The development of aqueous Zn batteries is limited by parasitic water reactions,corrosion,and dendrite growth.To address these challenges,an inner Helmholtz plane(IHP)regulation method is proposed by employing low-cos...The development of aqueous Zn batteries is limited by parasitic water reactions,corrosion,and dendrite growth.To address these challenges,an inner Helmholtz plane(IHP)regulation method is proposed by employing low-cost,non-toxic maltitol as the electrolyte additive.The preferential adsorption behavior of maltitol can expel the water from the inner Helmholtz plane,and thus hinder the immediate contact between Zn metal and H_(2)O.Meanwhile,strong interaction between maltitol and H_(2)O molecules can restrain the activity of H_(2)O.Besides,the"IHP adsorption effect"along with the low LUMO energy level of maltitol-CF_(3)SO_(3)^(-)can promote the in-situ formation of an organic-inorganic complex solid electrolyte interface(SEI)layer.As a result,the hydrogen/oxygen evolution side reaction,corrosion,and dendrites issues are effectively suppressed,thereby leading to highly reversible and dendrite-free Zn plating/stripping.The Zn‖I_(2)battery with hybrid electrolytes also demonstrates high electrochemical performance and ultralong cycling stability,showing a capacity retention of 75%over 20000 charge-discharge cycles at a large current density of 5 A g^(-1).In addition,the capacity of the device has almost no obvious decay over20000 cycles even at-30℃.This work offers a successful electrolyte regulation strategy via the IHP adsorption effect to design electrolytes for high-performance rechargeable Zn-ion batteries.展开更多
为揭示半干旱草原露天矿区生态环境质量状况,分离矿区人类活动生态累积效应并识别其演变态势,在厘清矿区生态累积效应概念的基础上,构建适用于半干旱草原的露天矿区生态环境质量评估指数(Surface Mining Areas Eco-environmental Evalua...为揭示半干旱草原露天矿区生态环境质量状况,分离矿区人类活动生态累积效应并识别其演变态势,在厘清矿区生态累积效应概念的基础上,构建适用于半干旱草原的露天矿区生态环境质量评估指数(Surface Mining Areas Eco-environmental Evaluation Index,SMAEEI)以及矿区生态累积效应定量评估模型。选取内蒙古胜利矿区为研究区,量化分析1986—2020年区域生态环境质量和生态累积效应的时空分布规律,以及主要人类活动的生态累积效应差异。结果表明:①SMAEEI适用于半干旱草原露天矿区,能客观呈现各地类生态环境质量高低顺序。35 a间研究区生态环境质量呈极显著下降趋势,且其空间差异显著减弱。露天矿场、城镇扩张区、锡林河湿地及北侧草地生态环境质量出现极显著、显著的退化趋势。②半干旱草原露天矿区生态累积效应定量评估模型能剔除气候因素对生态系统的耦合影响,分离并量化人类活动对矿区生态系统的累积效应,揭示累积的方向、程度和空间范围。35 a间研究区生态服务价值累积量(Change of Ecosystem Service Value Cumulant,COESVC)共减少1186157.03万元,出现负向生态累积效应,生态系统服务功能下降。高度、中度负向累积区集中在湿地和草地退化区、城镇区、露天矿场。③露天开采、城镇建设造成的单位面积负向生态累积效应最明显,前者在单位时间内带来的负向累积变化最剧烈,后者负向累积效应的局部影响程度和偏离度最大;放牧活动引起的负向生态累积效应影响范围最广、总量最大,但局部影响程度最小,生态系统服务功能较其余人类活动更稳定。研究成果可将矿区人类活动引起的生态环境实物量变动转化为价值量描述,为采用货币形式测算矿区生产生活行为的环境损害成本提供可行方法。展开更多
基金supported by the National Natural Science Foundation of China(52261160384)the Shenzhen Science and Technology Innovation Commission(RCYX20221008092934093)+1 种基金the Shenzhen Science and Technology Program(KJZD20230923114107014)the support from Testing Technology Center of Materials and Devices,Tsinghua Shenzhen International Graduate School。
文摘The development of aqueous Zn batteries is limited by parasitic water reactions,corrosion,and dendrite growth.To address these challenges,an inner Helmholtz plane(IHP)regulation method is proposed by employing low-cost,non-toxic maltitol as the electrolyte additive.The preferential adsorption behavior of maltitol can expel the water from the inner Helmholtz plane,and thus hinder the immediate contact between Zn metal and H_(2)O.Meanwhile,strong interaction between maltitol and H_(2)O molecules can restrain the activity of H_(2)O.Besides,the"IHP adsorption effect"along with the low LUMO energy level of maltitol-CF_(3)SO_(3)^(-)can promote the in-situ formation of an organic-inorganic complex solid electrolyte interface(SEI)layer.As a result,the hydrogen/oxygen evolution side reaction,corrosion,and dendrites issues are effectively suppressed,thereby leading to highly reversible and dendrite-free Zn plating/stripping.The Zn‖I_(2)battery with hybrid electrolytes also demonstrates high electrochemical performance and ultralong cycling stability,showing a capacity retention of 75%over 20000 charge-discharge cycles at a large current density of 5 A g^(-1).In addition,the capacity of the device has almost no obvious decay over20000 cycles even at-30℃.This work offers a successful electrolyte regulation strategy via the IHP adsorption effect to design electrolytes for high-performance rechargeable Zn-ion batteries.
文摘为揭示半干旱草原露天矿区生态环境质量状况,分离矿区人类活动生态累积效应并识别其演变态势,在厘清矿区生态累积效应概念的基础上,构建适用于半干旱草原的露天矿区生态环境质量评估指数(Surface Mining Areas Eco-environmental Evaluation Index,SMAEEI)以及矿区生态累积效应定量评估模型。选取内蒙古胜利矿区为研究区,量化分析1986—2020年区域生态环境质量和生态累积效应的时空分布规律,以及主要人类活动的生态累积效应差异。结果表明:①SMAEEI适用于半干旱草原露天矿区,能客观呈现各地类生态环境质量高低顺序。35 a间研究区生态环境质量呈极显著下降趋势,且其空间差异显著减弱。露天矿场、城镇扩张区、锡林河湿地及北侧草地生态环境质量出现极显著、显著的退化趋势。②半干旱草原露天矿区生态累积效应定量评估模型能剔除气候因素对生态系统的耦合影响,分离并量化人类活动对矿区生态系统的累积效应,揭示累积的方向、程度和空间范围。35 a间研究区生态服务价值累积量(Change of Ecosystem Service Value Cumulant,COESVC)共减少1186157.03万元,出现负向生态累积效应,生态系统服务功能下降。高度、中度负向累积区集中在湿地和草地退化区、城镇区、露天矿场。③露天开采、城镇建设造成的单位面积负向生态累积效应最明显,前者在单位时间内带来的负向累积变化最剧烈,后者负向累积效应的局部影响程度和偏离度最大;放牧活动引起的负向生态累积效应影响范围最广、总量最大,但局部影响程度最小,生态系统服务功能较其余人类活动更稳定。研究成果可将矿区人类活动引起的生态环境实物量变动转化为价值量描述,为采用货币形式测算矿区生产生活行为的环境损害成本提供可行方法。
