Leaching of boron （B） and zinc （Zn） can be significant in some pedomorphic conditions, which can cause contamination of shallow groundwater and economic losses. Boron and Zn adsorption and transport was studied us...Leaching of boron （B） and zinc （Zn） can be significant in some pedomorphic conditions, which can cause contamination of shallow groundwater and economic losses. Boron and Zn adsorption and transport was studied using 8.4 cm diameter × 28 cm long intact columns from two calcareous soil series with differing clay contents and vadose zone structures： Lyallpur soil series, clay loam （fine-silty, mixed, hyperthermic Ustalfic Haplargid）, and Sultanpur soil series, sandy loam （coarse-silty, mixed, hyperthermic Ustollic Camborthid）. The adsorption isotherms were developed by equilibrating soil with 0.01 tool L^-1 CaCl2 aqueous solution containing varying amounts of B and Zn and were fitted to the Langmuir equation. The B and Zn breakthrough curves were fitted to the two-domain convective-dispersive equation. At the end of the leaching experiment, 0.11 L 10 g L^-1 blue dye solution was also applied to each column to mark the flow paths. The Lyallpur soil columns had a slightly greater adsorption partition coefficient both for B and Zn than the Sultanpur soil columns. In the Lyallpur soil columns, B arrival was immediate but the peak concentration ratio （the concentration in solution at equilibrium/concentration applied） was lower than that in the Sultanpur soil columns. The breakthrough of B in the Sultanpur soil columns occurred after about 10 cm of cumulative drainage in both the columns; the rise in effluent concentration was fast and the peak concentration ratio was almost 1. Zinc leaching through the soil columns was very limited as only one column from the Lyallpur soil series showed Zn breakthrough in the effluent where the peak concentration ratio was only 0.05. This study demonstrates the effect of soil structure on B transport and has implications for the nutrient management in field soils.展开更多
以京沪高铁深厚地层细粒土固结试验数据为基础,以e-lgp曲线包含分式函数的复合函数表达和土体液限与压缩指数的线性关系为依据,提出了基于土体基本物性指标标准压缩模量E1？2和液限wL推求正常固结原状地基土全压力段压缩模量的简化方法...以京沪高铁深厚地层细粒土固结试验数据为基础,以e-lgp曲线包含分式函数的复合函数表达和土体液限与压缩指数的线性关系为依据,提出了基于土体基本物性指标标准压缩模量E1？2和液限wL推求正常固结原状地基土全压力段压缩模量的简化方法,其适用性得到了京津城际铁路试验数据的验证。结果表明,Harris函数能较好地描述土体压缩的e-lgp曲线特征,E1？2和wL能分别反映曲线低压力段割线斜率和高压力点切线斜率,建立的地基土压缩模量估算方法具有良好精度,其中,100-1 000 k Pa常压力段的误差均值仅为7.89%,高压力段约为13.70%,只在低压力段变异性较大;研究成果提供了缺少e-lgp曲线情况下简便快速获取土体压缩模量的新途径。展开更多
文摘Leaching of boron （B） and zinc （Zn） can be significant in some pedomorphic conditions, which can cause contamination of shallow groundwater and economic losses. Boron and Zn adsorption and transport was studied using 8.4 cm diameter × 28 cm long intact columns from two calcareous soil series with differing clay contents and vadose zone structures： Lyallpur soil series, clay loam （fine-silty, mixed, hyperthermic Ustalfic Haplargid）, and Sultanpur soil series, sandy loam （coarse-silty, mixed, hyperthermic Ustollic Camborthid）. The adsorption isotherms were developed by equilibrating soil with 0.01 tool L^-1 CaCl2 aqueous solution containing varying amounts of B and Zn and were fitted to the Langmuir equation. The B and Zn breakthrough curves were fitted to the two-domain convective-dispersive equation. At the end of the leaching experiment, 0.11 L 10 g L^-1 blue dye solution was also applied to each column to mark the flow paths. The Lyallpur soil columns had a slightly greater adsorption partition coefficient both for B and Zn than the Sultanpur soil columns. In the Lyallpur soil columns, B arrival was immediate but the peak concentration ratio （the concentration in solution at equilibrium/concentration applied） was lower than that in the Sultanpur soil columns. The breakthrough of B in the Sultanpur soil columns occurred after about 10 cm of cumulative drainage in both the columns; the rise in effluent concentration was fast and the peak concentration ratio was almost 1. Zinc leaching through the soil columns was very limited as only one column from the Lyallpur soil series showed Zn breakthrough in the effluent where the peak concentration ratio was only 0.05. This study demonstrates the effect of soil structure on B transport and has implications for the nutrient management in field soils.
文摘以京沪高铁深厚地层细粒土固结试验数据为基础,以e-lgp曲线包含分式函数的复合函数表达和土体液限与压缩指数的线性关系为依据,提出了基于土体基本物性指标标准压缩模量E1？2和液限wL推求正常固结原状地基土全压力段压缩模量的简化方法,其适用性得到了京津城际铁路试验数据的验证。结果表明,Harris函数能较好地描述土体压缩的e-lgp曲线特征,E1？2和wL能分别反映曲线低压力段割线斜率和高压力点切线斜率,建立的地基土压缩模量估算方法具有良好精度,其中,100-1 000 k Pa常压力段的误差均值仅为7.89%,高压力段约为13.70%,只在低压力段变异性较大;研究成果提供了缺少e-lgp曲线情况下简便快速获取土体压缩模量的新途径。
