Two Zn-based sorbents, L-991 and L-992 used for hot gas desulfurization (HGD) were introduced. Zn/Ti ratio of the two sorbent was 1:1 and 2:3 resptively and a certain proportion of Cu and Mn metal oxide were added int...Two Zn-based sorbents, L-991 and L-992 used for hot gas desulfurization (HGD) were introduced. Zn/Ti ratio of the two sorbent was 1:1 and 2:3 resptively and a certain proportion of Cu and Mn metal oxide were added into L-992, which provided better performance than L-991 in aspects of suitable work temperature, sulfur capacity and agglomeration on the surface of sorbent particles. The evaluation tests were done on both sorbents include multi cycles tests. ARD and SEM analysis were done on fresh and post tests sorbent. During continuous sulfidation/regeneration, the H2S concentra- tion can be reduced from about 10 g/m3 to less than 20 mg/m3, the H2S removal effi- ciency >99 %.展开更多
基金Supported by China National "95" Project (96-A26-03-02-01) China National "863" Project (2002AA529080) and China-UK, BRICC, CCRI
文摘Two Zn-based sorbents, L-991 and L-992 used for hot gas desulfurization (HGD) were introduced. Zn/Ti ratio of the two sorbent was 1:1 and 2:3 resptively and a certain proportion of Cu and Mn metal oxide were added into L-992, which provided better performance than L-991 in aspects of suitable work temperature, sulfur capacity and agglomeration on the surface of sorbent particles. The evaluation tests were done on both sorbents include multi cycles tests. ARD and SEM analysis were done on fresh and post tests sorbent. During continuous sulfidation/regeneration, the H2S concentra- tion can be reduced from about 10 g/m3 to less than 20 mg/m3, the H2S removal effi- ciency >99 %.