In-situ observation in high voltage electron microscope(HVEM) was used to investigate transformation from amorphous La(OH)3 to nanophase La2O3. Electron diffraction pattern indicates that the transition temperature fr...In-situ observation in high voltage electron microscope(HVEM) was used to investigate transformation from amorphous La(OH)3 to nanophase La2O3. Electron diffraction pattern indicates that the transition temperature from La(OH)3 to nanophase La2O3 is 400 ℃. Particle sizes for nanophase La2O3 are from 20 to 50 nm.展开更多
The moving process ofδ / δgrain boundary during the solidification process of Fe-0.2%C-0.8%Cr has been observed in-situ with confocal scanning laser microscope （ CSLM ）, and the establishment of δ/δ grain bounda...The moving process ofδ / δgrain boundary during the solidification process of Fe-0.2%C-0.8%Cr has been observed in-situ with confocal scanning laser microscope （ CSLM ）, and the establishment of δ/δ grain boundary , the moving mode , the moving speed and the influence of correlative factor were explored in detail.The results showed that the clear grain cannot be formed when δ phase merged during solidification process of the steel if the actual cooling rate was 0.045℃·s-1 .The δ/δgrain boundary with shape of flat will be formed if there is no essential conjunction betweenδphase in a long period of time.The movement ofδgrain boundary cross point drives other δ /δ grain boundaries to move.The moving process is not stable , and the moving rate variation ranges from 0.12to 1.65 μ m ·s-1 .Temperature of the system is the chief factor for influencing the moving rate of δ / δgrain boundary during the solidification.When the temperature fluctuation of system appears , the solidified grain boundary is re-melted , which results in the catastrophic fluctuation of moving rate for δ / δ grain boundary.When the solidification process reaches its end , the average moving rate of δ /δ grain boundary is quicker than that of L / δ interface.The coarsening rate of crystal grain in the melt is slower than that of solidified solid phase crystal grain.展开更多
文摘In-situ observation in high voltage electron microscope(HVEM) was used to investigate transformation from amorphous La(OH)3 to nanophase La2O3. Electron diffraction pattern indicates that the transition temperature from La(OH)3 to nanophase La2O3 is 400 ℃. Particle sizes for nanophase La2O3 are from 20 to 50 nm.
基金Item Sponsored by National Natural Science Foundation of China ( 50874060 )
文摘The moving process ofδ / δgrain boundary during the solidification process of Fe-0.2%C-0.8%Cr has been observed in-situ with confocal scanning laser microscope （ CSLM ）, and the establishment of δ/δ grain boundary , the moving mode , the moving speed and the influence of correlative factor were explored in detail.The results showed that the clear grain cannot be formed when δ phase merged during solidification process of the steel if the actual cooling rate was 0.045℃·s-1 .The δ/δgrain boundary with shape of flat will be formed if there is no essential conjunction betweenδphase in a long period of time.The movement ofδgrain boundary cross point drives other δ /δ grain boundaries to move.The moving process is not stable , and the moving rate variation ranges from 0.12to 1.65 μ m ·s-1 .Temperature of the system is the chief factor for influencing the moving rate of δ / δgrain boundary during the solidification.When the temperature fluctuation of system appears , the solidified grain boundary is re-melted , which results in the catastrophic fluctuation of moving rate for δ / δ grain boundary.When the solidification process reaches its end , the average moving rate of δ /δ grain boundary is quicker than that of L / δ interface.The coarsening rate of crystal grain in the melt is slower than that of solidified solid phase crystal grain.
