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水-正已烷-乙醇体系的液液平衡研究 被引量:6
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作者 徐桦 居红芳 +1 位作者 王雯 黄娟 《化学研究与应用》 CAS CSCD 北大核心 2006年第4期409-412,共4页
Four isothermal sections at 298.15K,308.15K,318.15K and 328.15K in system water-n-hexane-ethanol were measured by gas chromatograph method.The innerscaling method was used to determine the concentrations of n-hexane a... Four isothermal sections at 298.15K,308.15K,318.15K and 328.15K in system water-n-hexane-ethanol were measured by gas chromatograph method.The innerscaling method was used to determine the concentrations of n-hexane and ethanol in this ternary system.Ethy1 acetate was chosen as the sample of inner-scaling because of its separability and fit retainning time.Acetylacetone was chosen as diluent of the oil phase andn-butyl alcohol was chosen as diluent of the water phase.The experimental data of four isothermal sections at 298.15K,308.15K,318.15K adn 328.15K in system water-n-hexane-ethanol at normal pressure were given.Four schematic figures were also given.The character of these phase diagrams was analysed.They were compared with the phase diagram of system water-n-hexane-methanol.The possible causes of experimental error were discussed.The root mean square error of measurement is 1.47%. 展开更多
关键词 -正已烷-乙醇体系 三元系等温截面相图 液液平衡 气相色谱 内标法
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