In order to evaluate the applicability of the organic polymeric flocculants(OPF) in the treatment of oil refinery sludge, experiments were conducted to show that OPF have better performance of flocculation than inorga...In order to evaluate the applicability of the organic polymeric flocculants(OPF) in the treatment of oil refinery sludge, experiments were conducted to show that OPF have better performance of flocculation than inorganic flocculants. Both the anionic and cationic OPF have satisfactory flocculation efficiency in oil sludge treatment, but the latter are more cost efficient. Among the over 20 types of flocculants tested, 2 OPF(CPAM 2 and HPAM 2) were selected as the treatment agents, based on their good treatment performances, oil resistance and economic feasibility. It was demonstrated in the industrial scale centrifugal dewatering experiments that the application of either CPAM 2 or HPAM 2 could achieve high treatment efficiency of the oil sludge dewatering and reduce the COD of centrifugal liquid to less than 1000 mg/L.展开更多
Compared with traditional aluminum salts, polyaluminum chloride (PACI) has better coagulation-flocculation performance in turbidity removal. However, it is still inferior to organic polymers in terms of bridging fun...Compared with traditional aluminum salts, polyaluminum chloride (PACI) has better coagulation-flocculation performance in turbidity removal. However, it is still inferior to organic polymers in terms of bridging function. In order to improve the aggregating property of PACl, different composite PACl flocculants were prepared with various organic polymers. The effect of organic polymer on the distribution or Al(Ⅲ) species in composite flocculants was studied using ^27TAl NMR and Al-ferron complexation methods. The charge neutralization and surface adsorption characteristics of composite flocculants were also investigated. Jar tests were conducted to evaluate the turbidity removal efficacy of organic polymer modified composite flocculants. The study shows that cationic polymer and anionic polymer have significant influences on the coagulation-flocculation behaviors of PACl. Both cationic and anionic polymers can improve the turbidity removal performancc of PACl but the mechanisms arc much different: cationic organic polymer mainly increases the charge neutralization ability, but anionic polymer mainly enhances the bridging function.展开更多
Characterization of water, waste water and natural organic matter are involved in this paper, and as well as the features of flocculation and coagulation for removing natural organic matter from water and waste water ...Characterization of water, waste water and natural organic matter are involved in this paper, and as well as the features of flocculation and coagulation for removing natural organic matter from water and waste water Novel flocculant and coagualant is strongly asked for improving removal efficiency and environment friendly. Enhanced coagulation is introduced to meet the experimental and practical requirement.展开更多
文摘In order to evaluate the applicability of the organic polymeric flocculants(OPF) in the treatment of oil refinery sludge, experiments were conducted to show that OPF have better performance of flocculation than inorganic flocculants. Both the anionic and cationic OPF have satisfactory flocculation efficiency in oil sludge treatment, but the latter are more cost efficient. Among the over 20 types of flocculants tested, 2 OPF(CPAM 2 and HPAM 2) were selected as the treatment agents, based on their good treatment performances, oil resistance and economic feasibility. It was demonstrated in the industrial scale centrifugal dewatering experiments that the application of either CPAM 2 or HPAM 2 could achieve high treatment efficiency of the oil sludge dewatering and reduce the COD of centrifugal liquid to less than 1000 mg/L.
文摘Compared with traditional aluminum salts, polyaluminum chloride (PACI) has better coagulation-flocculation performance in turbidity removal. However, it is still inferior to organic polymers in terms of bridging function. In order to improve the aggregating property of PACl, different composite PACl flocculants were prepared with various organic polymers. The effect of organic polymer on the distribution or Al(Ⅲ) species in composite flocculants was studied using ^27TAl NMR and Al-ferron complexation methods. The charge neutralization and surface adsorption characteristics of composite flocculants were also investigated. Jar tests were conducted to evaluate the turbidity removal efficacy of organic polymer modified composite flocculants. The study shows that cationic polymer and anionic polymer have significant influences on the coagulation-flocculation behaviors of PACl. Both cationic and anionic polymers can improve the turbidity removal performancc of PACl but the mechanisms arc much different: cationic organic polymer mainly increases the charge neutralization ability, but anionic polymer mainly enhances the bridging function.
文摘Characterization of water, waste water and natural organic matter are involved in this paper, and as well as the features of flocculation and coagulation for removing natural organic matter from water and waste water Novel flocculant and coagualant is strongly asked for improving removal efficiency and environment friendly. Enhanced coagulation is introduced to meet the experimental and practical requirement.