For studying geochemical behavior of selenium, a marine investigation was conducted in September 1998 cruise in the Bohai Sea. Horizontal and vertical distributions of inorganic selenium and selenite were studied. The...For studying geochemical behavior of selenium, a marine investigation was conducted in September 1998 cruise in the Bohai Sea. Horizontal and vertical distributions of inorganic selenium and selenite were studied. The inorganic selenium varied from 0.73 to 2.41 nmol/L, with an average of 1.31 nmol/L; while selenite varied from 0.18 to 0.72 nmol/L with an average of 0.47 nmol/L. The average ratio of selenite to selenate was 0.68, and selenate was the predominant species of inorganic selenium in the most study area. Concentrations of inorganic selenium and selenite decreased with distance from the coast. No apparent variations of the concentration between surface and bottom was shown. There were two wa- ter masses in the area, one from the Huanghe (Yellow) River and other from the Yellow Sea. Of the two, Huanghe River was the major source of inorganic selenium.展开更多
A simple and convenient method has been developed for the pre-concentration and separation of inorganic selenium species from environmental water samples using anion exchange chromatographic column combined with high ...A simple and convenient method has been developed for the pre-concentration and separation of inorganic selenium species from environmental water samples using anion exchange chromatographic column combined with high resolution inductively coupled plasma mass spectrometry(HR-ICP-MS)measurement.^(75)Se(Ⅳ) and ^(75)Se(Ⅵ)were prepared and used as tracers during the experiments.The volatility of selenium during solution evaporation was investigated to establish a reliable water samples pretreatment procedure.The parameters which affect the uptake of Se(Ⅳ)and Se(Ⅵ)on Dowex1×8 resin was optimized and the procedure for Se(Ⅳ)and Se(Ⅵ)separation was proposed.Both Se(Ⅳ)and Se(Ⅵ)are retained on the column in natural or alkaline solution with high distribution coefficient.The successive gradient elution of pre-concentrated species of selenium with HNO_(3)solution allows to differentiate between them.Se(Ⅳ)and Se(Ⅵ)finally were eluted with 0.05 mol/L HNO_(3) and 5.0 mol/L HNO_(3),respectively.The proposed method has been successfully verified using the certified reference materials(CRMs)of real water samples,and spiked recoveries for real samples were 98%-104%with 5%relative standard deviations(RSDs).The developed procedure is proved to be reliable and can be used for the rapid determination of selenium species in environmental water samples.展开更多
基金This study was supported by Sino-Germany Joint Project "The Bohai Sea Ecosystem Analysis and Modeling" and NSFC (Nos. 40476037, 40476036, 90211009 and 40406017).
文摘For studying geochemical behavior of selenium, a marine investigation was conducted in September 1998 cruise in the Bohai Sea. Horizontal and vertical distributions of inorganic selenium and selenite were studied. The inorganic selenium varied from 0.73 to 2.41 nmol/L, with an average of 1.31 nmol/L; while selenite varied from 0.18 to 0.72 nmol/L with an average of 0.47 nmol/L. The average ratio of selenite to selenate was 0.68, and selenate was the predominant species of inorganic selenium in the most study area. Concentrations of inorganic selenium and selenite decreased with distance from the coast. No apparent variations of the concentration between surface and bottom was shown. There were two wa- ter masses in the area, one from the Huanghe (Yellow) River and other from the Yellow Sea. Of the two, Huanghe River was the major source of inorganic selenium.
基金The financial support from National Natural Science Foundation of China(Nos.22061132004,U21A20442,22106059,22106057,21771093)Fundamental Research Funds for the Central Universities of China(No.lzujbky-2021-kb11,lzujbky-2021-sp41)Gansu guiding program of Science and Technology Innovation(No.20JR10RA610)are gratefully appreciated。
文摘A simple and convenient method has been developed for the pre-concentration and separation of inorganic selenium species from environmental water samples using anion exchange chromatographic column combined with high resolution inductively coupled plasma mass spectrometry(HR-ICP-MS)measurement.^(75)Se(Ⅳ) and ^(75)Se(Ⅵ)were prepared and used as tracers during the experiments.The volatility of selenium during solution evaporation was investigated to establish a reliable water samples pretreatment procedure.The parameters which affect the uptake of Se(Ⅳ)and Se(Ⅵ)on Dowex1×8 resin was optimized and the procedure for Se(Ⅳ)and Se(Ⅵ)separation was proposed.Both Se(Ⅳ)and Se(Ⅵ)are retained on the column in natural or alkaline solution with high distribution coefficient.The successive gradient elution of pre-concentrated species of selenium with HNO_(3)solution allows to differentiate between them.Se(Ⅳ)and Se(Ⅵ)finally were eluted with 0.05 mol/L HNO_(3) and 5.0 mol/L HNO_(3),respectively.The proposed method has been successfully verified using the certified reference materials(CRMs)of real water samples,and spiked recoveries for real samples were 98%-104%with 5%relative standard deviations(RSDs).The developed procedure is proved to be reliable and can be used for the rapid determination of selenium species in environmental water samples.
