall for both November and July during the period from 2002 to 2011.Over the course of this study,it was observed that CO_(2) emission exhibited an upward trend,increasing from 327.5226 parts per million(ppm)in July 2002 to 390.0077 ppm in November 2011.Simultaneously,the rainfall demonstrated an increase,rising from 56.66 millimeters to 390.78 millimeters for both July and November from 2002 to 2011.Noteworthy findings emerged from the correlation analysis conducted.Specifically,from July 2000 to 2011,there was a weak positive correlation(0.3858)observed between CO_(2) emissions and minimum rainfall,while a strong negative correlation(–0.7998)was identified for maximum rainfall values.In November,both minimum and maximum CO_(2) emissions displayed strong negative correlations with rainfall,with coefficients of–0.8255 and–0.7415,respectively.These findings hold significant implications for comprehending the environmental dynamics within the Niger Delta.Policymakers and stakeholders can leverage this knowledge to formulate targeted strategies aimed at mitigating CO_(2) emissions and addressing potential climate change-induced alterations in rainfall patterns.展开更多
In this work,hollow Fe_(2)O_(3)/Co_(3)O_(4)microcubes have been successfully synthesized through a hydrothermal method followed by an annealing process using metal-organic framework of Prussian blue as a soft template...In this work,hollow Fe_(2)O_(3)/Co_(3)O_(4)microcubes have been successfully synthesized through a hydrothermal method followed by an annealing process using metal-organic framework of Prussian blue as a soft template.The morphologies,microstructures,surface area and element compositions have been carefully characterized by a series of techniques.Meanwhile,compared with that of pure Fe_(2)O_(3)and Co_(3)O_(4),the gas sensor based on the hollow microcubes exhibits enhanced sensing performances towards acetone,e.g.,a higher response of 21.2 and a shorter response time of 5 s towards 20 ppm acetone at a relatively low working temperature of 200℃.Moreover,the hollow microcubes-based gas sensor still shows perfect long-term stability,excellent repeatability and the ability of sub-ppm level detection,which provides a possibility for its application in real life.The enhanced gas sensing performances can be attributed to the hollow structure with a high surface area and the formed p-n heterojunctions within the microcubes.展开更多
文摘SnO_(2)/Co_(3)O_(4)nanofibers(NFs)are synthesized by using a homopolar electrospinning system with double jets of positive polarity electric fields.The morphology and structure of SnO_(2)/Co_(3)O_(4)hetero-nanofibers are characterized by using field emission scanning electron microscope(FE-SEM),transmission electron microscope(TEM),x-ray diffraction(XRD),and x-ray photoelectron spectrometer(XPS).The analyses of SnO_(2)/Co_(3)O_(4)NFs by EDS and HRTEM show that the cobalt and tin exist on one nanofiber,which is related to the homopolar electrospinning and the crystallization during sintering.As a typical n-type semiconductor,Sn O_(2)has the disadvantages of high optimal operating temperature and poor reproducibility.Comparing with Sn O_(2),the optimal operating temperature of SnO_(2)/Co_(3)O_(4)NFs is reduced from 350℃to 250℃,which may be related to the catalysis of Co_(2)O_(2).The response of SnO_(2)/Co_(3)O_(4)to 100-ppm ethanol at 250℃is 50.9,9 times higher than that of pure Sn O_(2),which may be attributed to the p–n heterojunction between the n-type Sn O_(2)crystalline grain and the p-type Co_(2)O_(2)crystalline grain.The nanoscale p–n heterojunction promotes the electron migration and forms an interface barrier.The synergy effects between Sn O_(2)and Co_(2)O_(2),the crystalline grain p–n heterojunction,the existence of nanofibers and the large specific surface area all jointly contribute to the improved gas sensing performance.
基金Supported by the National Nature Science Foundation of China(No.41527901)the Provincial Key Research and Development Program of Shandong,China(No.2019JZZY010417)the Special Program of Shandong Province for Qingdao Pilot National Laboratory of Marine Science and Technology(No.2021QNLM020002).
文摘The multi-point simultaneous long-term measurement of CO_(2) concentration in seawater can provide more-valuable data for further understanding of the spatial and temporal distribution of CO_(2).Thus,the requirement for a low-cost sensor with high precision,low power consumption,and a small size is becoming urgent.In this work,an in-situ sensor for CO_(2) detection in seawater,based on a permeable membrane and non-dispersive infrared(NDIR)technology,is developed.The sensor has a small size(Ф66 mm×124 mm),light weight(0.7 kg in air),low power consumption(<0.9 W),low cost(<US$1000),and high-pressure tolerance(<200 m).After laboratory performance tests,the sensor was found to have a measurement range of(0–2000)×10^(-6),and the gas linear correlation R^(2) is 0.99,with a precision of about 0.98%at a sampling rate of 1 s.A comparison measurement was carried out with a commercial sensor in a pool for 7 days,and the results showed a consistent trend.Further,the newly developed sensor was deployed in Qingdao nearshore water for 35 days.The results proved that the sensor could measure the dynamic changes of CO_(2) concentration in seawater continuously,and had the potential to carry out long-term observations on an oceanic platform.It is hoped that the sensor could be applied to field ocean observations in near future.
文摘This research utilizes geospatial methodologies to investigate the influence of gas flaring and carbon dioxide emissions on precipitation patterns within the Niger Delta region of Nigeria.The study relies on average mean precipitation data sourced from CHRS at the University of Arizona and carbon dioxide emissions data from NASA’s AIRS in Giovanni,spanning from July 2002 to November 2011.To carry out the analysis,ArcGIS 5.0 and SPSS 25,employing Inverse Distance Weighting(IDW),were employed to assess CO_(2) emissions and rainfall for both November and July during the period from 2002 to 2011.Over the course of this study,it was observed that CO_(2) emission exhibited an upward trend,increasing from 327.5226 parts per million(ppm)in July 2002 to 390.0077 ppm in November 2011.Simultaneously,the rainfall demonstrated an increase,rising from 56.66 millimeters to 390.78 millimeters for both July and November from 2002 to 2011.Noteworthy findings emerged from the correlation analysis conducted.Specifically,from July 2000 to 2011,there was a weak positive correlation(0.3858)observed between CO_(2) emissions and minimum rainfall,while a strong negative correlation(–0.7998)was identified for maximum rainfall values.In November,both minimum and maximum CO_(2) emissions displayed strong negative correlations with rainfall,with coefficients of–0.8255 and–0.7415,respectively.These findings hold significant implications for comprehending the environmental dynamics within the Niger Delta.Policymakers and stakeholders can leverage this knowledge to formulate targeted strategies aimed at mitigating CO_(2) emissions and addressing potential climate change-induced alterations in rainfall patterns.
基金supported by the National Key Research and Development Project(No.2019YFC0312602).
文摘In this work,hollow Fe_(2)O_(3)/Co_(3)O_(4)microcubes have been successfully synthesized through a hydrothermal method followed by an annealing process using metal-organic framework of Prussian blue as a soft template.The morphologies,microstructures,surface area and element compositions have been carefully characterized by a series of techniques.Meanwhile,compared with that of pure Fe_(2)O_(3)and Co_(3)O_(4),the gas sensor based on the hollow microcubes exhibits enhanced sensing performances towards acetone,e.g.,a higher response of 21.2 and a shorter response time of 5 s towards 20 ppm acetone at a relatively low working temperature of 200℃.Moreover,the hollow microcubes-based gas sensor still shows perfect long-term stability,excellent repeatability and the ability of sub-ppm level detection,which provides a possibility for its application in real life.The enhanced gas sensing performances can be attributed to the hollow structure with a high surface area and the formed p-n heterojunctions within the microcubes.
